Strength prediction of tubular composite adhesive joints under torsion

This paper addresses prediction of the strength of tubular adhesive joints with composite adherends by combining thermal and mechanical analyses. A finite element analysis was used to calculate the residual thermal stresses generated by cooling down from the adhesive cure temperature, and a nonlinear analysis incorporating the nonlinear adhesive behavior was performed to accurately estimate the mechanical stresses in the adhesive. Joint failure was estimated by three failure criteria: interfacial failure, adhesive bulk failure, and adherend failure. The distributions of residual thermal stresses were investigated for various stacking angles. The effect of residual thermal stresses on joint strength was also taken into consideration. The results indicate that the residual thermal stresses, depending on the stacking angle, have a significant influence on the failure mode and strength of adhesive joints when a subsequent mechanical load is applied. Good agreement is also obtained between the predicted joint strength and the available experimental data.     

The adhesive behaviour of poly(p-phenylene benzobisthiazole) (PBT)/epoxy composites

A modified scarf joint specimen was developed for characterizing the adhesive behaviour of poly (p-phenylene benzobisthiazole) (PBT) film/epoxy composites. This method subjected samples to varying amounts of normal stress (tensile or compressive) and shear stress. This resulted in the determination of two adhesive strengths; one in the absence of shear stress and one in the absence of normal stress. As a result, the dependence of the adhesive strength on the degree of normal stress was determined. The adhesive behaviour of PBT/epoxy composites was investigated at cure temperatures of 55, 85, 115 and 215°C. Adhesive strengths of 3.5 and 8.2 MPa were measured in the absence of shear and normal stress, respectively, for samples cured at 55° C. A decrease in adhesive strength with increasing cure temperature was attributed to residual cure and thermal stresses. The fracture of these composites was predominantly adhesive, resulting in a clean delamination of the PBT film from the epoxy surface. A modified Tsai-Wu failure criterion is suggested for these composites.     

Improvement of the fracture toughness of adhesively bonded stainless steel joints with aramid fibers at cryogenic temperatures

Adhesives should be reinforced with reinforcing fibers for the bonding of adherends at cryogenic temperatures because all the adhesives become quite brittle at cryogenic temperatures. In this work, the film-type epoxy adhesive was reinforced with randomly oriented aramid fiber mats to decrease the CTE (Coefficient of Thermal Expansion) of the adhesive and to improve the fracture toughness of adhesive joints composed of stainless steel adherends at the cryogenic temperature of −150 °C. The cleavage tests of the DCB (Double Cantilever Beam) adhesive joints were performed to evaluate the fracture toughness and crack resistance of the adhesive joints. Also, the thermal and mechanical properties of the fiber reinforced adhesive layer were measured to investigate the relationship between the fracture toughness of adhesive joints and fiber volume fraction of aramid fibers. From the experiments, it was found that the crack propagated in the adhesive with the stable mode of significantly increased fracture toughness when the film-type epoxy adhesive was reinforced with aramid fiber mats. The optimum volume fraction of aramid fibers was suggested for the film-type epoxy adhesive in the adhesive joint at the cryogenic temperature of −150 °C.     

服役低温老化对铝合金-玄武岩纤维增强树脂复合材料粘接接头力学性能的影响及失效预测

为了给铝合金-玄武岩纤维增强树脂(BFRP)复合材料粘接结构在汽车工业中的应用提供参考和指导,加工了铝合金-BFRP复合材料粘接接头。结合汽车服役中的温度区间,选取?10℃和?40℃的低温老化环境,对接头进行0、10、20、30天的老化。对老化后的粘接接头进行准静态拉伸试验和剪切试验,得到不同老化时间下铝合金-BFRP粘接接头的准静态失效强度。结合DSC和FTIR分析低温老化对BFRP复合材料的影响,并对粘接接头的失效断面进行宏观分析和SEM分析。结果表明:在低温老化环境中,胶粘剂与BFRP复合材料的化学性质受低温老化作用影响不大,BFRP中的官能团与玻璃化转变温度(T_g)没有发生明显的变化,接头的失效强度和失效模式主要受胶粘剂与粘接基材的热应力影响。对于拉伸接头,随着低温老化时间的增加,BFRP复合材料纤维与树脂基体间的结合力降低,铝合金-BFRP复合材料接头的失效断面中纤维撕裂的比例逐渐减少,拉伸接头失效强度逐渐下降。老化后剪切接头仍为内聚失效,BFRP复合材料的低温老化对铝合金-BFRP复合材料剪切接头的失效强度几乎没有影响,剪切接头失效强度的下降主要是胶粘剂与粘接基材热膨胀系数不一致引起的热应力的影响。采用二次应力准则公式对?10℃和?40℃低温环境下,拉应力、剪应力值随老化时间的变化规律进行了拟合,在此失效准则的基础上,根据响应面原理,建立接头失效强度随老化时间变化的三维曲面,为粘接技术在车身结构中的工程应用提供参考。      

In situ monitoring of the strain evolution and curing reaction of composite laminates to reduce the thermal residual stress using FBG sensor and dielectrometry

Generally, a large, thermal residual stress is generated during the curing process for composite laminates due to differences in the coefficients of thermal expansion of the respective layers. The thermal residual stress during fabrication greatly decreases the fatigue life and dimensional accuracy of the composite structures. In the present study, through a fiber bragg grating (FBG) sensor and dielectrometry in an autoclave, the strain evolution and curing reaction in composite laminates with a stacking sequence of [0₅/90₅]_S were monitored simultaneously during a conventional cure cycle and a modified cure cycle to reduce the thermal residual stress. From the study, it was verified that about 50% of the thermal residual stress during fabrication could be reduced in a composite laminate by adjusting the cure cycle; this improved the static strength and fatigue life by 16% and up to 614%, respectively, for a peak ratio of 0.9.     

Effect of thermal residual stress on the crack path in adhesively bonded joints

Mode I fracture behaviour of adhesively bonded double and cantilever beam (DCB) compact tension (CT) joints was studied using a rubber-modified epoxy (Araldite® GY260) as the adhesive. Adherends were prepared from a carbon fibre (CF)/epoxy composite or aluminium alloys. The crack path in the joints was studied based on the sign of the non-singularT-stress ahead of the crack tip by calculating the thermal residual stress in the joints using finite element analysis. The results indicate that the type of adherend materials influence the level of the thermal residual stress in the adhesive layer, which consequently causes different crack paths in the joints, i.e. a uniformly smooth fracture surface in both CT and DCB aluminium joints and a wavy crack growth in the DCB CF/epoxy composite joints. However, the fracture energies of different types of adhesive joints were almost identical to each other for bond thicknesst<0.2 mm, and a somewhat higher fracture resistance was obtained for the CF/epoxy DCB joints with large bond thickness.     

Design of a hybrid glass composite anchor for LNG cargo containment systems

Large cryogenic container for liquefied natural gas (LNG) should be joined to the inner hull of a ship. The minimum heat inflow, due to the large temperature difference between the LNG cargo container and inner hull, can induce considerable heat flux through the joined area.In this work, a hybrid composite anchor composed of two stainless steel caps and a glass fiber composite body was developed and optimized for strength, thermal stress and heat loss of the anchor. The stainless steel caps were adhesively bonded to the top and bottom areas of the glass composite body. The top stainless cap was then welded to the two stainless steel membranes, and the flange of the bottom stainless steel cap was bolt-fastened to the inner hull of a ship.The static adhesive strength and impact characteristics between the stainless steel caps and glass composite body of the hybrid glass composite anchor at the cryogenic temperature were investigated with respect to adhesive thickness. Finally, the optimal design for the hybrid glass composite anchor for the cryogenic containment systems of a LNG ship was suggested.     

服役温度对铝合金-碳纤维增强树脂复合材料粘接接头准静态失效的影响

为了研究服役温度对铝合金-碳纤维增强树脂(CFRP)复合材料粘接接头准静态失效的影响，本文加工了铝合金-CFRP复合材料粘接接头。考虑车辆实际运行工况下的服役温度，选取低温(?40℃)、常温(20℃)和高温(80℃)三种环境温度，结合设计的Arcan夹具对铝合金-CFRP复合材料粘接接头分别进行1 mm/min和100 mm/min的准静态试验，得到不同温度下铝合金-CFRP复合材料对接接头(BJs)、45°嵌接接头(45°SJs)和剪切接头(TSJs)的准静态失效强度，并结合失效断面对接头失效形式进行分析，建立了失效准则方程和三维响应曲面。结果表明:不同加载速率下的铝合金-CFRP复合材料粘接接头失效强度在高温环境下均呈明显的下降趋势，在低温环境下均呈一定程度的上升趋势。高温下的失效模式为胶层的内聚失效，低温下的失效模式中纤维撕裂的比例上升。相对于1 mm/min加载速率下的准静态失效强度，各温度和应力状态下的铝合金-CFRP复合材料粘接接头在100 mm/min加载速率下的准静态失效强度明显提高。      

Modification of polymer properties to minimize thermal stresses in adhesive joints

The adhesive behaviour of epoxy-glass microballoon composites was studied at 25 and 75° C for plate and tubular lap joints of various combinations. It was found that the adhesive bond for various joints is enhanced through addition of microballoons. High adhesive force is observed at higher temperatures for various joints combinations where the thermal stresses are lowered and the bond is strengthened. The obtained results for various joint combinations demonstrate that high strength can be achieved when significant thermal stresses do not exist. The filler effect on some physical properties such as density, glass transition temperature, thermal expansion and Poisson's ratio of the epoxy composites is also investigated. Simple analysis indicates the differential thermal expansion coefficient between the adhesive and metallic joints and bulk modulus of the adhesive dictates the stress state.     

Thermal and geometrically non-linear stress analyses of an adhesively bonded composite tee joint

Adhesive bonding technique is used successfully for joining the carbon fibre reinforced plastics to metals or composite structures. A good design of adhesive joint with either simple or more complex geometry requires its stress and deformation states to be known for different boundary conditions. In case the adhesive joint is subjected to thermal loads, the thermal and mechanical mismatches of the adhesive and adherends cause thermal stresses. The plate-end conditions may also result in the adhesive joint to undergo large displacements and rotations whereas the adhesive and adherends deform elastically (small strain). In this study, the thermal and geometrically non-linear stress analyses of an adhesively bonded composite tee joint with single support plus an angled reinforcement made of unidirectional CFRPs were carried out using the non-linear finite element method. In the stress analysis, the effects of the large displacements were considered using the small displacement–large displacement theory. The stress states in the plates and the adhesive layer of the tee joint configurations bonded to a rigid base and a composite plate were investigated. An initial uniform temperature distribution was attributed to the adhesive joint for a stress free state, and then variable thermal boundary conditions, i.e. air flows with different velocity and temperature were specified along the outer surfaces of the tee joints. The thermal analysis showed that a non-uniform temperature distribution occurred in the tee joints, and high heat fluxes took place along the free surfaces of the adhesive fillets at the adhesive free ends. Later, the geometrical non-linear thermal-stress analysis of the tee joint was carried out for the final temperature distribution and two edge conditions applied to the edges of the vertical and horizontal plates (HP). High stress concentrations occurred around the rounded adherend corners inside the adhesive fillets at the adhesive free ends, and along the adhesive–composite adherend interfaces due to their thermal–mechanical mismatches. The most critical joint regions were adhesive fillets subjected to high thermal gradients, the middle region of HP, the region of the vertical plate corresponding to the free end of the vertical adhesive layer–left support interface. In addition, the support length had a small effect of reducing the peak stresses at the critical adherend and adhesive locations.     

Thermal characteristics of composite sandwich structures for machine tool moving body applications

The thermal deformation affects the accuracy of a precision machine tool. There are various heat sources in machine tools such as motors, spindle units, and friction in LM-guide systems. In this work, the thermal characteristics of composite sandwich structures for machine tool parts were investigated both by FEM analysis and experiment. Then the machine tool slide of a high speed CNC milling machine was designed and manufactured with composite sandwich structures combined with a welded steel structure––a hybrid machine tool structure. In addition, the reliability of adhesive joints between the composite sandwich and the steel structure was investigated in terms of adhesive joint strength and thermal stress induced by heat generation of linear motors.     

Analysis of the distribution of thermal residual stresses in bonded composite repair of metallic aircraft structures

In this study, the distribution of the thermal residual stresses due to the adhesive curing in bonded composite repair is analysed using the finite element method. The computation of these stresses comprises all components of the structures: cracked plate, composite patch and adhesive layer. In addition, the influence of these residual stresses on the repair performance is highlighted by analysing their effect on the stress intensity factor at the crack tip. The obtained results show that the normal thermal stresses in the plate and the patch are important and the shear stresses are less significant. The level of the adhesive thermal stresses is relatively high. The presence of the thermal stresses increases the stress intensity factor at the crack tip, what reduce the repair performance.     

Reduction of residual stresses in thick-walled composite cylinders by smart cure cycle with cooling and reheating

The nozzle parts of solid rocket motors must endure both the internal pressure generated by high temperature exhaust gas and the mechanical load generated by steering operation. Therefore, the nozzle parts of solid rocket motors are fabricated with thick carbon fiber phenolic resin composites. When the thick-walled phenolic composite cylinder is cooled down from the curing temperature of about 155 °C to the room temperature, thermal residual stresses are created due to the anisotropic thermal deformation of the composite structure.

In this paper, a smart cure method with cooling and reheating was developed to reduce residual stresses in thick-wound composite cylinders made of carbon phenolic woven composite. The optimal cure cycle was obtained to reduce the residual stresses without increasing processing time and applied to fabrication of the thick-walled composite cylinder. From the residual stresses measured by the radial-cut-cylinder-bending method, it was found that the residual stresses were reduced 30% by using the smart cure method.     

Residual stress development during the composite patch bonding process: measurement and modeling

This paper presents an experimental technique for monitoring residual stress development throughout the composite patch repair curing process. Using this technique, process-induced strains and specimen warpage during a number of different cure cycles were measured for a simulated single-sided composite patch repair of an aluminum substrate. Models for adhesive cure rate and glass transition behavior of the patch adhesive resin (FM 300-1K) were combined with a simple bi-metallic strip model to predict specimen warpage and strain behavior during cure. Model predictions were compared with experimental measurements and were used to assist in the development of optimized cure cycles. Using these optimized cycles, it was found that it was possible to achieve significant (>20%) reductions in patch warpage and at the same time, minimize processing time and obtain a high final adhesive degree of cure. Experimental observations suggest that an improved patch model incorporating adhesive viscoelastic behavior during cure would assist in achieving additional process improvements.     

Study on the curing process for carbon/epoxy composites to reduce thermal residual stress

In this work, a cure monitoring system using dielectrometry and a fiber Bragg grating (FBG) sensor, was devised to measure the dissipation factor and thermal residual stress of carbon fiber-reinforced epoxy composite materials. Three rapid-cooling points, which were based on the cure initiation point, were chosen as test variables to investigate the effect of cure cycle on process-induced internal strain. The internal strains generated in the composite specimens were measured using embedded FBG sensors. Three-point bending tests were conducted to investigate the effect of thermal residual stress on the flexural strength of the composite specimens.     

高温老化对玄武岩纤维增强树脂复合材料-铝合金单搭接接头失效的影响

为了研究持续高温环境对车用新材料粘接结构力学性能的影响,加工了铝合金-铝合金（Al-Al）和玄武岩纤维增强树脂复合材料-铝合金（BFRP-Al）单搭接接头,在高温（80℃）环境下进行了0天（未老化）、5天、10天、15天的老化实验,并对胶粘剂和BFRP复合材料进行了DSC和FTIR测试,分析高温老化后胶粘剂、BFRP复合材料的玻璃化转变温度（T_g）和化学成分变化,通过准静态拉伸测试获得老化后接头的失效载荷,并对其失效模式进行分析。研究结果表明:高温环境下,胶粘剂会发生后固化及氧化反应,BFRP复合材料发生热分解及氧化反应;Al-Al接头的失效载荷随老化周期的增加而不断增大,老化前后的失效模式均为内聚失效,其性能变化主要由胶粘剂决定;BFRP-Al接头的失效载荷先增加后减小,不同老化周期的接头均发生内聚和撕裂的混合失效,其性能变化由胶粘剂和BFRP复合材料共同作用决定,且随着老化周期的增加,BFRP复合材料撕裂面积不断增大,BFRP-Al接头的失效模式越来越倾向于玄武岩纤维/树脂界面的破坏,BFRP复合材料老化对接头失效载荷的影响越来越显著。      

Cryogenic reliability of composite insulation panels for liquefied natural gas (LNG) ships

The major carrier of liquefied natural gas (LNG) is LNG ships, whose containment system is composed of dual barriers and composite insulation panels. The LNG containment system should have cryogenic reliability and high thermal insulation performance for safe and efficient transportation of LNG. The secondary barrier composed of adhesive bonded aluminum strips should keep tightness for 15 days, when the welded stainless primary barrier fails. However, cracks are generated in the composite insulation panels due to the local stress concentration and the brittleness of insulation materials at the cryogenic temperature of −163 °C. If cracks generated in the insulation panel propagate into the secondary barrier, LNG leakage problem might occur, which is a remaining concern in ship building industries.In this study, crack retardation capability in the composite insulation panel was investigated with glass fabric reinforcement. Finite element analysis was conducted to estimate the thermal stress at the cryogenic temperature and a new experimental method was developed to investigate the failure of secondary barrier of composite insulation panel. From the experimental results, it was found that the glass fabric reinforcement was effective to retard the crack propagation into the aluminum secondary barrier from the polyurethane insulation foam at the cryogenic temperature.     

Mode I fracture toughness of an adhesively bonded composite–composite joint in a cryogenic environment

To determine the effect of cryogenic temperature on the adhesive fracture toughness of an adhesively bonded joint with composite adherends, monotonic mode I adhesive fracture toughness tests were performed at liquid nitrogen temperature (−196 °C) and at room temperature (27 °C). From these experimental tests, the critical strain energy release rate for both test temperatures was evaluated for the selected bonded joint system constructed of carbon-BMI adherends bonded with AF-191M film adhesive. Experimental results exhibit reduced adhesive fracture toughness at the cryogenic temperature and a profound difference in fracture mode.     

Rapidly cured epoxy/anhydride composites: Effect of residual stress on laminate shear strength

The drive towards rapid cure thermosetting composites requires a better understanding of the residual stresses that develop during curing. This study investigates the impact of residual stresses on the interlaminar shear strength of resin-infused epoxy/anhydride carbon-fibre laminates. The magnitude of the residual stress was varied by changing the initial injection cure temperature between 75 °C and 145 °C. The corresponding cycle times and the final glass transition temperature of the resin were also measured. The experimentally measured chemical shrinkage and thermal expansion properties of the resin after vitrification were used as inputs to a finite element analysis to calculate the peak residual stresses in the composite. An increase in the initial cure temperature from 85 to 135 °C resulted in an increase of 25% in the residual stress, which led to an experimentally measured reduction in the composite’s short beam shear strength of approximately 16% (8 MPa), in good agreement with model prediction.     

Mechanical properties of In-based eutectic alloy solders used in Josephson packaging

InBiSn and InSn eutectic alloy solders are used in the packaging of the cryogenic Josephson processor. The ductile behaviour of these alloys is important to the application of joints which experience large thermal stresses. In order to characterize the mechanical behaviour at cryogenic temperatures, tensile and shear strengths of bulk solders were measured at and below room temperature. It is found that the ultimate tensile and shear strengths of bulk solders increase as temperature decreases. At low temperatures, the ultimate tensile strength of InBiSn alloy is about three times less than that of InSn alloy. The ductility of both alloys reduces at low temperatures. The fracture surfaces of both bulk solders and solder joints having an interface material (Pd and Au thin films) to the electrical contact pads (Nb thin film) were examined using SEM. Ductile fracture mode was observed for all the specimens down to liquid nitrogen temperature.