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1.
In this study, the graft copolymerization of methacrylic acid onto the biomass of baker's yeast was carried out in aqueous medium using potassium persulfate (PPS) as initiator. The poly (methacrylic acid) modified biomass obtained was characterized by Fourier transform infrared spectroscopy (FTIR), X‐ray photoelectron spectroscopy (XPS) and microscopic analyses. The number of functional groups was determined by potentiometric titration. The adsorption capacity of the modified biomass for Pb 2+, Cd 2+ and Cu 2+ showed a significant increase compared with the pristine biomass, due to the presence of a large number of functional groups. According to the Langmuir equation, the maximum uptake capacities ( qm) for Pb 2+, Cd 2+ and Cu 2+ were 243.9, 108.7 and 73.5 mg g ?1, respectively. Adsorption kinetics study showed that completion of the adsorption process needed only 30 min. The loaded biosorbent was regenerated using EDTA solution and used repeatedly three times with little loss of uptake capacity. Good results were obtained when the modified biomass was used to treat simulated wastewater containing Pb 2+, Cd 2+ and Cu 2+. Copyright © 2007 Society of Chemical Industry 相似文献
2.
Heavy metal ions such as Cu 2+ and Pb 2+ impose a significant risk to the environment and human health due to their high toxicity and non‐degradable characteristics. Herein, Al(OH) 3‐polyacrylamide chemically modified with dithiocarbamates (Al‐PAM‐DTCs) was synthesized using formaldehyde, diethylenetriamine, carbon disulfide, and sodium hydroxide for rapid and efficient removal of Cu 2+ and Pb 2+. The synthesized adsorbent was characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis, scanning electron microscopy–energy dispersive X‐ray spectroscopy analysis, and transmission electron microscope measurements. Al‐PAM‐DTCs showed rapid removal of Cu 2+ (<30 min) and Pb 2+ (<15 min) with high adsorption capacities of 416.959 mg/g and 892.505 mg/g for Cu 2+ and Pb 2+ respectively. Al‐PAM‐DTCs also had high capacities in removing suspended solids and metal ions simultaneously in turbid bauxite suspensions. FTIR, thermodynamic study, and elemental mapping were used to determine the adsorption mechanism. The rapid, convenient, and effective adsorption of Cu 2+ and Pb 2+ indicated that Al‐PAM‐DTCs has great potential for practical applications in purification of other heavy metal ions from aquatic systems. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45431. 相似文献
3.
Organofunctionalized nanostructured silica SBA-15 with tri(2-aminoethyl)amine tetradentate-amine ligand was synthesized and applied as adsorbent for the removal of Cu 2+, Pb 2+, and Cd 2+ from both synthetic wastewater and real paper mill and electroplating industrial effluents. The prepared materials were characterized by XRD, N 2 adsorption-desorption, TGA, and FT-IR analysis. The Tren-SBA-15 was found to be a fast adsorbent for heavy metal ions from single solution with affinity for Cu 2+, Pb 2+, than for Cd 2+ due to the complicated impacts of metal ion electronegativity. The kinetic rate constant decreased with increasing metal ion concentration due to increasing of ion repulsion force. The equilibrium batch experimental data is well described by the Langmuir isotherm. The maximum adsorption capacity was 1.85 mmol g ?1 for Cu 2+, 1.34 mmol g ?1 for Pb 2+, and 1.08 mmol g ?1 for Cd 2+ at the optimized adsorption conditions (pH=4, T=323 K, t=2 h, C 0=3 mmol L ?1, and adsorbent dose=1 g L ?1). All Gibbs energy was negative as expected for spontaneous interactions, and the positive entropic values from 103.7 to 138.7 J mol ?1 K ?1 also reinforced this favorable adsorption process in heterogeneous system. Experiment with real wastewaters showed that approximately a half fraction of the total amount of studied metal ions was removed within the first cycle of adsorption. Hence, desorption experiments were performed by 0.3M HCl eluent, and Tren-SBA-15 successfully reused for four adsorption/desorption cycles to complete removal of metal ions from real effluents. The regenerated Tren-SBA-15 displayed almost similar adsorption capacity of Cu 2+, Pb 2+, and Cd 2+ even after four recycles. The results suggest that Tren-SBA-15 is a good candidate as an adsorbent in the removal of Cu 2+, Pb 2+, and Cd 2+ from aqueous solutions. 相似文献
4.
Reusability and selective adsorption toward Pb 2+ with the coexistence of Cd 2+, Co 2+, Cu 2+ and Ni 2+ ions on chitosan/P(2-acrylamido-2-methyl-1-propanesulfonic acid- co-acrylic acid) [CS/P(AMPS- co-AA)] hydrogel, a multi-functionalized adsorbent containing –NH 2, –OH, –COOH and –SO 3H groups was studied. The CS/P(AMPS- co-AA) was prepared in aqueous solution by a simple one-step procedure using glow discharge electrolysis plasma technique. The reusability of adsorbent in HNO 3, EDTA-2Na and EDTA-4Na was investigated in detail. The competitive adsorption of the metal ions at the initial stage was compared between their equal mass concentration and equal molar concentration. In addition, the adsorption mechanism of the adsorbent for adsorption of Pb 2+ was also analyzed by XPS. The results showed that the optimum pH of adsorption was 4.8, and time of adsorption equilibrium was about 180 min. Adsorption kinetics fitted well in the pseudo second-order model. The equilibrium adsorption capacities of Pb 2+, Cd 2+, Co 2+, Cu 2+, and Ni 2+ at pH 4.8 were obtained as 673.3, 358.3, 176.7, 235.0 and 171.7 mg g ?1, in their given order. The adsorbent displayed an excellent reusability using 0.015 mol L ?1 EDTA-4Na solution as the eluent, and the desorption ratio could not correctly reflect the true characteristics of adsorption/desorption process. Moreover, the adsorbent showed good adsorption selectivity for Pb 2+. The molar adsorption capacity at the initial stage with equal molar concentration was more reliable than the mass adsorption capacity during the study of selective adsorption. According to the XPS results, the adsorption of Pb 2+ ions by the CS/P(AMPS- co-AA) absorbent could be attributed to the coordination between N atom and Pb 2+ and ion-exchange between Na + and Pb 2+. 相似文献
5.
The individual and competitive adsorption capacities of Pb 2+, Cu 2+ and Cd 2+ by nitric acid treated multiwalled carbon nanotubes (CNTs) were studied. The maximum sorption capacities calculated by applying the Langmuir equation to single ion adsorption isotherms were 97.08 mg/g for Pb 2+, 24.49 mg/g for Cu 2+ and 10.86 mg/g for Cd 2+ at an equilibrium concentration of 10 mg/l. The competitive adsorption studies showed that the affinity order of three metal ions adsorbed by CNTs is Pb 2+>Cu 2+>Cd 2+. The Langmuir adsorption model can represent experimental data of Pb 2+ and Cu 2+ well, but does not provide a good fit for Cd 2+ adsorption data. The effects of solution pH, ionic strength and CNT dosage on the competitive adsorption of Pb 2+, Cu 2+ and Cd 2+ ions were investigated. The comparison of CNTs with other adsorbents suggests that CNTs have great potential applications in environmental protection regardless of their higher cost at present. 相似文献
6.
BACKGROUND: The adsorption of Cu 2+ from aqueous solution using crosslinked chitosan hydrogels impregnated with Congo Red (CR) by ion‐imprint technology was systematically investigated with particular reference to the effects of contact time, pH, and initial concentration on adsorption. RESULTS: The adsorption capacity of the crosslinked chitosan without impregnation was only 68.68 mg g ?1 for Cu 2+. However, the adsorption capacity increased from 77.42 (without imprint ion) to 84.54 mg g ?1 (imprint ion content 0.5 mmol) after the chitosan was impregnated with a ratio of 1/12 of CR to chitosan. The as‐prepared adsorbents were found to be pH‐dependent and the process of adsorption agreed well with the Freundlich isotherm. The loaded adsorbents could be regenerated and reused without the appreciable loss of capacity. CONCLUSION: Chitosan hydrogels impregnated with CR showed higher Cu 2+ adsorption capacities compared with those prepared conventionally without imprint ion, and thus developed a good approach to increase Cu 2+ adsorption efficiency in the treatment of waste‐water. Copyright © 2012 Society of Chemical Industry 相似文献
7.
Poly(acrylamide) (PACM) used in this study was prepared through an effective atom transfer radical polymerization process and characterized by NMR, FTIR, and thermo gravimetric analysis. Resulting polymer was used for the uptake of heavy metal ions from aqueous solution. Partition coefficient, retention capacity, and metal ion uptake behavior in aqueous solution of PACM at different monomer percent conversions and effect of parameters for optimization of polymerization reaction gives thermally stable PACM. Efficiency of metal ion uptake of different molecular weights of PACM were tested in batches for Ni 2+, Pb 2+, Cu 2+, Zn 2+, and Hg 2+ ions in single metal solution. Metal ion sorption capacities increase with increase in polymer concentration. Metal ion sorption capacities in single metal system were 6.3 mg g ?1 Ni 2+, 6.0 mg g ?1 Pb 2+, 6.9 mg g ?1 Cu 2+, 6.2 mg g ?1 Zn 2+, 22.4 mg g ?1 Hg 2+ for PACM of 88% conversion (Mn = 19,850). Uptake by the PACM indicates that they are effective in removing metal ions from single metal ion solutions. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
8.
In this paper, Methacrylic acid (MAA) and 4-vinyl pyridine (4-VP) as functional monomers, Ethylene glycol two methyl acrylate (EGDMA) as crosslinking agent, isopropyl alcohol as the solvent, prepared the Cu(II)- and Pb(II)- imprinted polymers (IIPs) submicron spheres by precipitation polymerization. The presence/absence of the template ion in the preparation of the imprinted polymer was confirmed by EDX spectroscopy, and the structure of the particles was investigated using IR, SEM and BET analysis. From different components of crosslinker/monomer (C/M) ratio analysis, C/M at 1:3 was the optimal ratio for preparing IIPs. Atomic absorption spectroscopy (AAS) was characterized the imprinted polymers absorption behavior. The results show that the maximum adsorption capacity of Cu2+ and Pb2+ -imprinted polymer were 26.9 mg g?1 and 25.3 mg g?1, respectively. They also have good adsorption capacity and superior selectivity property for Cu2+ and Pb2+ in water, respectively. The selectivity factors (α) for Ni2+, Zn2+, Co2+ and Fe2+ were 16.5 (Cu2+) and 12.1 (Pb2+), 13.8 (Cu2+) and 16.2 (Pb2+), 10.8 (Cu2+) and 10.1 (Pb2+), 20.4 (Cu2+) and 20.7 (Pb2+), respectively. The regeneration experiment result demonstrates an excellent re-utilization property of these two type IIPs, after ten uses, the adsorption capacity can maintain above 60%. 相似文献
9.
A series of novel snake‐cage resins were synthesized using carboxymethyl chitosan (CM‐CTS) as the snake resin and urea–formaldehyde resin (UF) as the cage resin. Such factors as the optimal synthesis conditions, content of the crosslinking agent, and sorption capacities for metal ions of the above‐mentioned resins were investigated. The experimental results show that these resins have appropriate swelling properties and good mechanical stability. They do not run off in water, HCl, and NaOH aqueous solutions. To form a stable network system, NH 4Cl was used as a crosslinking agent to crosslink urea and formaldehyde in synthesis. The sorption experiment showed that the sorption properties of the resins in the presence of the crosslinking agent NH 4Cl are better than those without a crosslinking agent. The investigation of the FTIR spectra indicated that the chelate groups, such as —OH, —CO and NHCH 2CO, in snake‐resin molecules participated in the coordination with the metal ions, but the —C?O bonds in the cage resin UF did not. The snake resin CM‐CTS in the snake‐cage resins was the major contributor of sorption. The sorption dynamics showed that the sorption was controlled by liquid film diffusion. The isotherms can be described by Freundlich and Langmuir equations. The saturated sorption capacities of the resins for Cu 2+, Ni 2+, Zn 2+, and Pb 2+ were 1.48, 0.78, 0.13, and 0.02 mmol g ?1, respectively. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 310–317, 2002; DOI 10.1002/app.10331 相似文献
10.
Amidoximated chitosan‐ g‐poly(acrylonitrile) (PAN) copolymer was prepared by a reaction between hydroxylamine and cyano group in chitosan‐ g‐PAN copolymer prepared by grafting PAN onto crosslinked chitosan with epychlorohydrine. The adsorption and desorption capacities for heavy metal ions were measured under various conditions. The adsorption capacity of amidoximated chitosan‐ g‐PAN copolymer increased with increasing pH values, and was increased for Cu 2+ and Pb 2+ but a little decreased for Zn 2+ and Cd 2+ with increasing PAN grafting percentage in amidoximated chitosan‐ g‐PAN copolymer. In addition, desorption capacity for all metal ions was increased with increasing pH values in contrast to the adsorption results. Stability constants of amidoximated chitosan‐ g‐PAN copolymer were higher for Cu 2+ and Pb 2+ but lower for Zn 2+ and Cd 2+ than those of crosslinked chitosan. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 469–476, 1999 相似文献
11.
A novel graft copolymer gel made up of pectin (Pec), 2-(methacryloyloxyethyl)trimethylammonium chloride (METAC), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) and its composite with montmorillonite (MMT) were prepared using methylenebisacrylamide (MBA) as cross-linker via microwave irradiation and characterized using Fourier transform infrared (FTIR), Thermogravimetric Analysis (TGA) and Scanning electron microscopy (SEM) techniques. Swelling studies were carried out under different pH conditions. The graft copolymer gel and its composite showed maximum swelling in neural medium (pH 7.1) and the swelling process followed second order kinetics. The mechanism of water transport is found to be a Less Fickian diffusion process. The adsorption capacities of the graft copolymer gel and the composite towards divalent metal ions (Cu 2+, Pb 2+ and Hg 2+) were evaluated. The adsorption capacity of the representative samples, Pec- g-poly(METAC- co-AMPS)-A5 and Pec-g-poly(METAC- co-AMPS)/MMT-C2 respectively for Cu 2+ are 30.71 and 39.18 mg/g; for Pb 2+ are 58.06 and 79.78 mg/g and for Hg 2+ are 12.16 and 19.58 mg/g. The re-usability of the materials was also evaluated. The % recovery for the above two systems towards metals ion are 87.91 and 63.46 for Cu 2+, 32.13 and 58.30 for Pb 2+ and 78.53 and 51.92 for Hg 2+. respectively. The adsorption isotherm studies indicated the adsorption of Pb 2+, Cu 2+ and Hg 2+ in both samples is explained best by the Freundlich model except of Hg 2+ by Pec- g-poly(METAC- co-AMPS)-A5, which is best explained by the Langmuir model. 相似文献
12.
Amidoximated bacterial cellulose (Am‐BC) was prepared through successive polymer analogous reactions of bacterial cellulose with acrylonitrile in an alkaline medium followed by reaction with aqueous hydroxylamine. It was used as an adsorbent to remove Cu 2+ and Pb 2+ from aqueous solutions. The adsorption behaviors of Cu 2+ and Pb 2+ onto Am‐BC were observed to be pH‐dependent. The maximum adsorption capacity of 84 and 67 mg g –1 was observed, respectively, for Cu 2+ and Pb 2+ at pH 5. Scanning electronic microscopy (SEM) indicated that the microporous network structure of Am‐BC was maintained even after the modifacation. The adsorption mechanisms for Cu 2+ and Pb 2+ onto Am‐BC were investigated by fourier transform infrared spectroscopy (FTIR), ζ potential measurement and X‐ray photoelectron spectroscopy (XPS). The results revealed that the mechanism for the adsorption of Cu 2+ onto Am‐BC could be mainly described as between metal ions and nitrogen atom in the amidoxime groups or oxygen atom in the hydroxyl groups. However, in the adsorption process for Pb 2+, precipitation played the important role along with electrostatic interactions, although chelation action also existed in the process accounted for the adsorption process. The regeneration of Am‐BC was studied by treatment with a strong complexing agent, ethylenediaminetetracetic acid (EDTA). © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
13.
The objective of this study was to modify peanut shells to enhance their adsorptive properties toward the metal ions cadmium (Cd 2+), copper (Cu 2+), nickel (Ni 2+), lead (Pb 2+) and zinc (Zn 2+). Milled peanut shells were initially washed with water or 0.1 N NaOH or left unwashed. Following these treatments or lack of treatment, the shells were either left unmodified or modified by a heat treatment in the presence of either 1.0 M phosphoric acid or 0.6 M citric acid. Modified peanut shells were evaluated either for adsorption efficiency or for adsorption capacity using the five metal ions listed above. Adsorption efficiencies and capacities were compared with efficiencies and/or capacities for the commercial chelating or cation exchange resins Amberlite 200, Amberlite IRC‐718, Duolite GT‐73, and carboxymethylcellulose. For the adsorption efficiencies of individual metal ions, modified peanut shells met or exceeded the adsorption values for cadmium, copper, nickel or zinc ions compared with the commercial resins Duolite GT‐73 and carboxymethylcellulose. In a solution containing all five metal ions, modified peanut shells met or exceeded the adsorption efficiencies for cadmium, copper and lead ions compared with Duolite GT‐73, Amberlite IRC‐718 and carboxymethylcellulose. Adsorption capacities of modified peanut shells met or exceeded the adsorption capacity of Duolite GT‐73 for lead ions only. Citric or phosphoric acid‐modified peanut shells showed a preference for Cu 2+ and Pb 2+ and appear promising as potentially inexpensive adsorbents for selected metal ions. © 2001 Society of Chemical Industry 相似文献
14.
Summary Crosslinked hydroxyethyl cellulose-g-poly(acrylic acid) (HEC-g-pAA) graft copolymer was prepared by grafting of acrylic acid
(AA) onto hydroxyethyl cellulose (HEC) using [Ce(NH 4) 2(NO 3) 6]/HNO 3 initiator system in the presence of poly(ethyleneglycol diacrylate) (PEGDA) crosslinking agent in 1:1 (v/v) mixture of methanol
and water at 30 °C. Carboxyl content of copolymer was determined by neutralization of –COOH groups with NaOH solution and
sodium salt of copolymer (HEC-g-pAANa) was swelled in distilled water in order to determine the equilibrium swelling value
of copolymer. Both dry HEC-g-pAA and swollen HEC-g-pAANa copolymers were used in the heavy metal ion removal from three different
aqueous ion solutions as follows: a binary ion solution with equal molar contents of Pb 2+and Cd 2+, a triple ion solution with equal molar contents of Pb 2+, Cu 2+ and Cd 2+, and a triple ion solution with twice Cu 2+molar contents of Pb 2+and Cd 2+. Higher removal values on swollen HEC-g-pAANa were observed in comparison to those on dry polymer. The presence of Cu 2+decreased the adsorption values for Pb 2+ and Cd 2+ ions on both types of HEC copolymer. However, with further increase in Cu 2+ content both dry and swollen copolymers became apparently selective to Cu 2+ removal and Cu 2+ removal values exceeded the sum of adsorption values for Pb 2+ and Cd 2+. Maximum metal ion removal capacities were 1.79 and 0.85 mmol Me 2+/g polymer on swollen HEC-g-pAANa and dry HEC-g-pAA, respectively. 相似文献
15.
The aim of this study was to investigate the heavy metal adsorption performance of supermacroporous poly(hydroxyethyl methacrylate) [PHEMA] cryogel. The PHEMA cryogel was produced by cryo‐polymerization. The PHEMA cryogel was characterized by scanning electron microscopy (SEM). The PHEMA cryogel containing 385 μmol Reactive Green HE‐4BD/g were used in the adsorption studies. Adsorption capacity of the PHEMA cryogel for the metal ions, i.e., Cu 2+, Cd 2+, and Pb 2+ were investigated in aqueous media containing different amounts of the ions (5–600 mg/L) and at different pH values (3.2–6.9). The maximum adsorption capacities of the PHEMA cryogel were 11.6 mg/g (56 μmol/g) for Pb 2+, 24.5 mg/g (385 μmol/g) for Cu 2+ and 29.1 mg/g (256 μmol/g) for Cd 2+. The competitive adsorption capacities were 10.9 mg/g (52 μmol/g) for Pb 2+, 22.1 mg/g for Cd 2+ (196 μmol/g) and 23.2 mg/g (365 μmol/g) for Cu 2+. The PHEMA/Reactive Green HE‐4BD cryogel exhibited the following metal ion affinity sequence on molar basis: Cu 2+ > Cd 2+ > Pb 2+. The PHEMA/Reactive Green HE‐4BD cryogel can be easily regenerated by 50 m M EDTA with higher effectiveness. These features make the PHEMA/Reactive Green HE‐4BD cryogel a potential adsorbent for heavy metal removal. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
16.
Amberlite XAD‐2 has been functionalized by coupling through –SO 2‐with ethylenediamine, propylenediamine, and diethylenetriamine to give the corresponding polyamine chelating resins I–III. The solid metallopolymer complexes of the synthesized chelating resins with Cu 2+, Zn 2+, Cd 2+, and Pb 2+ were synthesized. The polyamine derivatives and their metal complexes were characterized by elemental analysis, spectral (IR, UV/V, and ESR), and magnetic studies. The batch equilibrium method was utilized for using the chelating polyamines for the removal of Cu +2, Zn +2, Cd +2, and Pb +2 ions from aqueous solutions at different pH values and different shaking times at room temperature. The selective extraction of Cu +2 from a mixture of the four metal ions and the metal capacities of the chelating resins were evaluated using atomic absorption spectroscopy. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1839–1846, 2005 相似文献
17.
In this study, L-cystein modified bentonite-cellulose (cellu/cys-bent) nanocomposite was synthesized and characterized by XRD, FTIR, SEM with EDS, TGA, and TEM techniques. In order to optimize the process the effect of various operational parameters such as pH, adsorbent dosage, contact time, and temperature were also investigated. The adsorption experiments were carried out in initial concentrations range of 20-100 mg L ?1and the adsorbent affinity for metal ions was found to be in order of Cu 2+ > Pb 2+ > Cd 2+. The optimum pH for adsorption of Cu 2+ and Cd 2+ was observed at 5 while for Pb 2+ it was pH 6. Based on the Langmuir model, the maximum adsorption capacity of Cu 2+, Pb 2+, and Cd 2+ at 50 ?C was found to be 32.36, 18.52, and 16.12 mg g ?1, respectively. The Langmuir isotherm and pseudo-second order model were found to be better fitted than the other isotherms and kinetic models. The results of thermodynamic parameters confirmed the process to be endothermic and spontaneous in nature. 相似文献
18.
Abstract For the functional enhancement of chelating resins containing carboxylic acids, copolymer beads were prepared by suspension polymerization of styrene (St), methyl methacrylate (MMA), and divinylbenzene (DVB) in the presence of toluene as diluent. The phenyl rings of the beads were directly chloromethylated, and the carboxylic ester groups of the beads were converted into hydroxymethyl groups by reduction followed by chlorination to give chloromethyl groups, respectively. The chelating resins containing a pair of neighboring carboxylic acid groups (NCAGs) were obtained by the alkylation of chloromethyl groups in copolymer beads with diethyl malonate in the presence of sodium hydride followed by hydrolysis using aqueous alkali solution. Accordingly, the structural effects of the resins on the adsorption of heavy metal ions were investigated. Poly(St‐ co‐DVB)‐based chelating resin containing NCAGs showed adsorption abilities toward heavy metal ions like Pb 2+, Cd 2+, and Cu 2+, whereas poly(MMA‐ co‐DVB)‐based chelating resin containing NCAGs showed adsorption abilities toward heavy metal ions like Cu 2+, Cd 2+, and Co 2+. On the other hand, poly(St‐ co‐MMA‐ co‐DVB)‐based chelating resin containing NCAGs showed adsorption abilities toward heavy metal ions like Pb 2+, Cd 2+, Hg 2+, Co 2+, and Cu 2+: a synergistic effect on the adsorption of heavy metal ions like Pb 2+, Cd 2+, Hg 2+, and Co 2+ was observed. The adsorption ability of poly(St‐ co‐MMA‐ co‐DVB)‐based chelating resin among three kinds of chelating resins was relatively good. 相似文献
19.
In this work, a novel polymer polyamic hydrazide (PAH) was synthesized via the reaction of terephthalohydrazide with pyromelitic dianhydride. The obtained PAH was characterized with nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared (FT‐IR) spectroscopy and elemental analysis. Finally, a novel magnetic nanocomposite was prepared by immobilization of PAH on the Fe 3O 4 nanoparticles in water. The prepared magnetic nanocomposite was successfully used for selective removal of Pb 2+ and Cd 2+ ions from industrial wastes and the effects of affecting parameters on the adsorption capacity of the magnetic nanocomposite adsorbent for the removal of Pb 2+ and Cd 2+ from model aqueous solutions were investigated. The maximum adsorption capacities of Pb 2+ and Cd 2+ were found to be 138.9 and 103.1 mg g ?1, respectively. The kinetics and mechanism of the adsorption of Pb 2+ and Cd 2+ on the surface of the prepared nanocomposite were studied and it was found that complex formation between active sites of the surface of the nanocomposite and metal ions is the possible mechanism for adsorption of metal cations. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42538. 相似文献
20.
Amine‐type adsorbents were prepared by radiation‐induced graft polymerization. The sorption behaviors for an individual metal ion of Cu 2+ and Pb 2+ separately, as well as with mixed Cu 2+/Pb 2+, were studied in both column and batch mode. Ethylenediamine‐type adsorbent exhibited a high capacity for Cu 2+ and Pb 2+ at a high flow rate of 1000 h ?1, but low selectivity in the mixed Cu 2+/Pb 2+ solutions. Radiation‐induced crosslinking of the amine‐type adsorbent was performed in water to improve selectivity. Crosslinking of the material was demonstrated by gel fraction, water content, and scanning electron microscopy image. Compared with the results from the noncrosslinked adsorbents, the breakthrough curve of Cu 2+ right shifted, whereas the breakthrough curve of Pb 2+ left shifted, indicating the higher adsorption capacity of Cu 2+ and the lower adsorption capacity of Pb 2+ from the crosslinked adsorbent. After 300 kGy irradiation, the crosslinked adsorbent was found to selectively adsorb Cu 2+ from the mixed Cu 2+/Pb 2+ solution. The results revealed that crosslinking raised the selectivity of the adsorbents. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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