Changes in P Bioavailability Induced by the Application of Liquid and Powder Sources of P, N and Zn Fertilizers in Alkaline Soils

Alkaline and/or calcareous soils provide significant challenges for management of crop P nutrition, due to rapid fixation of P into sparingly soluble forms not readily accessible by plants. Three powder products, mono- and diammonium phosphate (MAP, DAP) and triple superphosphate (TSP), were compared to three liquid products, liquid MAP, ammonium polyphosphate (APP) and phosphoric acid (H₃PO₄), as sources of P for wheat grown in four alkaline soils (grey and red calcareous soils, a Vertosol and a Sodosol) sampled in Eyre Peninsula (South Australia), Wimmera and Central Mallee areas (Victoria) of southern Australia. Soils were labelled with ³²P and the labile P pool and P derived from the fertilizer (P_dff) determined. Residual value of the fertilizers was determined after a 4 month wet/dry incubation. Liquid formulations outperformed powder products in the grey calcareous soil and in the Vertosol, as measured by wheat growth, P uptake, plant-labile P pools and P_dff. These increases in P efficiency were not related to differential acidification of the bulk soils. In the most calcareous soil, large proportions of the added DAP, MAP or TSP were rapidly converted (fixed) into non plant-labile pools, likely through precipitation of Ca–P compounds not accessible to plant roots, while conversely, liquid formulations minimized P fixation. Our results suggest that one of the most likely hypotheses to explain difference in efficiencies between powder and liquid forms of fertilizers was that in relatively dry conditions and in high P fixing soils, the dissolution and diffusion of P outwards from the powder is limited. This induces localized areas in the soil with high concentrations of P leading to precipitation of insoluble Ca–P solid phases. In the field, where powder fertilizers are applied as granules rather than as fine powder, differences between the two forms of fertilizer are likely to be larger. The residual value of liquid formulations was equal or superior to powder products. Liquid fertilizers injected into soil may therefore have potential to improve P nutrition in a wide range of calcareous soils under dryland agriculture throughout the world. Field trials have actually been performed in southern Australia to confirm this important issue.     

Effect of organic and inorganic phosphate fertilizers and their combination on maize yield and phosphorus availability in a Yellow Earth in Myanmar

Phosphorus (P) deficiency is a major constraint for crop production in many parts of the world including Myanmar and field research into management of P fertilizers and P responsiveness of crops on infertile soils has been limited. The purpose of this study is to determine maize yield response to different forms of P fertilizers on an acidic (pH 4.9) P deficient (Olsen-P 8 mg kg⁻¹) Yellow Earth (Acrisol) in Southern Shan State, Myanmar and to establish relationships between soil Olsen-P test values (0.5 M sodium bicarbonate extracted P) and maize yield. Field experiments were conducted during two cropping seasons. There were 15 treatments in total: P was applied at seven rates of a soluble P fertilizer as Triple superphosphate (TSP) (0–120 kg P ha⁻¹) to establish a P response curve; one rate of a partially soluble P fertilizer (Chinese partially acidulated phosphate rock, CPAPR) and two organic P fertilizers (farmyard manure (FYM) and Tithonia diversifolia) at 20 kg P ha⁻¹; combination of TSP and CPAPR at 20 kg P ha⁻¹ with FYM and Tithonia at 20 kg P ha⁻¹; an additional treatment (TSP 20 kg P ha⁻¹ plus 2.5 t ha⁻¹ dolomite) for assessing the liming effect of a local dolomite. In Year 1, applications of TSP at 40–60 kg P ha⁻¹ produced near maximum grain yields, whereas in Year 2 this could be achieved with a reapplication of 20–30 kg P ha⁻¹ on top of the residual value of the Year 1 application. In both years, CPAPR, TSP and Tithonia at 20 kg P ha⁻¹ significantly increased maize grain yield, but FYM failed to increase grain yield. In Year 1, CPAPR and TSP effects on grain yield were higher than that of Tithonia but in Year 2 the effects were same for all these three treatments. In both years the combination of FYM (20 kg P ha⁻¹) with TSP (20 kg P ha⁻¹) produced significantly higher grain yield than TSP at 20 kg P ha⁻¹ whereas 40 kg P ha⁻¹ of TSP application did not significantly increase grain yield over the TSP application at 20 kg P ha⁻¹. Similar results were obtained when half the P applied as CPAPR was substituted with P from Tithonia and FMP during the first year. The combined data from the two years experiment suggests that 90% of maximum maize grain yields can be obtained by raising the Olsen-P to 30–35 mg P ha⁻¹ soil at the silking stage of growth. Olsen-P for the treatments at silking in Year 1 was: Control < FYM, Tithonia < TSP, CPAPR and in Year 2 was: Control < FYM < Tithonia < TSP, CPAPR. The results showed that for a long-term approach, repeated annual applications of Tithonia can be considered as a potential P source for improving soil P status in P deficient Yellow Earths.     

Decomposition and phosphorus release of agroforestry shrub residues and the effect on maize yield in acidic soils of Rubona,southern Rwanda

Phosphorus release from decomposing leaf biomass of Calliandra calothyrsus Meissner, Tithonia diversifolia Hensley A.Gray and Tephrosia vogelii Hook.f. agroforestry species applied alone or combined with triple super phosphate (TSP) was studied at World Agroforestry Centre (ICRAF) laboratory for 56 days using an incubation method. The effects of above treatments on maize yield were evaluated in the field at Rubona, southern province of Rwanda between the years 2001 and 2004. The net cumulative phosphorus (P) mineralised ranged from 16.2 to 212.2 mg P kg⁻¹. The net P mineralisation rates from green manure, TSP applied alone or combined with green manure decreased in the order green manure > green manure + TSP > TSP > lime > control. The best plant residues quality for predicting P mineralisation is total P, C, and C:P & C:N ratios. Relative to the control, leaf biomass combined with TSP resulted in six times higher maize grain yield at the end of the experiment i.e., from 0.9 to 7.1 t ha⁻¹. In the fourth season, application of Tithonia diversifolia Hensley A.Gray green manure combined with TSP at 50 kg P ha⁻¹ resulted in higher maize yield (25% increase) than TSP and Tithonia diversifolia Hensley A.Gray (9% increase) applied alone at the similar rate. Therefore, application of plant residues and TSP alone might not be sufficient to meet maize plant P requirements and to achieve the yield potential of maize in the Rubona soils unless supplemented with mineral fertilisers.     

Effect of soil pH on the requirement for water-soluble phosphorus in triple superphosphate fertilizers

A greenhouse study was conducted to determine if soil pH affects the requirement for water-soluble P and the tolerance of water-insoluble impurities in TSP fertilizers. Two commercial TSP fertilizers were selected to represent a range in phosphate rock sources and impurities. Phosphate fertilizer impurities were isolated as the water-washed fraction by washing whole fertilizers with deionized water. TSP fertilizers with various quantities of water-soluble P (1.2 to 99% water-soluble P) were simulated by mixing the water-washed fertilizer fractions or dicalcium phosphate (DCP) with reagent-grade monocalcium phosphate (MCP). The fertilizers were applied to supply 40 mg AOAC available P kg^–1 to a Mountview silt loam (fine-silty, siliceous, thermic Typic Paleudults). Wheat (Triticum aestivum (L.)) was harvested at 49 and 84 days after planting. Soil pH values at the final forage harvest were 5.4±0.16 and 6.4±0.15. At a soil pH of 5.4, the TSP fertilizers required only 37% water-soluble P to reach maximum yields while at pH 6.4 the fertilizers required 63% water-soluble P. Results of this study show that higher levels of water -insoluble P can be tolerated in TSP fertilizers when applied to acid soils. Phosphorus uptake was not affected by soil pH, but for the mixtures containing the fertilizer residues the source having the lowest level of Fe and Al had a higher relative agronomic effectiveness.     

Extractable Bray-1 phosphorus and crop yields as influenced by addition of phosphatic fertilizers of various solubilities integrated with manure in an acid soil

Soil extractable Bray-1 P (B1P) and response to phosphate (P) of Setaria anceps cv. Kazungula (Setaria grass) were monitored in a field trial bimonthly for 14 months in an acid soil fertilized with triple super phosphate (TSP), Gafsa phosphate rock (GPR) or Christmas Island phosphate rock (CIPR) integrated with or without manure. Extractable B1P from the same soil incubated with the same fertilizers in wet and dry 3-day cycles for 91 days was determined. Field experimental design was randomized complete block (RCB) with three replications. Results indicated that B1P magnitude for field and incubation trial were; TSP > GPR > CIPR, consistent with their solubility. An integration of manure and fertilizers resulted in much higher extractable B1P than sole fertilizers or manure. Over time, P availability decreased at a fast rate for the first 6 months and later was relatively constant. The dry matter yields (DMYs) exhibited quadratic relationships with P rates. Maximum DMYs (6–11 t ha⁻¹) were attained between 100 and 200 kg P ha⁻¹, above which they declined. Average DMYs were not significantly different for TSP, GPR and CIPR (6.1–6.6 t ha⁻¹). Maximum individual DMY were attained at 2–6 months and then declined to a minimum (2–4 t ha⁻¹) after 1 year. Cumulative yields (20–55 t ha⁻¹) also were not significantly different for the three fertilizers. Manure-CIPR integration increased DMY whilst in GPR and TSP/manure combinations DMYs were depressed. The PRs could supplement the expensive TSP without loss of yields but the non-reactive PR should be integrated with manure.     

Mono- and diammonium phosphates and triple superphosphate as sources of P in a calcareous soil

Recovery of phosphorus from monoammonium phosphate (MAP), diammonium phosphate (DAP) and triple superphosphate (TSP), at rates of 0, 15, 30, or 45 mg P kg^–1 was determined in a pot experiment on a Calcaric Lithosol soil (21% CaCO₃). At the 15 mg P kg^–1 rate DAP was as effective as MAP and more effective than TSP in supplying P, but it was less effective than MAP and TSP at the higher rates of 30 and 45 mg P kg^–1. At the two higher P rates residual bicarbonate extractable P was also significantly lower with DAP. Yield dry matter was not affected by the source of P.     

Comparison of the agronomic effectiveness of a phosphate rock and triple superphosphate as phosphate fertilisers for tea (Camellia sinensis L.) on a strongly acidic Ultisol

Phosphorus deficiency is a major problem affecting tea production in the highly weathered acid soils of humid and sub-humid tropics which are known to have high P fixing capacities. As many of these soils are strongly acidic and receive high rainfall, low-cost phosphate rock (PR) may effectively supply the plant P needs and limited preliminary experiments suggest this is so. A long-term glasshouse trial was conducted on 8-month old tea seedlings to compare the agronomic effectiveness of a locally available PR (Eppawala phosphate rock, EPR) with triple superphosphate (TSP) applied to a strongly acidic (pH water 4.55) marginally P deficient Rhodustult from Sri Lanka at six rates ranging from 10 to 60 kg P ha⁻¹. The results showed that TSP or EPR fertiliser at a rate as low as 10 or 20 kg P ha⁻¹ was sufficient to obtain maximun tea yield. The agronomic effectiveness of EPR was equal to that of TSP at the 5- and 10-month samplings. The concentration of soil P extracted by a cation–anion exchange resin membrane (resin-P) was higher in the TSP treated soil at 5 months due to its greater solubility but at 10 months, the EPR produced higher resin-P due to its increased dissolution over time. In the presence of tea plants, 52% of P from the EPR applied at the rate of 10 kg ha⁻¹, was dissolved at 5 months compared to 75% of dissolution at the 10-month sampling. In the absence of plants, the corresponding dissolution figures were 40% at 5 months and 55% at 10 months. The concentration of inorganic P extracted by 0.1 M NaOH (NaOH-P_i) (loosely characterising Fe + Al bound P) was significantly higher in the TSP treated soil and concentration of P extracted by 0.5 M H₂SO₄ (Ca bound P) was higher in the EPR treated soil. The results suggest that the low-cost, locally available EPR may be used profitably as a maintenace P fertiliser for tea plantations in moderately P deficient soils, which need to be confirmed by field studies. This revised version was published online in June 2006 with corrections to the Cover Date.     

Effect of organic and inorganic phosphorus sources on maize yields in an acid soil in western Kenya

Maize production in western Kenya is commonly limited by P deficiencies and aluminum phytotoxicity. Due to high costs of imported fertilizers and lime, focus is now shifting to solutions that utilize local resources. We tested the effect of three inorganic P sources i.e., triple superphosphate (TSP), Minjingu phosphate rock (MPR) and Busumbu phosphate rock (BPR), each applied in combination with two organic materials (OMs) i.e., farmyard manure (FYM) and Tithonia diversifolia green manure (tithonia), or with urea on soil chemical properties related to soil acidity, P availability and maize yields for three consecutive seasons in western Kenya. The OMs and inorganic P sources were applied to provide 20 and 40 kg P ha⁻¹ respectively in their combination. Where urea was used, the inorganic P sources were applied at 60 kg P ha⁻¹. Maize did not respond to application of TSP, MPR or BPR with urea in the first two seasons. However, after three seasons, maize significantly responded to application of MPR with urea. FYM was more effective than tithonia in increasing the labile inorganic P pools but it gave lower maize yields than tithonia which was more effective in reducing the exchangeable Al. It appears that the ability of an OM to lower the exchangeable Al is more important in increasing maize yields than its ability to increase P availability. The effectiveness of the inorganic P sources in increasing maize yields followed the order of their effectiveness in increasing available P, i.e., TSP > MPR > BPR, once Al phytotoxicity was reduced by application of tithonia but the difference between TSP and MPR was not significant. The extra maize yield obtained by the additional 40 kg P ha⁻¹ from the inorganic P sources was, however, in most cases not substantial enough to justify their use. Economic considerations may therefore favour the use of tithonia or FYM when applied alone at 20 kg P ha⁻¹ than when combined with any of the inorganic P sources used in this study at a total P rate of 60 kg ha⁻¹.     

Nitrate and phosphorus loss from agricultural land: implications for nonpoint pollution

The impact of agriculture on flood plains and surface water quality has received much attention in temperate countries in recent years. Little attention has been given to loss of nutrients and its impact on the quality of buffer zones and adjacent streams in many tropical environments due to the believe that fertilizer use is still very low compared to temperate countries. This may not be totally true especially in agricultural research stations and University experimental fields where a large amount fertilizers are used continuously for many years. This study was conducted in 2 years (Four seasons) to evaluate the accumulated effect of a long term fertilizer application of an agricultural land on an adjacent stream. Results showed that applied fertilizer significantly contributed to the high levels of nitrate and phosphorus in the stream water. Highest concentration of soil NO₃-N and P were found in 0–15, 15–30 and 30–45 cm soil depths with about 75% reduction in these amounts in the 60–75 cm depth for NO₃-N and 77% reduction at the same depth for soil available phosphorus, the topsoil constituting about 45% of the concentration of the two plant nutrients assessed. There were evident of leaching of basic cations below 15 cm soil depth as indicated in the increased soil pH. There were significantly (P < 0.05) higher soil NO₃-N and P in the dry season relative to the wet season. The long term application of fertilizers to the sandy loam soil significantly contributed to nitrate and phosphate pollution of the stream in excess of the maximum level accepted for potable water. The stream’s pH, temperature, nitrate and phosphate were significantly higher in the dry season. Correlation analyses indicated that agricultural runoffs from the topsoil contributed significantly to the pollution of the stream. There was also positive and significant correlation between the soil nitrate and soil phosphorus at different soil depths, thus indicating that the N and P might have been applied jointly as compound fertilizer and move down the slope through runoff.     

Partially acidulated phosphate rocks: Controlled release phosphorus fertilizers for more sustainable agriculture

Phosphate rocks partially acidulated either with H₃PO₄ or H₂SO₄ were compared against SSP or TSP as phosphate fertilizers for permanent pasture. Eleven field trials were conducted over periods of up to 6 yrs. Fertilizers were surface applied annually. Initial soil pHw values ranged from 5.5–6.3 and Soil P retention from 25% to 97%. The PRs used for partial acidulation were unground or ground North Carolina PR, ground Khouribga PR, and a blend of ground PRs of North Carolina, Arad and Khouribga PRs. From the DM yields, fertilizer substitution values were calculated: fertilizer substitution value was the ratio of total P applied as superphosphate to total P as PAPR required to produce the same DM yield.Rates of dissolution of the PR component of PAPRs were also determined in soils collected from two trials.Agronomic results demonstrated that 30% acidulated phosphoric PAPRs (about 50% of total P as water-soluble P) were as effective as TSP, when the PR acidulated was from unground North Carolina PR. Results from one field trial indicated that when PAPR was from ground North Carolina PR, 20% acidulated product (water-soluble P 30–40% of total P) was equally effective as TSP. Replacement of ground North Carolina PR by a less reactive Khouribga PR did not appear to decrease the yield. Results indicated that per unit P released into soil solution, PAPRs were more efficient fertilizers than TSP. With annual applications, fertilizer substitution value of PAPR 30% tended to increase with time.Sulphuric PAPRs prepared from North Carolina PR were generally inferior to phosphoric PAPRs containing similar amounts of water-soluble P. This was attributed to the presence of CaSO₄ coatings.Abbreviations DM Dry matter - PAPR Partially acidulated phosphate rock - PR Phosphate rock - SSP Single superphosphate - TSP Triple superphosphate     

Dissolution of phosphorus from animal bone char in 12 soils

Heat-treated animal bone char (ABC) has not previously been evaluated for its potential as a phosphorus (P) fertilizer. ABC, Gafsa phosphate rock (GPR) and triple superphosphate fertilizer (TSP) were incubated in 12 soils. Dissolved-P was assessed by extraction with NaOH and bioavailability with the Olsen extractant. The rate of P dissolution from ABC was described almost equally well by the Elovich and Power equations. After 145 days, the fraction of P dissolved ranged from 0 to 73% and to 56% for ABC and GPR, respectively. The most important soil properties determining P dissolution from ABC were pH and P sorption. P dissolution was not significant at soil pH >6.1 (ABC) and >5 (GPR) and the lower the pH, the greater the Dissolved-P. Dissolved-P also correlated positively and significantly with inorganic P sorption, measured by the Freundlich isotherm and the P sorption index of Bache and Williams (1971). Soil pH and P sorption index could be combined in multiple regression equations that use readily measured soil properties to predict the potential for ABC dissolution in a soil. Dissolution of P from GPR correlated with soil pH and exchangeable acidity. In comparison with GPR, ABC was a better source of available P, assessed by Olsen-P. In most soils, ABC increased Olsen-P immediately after application, including soils of relatively high pH in which GPR was ineffective. ABC is a P fertilizer of solubility intermediate between GPR and TSP.     

Agronomic evaluation of modified phosphate rock products

Phosphorus (P) is critically needed to improve the soil fertility for crop production in large areas of developing countries. The high cost of conventional, water-soluble P fertilizers constrains their use by resource-poor farmers. Finely ground phosphate rock (PR) has been tested and used as a direct application fertilizer on tropical acid soils as a low-cost alternative where indigenous deposits of PR are located. However, direct application of PR with low reactivity or with inappropriate soil/crop combinations does not always give satisfactory results. Partial acidulation of PR (PAPR) or compaction with triple superphosphate (PR + TSP) or single superphosphate (PR + SSP) represent technologies that can be used to produce highly effective P fertilizers from those indigenous deposits. Numerous field trials conducted by IFDC in Asia, sub-Saharan Africa, and Latin America have demonstrated that PAPR at 40-50% acidulation with H₂SO₄ or at 20% with H₃PO₄ approaches the effectiveness of SSP or TSP in certain tropical soils and crops. This paper discusses how the agronomic effectiveness of PAPR is affected by mineralogical composition and reactivity of PR used and by soil properties and soil reactions. The paper also indicates that if a PR has high Fe₂O₃ + Al₂O₃ content, it may not be suitable for PAPR processing because of the reversion of water-soluble P to water-insoluble P during the PAPR manufacturing process. Under these conditions, compaction of PR with water-soluble P fertilizers (e.g. SSP, TSP) at P ratio of approximately 50:50 can be agronomically and economically attractive for utilizing the indigenous PRs in developing countries.     

Thermal and chemical stability of Cu–Zn–Cr-LDHs prepared by accelerated carbonation

Layered double hydroxides Cu_xZn_6 − xCr₂(OH)₁₆(CO₃)·4H₂O with different molar ratios of Cu/Zn/Cr were synthesized by accelerated carbonation. The products were characterized by XRD, SEM, FT-IR and TG-DTG-DSC-MS. The chemical stability was tested by the modified Toxicity Characteristic Leaching Procedure (TCLP). The results showed that the products were the mixture of Cu_xZn_6 − xCr₂(OH)₁₆(CO₃)·4H₂O and (CuZn)₂(CO₃)(OH)₂, with similar thermal behavior. All products were chemically stable with reduced leaching at pH > 6 (Cu²⁺, Zn²⁺) or > 5 (Cr³⁺).     

Effects of nutrient cycling on grain yields and potassium balance

Soybean-maize rotation is a profitable cropping system and is used under rain fed conditions in north China. Since crop yields have been reported to decrease when K fertilizers are not used, we analyzed the productivity trends, soil-exchangeable and non-exchangeable K contents, and K balance in a continuous cropping experiment conducted in an area with an alfisol soil in the Liaohe River plain, China. The trial, established in early 1990 and continued till 2007, included 8 combinations of recycled manure and N, P, and K fertilizers. In the unfertilized plot, the yields of soybean and maize were 1,486 and 4,124 kg ha⁻¹ respectively (mean yield over 18 years). The yields of both soybean and maize increased to 2,195 and 7,476 kg ha⁻¹, respectively, in response to the application of inorganic N, P, and K fertilizers. The maximum yields of soybean (2,424 kg ha⁻¹) and maize (7,790 kg ha⁻¹) were obtained in the plots under treatment with N, P, and K fertilizers and recycled manure. K was one of the yield-limiting macronutrients: regular K application was required to make investments in the application of other mineral nutrients profitable. The decrease in the yields of soybean and maize owing to the absence of K application averaged 400 and 780 kg ha⁻¹, respectively. Soybean seed and maize grain yields significantly increased with the application of recycled manure. For both these crops, the variation coefficients of grain were lower with treatments that included recycled manure than without treatment. After 18 years, the soil-exchangeable and non-exchangeable K concentrations decreased; the concentrations in the case of treatments that did not include K fertilizers were not significantly different. Treatment with N, P, and K fertilizers appreciably improved the fertility level of the soil, increased the concentration of soil-exchangeable K, and decreased the non-exchangeable K concentration. In soils under treatment with N, P, and K fertilizers and recycled manure, the soil-exchangeable and non-exchangeable K levels in the 0–20 cm-deep soil layer increased by 34% and 2%, respectively, over the initial levels. Both soil-exchangeable and non-exchangeable K concentrations were the highest with on treatment with N, P, and K fertilizers and recycled manure, followed by treatment with N, P, and K fertilizers. These concentrations were lowest in unfertilized soils; the other treatments yielded intermediate results. The results showed a total removal of K by the crops, and the amount removed exceeded the amount of K added to the soil; in treatments that did not include K fertilizers, a net negative K balance was observed, from 184 to 575 kg ha⁻². The combined use of N, P, and K fertilizers and recycled manure increased the K content of the 0–20 cm-deep soil layer by 125% compared to the increase obtained with the application of N, P, and K fertilizers alone. The results clearly reveal that current mineral fertilizer applications are inadequate; instead, the annual application of recycled manure along with N, P, and K fertilizers could sustain future yields and soil productivity.     

Comparison of greenhouse and 32P isotopic laboratory methods for evaluating the agronomic effectiveness of natural and modified rock phosphates in some acid soils of Ghana

Phosphorus deficiency is one of the major constraints for normal plant growth and crop yields in the acid soils of Ghana and therefore addition of P inputs is required for sustainable crop production. This is often difficult, if not impossible for small-scale farmers due to the high cost of mineral P fertilizers and limited access to fertilizer supplies. Direct application of finely ground phosphate rocks (PRs) and their modified forms have been recommended as alternatives for P fertilization. The direct application of the natural and modified PRs to these acid soils implies the need to predict their agronomic effectiveness of the PRs in the simplest and most cost-effective manner. In this study the classical greenhouse pot experiment was compared to the ³²P isotopic kinetics laboratory method for evaluating the agronomic effectiveness of natural and modified Togo PR in six highly weathered Oxisols from southwest Ghana. In the ³²P isotopic kinetics laboratory experiment the six soil samples were each fertilised at the rate of 50 mg P kg^–1 soil in the form of triple superphosphate (TSP), Togo PAPR-50%, and Togo PR, respectively. Controls without P amendment were also included. Isotopic exchange kinetics experiments were carried out on two sets of samples, immediately after P fertilizer additions (without incubation) and after 6 weeks of incubation under wet conditions and at a room temperature of 25 °C. In the greenhouse pot experiment, P fertilizers in the form of Togo PR, Togo PAPR, Mali PR and TSP were each applied to the six soils at rates equivalent to 0, 30, 60, and 120 kg P ha^–1, respectively. The P fertilizers were mixed with the soils and maize (Zea mays L.) variety Obatanpa was grown for 42 days before harvest. The isotopic kinetics data of the control samples indicated that 5 of the studied soils had very low P fertility status as reflected by their low P concentrations in solution (C_P<0.02 mg P l^–1) and low exchangeable P (E₁min < 5 mg P kg^–1). The capacity factor and the fixation index of the soils were variable. Application of water-soluble P as TSP increased both the C_P and E₁ values of all the soils above the critical levels. Togo PR was least effective among the fertilizers tested for all soil soils, except in Boi soil. Acidulation of Togo PR (Togo PAPR-50%) was an effective means to increase its agronomic effectiveness. Direct application of natural Togo PR would be only feasible in the Boi soil series as reflected by its high Pdff% value in soil solution. Incubation with the P fertilizers caused an increase in the soil pH and a decline in the effectiveness of the applied P fertilizers, irrespective of the soil and the fertilizer utilized. Based upon the results of the greenhouse pot experiment, the relative crop response index (RCRI) in terms of increasing dry matter yield and P uptake followed the order of TSP > PAPR = Mali PR >Togo PR = Control. Both the laboratory index, Pdff% in soil solution derived from the isotopic method and the RCRI values obtained from the pot experiment produced similar results in ranking the P fertilizers tested according to their agronomic effectiveness. The isotopic kinetic method may be considered as an alternative to both greenhouse and field methods in the evaluation of agronomic effectiveness of P fertilizers in tropical acid soils when it offers comparative advantages in assessing the soil P status and its changes. But trained staff and adequate laboratory facilities are needed to perform this technique. Also the method can be used as a reference for comparison purposes as in this case. Further research is needed to assess the overall agronomic effectiveness (immediate and residual effects) of PR sources in predominant cropping systems of this region of Ghana.     

Agronomic evaluation of fertilizer products derived from Sukulu Hills phosphate rock

Partial acidulation of phosphate rock (PR) or compaction of PR with soluble P fertilizers can improve the usefulness of unreactive PR for use as P fertilizer. A greenhouse study was conducted to evaluate nonconventional phosphate fertilizers derived from a low reactive Sukulu Hills PR from Uganda. Raw PR (which contained 341.0 g kg^–1 Fe₂O₃), beneficiated or concentrate PR, partially acidulated PR (PAPR) and PR compacted with triple superphosphate (TSP) were evaluated. Compacted materials had a P ratio of PR:TSP = 50:50. PAPR materials were made by 50% acidulation with H₂SO₄. TSP was used as a reference fertilizer. Fertilizers were applied to an acidic (pH = 5.4) Hiwassee loam (clayey, kaolinitic, thermic Rhodic Kanhapludults) at rates of 0, 50, 100, 200, 300 and 400 mg P kg^–1 soil. Two successive corn (Zea mays L.) crops were grown for 6 weeks. Compacted concentrate PR + TSP and raw PR + TSP were 94.4 and 89.7% as effective as TSP, respectively, in increasing dry-matter yields for the first corn crop. PAPR from the concentrate was 54.8% as effective as TSP. Raw PR, concentrate PR and the PAPR from the raw PR were ineffective in increasing dry-matter yields. The same trends were obtained when P uptake was used to compare effectiveness. Ineffectiveness of the raw PR and its corresponding PAPR was attributed to a high Fe₂O₃ content in the raw PR. Bray I and Pi paper were found to be nearly equally suitable at estimating available P in the soils treated with responsive fertilizer materials. Mehlich 1 overestimated available P in soil treated with raw PR, concentrate PR or the PAPR from the raw PR.     

Soil organic carbon fractions after 16-years of applications of fertilizers and organic manure in a Typic Rhodalfs in semi-arid tropics

Agricultural soils can act as a potential sink of the increased carbon dioxide in the atmosphere if managed properly by application of organic manures and balanced fertilizers. However, the rate of carbon (C) sequestration in soils is low in warm climates and thus the short term changes in soil organic carbon (SOC) contents are almost negligible. Therefore, the knowledge about other C fractions that are more sensitive or responsive and indicative of the early changes in SOC can help to determine the effect of the management practices on soil C sequestration. The objective of this study was to determine the soil C sequestration after 16-years of applications of chemical fertilizers and farmyard manure (FYM) to rice (Oryza sativa)—cowpea (Vigna unguiculata) rotation system in a sandy loam soil (Typic Rhodalfs). The treatments were—(1) one control (no fertilizer or FYM); (2) three chemical fertilizer treatments [100 kg N ha⁻¹ (N), 100 kg N ha⁻¹ + 50 kg P₂O₅ ha⁻¹ (NP), 100 kg N ha⁻¹ + 50 kg P₂O₅ ha⁻¹ + 50 kg K₂O ha⁻¹ (NPK)]; (3) one integrated treatment [(50 kg N ha⁻¹ + 25 kg P₂O₅ ha⁻¹ + 25 K₂O ha⁻¹) + (50 kg N ha⁻¹ from FYM)]; and (4) one organic treatment at10 Mg ha⁻¹ FYM. Compared to the control treatment, the increase in SOC was 36, 33, and 19% greater in organic, integrated, and NPK treatments. The 16-years application of fertilizers and/or FYM resulted in much greater changes in water soluble C (WSC), microbial biomass C (MBC), light fraction of C (LFC), and particulate organic matter (POM) than SOC. Of the SOC, the proportion of POM was highest (24–35%), which was followed by LFC (12–14%), MBC (4.6–6.6%), and WSC (0.6–0.8%). The application of fertilizers and/or FYM increased the mean weight diameter of soil aggregates; thus provided physical protection to SOC from decomposition. Our results suggests that the application of fertilizers and/or FYM helps to sequester C in the soil and that the labile fractions of C can be used as indicators to determine the amount of C sequestered as a result of different management practices.     

Nitrogen leaching and plant uptake from controlled-release fertilizers

Controlled-release N fertilizers are commonly used in the production of container-grown ornamental crops, yet the relative effects of various nutrient sources on N leaching are not well known. A 27-week experiment was conducted to evaluate N leaching loss and plant growth following two applications of six controlled-release N fertilizers and one soluble N fertilizer to container-grownEuonymus patens Rehd. The controlled-release fertilizers evaluated were (noncoated) isobutylidene diurea, oxamide, urea formaldehyde, and (coated) Osmocote, Prokote Plus, and sulfur-coated urea. Of the fertilizers tested, the coated fertilizers generally out-performed the noncoated fertilizers in reducing N leaching losses, stimulating plant growth, and increasing tissue N concentrations. Low N concentrations in the leachate of some treatments indicated efficient nutrient use by the plant. In other treatments, low N concentrations in the leachate merely reflected incomplete N release from the fertilizer. A daily application of NH₄NO₃ resulted in a constant rate of N loss but was not the most effective in promoting growth. Plant growth, tissue N concentrations, and N leaching losses were all increased by doubling the fertilizer application rate from 1 kg N m^–3 to 2 kg N m^–3.     

Wheat Responses in Semiarid Northern Ethiopia to N2 Fixation by Pisum Sativum Treated with Phosphorous Fertilizers and Inoculant

Nitrogen fixation (N₂) by leguminous crops is a relatively low-cost alternative to N fertilizers for smallholder farmers in Africa. Nitrogen fixation in pea (Pisum sativum L. cv. Markos) as affected by phosphorus (P) fertilization (0, 30 kg P ha⁻¹) and inoculation (uninoculated and inoculated) in the semiarid conditions of Northern Ethiopia was studied using the ¹⁵N isotope dilution method and locally adapted barley (Hordeum vulgare L. cv. Bureguda) as reference crop. The effect of pea fixed nitrogen (N₂) on yield of the subsequent wheat crop (Triticum aestivum L.) was also assessed. Phosphorus and inoculation significantly influenced nodulation at the late flowering stage and also significantly increased P and N concentrations in shoots, and P concentration in roots, while P and N concentrations in nodules were not affected. Biomass, pods m⁻² and grain yield responded positively to P and inoculation, while seeds pod⁻¹ and seed weights were not significantly affected by these treatments. Phosphorus and inoculation enhanced the percentage of N derived from the atmosphere in the whole plant ranging from 53 to 70%, corresponding to the total amount of N₂ fixed varying from 55 to 141 kg N ha⁻¹. Soil N balance after pea ranged from − 9.2 to 19.3 kg N ha⁻¹ relative to following barley, where barley extracted N on the average of 6.9 and 62.0 kg N ha⁻¹ derived from fertilizer and soil, respectively. Beneficial effects of pea fixed N₂ on yield of the following cereal crop were obtained, increasing the average grain and N yields of this crop by 1.06 Mg ha⁻¹ and 33 kg ha⁻¹, respectively, relative to the barley–wheat monocrop rotation. It can be concluded that pea can be grown as an alternative crop to fallow, benefiting farmers economically and increasing the soil fertility.     

The first polypseudo-rotaxane structure based on the Wells–Dawson polyoxometalate

A polyoxometalate-based compound, (bix)[Cu(bix)][Cu₂(bix)₂(P₂W₁₈O₆₂)]·2H₂O (1) (bix = 1,4-bis(imidazol-1-ylmethyl)benzene), was hydrothermally synthesized, and characterized by elemental analyses, IR spectroscopy, thermogravimetric analysis, and single X-ray diffraction. Compound 1 exhibits the 1D + 1D polypseudo-rotaxane structure consists of two parts: the P₂W₁₈–Cu₂–(bix)₂ chain which contains 26-membered Cu₂(bix)₂ macrocycles and the 1D Cu-bix line. Remarkably, it represents the first polypseudo-rotaxane structure based on the Wells–Dawson polyoxometalate.