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An excellent methodology for the synthesis of nanocomposite materials using a biodegradable polymer as matrix (polylactic acid, PLA) and functionalized by Fenton reaction carbon nanotubes (fMWCNTs) as reinforcement was developed. PLA was modified with benzoyl chloride and both modified materials were bounded covalently by esterification reaction. Infrared spectroscopy (FTIR) and thermogravimetry (TGA) studies were performed to verify the synthesis of the composites obtained. Films based on modified PLA reinforced with fMWCNTs (PLAmfMWCNTs) were conformed observing excellent dispersion of the filler in the PLA matrix. Finally it was shown that the addition of fMWCNTs improves Young’s modulus and strength without losing deformation. Also it was observed that the good stability of the film let us to process it until 300 °C. Taking into account all these results, the new biodegradable nanocomposite material developed could be very promising to be used in packaging and biomedical industries as a replacement of the synthetic materials. 相似文献
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以壳聚糖为吸附剂,戊二醛作为交联剂,采用反相悬浮交联法制备球状壳聚糖树脂,利用二硫化碳作为改性剂,在碱性条件下对壳聚糖树脂进行黄原酸化改性,制备成交联黄原酸化壳聚糖树脂(crosslinked xanthated chitosan resin,CXCR)。对CXCR进行红外表征,并研究了其对水溶液中棒曲霉素的吸附性能。结果表明,CXCR在棒曲霉素初始浓度为8 mg/L,CXCR用量为1 g/L,溶液p H值=4,25℃下吸附16 h,吸附量可达6.53 mg/g,可有效地吸附水溶液中的棒曲霉素。CXCR对棒曲霉素的吸附符合拟二级动力学模型;吸附热力学符合Freundlich吸附等温线模型。CXCR有望作为一种新型的材料用于棒曲霉素的吸附,具有广阔的应用前景。 相似文献
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TiO2 thin films grown using microwave-activated solutions 总被引:2,自引:0,他引:2
E. Vigil L. Saadoun R. Rodriguez-Clemente J. A. Ayllon X. Domenech 《Journal of Materials Science Letters》1999,18(13):1067-1069
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Rolf D. Joerger Subramaniam Sabesan Donna Visioli Dave Urian Melissa C. Joerger 《Packaging Technology and Science》2009,22(3):125-138
Ethylene copolymer film was coated with chitosan by attachment of the polymer to the corona‐treated surface of the film, and the composite film was analysed for antimicrobial activity. The film was active against bacteria in 0.625 mM phosphate buffer; it reduced colony counts of Escherichia coli 25922 and of Listeria monocytogenes Scott A by 5 and 2–3 log10, respectively after 24 h exposure. The activity of the chitosan‐coated film against bacteria in buffer was increased when silver ions were incorporated into the films as demonstrated by complete killing of Escherichia coli O157:H7 DD3795 and the chicken exudate isolate Stenotrophomonas maltophilia within 2 h in buffer. The film was active against L. monocytogenes Scott A in 0.5% buffered peptone water up to a pH of about 7.0. Tests on beef and chicken meat exudates revealed antimicrobial activity of the film against Escherichia coli O157:H7 and L. monocytogenes Scott A of about 2 and 1–2 log10 reductions in colony‐forming units, respectively. The antimicrobial activity of the film against L. monocytogenes Scott A was also tested on turkey breast, and a log10 reduction of about 1.7 log10 units after 10 days and 1.2 log10 after 15 days at 4°C was achieved. Exposure to chitosan‐coated film and 350 MPa of pressure, 55°C or 1% sodium diacetate resulted in a synergistic effect. Copyright © 2008 John Wiley & Sons, Ltd 相似文献
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Hamilton V Yuan Y Rigney DA Puckett AD Ong JL Yang Y Elder SH Bumgardner JD 《Journal of materials science. Materials in medicine》2006,17(12):1373-1381
Chitosan has been researched for implant and wound healing applications. However, there are inconsistencies in reports on
the tissue and fibroblast responses to chitosan materials. These inconsistencies may be due to variations in chitosan material
characteristics. The aim of this study was to correlate fibroblast responses with known chitosan material characteristics.
To achieve this aim, chitosan was characterized for degree of deacetylation (DDA), molecular weight (MW), residual protein
and ash contents, and then solution cast into films and characterized for hydrophilicity by water contact angle. The films
were seeded with normal human dermal fibroblasts and the number of attached cells was evaluated for after 30 min. Cell proliferation
was evaluated over 5 days. This study found no relationship between DDA, contact angle, cell attachment, and or proliferation.
General trends were observed for increasing proliferation with increasing residual ash content and decreasing residual protein.
These data indicate that chitosan characteristics other than DDA may be important to their biological performance. 相似文献
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Abdul Razak Rahmat Wan Aizan Wan Abdul Rahman Lee Tin Sin A.A. Yussuf 《Materials science & engineering. C, Materials for biological applications》2009,29(8):2370-2377
When hydrophilic starch is incorporated into synthetic polymers, the resulting products are weakened, especially blending with hydrophobic polymers. Many researchers have been undertaking various approaches to improve compatibility of starch and synthetic polymers. However, no ultimate and comprehensive approach can be determined. This paper aims to investigate and discuss the improvement approaches which have been recently developed by researchers. Also, the extents of improvement are summarized as well. In order to simplify this review, synthetic polymers are categorized into polar and non-polar types. Low density polyethylene was studied as non-polar type polymer, while polyvinyl alcohol was studied to represent as polar type polymer. Both types of synthetic polymers were blended with starches and their results were reported well by researchers. All findings are very informative and further encourage research for other starch filled polymer systems as well. In short, appropriate modifications to starch filled polymer system would induce polarity of the materials and subsequently create harmonious intermolecular interactions among blending components for better product properties. 相似文献
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Ambalangodage C. Jayasuriya Ashkan Aryaei Ahalapitiya H. Jayatissa 《Materials science & engineering. C, Materials for biological applications》2013,33(7):3688-3696
The aim of this paper is to develop novel chitosan–zinc oxide nanocomposite films for biomedical applications. The films were fabricated with 1, 5, 10 and 15% w/w of zinc oxide (ZnO) nanoparticles (NPs) incorporated with chitosan (CS) using a simple method. The prepared nanocomposite films were characterized using atomic force microscopy, Raman and X-ray diffraction studies. In addition, nano and micro mechanical properties were measured. It was found that the microhardness, nanohardness and its corresponding elastic modulus increased with the increase of ZnO NP percentage in the CS films. However, the ductility of films decreased as the percentage of ZnO NPs increased. Cell attachment and cytotoxicity of the prepared films at days two and five were evaluated in vitro using osteoblasts (OBs). It was observed that OB viability decreased in films with higher than 5% ZnO NPs. This result suggests that although ZnO NPs can improve the mechanical properties of pure CS films, only a low percentage of ZnO NPs can be applied for biomedical and bioengineering applications because of the cytotoxicity effects of these particles. 相似文献
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The effects of interface, contact hardness, deformation, and adhesion of Al/Ni multilayered films under nanoindentation were investigated using molecular dynamics (MD) simulations. The results show that the indentation force of the sphere indenter is the largest among nanoindentations using sphere, cone, Vickers, or Berkovich type indenters at the same penetration depth. Force increasing, relaxation and adhesion took place during loading, holding depth and unloading, respectively. The interface occurred along the {111} (110) slip systems and the maximum width of the glide bands was about 1 nm. The reaction force and plastic energy of the indented films are also discussed. 相似文献
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Preparation of diamond-like carbon films by cathodic micro-arc discharge in aqueous solutions 总被引:1,自引:0,他引:1
Diamond-like carbon films (DLC) and silicon doped diamond-like carbon films were deposited on Ni substrate by cathodic micro-arc discharge at room temperature in aqueous solutions. The deposit potential was 130 V. The structure of the films was characterized by a scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Raman spectra and XPS analysis demonstrated that the films were diamond-like carbon clearly. SEM observation showed that the DLC films were uniform and the thickness was about 200 nm. Potentiodynamic polarization curve indicated the corrosion resistance of the Ni substrate was markedly improved by DLC films. 相似文献
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Li Zhao Jiang Chang Wanyin Zhai 《Journal of materials science. Materials in medicine》2009,20(4):949-957
Titania/chitosan composite scaffolds were prepared through a freeze-drying technique. The composite scaffolds were highly
porous with the average pore size of 120–300 μm, and the titania (TiO2) powders were uniformly dispersed on the surface of the pore walls. The compressive strength of the composite scaffolds was
significantly improved compared to that of pure chitosan scaffolds. Composite scaffold with 0.3 of TiO2/chitosan weight ratio showed the maximum compressive strength of 159.7 ± 21 kPa. Hepatic immortal cell line HL-7702 was used
as seeding cells on the scaffolds, and after different culture periods, cell attachment and function was analyzed. HL-7702
cells attached on the pore walls of the scaffolds with the spheroid shape after 1 day of culture, but more cell aggregations
formed within the TiO2/chitosan composite scaffolds as compared to pure chitosan scaffolds. Liver-specific functions, albumin secretion and urea
synthesis were detected using a spectrometric method. The results showed that albumin secretion and urea synthesis rate of
HL-7702 cells slightly decreased with the culture time, and there was no significant difference between composite scaffolds
and pure chitosan scaffolds. In conclusion, the TiO2/chitosan composite scaffolds possessed an improved mechanical strength compared to pure chitosan scaffolds and supported
the attachment and functional expression of hepatocyte, implying their potential application in liver tissue engineering. 相似文献
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A simple method was developed to produce silicon carbide foams using polysilane polymeric precursors. Polyurethane foams were immersed in polysilane precursor solutions to prepare pre-foams. Subsequently, these were heated in nitrogen at different temperatures in the range of 900°C to 1300°C. The silicon carbide foams produced in this manner showed well-defined open-cell structures and the struts in the foams were free of voids. The shrinkage which accompanies pyrolysis of the pre-foams was reduced with increasing the concentration of the polymeric precursor solutions. 相似文献
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The aim of the present research was to improve the impact strength of epoxy-based glass fiber-reinforced nanocomposites by the addition of polyethylene terephthalate (PET) fibers as reinforcement along with nanoclay. Hybrid nanocomposites containing clay as nano-filler and PET fibers as micro-reinforcement were fabricated. Nanocomposites with 1?phr clay and varying concentrations of PET fibers (1–3?phr) were processed using a vacuum-assisted hand layup. Addition of untreated PET fibers did not improve the impact strength of nanocomposites due to the lack of interaction between the inert PET fibers and other constituents. To improve the interfacial interaction, two different compatibilization procedures for the surface modification of PET fibers were used. In the first procedure, silane treatment of fibers was performed using two separate silane agents. In the second method, maleic anhydride (MAH) grafting was performed in the presence of ultraviolet radiations. Compatibilization of fibers was confirmed with scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) and Fourier transform infrared spectroscopy (FTIR). The results of impact and tensile testing showed an improvement of 19% in the impact strength of nanocomposites at 2?phr silane-treated PET fiber loading without significant loss in tensile strength. Finally, scanning electron micrographs of various nanocomposites were analyzed to correlate with the improved impact strength. 相似文献
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T. V. Safronova M. A. Shekhirev V. I. Putlyaev Yu. D. Tret’yakov 《Inorganic Materials》2007,43(8):901-909
Hydroxyapatite, Ca10(PO4)6(OH)2, powders with enhanced sinterability have been synthesized through precipitation from calcium nitrate and ammonium hydrogen phosphate solutions at pH 9, t= 60°C, and a Ca/P atomic ratio of 1.67, and their properties have been studied: phase composition, particle size distribution, loose density, and green density. The initial solution concentration is shown to influence the properties of the powders and the ceramics fabricated from them. Comparison of the particle size distributions in disaggregated powders and the grain size distributions in the ceramics indicates that the ceramics inherit the structure of the corresponding powders. Optimizing the synthesis conditions in order to enhance the sinterability of the powders, we obtained green compacts with the highest shrinkage rate in the range 850–950°C and shrinkage onset at 600°C, which is 100–150°C lower in comparison with powders synthesized in earlier studies from calcium nitrate and ammonium hydrogen phosphate. 相似文献