Potassium-ion batteries (PIBs) have attracted increasing interest as promising alternatives to lithium-ion batteries (LIBs) for application in large-scale electrical energy storage systems (EESSs) owing to a wide earth-abundance, potential price advantages, and low standard redox potential of potassium. Developmental materials for use in PIBs that can yield high specific capacities and durability are widely sought with emerging studies on alloying-type anode materials offering significant prospects to meet this challenge. Here, recent advances on alloying-type anodes and their composites for PIBs are reviewed in detail and in a systematic way to capture key aspects from fundamental working principles through major progress and achievements to future perspectives and challenges. Emphasis is placed on critical aspects such as the alloying mechanism and correlation of electrode design and structural engineering for performance enhancement and the crucial role of electrolyte compatibility, additives and binders. The review in appraising all the important contributions on this topic allows for a critical assessment of the research challenges and provides insights on future research directions that can accelerate the important development of PIBs as a viable battery energy storage system. 相似文献
Potassium-ion batteries (PIBs) have aroused considerable interest as a promising next-generation advanced large-scale energy storage system due to the abundant potassium resources and high safety. However, the K+ with large ionic radius brings restricted diffusion kinetics and severe volume expansion in electrode materials, resulting in inferior actual rate characteristics and rapid capacity fading. Designing electrode materials with one-dimensional (1D) nanostructure can effectively enhance various electrochemical properties due to the well-guided electron transfer pathways, short ionic diffusion channels and high specific surface areas. In this review, we summarize the recent research progress and achievements of 1D nanostructure electrode materials in PIBs, especially focusing on the development and application of cathode and anode materials. The nanostructure, synthetic methods, electrochemical performances and structure-performance correlation are discussed in detail. The advanced characterizations on the reaction mechanisms of 1D nanostructure electrode materials in PIBs are briefly summarized. Furthermore, the main future research directions of 1D nanostructure electrode materials are also predicted, hoping to accelerate their development into the practical PIBs market. 相似文献
Although potassium-ion batteries (KIBs) are considered a very promising energy storage system, their development for actual application still has a long way to go. Advanced electrode materials, as a fundamental component of KIBs, are essential for optimizing electrochemical performance and promoting effective energy storage. Due to their unique structural benefits in terms of cycle capability, strong ionic conductivity, and tunable operating voltage, polyanionic compounds are one type of viable electrode material for manufacturing high-performance KIBs. The huge size of K+ ion, on the other hand, places great demands on polyanionic materials, which must be able to withstand severe structural deformation during K+ intercalation/delamination. To maintain steady electrochemical performance, it is critical to follow the appropriate design guidelines for electrode materials. This paper provides a summary of current advancements in polyanionic compound for KIBs, with a focus on electrode material structural design. The effects of various parameters on electrochemical performance are examined and summarized. In addition, various viable solutions are proposed to address the impending issues posed by polyanionic compounds for KIBs, with the hope of providing a clearer picture of the field's future development path. 相似文献
Journal of Materials Science - The special wettable gel material solves the problem that the rigid solid surface with special wettability does not perform well in the face of flexibility... 相似文献
Lithium-ion batteries have emerged as the best portable energy storage device for the consumer electronics market. Recent progress in the development of lithiumion batteries has been achieved by the use of selected anode materials, which have driven improvements in performance in terms of capacity, cyclic stability, and rate capability. In this regard, research focusing on the design and electrochemical performance of full cell lithium-ion batteries, utilizing newly developed anode materials, has been widely reported, and great strides in development have been made. Nanostructured anode materials have contributed largely to the development of full cell lithium-ion batteries. With this in mind, we summarize the impact of nanostructured anode materials in the performance of coin cell full lithium-ion batteries. This review also discusses the challenges and prospects of research into full cell lithium-ion batteries. 相似文献
Solid polymer electrolytes are light-weight, flexible, and non-flammable and provide a feasible solution to the safety issues facing lithium-ion batteries through the replacement of organic liquid electrolytes. Substantial research efforts have been devoted to achieving the next generation of solid-state polymer lithium batteries. Herein, we provide a review of the development of solid polymer electrolytes and provide comprehensive insights into emerging developments. In particular, we discuss the different molecular structures of the solid polymer matrices, including polyether, polyester, polyacrylonitrile, and polysiloxane, and their interfacial compatibility with lithium, as well as the factors that govern the properties of the polymer electrolytes. The discussion aims to give perspective to allow the strategic design of state-of-the-art solid polymer electrolytes, and we hope it will provide clear guidance for the exploration of high-performance lithium batteries. 相似文献
Thermoelectric materials are crucial in renewable energy conversion technologies to solve the global energy crisis. They have been proven to be suitable for high-end technological applications such as missiles and spacecraft. The thermoelectric performance of devices depends primarily on the type of materials used and their properties such as their Seebeck coefficient, electrical conductivity, thermal conductivity, and thermal stability. Classic inorganic materials have become important due to their enhanced thermoelectric responses compared with organic materials. In this review, we focus on the physical and chemical properties of various thermoelectric materials. Newly emerging materials such as carbon nanomaterials, electronically conducting polymers, and their nanocomposites are also briefly discussed. Strategies for improving the thermoelectric performance of materials are proposed, along with an insight into semiconductor physics. Approaches such as nanostructuring, nanocomposites, and doping are found to enhance thermoelectric responses by simultaneously tuning various properties within a material. A recent trend in thermoelectric research shows that high-performance thermoelectric materials such as inorganic materials and carbon nanomaterials/electronically conducting polymer nanocomposites may be suitable for power generation and energy sustainability in the near future. 相似文献
Lithium-ion batteries (LIBs), known as “rocking-chair batteries”, have shown a huge success in consumer electronics and energy vehicles. However, the soaring cost caused by the shortage of lithium and cobalt resources as well as the need for ever-higher performance and safety has promoted an urgent need to develop high-efficient battery systems. Dual-ion batteries (DIBs), based on different working mechanism that involves both cations and anions during the charging/discharging processes, are expected to be an alternative to conventional batteries due to their environmental friendliness, low cost, excellent safety, high work voltage, and high energy density. Despite these merits, DIBs also face various challenges from the limited capacity caused by intercalation-type graphite electrodes and shorter cycle life resulted from large anions intercalation and electrolyte decomposition at high voltage. To overcome those challenges, various effective strategies have been adopted and many inspiring results have been also reported. In this review, we briefly outlined the history, mechanism and configuration of DIBs and mainly summarized the recent developments of electrode materials for DIBs, covering inorganic electrode materials and organic electrode materials, along with their application in various metal-based DIBs. Especially, recent studies on organic electrode materials based on so-called DIB working mechanism are also highlighted. In addition, the existing problems and future perspectives are finally proposed. We hope this review will provide some inspiration for researchers to rationally design more efficient electrode materials for more advanced DIB systems. 相似文献
Bismuth (Bi)-based electrode has aroused tremendous interest in potassium-ion batteries (PIBs) on account of its low cost, high electronic conductivity, low charge voltage and high theoretical capacity. However, the rapid capacity fading and poor lifespan induced by the normalized volume expansion (up to ~ 406%) and serious aggregation of Bi during cycling process hinder its application. Herein, bismuth molybdate (Bi2MoO6) microsphere assembled by 2D nanoplate units is successfully prepared by a facile solvothermal method and demonstrated as a promising anode for PIBs. The unique microsphere structure and the self-generated potassium molybdate (K-Mo-O species) during the electrochemical reactions can effectively suppress mechanical fracture of Bi-based anode originated from the volume variation during charge/discharge of the battery. As a result, the Bi2MoO6 microsphere without hybridizing with any other conductive carbon matrix shows superior electrochemical performance, which delivers a high reversible capacity of 121.7 mAh·g−1 at 100 mA·g−1 over 600 cycles. In addition, the assembled perylenetetracarboxylic dianhydride (PTCDA)//Bi2MoO6 full-cell coupled with PTCDA cathode demonstrates the potential application of Bi2MoO6 microsphere. Most importantly, the phase evolution of Bi2MoO6 microsphere during potassiation/depotassiation process is successfully deciphered by ex situ X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), and transmission electron microscopy (TEM) technologies, which reveals a combination mechanism of conversion reaction and alloying/dealloying reaction for Bi2MoO6 anode. Our findings not only open a new way to enhance the performance of Bi-based anode in PIBs, but also provide useful implications to other alloy-type anodes for secondary alkali-metal ion batteries.
Disordered carbonaceous materials were synthesized by the pyrolysis of banana fibers treated with pore-forming substances such as ZnCl2 and KOH. X-ray diffraction studies indicated a carbon structure with a large number of disorganized single layer carbon sheets. Addition of porogenic agent led to remarkable changes in the structure and morphology of the carbonaceous products. The product obtained with ZnCl2 treatment gave first-cycle lithium insertion and de-insertion capacities of 3325 and 400 mAh g−1, respectively. Lower capacities only could be realized in the subsequent cycles, although the coulombic efficiency increased upon cycling, which in the 10th cycle was 95%. 相似文献
Novel nickel-cobalt oxides/carbon nanoflakes with Ni/Co molar ratio = 1:1 and 1:2 have been synthesized by a convenient hydrothermal method followed by a simple calcination process. X-ray diffraction results showed that the composites were composed of NiO, Co3O4, and carbon. Scanning electron microscope measurements demonstrated that the composites were flakes less than 100 nm in thickness, and the corresponding energy dispersive spectroscopy mapping showed that the carbon was distributed homogeneously in the composites. The electrochemical results showed that the composite electrodes exhibited low initial coulombic efficiency and excellent charge-discharge cycling stability. Additionally, the effect of different Ni/Co molar ratios on the electrochemical properties of the composites was investigated, and better performance was obtained for the sample with a Ni/Co molar ratio of 1:2. 相似文献
SnO nanoflakes were successfully prepared by a simple hydrothermal process, with the use of hydrazine hydrate as the mineralizer
and polyethylene glycol (PEG) or citric acid as an additive. Hydrazine hydrate serves as both a mineralizer and a protective
agent against the oxidation of the SnO products at the hydrothermal stage. X-ray diffraction, field-emission scanning electron
microscopy (FESEM), and transmission electron microscopy were employed to characterize the products. FESEM images reveal that
the thickness of the SnO nanoflakes prepared by the hydrothermal process with the use of PEG as an additive is around 15 nm.
The first reversible specific capacity of the SnO nanoflakes reaches 856 mA h/g, which is near the theoretical value (876
mA h/g). Hydrazine hydrate, the hydrothermal temperature, and the surfactant/complexing agent are three key factors for the
hydrothermal synthesis of the SnO nanoflakes by the process presented here.
The text was submitted by the authors in English. 相似文献