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1.
The total specific heat of YBa2Cu3O6.95 single crystals includes contributions from phonons and spin-1/2 particles, as well as electronic contributions. The electronic specific heat is described by a quadratic term T2 in zero field and a linear term [(0)+(H)]T which is increased when a magnetic field H is applied perpendicular to the CuO2 planes. In agreement with d-wave superconductivity, we find that n/Tc and (H)n(H/Hc2)1/2, where n is the coefficient of the normal-state linear term. The H1/2 dependence of the density of states at the Fermi level was predicted by G. Volovik for lines of nodes in the gap: the quasiparticles which contribute to this density of states are close to the nodes in momentum space and are located outside the vortex core.  相似文献   

2.
Precise parallel- and tilted-field radiofrequency size-effect measurements of the temperature dependence of the electron scattering frequency v(T) have been made on symmetric orbits on the first-, second-, and third-band Fermi surface sheets in samples with normals 11\-20 and 10\-10. The limiting point measurements on the third-band lens near 0001 provide the clearest evidence for a T 2 contribution to v(T) that is the right order of magnitude for electron-electron scattering in cadmium. In parallel field measurements on orbits on the first and second bands (including a broken orbit) we find v(T) T 2 + T 3. On these orbits the values for are 5–20 times larger than for the limiting point and other orbits on the third band. The temperature dependence of v(T\> 2 K) on extremal, limiting point, and open orbits on the second- and third-band Fermi surface sheets can be well accounted for by a simple plane wave model for electron-phonon intersheet scattering. This contribution to v(T) turns on approximately as exp (–T t /T) above T t /10, where T t is the minimum gap temperature on the orbit for intersheet scattering by quasi-transversely polarized phonons. The fitted gap temperatures as well as the other parameters of the plane wave model agree well with the known dimensions of the Fermi surface of cadmium. While clear evidence is lacking, we note that this intersheet scattering model can also be used to explain the large T 2 coefficients obtained for the first- and second-band orbits, where, in fact, one has gap temperatures T t smaller than 1 K.Supported by the Fonds National Suisse de la Recherche Scientifique.  相似文献   

3.
The Gibbs' energies of formation of BaCuO2, Y2Cu2O5 and Y2BaCuO5 from component oxides have been measured using solid state galvanic cells incorporating CaF2 as the solid electrolyte under pure oxygen at a pressure of 1.01×105 Pa BaO + CuO BaCuO2 G f,ox o (± 0.3) (kJ mol–1)=–63.4–0.0525T(K) Y2O3 + 2CuO Y2Cu2O2 G f,ox o (± 0.3) (kJ mol–1)=18.47–0.0219T(K) Y2O3 + BaO + CuO Y2BaCuO5 G f,ox o (± 0.7) (kJ mol–1)=–72.5–0.0793T(K) Because the superconducting compound YBa2Cu3O7– coexists with any two of the phases CuO, BaCuO2 and Y2BaCuO5, the data on BaCuO2 and Y2BaCuO5 obtained in this study provide the basis for the evaluation of the Gibbs' energy of formation of the 1-2-3 compound at high temperatures.  相似文献   

4.
The shear viscosity (T) in the Balian-Werthamer (BW) state of superfluid 3 He is calculated variationally throughout the region 0t 1(t=T/T c) from the transport equation for Bogoliubov quasiparticles. Coherence factors are treated exactly in the calculation of the collision integral. The numerical result for =s= s(T)/n(Tc) agree very well with experiment in the range 0.8t1.0. Analytic expressions = 0.577 (1–1.0008t) and =1–(23/64) [=(T)/k B T] are obtained in the low-temperature region and in the vicinity ofT c, respectively. From the numerical analysis it is shown that the latter equation is valid only in the temperature range 0.9997t1.0.Supported by the Research Institute for Fundamental Physics, Kyoto University.  相似文献   

5.
We have measured ac susceptibility, nuclear magnetic resonance, and nuclear heat capacity of two PtFe x samples with concentrations of magnetic impurities x = 11 ppm and 41 ppm at magnetic fields (0 ± 0.05) mTB248 mT. The susceptibility data have been measured at temperatures of 0.3 KT100 mK, no hint for nuclear magnetic ordering could be detected to a temperature of 0.3 K. The nuclear heat capacity data taken at 1.4 KT10 mK show enhanced values which scale with x at low polarization. This effect is described by a model assuming an internal magnetic field caused by the impurities. No indication for nuclear magnetic ordering could be detected to 1.4 K. The nuclear magnetic resonance experiments have been performed on these samples at 0.8 KT0.5 mK and 2.5 mTB22.8 mT as well as on three other samples with x = 5, 10, 31 ppm in a different setup at 40 KT0.5 mK and at 5.4 mTB200 mT. Spin-lattice and effective spin-spin relaxation times 1and 2 * of 195 Pt strongly depend on x and on the external magnetic field. No temperature dependence of 1and 2 * could be detected and the NMR data, too, give no hint for nuclear magnetic ordering to 0.8 K.  相似文献   

6.
Measurements of the pressure coefficient (P/T),x are reported for a 3 He- 4 He mixture with a mole fractionX=0.805 of 3 He in the neighborhood of the liquid-vapor critical point. These include data on 16 isochores taken over the density interval–0.50.5 and over the temperature range–0.1 t0.1, where =(– c )/ c andt=(T-T c )/T c ,with c andT c ,respectively, the critical density and temperature of the mixture. From the discontinuity of (P/T),x at the boundary between the two-phase and the one-phase regions we determine the dew-bubble curve nearT c with better precision than was done in recentPVT experiments. From the extrapolation of data not approachingT c closer than1 mK, (P/T),x along the critical isochore appears to be discontinuous atT c ,while for the isochore / c 0.92, (P/T),x is continuous across the dew curve. It is found that this latter isochore cuts the dew curve at its highest temperature. These observations are discussed in terms of general thermodynamic arguments and theoretical predictions of the asymptotic behavior. We calculate (P/T),x from the scaling equation of state proposed by Leung and Griffiths for 3 He- 4 He mixtures, using their numerical parameters. In spite of some systematic deviations, especially in the two-phase region, there is in general good agreement with experimental results. In particular, the shape of the measured dew-bubble curve and the apparent discontinuity of (P/T),x along the critical isochore show excellent agreement with theory.Work supported by a grant from the National Science Foundation. A report of this work has been presented at the Washington Meeting of the APS [Bull. Am. Phys. Soc. 20, 618 (1975)].  相似文献   

7.
Energy losses to radiation of internal waves during the vertical motion of a point dipole in two-dimensional and three-dimensional cases are computed.Notation o(z), po(z) density and pressure of the ground state - z vertical coordinate - v, p, perturbed velocity, pressure, and density - H(d 1n o/dz)–1 characteristic length scale for stratification - N=(gH–1–g2c o –2 )1/2 Weisel-Brent frequency - g acceleration of gravity - co speed of sound - vertical component of the perturbed velocity - V vector operator - k wave vector - frequency - d vector surface element - W magnitude of the energy losses - (t), (r) (x)(y)(z) Dirac functions - vo velocity of motion of the source of perturbations - d dipole moment of the doublet - o,l length dimension parameters - o intensity of the source Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 4, pp. 619–623, October, 1980.  相似文献   

8.
The shear viscosity of fluids exhibits an anomalous enhancement in the close vicinity of the critical point. A detailed experimental study of the viscosity of steam in the critical region has been reported by Rivkin and collaborators. A reanalysis of the experimental data indicates that the behavior of the viscosity of steam near the critical point is similar to that observed for other fluids near the critical point. An interpolating equation for the viscosity of water and steam is presented that incorporates the critical viscosity enhancement.Nomenclature a critical region equation of state parameter - a k coefficients in equation for 0 - a ij coefficients in equation for ¯ - b critical region equation of state parameter - c p specific heat at constant pressure - c v specific heat at constant volume - k critical region equation of state parameter - k B Boltzmann constant - P pressure - P r 22.115 MPa - P * P/P r - P c critical pressure - P i coefficients in critical region equation of state - R~P (P-P c )/P c - q parameter in equation for critical viscosity enhancement - r parametric variable in critical region equation of state - T temperature in K (IPTS-48) - T r 647.27 K - T * T/T r - T c critical temperature - T (T–T c )/T c - V volume - critical exponent of specific heat - critical exponent of coexistence curve - critical exponent of compressibility - critical exponent of chemical potential at T=T c - dynamic viscosity - 0 lim 0 - ¯ normal viscosity - critical viscosity enhancement - ¯ thermal conductivity - normal thermal conductivity - critical thermal conductivity enhancement - parametric variable in critical region equation of state - correlation length - 0 correlation length amplitude above T c at = c - critical exponent of correlation length - density - r 317.763 kg/m3 - * / r - c critical density - (– c )/ c - p estimated error of pressure - T estimated error of temperature - estimated error of viscosity - exponent of critical viscosity enhancement - t (/P) T symmetrized compressibility - T * T P r / r 2 - t t P c / c 2  相似文献   

9.
The effect of the type of energy supply on the formation of temperature and concentration fields in the thermal processing of polymer compositions is considered.Notation T0, T initial and current temperature of the coating - Tm temperature of the air - =(T-To)/(Tm-T0) dimensionless temperature of the coating - a thermal diffusivity - A absorption power of the coating - D diffusion coefficient - thermal conductivity - c thermal capacity - density - k convective heat transfer coefficient - i number of moles of reacting groups per unit volume of polymer - K0 factor in front of the exponential - R gas constant - u concentration - Q thermal effect of the reaction - qn density of the incident radiant flux - =x/ dimensionless coordinate over the thickness of the coating - Ki=Aqn /(Tm-T0) Kirpichev criterion characterizing the thermal effect of the reaction - Kip=Qi/c (Tm-T0) analog of the Predvoditelev criterion, characterizing the rate of occurrence of a chemical excess in the system - Bu= Bouguer criterion - Lu=D/a Lykov number - Fo=a/2 Fourier number - Bi= k Biot number Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 26–33, July, 1980.  相似文献   

10.
We present steady-state measurements of the thermal diffusion ratiok T and of the heat conductivity for three dilute mixtures of3He in4He with concentrations 9×10–3X(3He)5×10–2 at saturated vapor pressure in the normal phase close to the superfluid transition. The data are compared with predictions by Dohm and Folk from the renormalization group (RG) theory. From auxiliary determinations of thermodynamic derivatives for these mixtures, we obtain the separation factor =–(k T /T)×(/X) T,P /(/T) X,P above T over the range wherek T is positive. Here is the mass density. From the transients of X(t) as a function of time, we obtain an estimation for the mass diffusion coefficientD and compare the results with predictions by Dohm and Folk and with results from other experiments.  相似文献   

11.
Dielectric and electro-optic properties of phenyl ester FLC mixture have been studied in detail. Dielectric relatation spectroscopy was used to study the molecular dynamics and dipolar ordering. In the SmA* phase, this is accompanied by a sharp increase in the dielectric strength s on approaching T c. At such high frequency (2 MHz) is usually negative in the SmC* and SmA* phase. In the N* phase, at lower frequencies, had a weakly positive value. In the SmC* phase, is positive and its maximum value is less than 0.1. The dielectric biaxiality is discussed as an order parameter of the tilted smectic phase. It is verified that if the tilt angle increases according to (T CT), the biaxiality increases according to (T CT)2. A critical exponent for and are 0.27 and 0.54, respectively. The rotational viscosity for soft mode is of 10 Nsec/m2 in the SmA* phase. The activation energy for the rotational dynamics of Goldstone mode is estimated to be 1.4 eV from an Arrhenius plot. Optical response time is of about 50 s at room temperature in SmC* phase, and is on the order of 10 s in the N* phase and almost independent of the applied field.  相似文献   

12.
Results concerning V3Si films produced by a simple annealed multilayer technique are reported together with X-ray diffraction patterns, Auger spectroscopy, and Rutherford backscattering analysis. Low-temperature electrical resistivity measurements are discussed. It is found that the V3Si films exhibit aT 2 dependence in the temperature rangeT c T23 K and aT 2.6 dependence in the rangeT c T40 K. The normal-state resistivity in the whole temperature range (T c T600 K) is analyzed in the framework of Cote-Meisel theory. Consistent values of the saturation resistivity m and of the Debye temperature are obtained by fitting the experimental data with the Cote-Meisel expression for (T).  相似文献   

13.
Ultrasonic wave velocity measurements have been used to determine the elastic stiffness moduli and related elastic properties of high-purity, dense -Si3N4 ceramic samples as functions of temperature in the range 150–295 K and hydrostatic pressure up to 0.2 GPa at room temperature. Due to its covalently bonded, rigid structural framework -Si3N4 is an elastically stiff material; the elastic stiffness moduli of the ceramic at 295 K are: C L = 396 GPa, = 119 GPa, B S = 238 GPa, E = 306 GPa, Poisson's ratio = 0.285. The longitudinal elastic stiffness C L increases with decreasing temperature and shows a knee at about 235 K; the decrease in slope below the knee indicates mode softening. The shear elastic stiffness shows mode softening which results in a plateau centred at about 235 K and an anomalous decrease with further reduction in temperature. The hydrostatic-pressure derivatives of elastic stiffnesses at 295 K are (C L/P) P=0 = 4.5 ± 0.1, (B S/P) P=0 = 4.3 ± 0.1 and (/P) P=0 = 0.17 ± 0.02 (pressure < 0.12 GPa). An interesting feature of the nonlinear acoustic behaviour of this ceramic is that, in the pressure range above 0.12 GPa, the values obtained for (/P) P=0 and the shear mode Grüneisen parameter (S) are small and negative, indicating acoustic-mode softening under these higher pressures. Both the anomalous temperature and pressure dependences of the shear elastic stiffness indicate incipient lattice shear instability. The shear S(=0.005) is much smaller than the longitudinal L(=1.18) accounting for the thermal Grüneisen parameter th(=1.09): since the acoustic Debye temperature D(=923 ± 5 K) is so high, the shear modes play an important role in acoustic phonon population at room temperature. Hence knowledge of the elastic and nonlinear acoustic properties sheds light on the thermal properties of ceramic -Si3N4.  相似文献   

14.
The melt spinning of Pb-Bi-Ge alloys with Pyrex glass was investigated as a means of producing a superconducting long filament with highT c. Continuous filaments with maximumT c of more than 10 K of Pb100-x-y Bi x Ge y (15x37 and 725) were obtained from the molten state at 1500 K with a winding speed of 0.95 m sec–1. The Pb49Bi33Ge18 filament, which was 34×10–6 m diameter and a ductile material with a tensile strength of 20 MPa and elongation of 2.7%, exhibited superconductivity at the highestT c of 14.3 K. These filaments were found to be polycrystalline with a grain size of more than 5000×10–10 m and had a mixed structure of germanium (diamond) (h c p) and bismuth phases. The germanium element distributed homogeneously in the filament.  相似文献   

15.
The electrical resistivity (T) of V-rich V3Si single crystals (T c-11.4 K) was measured from 4.2 to 300 K along the directions of [1 0 0] and [1 1 1] before and after plastic deformation at 1573 K. Anisotropy of (T) was observed although V3Si has the cubic A15 structure. Plastic deformation does not affect the normal-state (T) behaviour but changes the normal-superconducting transition width Tc. At low temperatures (T c<T 40 K), (T) varies approximately as T n where n-2.5 and this behaviour does not contradict the (0)- phase-diagram plot proposed by Gurvitch, where is the electron-phonon coupling constant and (0) is the residual resistivity.  相似文献   

16.
We have performed high-resolution measurements of the magnetic field (0 TB9 T) and temperature (10 KT<140 K) dependence of the longitudinal and transverse Hall thermal conductivity of a twinned YBa2Cu3O6.95 single crystal. We have used and compared two recently published methods to extract the thermal Hall angle H(T, B). Our results indicate that cot(H) varies quite accurately as T4 in the intermediate temperature range 0.3c. It shows a well defined minimum at Tm20 K which resembles that observed in the c-axis microwave conductivity. The electronic part of the longitudinal and the transverse thermal conductivity show the scaling behavior for transport properties predicted for d-wave superconductors in the temperature range 18 KT30 K.  相似文献   

17.
The thermal conductivity and the electrical conductivity of niobium crystals and niobium films have been investigated in the normal state from 9 to 50 K. The deviations from the Matthiessen rule, w=/T+T2, have been studied in detail for the thermal case. The investigation shows a slight dependence of the electron-phonon scattering coefficient upon the impurity content of the sample. With the specific electrical residual resistivity 0 as the measure for the impurity content, the following correlation can be formulated: =1.2×10-2[0/-cm)]0.04, being obtained in cm/W K. Above 20 K an additional scattering mechanism occurs. The temperature dependence of the additional resistance W between 20 and 50 K is proportional to T 5.5 ··· T 4. Possible causes of this phenomenon are discussed. For the discussion, all the data available in the literature on the thermal conductivity of niobium in this temperature region are used.  相似文献   

18.
An equation is obtained for the breakup radius with consideration of tipping moments and Laplacian pressure forces acting on the liquid ridge at the critical point.Notation K, n rhenological constants - density - surface tension - r current cup radius - R maximum cup radius - rc critical radius for film breakup - ¯r=¯r=r/R dimensionless current radius - ¯rc=rc/R dimensionless critical radius - 0, c actual and critical film thicknesses - current thickness - Rr ridge radius - h0 ridge height - h current ridge height - 0 limiting wetting angle - current angle of tangent to ridge surface - angle between axis of rotation and tangent to cup surface - angular velocity of rotation - q volume liquid flow rate - v1 and v meridional and tangential velocities - =4vv lm/r,=4vm/r dimensionless velocities - M moments of surface and centrifugal forces - Mv moment from velocity head - pr pressure within ridge - Pvm pressure from velocity head - pm, ppm pressures from centrifugal force components tangent and normal to cup surface - deviation range of breakup radius from calculated value - ¯rmax, ¯rmin limiting deviations of breakup radius - c angle of tangent to curve c0=f(¯r) at critical point - t random oscillation of ratio c/c Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 51–56, July, 1980.  相似文献   

19.
Plastic zones generated in double-cantilever-beam specimens of an Fe-3Si steel are revealed by etching. Zones corresponding to relative stress intensity levels in the range 0.4 (in.)<K/Y< 0.8(in.), beam height to length ratios H/W = 0.125 and 0.35, and conditions approaching plane strain are examined. The fürthest extent of the zones, p 0.13 (K/Y)2, is about half that previously observed in plates loaded in tension to comparable K-levels. The results are consistent with previous, measurements by Clark and lend support to Wilson's calculations. At high stress levels, when the zone size to beam height ratio /H 0.09, the zone begins to tilt backwards and undergoes a transition from a crack- to a beam-zone. Implications of this transition with respect to the minimum beam height requirement are examined.
Zusammenfassung In Doppelkamileverproben aus Fe-3 Si-Stahl gebildete plastische Zonen werden durch Ätzen sichtbar gemacht. Zonen welche einem relativen Spannungsintensitätsniveau im Bereich von 0,4,(in.)<K/Y< 0,8,(in.) entsprechen, Höhen zu Längen-Verhältnisse H/W = 0,125 und 0,35 sowie Bedingungen, welche sich der planen Verformung annähern, werden untersucht.Die größte Ausbreitung dieser Zonen, 0,13 (K/Y)2 erreicht nur die Hälfte derer die früher in Blechen beobachtet worden waren, welche bei gleichen K-Werten Zugspannungen ausgesetzt wurden. Diese Ergebnisse sind in guter Übereinstimmung mit den schon von Clark durchgeführten Messungen und bekräftigen die Berechnungen von Wilson.Bei hohem Spannungsniveau, wo das Verhältnis /H 0,09 ist, beginnt die Zone sich nach rückwärts zu beugen und sich vom Rissbereich ins Innere des Trägers zu verschieben. Die sich hieraus ergebende Folgerung für die erforderliche minimale Trägerhöhe wird untersucht.

Résumé Les zones de déformation plastique qui se développent dans des éprouvettes en forme de double poutre cantilever d'acier Fe-3Si ont été mises en évidence par attaque chimique. On envisage les zones correspondant aux conditions suivantes: niveaux relatifs de l'intensité de contraintes compris dans la fourchette: 0,4(in)<K/y<0,8(in) et rapports hauteur/longueur de poutre H/W = 0,125 et 0,350. On examine les conditions voisines de l'état plan de déformation. L'épanouissement le plus large des zones, exprimé par 0,13 (K/Y)2, est la moitié de celui que l'on a observé précédemment dans le cas de tôles sollicitées en traction à des niveaux K comparables.Ces résultats sont compatibles avec les mesures qu'a obtenues Clark, et confirment les calculs de Wilson. Sous contraintes élevées, lorsque le rapport de la dimension de la zone plastifiée à la hauteur de la poutre /H 0,09, cette zone commence à se cambrer vers l'arrière et passe de la fissure au corps même de la poutre.On examine les implications que comporte cette transition sur les hauteurs minimum de poutres à observer.
  相似文献   

20.
The rejuvenation procedures to recover the creep properties of nickel-base superalloys by atmospheric pressure heat treatment and hot isostatic pressing techniques have been reviewed in detail. It is very important that such treatments be applied at an optimum stage in the service life of a turbine blade. In other words, the rejuvenation procedures must be applied early enough to prevent catastrophic failures or irreparable damage and late enough to give a cost-effective benefit. The optimum stage at which to undertake a rejuvenation procedure to extend the creep lives of superalloys is immediately prior to the tertiary stage. By using these techniques it is not possible to extend the creep lives of superalloys indefinitely because of the accumulation of some permanent damage incurred during service conditions.Nomenclature ERF Economic repair factor - P r Price of repaired and rejuvenated part - P n Price of new part - L n Potential operational life of new part - L r Potential operational life of repaired/rejuvenated part - N Cavity density or number of cavities per unit area (mm–2) - n v Number of cavities per unit volume (mm–3) - Creep strain - 1 Maximum principal stress (MPa) - ¯ von Mises effective shear stress (MPa) - t f Time to failure - t t Time to commencement of tertiary creep - Creep damage tolerance parameter - f Strain at fracture (or failure) - T m Absolute melting temperature - 0 Friction stress - r Spherical radius of cavities - 2x Intercavity spacing - Grain boundary width - P I Cavity gas pressure - P H External hydrostatic pressure - Atomic volume - k Boltzmann constant - T Absolute temperature - Surface energy of the cavity - D b Grain boundary diffusion coefficient - d Ductility recovery parameter - Strain to reach the same acceleration after recovery annealing - 0 Strain necessary for standard material to reach a given acceleration of the secondary-creep rate in the tertiary region - t Strain needed to have produced the reduced cavity volume after rejuvenation annealing - Creep rate - Secondary or minimum creep rate - 1 Strain previous to the regenerative annealing period - n Total number of strain/regenerative anneal cycles - v Recovery parameter for cavity volume - V 0 Original total cavity volume at the start of the recovery - V t Cavity volume after recovery annealing for a timet  相似文献   

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