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空气电弧等离子体作用下发射药的燃烧特性 总被引:2,自引:1,他引:1
为了研究发射药等离子体点火作用机理,用扫描电子显微镜研究了不同强度电弧放电等离子体揭示的3种制式发射药及新型ETPE发射药在等离子体作用后的燃烧表面变化规律,得到等离子体点火后发生燃烧反应的质量.结果表明,电弧等离子体输入电能对发射药的点火有着重要影响,随着输入电能的增加,参加反应的发射药质量逐渐增加.ETPE发射药燃烧表面与常规制式发射药燃烧表面有较大差别.发射药对电弧等离子体的相对敏感程度不同,双基发射药最强,ETPE发射药最弱. 相似文献
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将聚苯乙烯(PS)树脂与改性后的氢氧化镁(MH)进行熔融共混制备PS/MH复合材料。通过X射线衍射分析了复合材料的微观结构,采用水平燃烧实验、氧指数实验和高温处理实验研究了复合材料的燃烧性能。结果表明:在制备和加工过程中,复合材料中的MH的微观结构并没有发生变化。因此,复合材料中MH的阻燃机理不变。随着MH含量增加,复合材料的发烟和滴落减少,水平燃烧速率从34.08mm/min下降至22.84mm/min.MH用量达到80phr时复合材料能够自熄,材料的氧指数达24.O%。MH的引入使复合材料在高温下的残留率增大,热稳定性和阻燃性能增强. 相似文献
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为了研究等离子体对发射药的点火燃烧作用机理,在Keidar教授处理烧蚀问题的双层动力学模型基础上,建立了用于描述等离子体对发射药烧蚀作用的物理模型和数学模型。研究了等离子体对SF-3发射药、GR5发射药及新型ETPE发射药的烧蚀作用,利用所获得的电弧等离子体特性参数与发射药的特性参数对烧蚀质量进行了数值模拟。结果表明,在较低的电弧等离子体能量作用下,理论计算结果与实验结果具有较好的一致性,所建立的模型能够反映等离子体对发射药的烧蚀作用过程。随着等离子体能量的升高,理论计算结果与实验结果之间的偏差逐渐加大,反应作用因素影响增强。3种类型发射药中,ETPE发射药对电弧等离子体的敏感程度最弱,SF-3发射药对电弧等离子体的敏感程度最强。 相似文献
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原位聚合法PS/蒙脱土复合材料燃烧性能的研究 总被引:4,自引:0,他引:4
采用原位聚合法分别制备了聚苯乙烯/有机蒙脱土(PS/OMMT)复合材料和聚苯乙烯/无机蒙脱土(PS/MMT)复合材料、用锥形量热仪测量测试了复合材料的燃烧性能,结果发现复合材料的热释放速率、质量损失速率、生烟速率等均显著降低,说明复合材料具有阻燃性。通过分析材料的燃烧性能和燃烧残余物,探讨了其可能的阻燃机理。还考察了原位聚合法对聚合转化率的影响。研究表明原位聚合法制备的PS/蒙脱土复合材料是一种阻燃效能高、环境友好且实际可行的阻燃体系。 相似文献
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对3种不同的聚醚醚酮( PEEK)复合材料进行高温蠕变实验研究,根据蠕变曲线和蠕变速率曲线获得了不同PEEK复合材料的抗蠕变能力,探讨了不同PEEK复合材料的蠕变机理. 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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A perturbation viscometer is a differential capillary viscometer that measures the logarithmic viscosity gradient of the viscosity-composition curve for gas mixtures. Measurements are made at different gas mixture compositions. Integration of the logarithmic viscosity gradients measured over the full composition range gives the mixture viscosity relative to the viscosity of one of the pure components of the gas mixture. This method is attractive because, for measurements of equal precision, integration of the gradients is potentially an order of magnitude more precise than measurement of the viscosities directly. It can also work at high and low temperatures and perhaps high pressures.The perturbation viscometer has been used to make measurements on ideal gas mixtures at ambient and elevated temperatures. The situation is more complicated when the gas mixtures are non-ideal. Extra effects due to density differences, molar volume change on mixing and differential thermal expansion may be measured in addition to the desired viscosity change producing systematic errors in the results. Thus, a more sophisticated apparatus is required. The standard perturbation viscometer has been modified to separate out the extra effects to permit measurement of the true change in viscosity. In addition, the theoretical operation of the modified apparatus has been revised to account for the design changes to permit calculation of the viscosity-composition profiles from the results.The apparatus has been tested using helium-HFC-125 mixtures and two new viscosity-composition profiles are presented for these mixtures at 23 and . Internal consistency tests have been used to confirm that the data produced are of high quality with an estimated uncertainty in the viscosity ratio data at of 0.9% and at of 1.5%. 相似文献
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塔设备改造选型的分析 总被引:2,自引:0,他引:2
就当前扩产增容中塔设备设计和改造时板式塔和填料塔的选型问题加以分析。在评述目前国内常用的几种塔板和新型填料之后,着重介绍一种新型塔板(导向梯形浮阀塔板)和一种新型填料(波环填料——乾隆帕克)。 相似文献