Thermodynamic based comparison of sorption systems for cooling and heat pumping: Comparaison des performances thermodynamique des systèmes de pompes à chaleur à sorption dans des applications de refroidissement et de chauffage

A comparison of thermodynamic performances of sorption systems (liquid absorption, adsorption, ammonia salts and metal hydrides) is carried out for typical applications (deep-freezing, ice making, air-conditioning and heat pumping) with either air-cooled or water-cooled heat sink. The results are given in terms of cooling coefficient of performance (COP) (heating COP or coefficient of amplification (COA) for the heat pump), cooling (heating) power versus reactor volume or weight and thermodynamic efficiency. LiBr–water systems show the best results for air-conditioning except when small units are required (metal hydride systems lead to more compact units). Other systems, however, show better results for other applications (chemical reaction with ammonia salts for deep-freezing, adsorption for heat pumping).     

Evaluation of metal hydride machines for heat pumping and cooling applications: Evaluation des machines à hydrure métallique dans les applications de pompes à chaleur et de refroidissement

Three different schemes of metal hydride solid sorption devices for heat pumping and cooling applications are presented and compared based on theoretical evaluations. Key parameters obtained from experimental and simulation results from coupled metal hydride reaction beds have been used for the theoretical evaluation. The single (HS) and double stage (HD) devices show reasonable performances, but they require many moving parts. Using high performance reaction beds, e.g. a capillary tube bundle reaction bed, cycle times of about 5–10 min can be obtained with these devices. This corresponds to a specific power output of 100–200 W kg⁻¹ (HS) or 150–300 W kg⁻¹ (HD), referred to the total hydride inventory of the machine. The multi-hydride-thermal-wave (HW) system has a lower specific power output, but it offers significant advantages like modest hardware effort, low pumping power and a very wide operating temperature range.     

Production de froid par transformation thermochimique : expérimentation d'un nouveau système à double effet à contactThermochemical cooling sorption process: experimentation of a new double effect by contact system

The processes proposed in order to improve the energetic performances of thermochemical cooling sorption systems involve an increase of the technological complexity of the installation that can limit their practical interest. The double effect by contact studied allow to consider high energetic performances, simple working mode and also a good compactness of the installation. The analysis of the theoretical working mode of this process, compared to the classic double effect, permits putting forward both advantages and inconveniences of this new process. These are quantified with the help of results supplied from an experimental pilot.     

Performance of a packed bed absorber for aqua ammonia absorption refrigeration systemPerformance d''un matelas dispersant dans un système frigorifique à absorption à ammoniac/eau

A mathematical model of a packed bed absorber for aqua-ammonia absorption refrigeration system is presented. The model is used to predict the performance of the bed at various design and operating conditions. The governing equations and the boundary conditions are derived to predict the bed performance. A numerical integral method and an iteration scheme are used to solve the governing one dimensional, non-linear simultaneous differential equations which are subjected to three point boundary value problem. A computer program is prepared and carefully debugged to solve the governing equations with the help of some supporting equations to describe the properties of the working fluids and the heat and mass transfer coefficients in the bed. The analysis show that the absorption process is affected by the following parameters: the volumetric heat rejection model, bed height, vapor and solution flow rates to the bed and the inlet conditions; and packing material type. The effect of changing each of those parameters on the performance of the bed is studied after suggesting a model for the volumetric heat rejection from the bed. The results showed that changing the bed pressure and/or the vapor inlet temperature have negligible effect on the performance of the bed. Changing other parameters are found to affect the performance of the bed by different degrees. Also, the results show that within the present range of parameters, a bed height less than 0.7 m guarantees an absorption efficiency better than 91%.

Résumé

On présente un modèle mathématique d'un matelas dispersant dans un système frigorifique à absorption à ammoniac/eau. On utilise ce modèle pour prévoir la performance du matelas utilisant diverses conceptions et sous diverses conditions de fonctionnement. On établit des équations qui décrivent ce processus et les conditions limites afin de prévoir la performance du matelas. On utilise une méthode numérique intégrale et un schéma d'itération afin de résoudre les équations unidimensionnelles, non-linéaires, simultanées et différentielles, qui sont soumises au problème des limites à trois points. Un programme informatique est préparé et débogué afin de résoudre les équations qui gouvernent le processus étudié, avec l'aide de quelques équations supplémentaires qui décrivent les caractéristiques des fluides actifs et les coefficients de transmission thermique et de transfert d'énergie massique du matelas. L'analyse montre que le processus d'absorption est influencé par des paramètres suivants: le modèle de rejet de chaleur volumétrique, la hauteur du matelas, les débits d'écoulement de la vapeur et de la solution vers le matelas, les conditions d'entrée et le matériau dispersant utilisé. On étudie également l'influence de la variation de chacun de ces paramètres sur la performance du matelas apres avoir proposé un modèle de rejet de chaleur volumétrique par le matelas. Les résultats montrent que si on change la pression dans le matelas et/ou la température de la vapeur à l'arrivée, de tels changements ont un effet negligeable sur le matelas. Suite au changement d'autres paramètres, la performance du matelas a été modifée de diverses façons. Les résultats montrent également qu'avec les paramètres adoptés ici, une hauteur du matelas inférieure à 0,7 m assure un taux d'absorption supérieur à 91%.     

Simulation d'une machine frigorifique à absorption fonctionnant avec des mélanges d'alcanes

We propose in this article an absorption chiller operating with binary alkane mixtures as an alternative to compression machines. It is an installation using low-level energy at a temperature below 150 °C (waste heat or solar energy) and operating with environmentally friendly fluids. Ten mixtures are considered and compared with two cooling mediums of the condenser and the absorber: the ambient air at 35 °C and the water at 25 °C. For an air-cooled chiller, the COP reaches 0.37 for the n-butane/octane system. This value remains 27% lower than that of an ammonia/water installation operating under the same conditions. For a water-cooling chiller, the n-butane/octane and propane/octane systems give a COP of about 0.63, which is comparable to that of the ammonia/water system. When n-butane is used as refrigerant, the machine works at a pressure under 5 bars, which is an advantage compared with machines working with ammonia/water mixtures.     

Energetic efficiency of cogeneration systems for combined heat, cold and power productionEfficacité énergétique des systèmes de cogénération utilisés pour produire simultanément de la chaleur, du froid et de la puissance électrique

This paper deals with the problem of energetic efficiency evaluation of cogeneration systems for combined heat, cold and power production. Cogeneration systems have a large potential for energy saving, especially when they simultaneously produce heat, cold and power as useful energy flows. Various cogeneration systems for combined heat, cold and power production are designed by means of computer simulation to minimize consumption of the primary energy. Equations of energetic efficiency of this combined cogeneration systems are presented, that relate the primary energy rate (PER) and comparative primary energy saving (Δq_p) to energy parameters of designed systems. Comparison of energetic efficiency of combined cogeneration systems with contemporary conventional separate production of heat, cold and power shows a large potential for energy saving by designed combined cogeneration systems.     

Empirical correlation for ejector designCorrélation empirique pour la conception des éjecteurs

In the present study, two empirical correlations from the test results of 15 ejectors are derived for the performance prediction of ejectors using R141b as the working fluid. The ratio of the hypothetical throat area of the entrained flow to the nozzle throat area A_e/A_t, the geometric design parameter of the ejector A₃/A_t, and the pressure ratios P_g/P_e and P_c*/P_e are used to correlate the performance of the ejector. The prediction of the entrainment ratio ω using the correlations is within ±10% error. A method of calculation for the ejector design using the correlations is also developed. R141b is shown in the present study to be a good working fluid for an ejector. The measured ω for the ejectors used in the present study can reach as high as 0.54 at P_g=0.465 MPa (84°C), P_c^*=0.087 MPa (28°C) and P_e=0.040 MPa (8°C). For P_g=0.538 MPa (90°C), P_c^*=0.101 MPa (32°C) and P_e=0.040 MPa (8°C), ω reaches 0.45.

Résumé

Dans cette étude, on a établi deux corrélations empiriques à partir des résultats expérimentaux obtenus utilisant 15 éjecteurs; ces corrélations ont été utilisées ensuite pour prédire la performance d'éjecteurs utilisant le R141b comme fluide frigorigène. Les rapports A_e/A_t (section de passage du fluide entraîné rapporté à la section théorique du col de l'éjecteur), et A₃/A_t (section de sortie de l'éjecteur rapporté à la section théorique du col de l'éjecteur) et les relations entre pressions P_g/P_e et P_c*/P_e sont utilisés pour trouver la corrélation de la performance de l'éjecteur. La prévision du taux d'entraînement à partir des corrélations est précise à la hauteur de ±10%. Les auteurs ont également développé une méthode de calcul permettant de concevoir des éjecteurs à partir des corrélations. On a montré dans cette étude que le R141b s'avère être un fluide actif efficace pour cette utilisation. Le ω mesuré des éjecteurs utilisés dans cette étude peuvent atteindre 0.54 à P_g=0.465 MPa (84°C), P_c^*=0.087 MPa (28°C) et P_e=0.040 MPa (8°C). Pour P_g=0.538 MPa (90°C), P_c^*=0.101 MPa (32°C) et P_e=0.040 MPa (8°C), ω atteint 0.45.     

Studies on bubble pump for a water–lithium bromide vapour absorption refrigerator: Etudes sur une pompe à bulles pour réfrigérateur à absorption eau–bromure de lithium

The hydrostatic principle and bubble pump technique are used in the two-fluid pumpless continuous vapour absorption refrigerator to create the circulations of the solution and refrigerant. In this paper, the bubble pump, which is the ‘heart' of this natural circulation type of refrigerator, has been investigated both analytically and experimentally. The bubble pump is modelled for intermittent slug flow of solution and vapour mixture. A test rig is built in glass to evaluate the performance of the bubble pump, to visualize the flow behavior and to validate the analytical model. Bubble pump tube diameter, pump lift, driving head and heat input are varied to analyze the pump performance. Results indicate that pumping ratio is nearly independent of the heat input, but increases with decrease in pump tube diameter, decrease in pump lift and increase in driving head.     

A general thermodynamic framework for understanding the behaviour of absorption chillersCadre thermodynamique facilitant la compréhension du comportement des refroidisseurs à absorption

In this article, a general definition of the process average temperature has been developed, and the impact of the various dissipative mechanisms on 1/COP of the chiller evaluated. The present component-by-component black box analysis removes the assumptions regarding the generator outlet temperature(s) and the component effective thermal conductances. Mass transfer resistance is also incorporated into the absorber analysis to arrive at a more realistic upper limit to the cooling capacity. Finally, the theoretical foundation for the absorption chiller T–s diagram is derived. This diagrammatic approach only requires the inlet and outlet conditions of the chiller components and can be employed as a practical tool for system analysis and comparison.     

Simulation and measurement on the full-load performance of a refrigeration system in a shipping containerSimulation et mesures de la performance d'un système frigorifique d'un conteneur maritime entièrement chargé

A mathematical model of a refrigeration system in a shipping container has been developed to allow for full-load simulation of its thermal performance. Sub-models are created on the key components: compressor, evaporator, condenser, and thermostatic expansion valve. The sub-models are then coupled by appropriate mass and energy transfer relations to form the full model. Comparison with a series of cooling capacity tests conducted on a 2.2 m (40 ft) fullscale container housed in a temperature-controlled environmental test chamber indicates good agreement, with simulation results being within ±10% uncertainty of measurements.     

Performances of adsorption systems for ambient heating and air conditioning: Performances de systèmes à adsorption pour le chauffage et le conditionnement d'air d'ambiance

Two adsorption systems are considered: zeolite–water and activated carbon–methanol, both consisting of two ‘uniform temperature' adsorbent beds operating with internal heat recovery by a heat carrier circuit. Regarding the zeolite–water system, the performance obtained with a new adsorbent bed, with good heat transfer properties, is compared with a traditional tube and fin exchanger embedded with zeolite pellets. The performances were calculated by using a dynamic model developed and validated previously. Results show that the system based on the new adsorber has a higher specific power and the same Coefficient of Performance. Results of simulation for adsorbers consisting of finned tube heat exchangers and utilising the activated carbon–methanol pair are also presented.     

Forced convection adsorption cycle with packed bed heat regeneration: Cycle à adsorption à convection forcée avec régénération thermique du lit fixe

The convective thermal wave is part of a patented cycle which uses heat transfer intensification to achieve both high efficiency and small size from a solid adsorption cycle. Such cycles normally suffer from low power density because of poor heat transfer through the adsorbent bed. Rather than attempting to heat the bed directly, it is possible to heat the refrigerant gas outside the bed and to circulate it through the bed in order to heat the sorbent. The high surface area of the grains leads to very effective heat transfer with only low levels of parasitic power needed for pumping. The new cycle presented here also utilises a packed bed of inert material to store heat between the adsorption and desorption phases of the cycle. The high degree of regeneration possible leads to good coefficients of performance (COPs). Thermodynamic modelling, based on measured heat transfer data, predicts a COP (for a specific carbon) of 0.90 when evaporating at 5°C and condensing at 40°C, with a generating temperature of 200°C and a modest system regenerator effectiveness of 0.8. Further improvement is possible. Experimental heat transfer measurements and cycle simulations are presented which show the potential of the concept to provide the basis of a gas-fired air conditioner in the range 10–100 kW cooling. A research project to build a 10-kW water chiller is underway. The laboratory system, which should be operational by June 1997, is described.     

A study on the performance of multi-stage heat pumps using mixturesEtude sur la performance de pompes à chaleur multi-étagées utilisant des mélanges

Multi-stage heat pumps composed of a condenser, evaporator, compressor, suction line heat exchanger, and low and/or high stage economizers are studied by computer simulation. Their thermodynamic performance and design options are examined for various working fluids. In the simulation, HCFC22/HCFC142b and HFC134a are studied as an interim and long term alternatives for CFC12 while HFC32/HFC134a and HFC125/HFC134a are studied as long term alternatives for HCFC22. The results indicate that the three-stage super heat pump with appropriate mixtures is up to 27.3% more energy efficient than the conventional single-stage system with pure fluids. While many factors contribute to the performance increase of a super heat pump, the most important factor is found to be the temperature matching between the secondary heat transfer fluid and refrigerant mixture, which is followed by the use of a low stage economizer and suction line heat exchanger. The contribution resulting from the use of a high stage economizer, however, is not significant. With the suction line heat exchanger, the system efficiency increases more with the fluids of larger molar liquid specific heats. From the view point of volumetric capacity and energy efficiency, a 40%HCFC22/60%HCFC142b mixture is proposed as an interim alternative for CFC12 while a 25%HFC32/75%HFC134a mixture is proposed as a long term alternative for HCFC22.     

A study on the performance of multi-stage condensation heat pumpsEtude sur la performance des pompes à chaleur à condensation en plusieurs étages

In this study, computer simulation programs were developed for multi-stage condensation heat pumps and their performance was examined for CFC11, HCFC123, HCFC141b under the same condition. The results showed that the coefficient of performance (COP) of an optimized ‘non-split type’ three-stage condensation heat pump was 25–42% higher than that of a conventional single-stage heat pump. The increase in COP differed among the fluids examined. The improvement in COP was due largely to the decrease in average temperature difference between the refrigerant and water in the condensers, which resulted in a decrease in thermodynamic irreversibility. For the three-stage heat pump, the highest COP was achieved when the total condenser area was evenly distributed to the three condensers. For the two-stage heat pump, however, the optimum distribution of total condenser area varied with working fluids. For the three-stage system, splitting the condenser cooling water for the use of intermediate and high pressure subcoolers helped increase the COP further. When the individual cooling water for the intermediate and high pressure subcoolers was roughly 10% of the total condenser cooling water, the optimum COP was achieved showing an additional 11% increase in COP as compared to that of the ‘non-split type’ for the three-stage heat pump system.     

Experimental correlation of combined heat and mass transfer for NH3–H2O falling film absorptionCorrélation expérimentale entre le transfert de chaleur et de masse pour de l'absorption au NH3–H2O à film tombant

In this article, experimental analysis was performed for ammonia–water falling film absorption process in a plate heat exchanger with enhanced surfaces such as offset strip fin. This article examined the effects of liquid and vapor flow characteristics, inlet subcooling of the liquid flow and inlet concentration difference on heat and mass transfer performance. The inlet liquid concentration was selected as 5%, 10% and 15% of ammonia by mass while the inlet vapor concentration was varied from 64.7% to 79.7%. It was found that before absorption started, there was a rectification process at the top of the test section by the inlet subcooling effect. Water desorption phenomenon was found near the bottom of the test section. It was found that the lower inlet liquid temperature and the higher inlet vapor temperature, the higher Nusselt and Sherwood numbers are obtained. Nusselt and Sherwood number correlations were developed as functions of falling film Reynolds Re₁, vapor Reynolds number Re_v, inlet subcooling and inlet concentration difference with ±15% and ±20% error bands, respectively.     

Effects of metal mass on the performance of adsorption heat pumps utilizing zeolite 4A coatings synthesized on heat exchanger tubesEffets de la masse métallique sur la performance des pompes à chaleur à adsorption utilisant des revêtements en zéolite 4A synthétisé sur les tubes de l'échangeur de chaleur

The effects of the wall thickness of stainless steel heat exchanger tubes on the performance of adsorption machines, employing zeolite 4A coatings synthesized on metal heat exchanger tubes, are investigated. A recently developed mathematical model is used to determine the cycle durations when various wall thicknesses of the heat exchanger tubes as well as different zeolite layer thicknesses are utilized. For each case, the power and the COP_cycle values of the system are estimated. In general, very high power and quite low COP_cycle values are obtained when the proposed arrangement is utilized in the adsorption heat pumps. The zeolite layer thicknesses that may result in obtaining high COP_cycle values are generally much higher than the optimum layer thickness value that maximizes the power and the utilization of layers thicker than the optimum value may lead to significant extensions in the cycle durations and hence to a decrease in the power obtained from the system. Decreasing the wall thickness of the heat exchanger tubes increases both the power and the COP_cycle values when the optimum zeolite layer thickness for each wall thickness is taken into account. The possibility of such an enhancement will most probably be limited by the minimum wall thickness value that can actually be obtained by the available technology. The COP values of adsorption heat pumps may also be increased by using regenerative processes. Due to the generally low COP values obtained, the proposed arrangement seems especially suitable to be employed in adsorption machines utilizing energy sources of low economical value, such as waste heat. An optimum compromise between the COP value, which is closely related to the operating costs, and the power of the system should be provided, in case more valuable energy sources are utilized.     

A 1-D analysis of ejector performanceAnalyse unidimensionnelle de la performance d'un éjecteur

A 1-D analysis for the prediction of ejector performance at critical-mode operation is carried out in the present study. Constant-pressure mixing is assumed to occur inside the constant-area section of the ejector and the entrained flow at choking condition is analyzed. We also carried out an experiment using 11 ejectors and R141b as the working fluid to verify the analytical results. The test results are used to determine the coefficients, η_p, η_s, φ_p and φ_m defined in the 1-D model by matching the test data with the analytical results. It is shown that the1-D analysis using the empirical coefficients can accurately predict the performance of the ejectors.     

Performance characteristics correlation for round tube and plate finned heat exchangers: Equations relatives aux performances d'échangeurs de chaleur constitués de tubes ronds et de plaques à ailettes

A number of correlation equations describing the performance characteristics of round tube and plate fin have been published in the open literature. However, many of these correlations are restricted to flat finned heat exchangers and a limited number of geometrical configurations. In this study, 28 heat exchanger samples were tested in an open circuit thermal wind tunnel over a velocity range of 1 to 20 m/s for a number of geometries. The geometrical variations include the number of tube rows, fin thickness and the spacing between fins, rows and tubes. Both flat and corrugated fins were tested and the results were correlated in terms of j and f factors as a function of Reynolds number and the geometrical parameters of the heat exchangers. An important feature of this correlation is the novel way in which the geometric parameters are expressed in the correlation. Ratios of these parameters are derived from consideration of the physics of the flow and heat transfer in the heat exchangers. This results in a more accurate and physically meaningful correlation which can be applied to a broader range of geometries. The correlation was validated against test data in the literature for round tube and plate fin with good agreement. It was found that the fin type affects the heat transfer and friction factor, and that the number of tube rows has a negligible effect on the friction factor. The number of tube rows effect was found to be influenced by the fin and tube geometries as well as the Reynolds number.Un certain nombre d'équations pour des caractéristiques du rendement des échangeurs de chaleur à tubes ronds plaques à ailettes ont été publiés dans le littérature. Cependant, dans bien des cas, ces corrélations se limitent aux échangeurs à ailette plate dans un nombre limité de configurations géométriques. Dans cette étude, 28 échangeurs de chaleur ont été testés utilisant une soufflerie à circuit ouvert avec une vitesse d'air de 1 à 20 m/s pour plusieurs formes géométriques. Les variations géométriques portaient sur le nombre de rangées de tubes, l'épaisseur des ailettes et la distance séparant des ailettes, des rangées et des tubes. Les ailettes plates et ondulées ont été testées et les corrélations en termes de facteurs j et f en fonction du nombre de Reynolds et les paramètres géométriques des échangeurs de chaleur. Un aspect important de cette corrélation est le façon originale d'exprimer des paramètres géométriques. Les rapports de ces paramètres sont obtenus à partir des flux et transferts de chaleur dans des échangeurs de chaleur. Ce procedé permet d'obtenir une corrélation plus précise et utilé qui s'applique à une gamme de formes géomátriques plus large. La corrélation a été validée en fonction des données concernant des échangeurs à tube et à plaque à ailettes dans la littérature: les données expérimentales et théoriques concordent bien. On a montré que le type d'ailette exerce une influence sur le transfert de chaleur et le facteur de frottement. Cependant, le nombre de rangées de tubes a un effet negligeable sur le coéfficient de frottement. On a démontré que l'effet nombre de rangées de tube est influencé par les géométries des ailettes et des tubes ainsi que par le nombre de Reynolds.     

Modélisation des données thermodynamiques du mélange ammoniac/eauModelling of the thermodnyamic properties of the ammonia/water mixture

The present work deals with the modeling of the thermodynamic properties of the ammonia/water mixture using the Gibbs free energy function. For the liquid phase, a three constant Margules model of the excess free enthalpy is formulated. The vapour phase is considered as a perfect mixture of real gases, each pure gas being described by a virial equation state in pressure truncated after the third term. The model developed describes with a good accuracy the mixture in the three states, subcooled liquid, superheated vapour and liquid-vapour saturation for temperatures from 200 to 500 K and pressures up to 100 bar.