Sr复合变质剂对Al—Si合金变质影响的研究

运用正交试验研究Al—10％Sr变质剂对G01铝合金的变质工艺,研究不同变质剂添加量、变质温度、变质时间对变质效果的影响,探索Sr变质剂在Al—Si合金生产中的工艺方法。     

Sr复合变质剂对Al-Si合金变质影响的研究（续）

运用正交试验研究Al-10%Sr变质剂对G01铝合金的变质工艺,研究不同的变质剂添加量、变质温度、变质时间对变质效果的影响,探索Sr变质剂在Al-Si合金生产中的工艺方法。     

变质处理对ADC12铸造铝硅合金组织及性能的影响

借助金相显微分析实验、拉伸实验等手段,研究不同含量的Al-10Sr变质剂对ADC12铸造铝硅合金组织及性能的影响,结果表明:添加变质剂后,ADC12合金的显微组织得到明显的细化,抗拉强度及延伸率得到极大提高,其中当采用w(Sr)为0.06%进行变质处理时其效果最佳。     

Sr含量对4004铝合金铸锭变质效果的研究

研究了Sr加入量分别为0．01％、0．015％、0．02％,变质保温时间分别为60min、80min、100min,对4004铝合金变质效果的影响。结果表明：Sr加入量低于0．015％、变质保温时间小于80min时,合金组织和力学性能均没有达到完全变质状态;Sr加入量0．015％、变质保温时间80min时,4004铝合金变质效果最好,合金组织中的初晶硅转变为细小的圆状或短棒状,共晶硅也由片状或针状转变为纤维状,合金的抗拉强度和伸长率达到最大值193MPa和4．2％;Sr加入量超过0．015％、变质保温时间超过80min时,随着加入量的增加,合金组织开始变得粗大,抗拉强度随着下降。     

P、Sr、RE变质对过共晶Al-Si合金组织形态的影响

采用P、Sr、混合RE对含Si量22%～26%的过共晶铝硅合金进行变质处理,利用金相显微镜分析了单一元素变质及复合变质对合金初晶硅和共晶硅组织形态的影响。结果表明,P为初晶硅变质元素,Sr为共晶硅变质元素,RE能同时细化初晶硅和共晶硅;试验发现Sr虽然不能细化初晶硅,但对初晶硅有明显的裂解作用;P和RE复合变质使得初晶硅尺寸减小到25μm,而加入Sr后,由于Sr对初晶硅的裂解作用,使得初晶硅的尺寸减小到15μm,共晶硅大部分呈蠕球杆状或团球状,均匀弥散分布;试验得到了一种初晶硅和共晶硅细化效果均良好的复合变质剂。     

Al-5Ti-1B-4Sr中间合金对Al-8Si合金同时细化和变质效果

采用氟盐法和对掺法成功制备了Al-5Ti-1B-4Sr中间合金,采用X射线衍射(XRD)和扫描电镜(SEM)分析了Al-5Ti-1B-4Sr中间合金的组织及相组成。通过改变Al-5Ti-1B-4Sr中间合金细化变质保温时间,采用微观组织分析和宏观组织分析方法,研究了Al-5Ti-1B-4Sr中间合金对Al-8Si亚共晶铝硅同时细化和变质的效果。研究结果表明,Al-5Ti-1B-4Sr中间合金中含有Al_3Ti相、TiB_2相和Al_4Sr相,Al-5Ti-1B-4Sr中间合金对亚共晶铝硅合金有良好的同时细化变质效果。Al-5Ti-1B-4Sr中间合金可使共晶硅从针状或板片状形貌转变为纤维状或块状。与未变质试样相比,细化变质时间为10 min时,Al-8Si合金中针状或板片状共晶硅显著减少;变质时间超过20 min时,看不到针状或板片状共晶硅存在;当变质时间达到80 min时,部分针状或板片状共晶硅再次出现。随着Al-5Ti-1B-4Sr细化变质保温时间的变化,α-Al的二次枝晶臂间距和共晶团尺寸先减小后增大,细化变质保温时间为30 min时效果最好。Al-5Ti-1B-4Sr中间合金对亚共晶铝硅合金细化变质的孕育期为10~20 min,衰退期为60 min。     

细晶Al-Sr中间合金对AZ91D组织和性能的影响

通过真空感应炉对Al-Sr中间合金进行了铜模喷铸处理,得到了细晶Al-Sr变质剂。然后分别采用粗晶与细晶Al-Sr对AZ91D进行了变质处理。SEM、OM、XRD、拉伸试验及硬度测试结果表明:经铜模喷铸处理的Al-Sr中间合金中的第二相Al4Sr的平均尺寸从100μm减小至5μm;经Al-Sr中间合金变质的AZ91D,晶粒明显细化,力学性能明显提高,但细晶Al-Sr的变质效果更好。因此,铜模喷铸是提高Al-Sr变质效果的有效途径。     

新型Al—Sr—RE复合细化变质剂及其在ZL102合金中的作用

研制了一种新型、高效的Al-Sr-RE复合细化变质剂,该合金熔点较低（639．2－740℃）,变质潜伏期短（≤10min),变质能力强,变质效果好,并且可以显著细化Al-Si合金枝晶组织,与工作用Al-10Sr,Al-8.7Sr-2.8Ti-0.2B合金相比,该合金使ZL102合金的二次枝晶间距减小了22．65－23．2％。     

锶铝中间合金及其应用

1.概述锶铝合金是国内近年来开发的一种优良合金变质剂,主要用于亚共晶及共晶铝硅合金的变质。其变质类型与传统使用的钠元素相当,但比钠有以下显著优点: 1.1 锶变质有效期长,可达6～8小时以上,重熔4～5次仍有变质效果,能够满足持续时间长的低压铸造和金属型铸造需要,特别适于浇注大型铸件和连续化生产。     

利用炉料遗传性原理控制铝合金圆铸锭熔铸质量的探讨

在研究相关文献的基础上介绍了炉料中铝硅合金、铝硅合金用变质剂Sr、铝合金晶粒细化剂组织、电解铝液和重熔铝锭中含铁相的遗传性。提出了利用炉料遗传性原理进行铝合金铸锭熔铸生产的一些措施。     

Study on Improving Solidification Structure of Rare Earth Al-Si Alloys with Electropulse Acting on Liquid Alloy

Electropulse modification (EPM) process, a new physical field method for improving the solidification structure of metals was introduced.Different from other research, EPM is only acting pulse current on melt under liquid state.The solidification structure of Al-Si alloys, A1-Cu alloys,cast iron and steel can be modified obviously with this method: the solidification structure of ZL101 alloy presented the Na and Sr modification and the mechanical properties were enhanced; a large number of primary silicon appeared in the microstructure of ZL109 alloy; the equiaxed grain zone was expanded and the grains were fined in Al-5.0wt% Cu alloy; the graphitization took place in solidification process of molten cast iron; the grain sizes of solidification structure of T8 steel were reduced significantly and the shape of steel pearlites also changed; the equiaxed grain zone increased to 88% from original untreated 19%, the equiaxed grains were fined and the intercrystalline crack was avoided in concasting billet by continuously treating liquid electrical sheet steel in tundish.Effects of rare earths on casting Al-Si alloys were also summarized.The method of modifying the solidification structure of rare earth Al-Si alloys with EPM in producing the alloys was proposed.     

亚共晶Al-Si合金的Sr变质处理工艺

对亚共晶Al-Si合金进行Sr变质处理,试验结果表明:变质处理能使合金的组织细化,力学性能得到提高。     

Heterogeneous nucleation of solidification of Si by solid AI in hypoeutectic Al-Si alloy

Melt-spun Al-3 wt pct Si with and without ternary additions of Na and Sr has been heat-treated above the Al-Si eutectic temperature in a differential scanning calorimeter to form a microstructure of Al-Si eutectic liquid droplets embedded in the α-Al matrix. During subsequent cooling in the calorimeter, the heterogeneous nucleation temperature for solidification of Si in contact with the surrounding Al matrix depends sensitively on the alloy purity, with a nucleation undercooling which increases with increasing alloy purity from 9 to 63 K below the Al-Si eutectic temperature. These results are consistent with Southin’s hypothesis that low levels of trace P impurities are effective in catalyzing Si nucleation in contact with the surrounding Al matrix. With a low Al purity alloy, 0.1 wt pct Na addition increases the Si nucleation undercooling from 9 to 50 K, 0.15 wt pct Sr addition does not affect the Si nucleation temperature, and 0.3 wt pct Sr addition decreases the Si nucleation undercooling from 9 to 3 to 4 K. The solidified microstructure of the liquid Al-Si eutectic droplets embedded in the Al matrix depends on the Si nucleation undercooling. With low Si nucleation undercooling, each Al-Si eutectic liquid droplet solidifies to form one faceted Si particle; however, with high Si nucleation undercooling, each Al-Si eutectic droplet solidifies to form a large number of nonfaceted Si particles embedded in Al. Formerly with the Oxford Centre for Advanced Materials and Composites, Department of Materials, Oxford University     

4004铝合金使用不同变质剂变质效果对比研究

本文介绍了Na变质和Sr变质对4004合金性能的影响,两种变质工艺生产的4004合金扁锭无论成分、组织、性能差异均不大,但Na变质对设备影响较大,而Sr变质成本较高,就质量而言,使用Sr变质工艺更为合理。     

The effect of na and Sr modification on surface tension and volumetric shrinkage of A356 alloy and their influence on porosity formation

Modification of the eutectic Si in Al-Si foundry alloys by adding strontium or sodium is, unfortunately, accompanied by an increase of porosity in the casting. In an attempt to understand the nature of this problem, this study used a sessile-drop method to investigate the effect of Sr and Na on surface tension and volumetric shrinkage, two probable causes of porosity occur-rence. The addition of 0.01 wt pct Sr and 0.005 wt pct Na to A356 alloy decreases the surface tension of the liquid by about 19 and 10 pct, respectively, and may increase the volume shrink-age by about 12 pct. These changes to surface tension and volumetric shrinkage promote the early formation of the pores during solidification and give the availability of a longer period of growth prior to complete solidification, resulting in a larger pore size. The effect of surface tension on the pores is more significant than volumetric shrinkage. Although the predicted pore diameter increases with lower surface tension or higher volumetric shrinkage, these two effects alone do not seem able to completely account for the observed increase in porosity that is associated with modification.     

铝硅合金变质效果的快速检测试验

以铝硅共晶合金为研究对象,分别加入0、1.5%、2.5%和3%的Na盐变质剂,应用计算机快速检测系统对变质效果进行了检测。结果表明,变质过冷度△T与变质程度之间有明确的数量关系:△T≥5℃,变质效果较好(变质剂加入量2.5%);△T=8℃时,变质效果良好(变质剂加入量3%)。其判据与力学性能、断口形貌、金相组织的检测结果一致。     

Al-3B变质对铸造Al-10Si合金显微组织与力学性能的影响

采用Al-3B对铸造Al-10Si合金进行了变质处理,运用非平衡相图和杠杆定律分析了变质处理Al-10Si合金显微组织变化规律,研究了变质处理对合金力学性能的影响.研究表明,Al-3B变质处理使铸造Al-10Si合金的凝固过冷度减小;当变质温度一定时,随着Al-3B加入量增加,铸造Al-10Si合金组织中初生α-Al相...     

稀土Nd对铸造铝硅合金变质作用的长效性及重熔性研究

以稀土元素Nd为变质剂,采用金属型铸造工艺制备铸造铝硅合金ZL101,并通过金相显微镜、扫描电镜、布氏硬度计和电子万能试验机研究变质时间及重熔次数对合金显微组织和力学性能的影响.结果表明,稀土Nd对合金具有较好的变质作用,并具有长效性和重熔性,变质6h及重熔4次后合金中的共晶硅组织仍呈小片状的变质状态,且合金硬度及拉伸性能均未受明显影响.变质不同时间及重熔不同次数的合金拉伸试样均为解理断裂.