共查询到18条相似文献,搜索用时 103 毫秒
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以孔径为200nm的多孔氧化铝膜(AAO)为模板、常规分子量的通用聚合物为原料,采用聚合物溶液或熔体浸润模板纳米孔的物理技术,进行了多种聚合物纳米管的制备研究。结果表明:聚苯乙烯、尼龙66、聚丙烯、ABS、热塑性聚氨酯等多种聚合物纳米管及其纳米管阵列成功制得。运用扫描电子显微镜(SEM)和透射电子显微镜(TEM)观察了纳米管的微观形貌和阵列结构。并探讨了聚合物性质、纳米管制备工艺与纳米管结构的关系,初步探索了多孔模板法制备聚合物纳米管的机理。 相似文献
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以孔径为200nm的阳极氧化铝(AAO)为模板,用简单的物理方法制备了生物可降解聚合物聚己内酯(PCL)的纳米管、线及其阵列结构。SEM和TEM测试结果表明:熔融法在120℃和140℃都能制得整齐的纳米管阵列结构,管径均匀,约300nm。在溶液法中,5%浓度的溶液制得了杂乱的纳米管,而10%浓度的溶液制得的是纳米线阵列,直径在200nm左右。 相似文献
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采用减压抽滤法在多孔阳极氧化铝模板(AAM)纳米孔道中构筑DyCo_xZn_yO_z纳米管阵列,采用扫描电镜(SEM)和透射电镜(TEM)观察DyCo_xZn_yO_z纳米管阵列和单根纳米管形貌,用选区电子衍射(SAED)、X-射线衍射(XRD)及能量色散谱(EDS)表征纳米管的结构和元素组成,结果表明,DyCoxZnyOz纳米管为非晶态结构,纳米管元素组成的原子百分比Dy:Co:Zn:O为4.86:1.67:1.70:91.77,质量百分比Dy:Co:Zn:O为32:4.42:4.07:59.51。以振动样品磁强计(VSM)研究了DyCo_xZn_yO_z纳米管阵列磁性能,实验结果表明,DyCo_xZn_yO_z纳米管阵列易磁化方向为垂直于纳米管阵列方向,磁各向异性源于形状各向异性,DyCo_xZn_yO_z纳米管阵列具备软磁体特征。 相似文献
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《Journal of Experimental Nanoscience》2013,8(1):26-39
This article demonstrates a method for the fabrication of patterned surfaces using hairpin oligonucleotides carrying a novel photolabile group at the apex of the loop. Photolysis of surfaces carrying photolabile hairpin oligonucleotides results in the formation of areas carrying single-stranded DNA sequences that direct the deposition of the complementary sequence at the photolysed sites. The non-photolysed areas carrying the intact hairpin do not bind to complementary sequences due to the presence of the more stable intramolecular hairpin duplex. The photolithographic process was performed on silicon wafers and followed by atomic force microscopy and epi-fluorescent microscopy. The method described offers an attractive option for the fabrication of biologically interfaced patterned surfaces with specific recognition properties with potential uses in electronics and as biosensors. 相似文献
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A rapid fabrication and prototyping technique to incorporate microwell arrays with sub-10 μm features within a single layer of microfluidic circuitry is presented. Typically, the construction of devices that incorporate very small architecture within larger components has required the assembly of multiple elements to form a working device. Rapid, facile production of a working device using only a single layer of molded polydimethylsiloxane (PDMS) and a glass support substrate is achieved with the reported fabrication technique. A combination of conventional wet-chemical etching for larger (≥20 μm) microchannel features and focused ion beam (FIB) milling for smaller (≤10 μm) microwell features was used to fabricate a monolithic glass master mold. PDMS/glass hybrid chips were then produced using simple molding and oxygen plasma bonding methods. Microwell structures were loaded with 3 μm antibody-functionalized dye-encoded polystyrene spheres, and a sandwich immunoassay for common cytokines was performed to demonstrate proof-of-principle. Potential applications for this device include highly parallel multiplexed sandwich immunoassays, DNA/RNA hybridization analyses, and enzyme linked immunosorbent assay (ELISA). The fabrication technique described can be used for rapid prototyping of devices wherever submicrometer- to micrometer-sized features are incorporated into a microfluidic device. 相似文献
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Fabrication processes of arrayed magnetic nanodots for the use of patterned magnetic recording media were reviewed. One candidate for the patterned media is ordered assemble of magnetic nanoparticles, and the other is patterned magnetic thin films fabricated using various micro/nano scale machining processes. For the formation of patterned masks and molds, lithography processes as well as self-organized pattern formation are utilized. For the deposition processes of magnetic dots, electrochemical deposition processes were widely used. These fabrication processes are reviewed mainly from recent reports. The recording systems for the patterned media including probe-type-recording are also overviewed. 相似文献
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We demonstrate that depletion effects in the fluids used to fill a poly(dimethylsiloxane) microfluidic device can be used in conjunction with its design rules to generate patterned protein gradients. The linear portions of these structures can be designed to present gradients of bound protein coverage-varying from near-saturation to effectively zero-over distances ranging from a few hundred micrometers to more than 1 cm by design. Such patterns can be developed in a simple, single-channel form as well as in a multichannel gradient array of more complex design. The patterning protocols also support the use of multiple protein sources, and we demonstrate an assembly process mediated by a protein that inhibits adsorption to generate a gradient array in pixel form. We describe examples of multiple protein gradient patterns along with simple immunoassays to illustrate the scope of the methodology, the activity of the patterned proteins, and their recognition in gradient form on a surface. These gradients should prove useful to studies in biosensor and bioassay development and as substrates for cell culture to study growth and motility. 相似文献
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SPM based lithographic techniques have been developed to pattern various substrates such as metals, semiconductors, and organic/polymer films due to its simplicity and high spatial precision nanostructure. Fabrication of nanostructure using polymeric materials is a key technique for the development of nanodevices. Here, we report the fabrication of nanostructures from polyacrylicacid (PAA) and polymethacrylicacid (PMAA) film on a silicon substrate using atomic force microscope (AFM). The formation of the nanopattern from the polymer film was studied using electrostatic nanolithography and the optimization of the conditions for nanopatterning of the polymer film was investigated with respect to the applied potential and translational speed of the AFM tip. The nanostructure of size 28 nm was created using the biased AFM tip on the PMAA film coated on Si(100) substrate and found that this method is a direct and reliable method to produce uniform nanostructures on a polymer film. 相似文献
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《Composites Part A》2008,39(4):588-596
The novel fabrication technique that patterns the multiple electrodes of the ionic polymer metal composite actuators was developed to mimic the swimming and flapping locomotion of a living thing. The developed method is to combine electroplating with the electroless chemical reduction using the patterned mask. The advantages of this fabrication method are that the initial compositing between the polymer and platinum particles can be assured by the chemical reduction method, and the thickness of each electrode can be controlled easily and rapidly by electroplating. By using the fabricated actuator with a multiple degree of freedom, the oscillatory and undulatory waves of the flexible membrane actuator was generated and a twisting motion was also realized to verify the possibility of mimicking the fish-like locomotion. Present results show that this novel method combining electroplating with electroless plating can be a promising technique to easily pattern multiple electrodes and to implement the biomimetic motion of the polymer actuators with good mechanical bending performance. 相似文献
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A range of proposed devices relies on the electronic, optical or magnetic properties of one-dimensional (1D) chains of nanoparticles. Here, well-controlled 1D arrays have been formed by templating a spherical-morphology block copolymer within a narrow groove. Significantly, the domains are distorted into ellipses with aspect ratio and major axis orientation controlled by the groove width. This technique gives unprecedented control over the period, particle size, aspect ratio, and orientation of nanoparticles in 1D arrays, making it valuable for creating self-assembled masks for the fabrication of novel devices. 相似文献