Simplified speciation and atmospheric volatile organic compound emission rates from non-aerosol personal care products

Volatile organic compounds (VOCs) emitted from personal care products (PCPs) can affect indoor air quality and outdoor air quality when ventilated. In this paper, we determine a set of simplified VOC species profiles and emission rates for a range of non-aerosol PCPs. These have been constructed from individual vapor analysis from 36 products available in the UK, using equilibrium headspace analysis with selected-ion flow-tube mass spectrometry (SIFT-MS). A simplified speciation profile is created based on the observations, comprising four alcohols, two cyclic volatile siloxanes, and monoterpenes (grouped as limonene). Estimates are made for individual unit-of-activity VOC emissions for dose-usage of shampoos, shower gel, conditioner, liquid foundation, and moisturizer. We use these values as inputs to the INdoor air Detailed Chemical Model (INDCM) and compare results against real-world case-study experimental data. Activity-based emissions are then scaled based on plausible usage patterns to estimate the potential scale of annual per-person emissions for each product type (eg, 2 g limonene person⁻¹ yr⁻¹ from shower gels). Annual emissions from non-aerosol PCPs for the UK are then calculated (decamethylcyclopentasiloxane 0.25 ktonne yr⁻¹ and limonene 0.15 ktonne yr⁻¹) and these compared with the UK National Atmospheric Emissions Inventory estimates for non-aerosol cosmetics and toiletries.     

Organ specific antioxidant responses in golden grey mullet (Liza aurata) following a short-term exposure to phenanthrene

Phenanthrene (Phe) is among the most abundant and ubiquitous polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment as a result of human activities. Even so, the knowledge about its impact on fish health is still limited. In this study, the teleost Liza aurata was exposed to 0.1, 0.3, 0.9 and 2.7 µM Phe concentrations during 16 h. Enzymatic antioxidants such as selenium dependent glutathione peroxidase (GPx), glutathione S-transferase (GST), glutathione reductase (GR) and catalase (CAT), as well as a non-enzymatic antioxidant (glutathione — GSH) were quantified in three target organs — gill, kidney and liver. The lipid peroxidation (LPO) was also assessed as a marker of oxidative damage. GPx activity was decreased in gill (0.1 and 0.9 µM), whereas in the liver it was increased (0.3-2.7 µM). GST activity was decreased in kidney (0.3-2.7 µM) and CAT activity was increased in gill after 0.9 µM exposure. GSH content was significantly increased in gill by the lowest concentration and in liver by all Phe concentrations. Despite the antioxidant defense responses, LPO increased in gill (0.3-2.7 µM), kidney (0.1 µM) and liver (0.1 and 2.7 µM). These results revealed organ specific antioxidant defenses depending on the Phe concentration. Liver demonstrated a higher adaptive competence expressed as antioxidant defenses activation, namely GSH and GPX. The lower vulnerability of the kidney to oxidative damage (compared to gill and liver) seems to be related to its higher antioxidant basal levels. Globally, current data highlight the Phe potential to induce oxidative stress and, consequently, to affect the well-being of fish.     

The effects of biofilm on the transport of stabilized zerovalent iron nanoparticles in saturated porous media

The transport of stabilized zerovalent iron nanoparticles (nZVI) has recently been the topic of extensive research due to its proven potential as an in situ remediation tool. However, these studies have ignored the effects of biofilms—complex aggregations of bacterial cells and excreted extracellular polymeric substances present in nearly all aquatic systems—on the transport of these particles. This study examines the effects of Pseudomonas aeruginosa (PAO1) biofilm, at a cell concentration similar to that reported for saturated aquifers, on the transport of commercially available, poly (acrylic acid) stabilized nZVI (pnZVI) in 14 cm long columns packed with saturated glass beads at salt concentrations of 1 and 25 mM NaCl. Compared to retention on uncoated columns, in the presence of biofilm the retention of pnZVI increased at higher ionic strength, while ionic strength played no role in retention of these nanoparticles in the absence of biofilm. The Tufenkji-Elimelech correlation equation predicts lower retention of pnZVI on biofilm coated columns compared to uncoated columns due to a lower Hamaker constant, and DLVO energy considerations predict the most favorable attachment to uncoated porous media at higher ionic strength. A steric (polymer-mediated) model that considers the combined influence of steric effects of polymers and DLVO interactions is shown to adequately describe particle retention in columns.     

Efficacy of monitoring and empirical predictive modeling at improving public health protection at Chicago beaches

Efforts to improve public health protection in recreational swimming waters have focused on obtaining real-time estimates of water quality. Current monitoring techniques rely on the time-intensive culturing of fecal indicator bacteria (FIB) from water samples, but rapidly changing FIB concentrations result in management errors that lead to the public being exposed to high FIB concentrations (type II error) or beaches being closed despite acceptable water quality (type I error). Empirical predictive models may provide a rapid solution, but their effectiveness at improving health protection has not been adequately assessed. We sought to determine if emerging monitoring approaches could effectively reduce risk of illness exposure by minimizing management errors. We examined four monitoring approaches (inactive, current protocol, a single predictive model for all beaches, and individual models for each beach) with increasing refinement at 14 Chicago beaches using historical monitoring and hydrometeorological data and compared management outcomes using different standards for decision-making. Predictability (R²) of FIB concentration improved with model refinement at all beaches but one. Predictive models did not always reduce the number of management errors and therefore the overall illness burden. Use of a Chicago-specific single-sample standard—rather than the default 235 E. coli CFU/100 ml widely used—together with predictive modeling resulted in the greatest number of open beach days without any increase in public health risk. These results emphasize that emerging monitoring approaches such as empirical models are not equally applicable at all beaches, and combining monitoring approaches may expand beach access.     

A design model for stainless steel box columns in fire

A study of stainless steel cold-rolled box columns at elevated temperatures is presented, which is a part of an on-going RFCS project “Stainless Steel in Fire”, 2004-2007. Experimental results of six, class 4, stub columns at elevated temperature, tested by Ala-Outinen [Members with Class 4 cross-sections in fire: Work package 3, ECSC project stainless steel in fire. Contract no. RFS-CR-04048, Espoo, Finland; 2005], were used to evaluate the finite element (FE) model. The FE analysis obtained using the commercially available software, ABAQUS, shows that the critical temperature was closely predicted. Further, a parametric study was performed using the same numerical model. This was a basis to check the quality of prediction of a newly proposed improvement for design rules of class 4 cross-sections in fire according to EN 1993-1-4 [Eurocode 3 - Design of steel structures — Part 1-4: General rules — Supplementary rules for stainless steels, CEN; 2006] and EN 1993-1-2 [Eurocode 3: Design of steel structures — Part 1.2: General rules — Structural fire design, CEN; 2005].     

Extreme selenium and tellurium contamination in soils — An eighty year-old industrial legacy surrounding a Ni refinery in the Swansea Valley

Elevated levels of selenium (maximum 200 mg/kg) and tellurium (maximum 11 mg/kg) are reported in topsoils (< 5 cm) from around a long-established nickel refinery at Clydach in the Lower Swansea Valley, UK. Se and Te are correlated with each other and when these data are plotted as contour diagrams they show a concentric pattern centred on the refinery site. The origin of the Se and Te contamination is investigated. A review of the changes in the refinery practices at the site is presented and used to link the soil contamination to industrial pollution which took place over 80 years ago. The most recent air quality data available cannot rule out some Se contamination up to 2003.     

A simple model of domestic lighting demand

This paper presents a new model of domestic lighting demand. The model is based on half-hourly data measured for a sample of 100 UK homes. It represents one sub-model in an end-user based distributed load model that is being developed to support investigations into the effects on low voltage urban electricity networks of future wide-scale uptake of solar technologies. To capture these effects and to serve applications involving renewable energy technologies (RETs) generally, the model is capable of representing load variations on very fine time-scales, down to 1 min intervals. Additionally, scaling factors are provided to enable prediction of long-term trends and to model some of the most important elements of diversity between connection points that are likely to impact on network performance and design below the 11 kV substation level.     

Enabling the hybrid use of air conditioning: A prototype on sustainable housing in tropical regions

This paper demonstrates how the use of active or passive means only does not give the appropriate answers to a tropical design when considering housing. The author discusses about the idea of both modes of operation being used simultaneously or in parallel, and how this concept has been developed for one experimental building prototype in tropical areas of Brazil (Northeast region). Quantification is given through extensive parametric simulations which have been conducted using different environmental simulation programmes—TAS (EDSL, UK), ESP-r (ESRU, UK) and photovoltaic (PV)-Design PRO-G (Sandia Labs, USA). Thermal comfort levels along with energy use were assessed and compared, in terms of degree hours of overheating/under heating and cooling energy use. The prototype design has also taken into account the appropriate use of resources through sustainable design features: efficient use of energy, water and materials. The results have demonstrated that for regions such as the warm-humid tropics, the use of a mixed running strategy have optimized energy performance and provided better levels of thermal comfort in a much more effective way. For some cases, cooling energy savings up to 80% were feasible on a hybrid mode, where thermal comfort was improved up to 65%. It has also demonstrated the integration of energy efficiency and a PV grid-connected system, while enabling those daytime electrical needs to be accomplished by the photovoltaic component.     

Interaction formulae for members subjected to bending and axial compression in EUROCODE 3—the Method 2 approach

The final version of EN1993-1-1, EUROCODE 3 [EN1993-1-1. Eurocode 3. Design of steel structures, general rules and rules for buildings. 2005] for Steel Structures provides two alternatives for the buckling check of members subjected to axial compression and bending by interaction formulae, which are called there Method 1 and Method 2. This paper presents the characteristics, the background and the use of Method 2. The analogous presentation of Method 1 has already been given in [Boissonnade N, Jaspart J-P, Muzeau J-P, Villette M. New Interaction formulae for beam-columns in Eurocode 3. The French-Belgian approach. Journal of Constructional Steel Research 2004;60;421-31].The Method 2 formulae have been derived on the basis of the general format of the interaction concept of existing codes, e.g. the ENV-rules; however with advanced numerical background and consistent classification of the buckling modes. In this respect new improved interaction factors were developed from a wide scope of numerical simulations and the concept of the formulae was focussed distinctly on describing the modes of in-plane and out-of-plane buckling for members susceptible to fail either in flexural buckling or in lateral-torsional buckling. As result two sets of formulae are provided, which each cover a clear scope of physical member behaviour. Hereby, the specific effects of intermediate lateral restraints—as often found in steel structures—have also been included.The Method 2 formulae aim at providing buckling rules with compact simplified interaction factors and transparent application for standard cases.     

Connection research and its impact on practice during the Dowling era

Changes in the nature, importance and effectiveness of research in the area of steelwork connections over the past 50 years are identified. The emphasis is on heavy gauge construction for building structures — but similar developments exist in parallel fields e.g. light gauge construction, bridges, offshore structures etc. The key factor is greatly increased recognition of the primary role of connections in both controlling structural performance and in influencing economics. This has resulted in a much higher profile, more scientific treatment and greater translation of research findings into practice through specialised initiatives. Aspects of all of this work are reviewed, focusing on the UK scene during the second half of the 20th century.     

Comparison of methods for converting Dylos particle number concentrations to PM2.5 mass concentrations

The aim of this study was to (a) develop a method for converting particle number concentrations (PNC) obtained by Dylos to PM2.5 mass concentrations, (b) compare this conversion with similar methods available in the literature, and (c) compare Dylos PM2.5 obtained using all available conversion methods with gravimetric samples. Data were collected in multiple residences in three European countries using the Dylos and an Aerodynamic Particle Sizer (APS, TSI) in the Netherlands or an optical particle counter (OPC, GRIMM) in Greece. Two statistical fitted curves were developed based on Dylos PNC and either an APS or an OPC particle mass concentrations (PMC). In addition, at the homes of 16 volunteers (UK and Netherlands), Dylos measurements were collected along with gravimetric samples. The Dylos PNC were transformed to PMC using all the fitted curves obtained during this study (and three found in the literature) and were compared with gravimetric samples. The method developed in the present study using an OPC showed the highest correlation (Pearson (R) = 0.63, Concordance (ρ_c) = 0.61) with gravimetric data. The other methods resulted in an underestimation of PMC compared to gravimetric measurements (R = 0.65‐0.55, ρ_c = 0.51‐0.24). In conclusion, estimation of PM2.5 concentrations using the Dylos is acceptable for indicative purposes.     

Water quality, nutrients and the European union's Water Framework Directive in a lowland agricultural region: Suffolk, south-east England

The water quality of 13 rivers in the lowland, agricultural county of Suffolk is investigated using routine monitoring data for the period 1981 to 2006 collected by the Environment Agency of England and Wales (EA), and its predecessors, with particular emphasis on phosphorus (as total reactive phosphorus, TRP) and total (dissolved and particulate) oxidised nitrogen (TOxN — predominantly nitrate NO₃). Major ion and flow data are used to outline fundamental hydrochemical characteristics related to the groundwater provenance of base-flow waters. Relative load contributions from point and diffuse sources are approximated using Load Apportionment Modelling for both TRP and TOxN where concurrent flow and concentration data are available. Analyses indicate a mixture of point and diffuse sources of TRP, with the former being dominant during low flow periods, while for TOxN diffuse sources dominate.Out of 59 sites considered, 53 (90%) were found to have annual average TRP concentrations greater than 0.05 mg P l^− 1, and 36 (61%) had average concentrations over 0.120 mg P l^− 1, the upper thresholds for ‘High’ and ‘Good’ ecological status, respectively. Correspondingly, for TOxN, most of the rivers are already within 70% of the 11.3 mg N l^− 1 threshold, with two rivers (Wang and Ore) being consistently greater than this.It is suggested that the major challenge is to characterise and control point-source TRP inputs which, being predominant during the late spring and summer low-flow period, coincide with the peak of primary biological production, thus presenting the major challenge to achieving ‘good’ ecological status under the Water Framework Directive. Results show that considerable effort is still required to ensure appropriate management and develop tools for decision-support.     

Land management as a factor controlling dissolved organic carbon release from upland peat soils 1: Spatial variation in DOC productivity

The importance of soil storage in global carbon cycling is well recognised and factors leading to increased losses from this pool may act as a positive feedback mechanism in global warming. Upland peat soils are usually assumed to serve as carbon sinks, there is however increasing evidence of carbon loss from upland peat soils, and DOC concentrations in UK rivers have increased markedly over the past three decades. A number of drivers for increasing DOC release from peat soils have been proposed although many of these would not explain fine-scale variations in DOC release observed in many catchments.We examined the effect of land use and management on DOC production in upland peat catchments at two spatial scales within the UK. DOC concentration was measured in streams draining 50 small-scale catchments (< 3 km²) in three discrete regions of the south Pennines and one area in the North Yorkshire Moors. Annual mean DOC concentration was also derived from water colour data recorded at water treatment works for seven larger scale catchments (1.5-20 km²) in the south Pennines. Soil type and land use/management in all catchments were characterised from NSRI digital soil data and ortho-corrected colour aerial imagery.Of the factors assessed, representing all combinations of soil type and land use together with catchment slope and area, the proportion of exposed peat surface resulting from new heather burning was consistently identified as the most significant predictor of variation in DOC concentration. This relationship held across all blanket peat catchments and scales.We propose that management activities are driving changes in edaphic conditions in upland peat to those more favourable for aerobic microbial activity and thus enhance peat decomposition leading to increased losses of carbon from these environments.     

An evaluation of the reactivity of synthetic and natural apatites in the presence of aqueous metals

Metal removal from contaminated effluents was examined following reaction with natural apatites of biological and geological origin or a synthetic hydroxylapatite (HAP). Mammalian meat and bone meal (MBM), a by-product from meat industry, was the biological apatite source. The effect of incineration on metal removal capacity of MBM and HAP was also examined. The reactivity of apatites for all tested metals (Pb, Cd, Cu and Zn) followed the general order: synthetic > biological > mineral. For all apatites tested, Pb was removed best and preferentially from multi-metal solutions. MBM and HAP (0.5 g solid) removed Pb completely from both highly concentrated single metal solutions (50 ml, 1000 mg/L Pb) and from multi-metal solutions (50 ml) with 100 mg/L each of Cd, Cu and Zn in addition to Pb. The incineration of MBM (725 °C and 850 °C) reduced significantly its capacity for removal of Zn (by 47%, from 56 mg/g to 9 mg/g) and Cd (by 38%, from 53 mg/g to 13 mg/g) in particular and to a lesser extent for Cu (by 14%, from 61 mg/g to 46 mg/g) while the removal of Pb was not affected (100 mg/g). The same pattern was observed for incinerated HAP. SEM and XRD analysis indicated that HAP reacted with the metals by precipitation of pure metal phosphates—Pb hydroxylapatite, Zn phosphate (hopeite), a Cd phosphate (identified only by ED-SEM) and Cu phosphate (libenthenite).     

单点动载下路基动应力状态及有效作用半径分析

 基于传统的Boussinesq课题解答,利用集中荷载作用下半无限空间弹性路基中不同空间位置,且满足一定限制条件的点的应力应变状态的集合来表征单次行车荷载下路基岩土体内某一点加载、卸载全过程的应力、应变等力学响应,将动力学问题转化为准静力学问题,建立着眼于简单与实用的路基动力学行为分析模型。借助建立的模型探讨路基一个加载、卸载全过程的应力状态及其有效作用半径。研究表明,(1) 路基单元体动正应力差( )和( )曲线表现为脉冲状,而( )曲线为双峰状;(2) 最大主应力 绕z轴可能突发大角度旋转,但与z轴交角则连续旋转180°,最小主应力 整体旋转特征不甚明显,中间主应力 方向变化规律性较差;(3) 单次交通荷载对路基路面系统的有效作用半径确定为10 m,影响范围确定为以荷载作用点为圆心,以10 m为半径的空间半球体。最后,利用原位监测数据对确定单次交通荷载的有效作用半径为10 m的合理性进行验证。     

Persistence and partitioning of eight selected pharmaceuticals in the aquatic environment: Laboratory photolysis, biodegradation, and sorption experiments

We selected eight pharmaceuticals with relatively high potential ecological risk and high consumption—namely, acetaminophen, atenolol, carbamazepine, ibuprofen, ifenprodil, indomethacin, mefenamic acid, and propranolol—and conducted laboratory experiments to examine the persistence and partitioning of these compounds in the aquatic environment. In the results of batch sunlight photolysis experiments, three out of eight pharmaceuticals—propranolol, indomethacin, and ifenprodil—were relatively easily photodegraded (i.e., half-life < 24 h), whereas the other five pharmaceuticals were relatively stable against sunlight. The results of batch biodegradation experiments using river water suggested relatively slow biodegradation (i.e., half-life > 24 h) for all eight pharmaceuticals, but the rate constant was dependent on sampling site and time. Batch sorption experiments were also conducted to determine the sorption coefficients to river sediments and a model soil sample. The determined coefficients (K_d values) were much higher for three amines (atenolol, ifenprodil, and propranolol) than for neutral compounds or carboxylic acids; the K_d values of the amines were comparable to those of a four-ring polycyclic aromatic hydrocarbon (PAH) pyrene. The coefficients were also higher for sediment/soil with higher organic content, and the organic carbon-based sorption coefficient (log K_oc) showed a poor linear correlation with the octanol-water distribution coefficient (log D_ow) at neutral pH. These results suggest other sorption mechanisms—such as electrochemical affinity, in addition to hydrophobic interaction—play an important role in sorption to sediment/soil at neutral pH.     

Functional properties of DOM in a stream draining blanket peat

The functional properties of dissolved organic matter (DOM) from Rough Sike, a stream draining blanket peat in the northern Pennines, UK, were investigated using a series of 12 standardised assays. Nine stream samples were collected at different discharges during 2003-2006, and DOM concentrates obtained by low temperature rotary evaporation. Suwannee River Fulvic Acid was used as a quality control standard in the assays. Dissolved organic matter in high-discharge samples was more light-absorbing at 280 and 340 nm and adsorbed more strongly to alumina, than DOM characteristic of low streamflow, but was less fluorescent and hydrophilic, and poorer in proton-dissociating groups. No significant differences were found in light absorption at 254 nm, copper- or benzo(a)pyrene binding, or photochemical fading. Combination of the Rough Sike data with previously-published results for other streams and a lake yields totals of 20-23 values per assay, for a range of DOM types. For the combined data, variability in all the assays is significant (p < 0.001), as judged by comparison with variations in repeat measurements on the quality control standard. Analysis of the combined data shows that DOM hydrophilicity and adsorption are well-predicted by linear relationships with the extinction coefficient at 340 nm (E₃₄₀), while good quadratic relationships exist between E₃₄₀ and both buffering capacity and fluorescence.     

Assessing regional intake fractions in North America

This paper develops the IMPACT North America model, a spatially resolved multimedia, multi-pathway, fate, exposure and effect model that includes indoor and urban compartments. IMPACT North America allows geographic differentiation of population exposure of toxic emissions for comparative risk assessment and life cycle impact assessment within U.S. and Canada. It looks at air, water, soil, sediment and vegetation media, and divides North America into several hundred zones. It is nested within a single world box to account for emissions leaving North America. It is a multi-scale model, covering three different spatial scales — indoor, urban and regional — in all zones in North America. Model results are evaluated against monitored emissions and concentrations of benzo(a)pyrene, 2,3,7,8-TCDD and mercury. Most of the chemical concentrations predicted by the model fall within two orders of magnitude of the monitored data. The model shows that urban intake fractions are one order of magnitude higher than rural intake fractions. The model application and importance is demonstrated by a case study on spatially-distributed emissions over the life cycle of diesel fuel. Depending on population densities and agricultural intensities, intake fractions can vary by eight orders of magnitudes, and even limited indoor emissions can lead to intakes comparable to those from outdoor emissions. To accurately assess these variations in intake fraction, we require the essential three original features described in the present paper: i) inclusion of the continental model within a world box for persistent pollutants, ii) addition of an urban box for short- and medium-lived substances (for grid size larger than 100 km), and iii) assess indoor emissions. This model can therefore be used to screen chemicals and assess regionalized intake fractions within North America for population-based human exposure assessment, life cycle impact assessment, and comparative risk assessment. The model can be downloaded at http://www.impactmodeling.org.