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Modern understanding of possible mechanisms of crack growth in corrosion cracking of aluminium alloys immersed in various corrosion media such as aqueous solutions, saturated and undersaturated vapour, gaseous hydrogen, etc. is discussed in this review. The experimental data used as a basis to conclusions about the mechanisms of corrosion cracking in aluminium alloys are critically examined. A special emphasis is given to new methods to determining the effect of local anodic dissolution and hydrogen embrittlement in crack growth, i.e. the method of comparative tension and torsion tests deformations of types I and III, and the method based on evaluating ambiguous effect of cathodic polarization on crack growth.  相似文献   

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The results of recent experiments on measuring corrosion fatigue crack propagation rates in structural steel immersed in seawater with and without cathodic polarisation are reported. These include measurements of electrochemical potentials near the growing crack tip. The experiments have been designed to learn more about the mechanisms and rate-determining processes influencing the rate of crack growth. From these and other results in the literature, deductions are made about the relative importance of mechanical and electrochemical limitations on the rate of crack propagation.  相似文献   

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《Acta Materialia》2002,50(13):3487-3500
The phenomenon of vapor pressure assisted void growth and rupture is studied. Plastic electronic packages absorb moisture which condenses within numerous micropores in the substrate, solder mask and die attach materials as well as near their interfaces. During reflow soldering, the condensed moisture vaporizes with the result that these micropores as well as interfaces are subjected to high vapor pressure. Under extreme conditions, our study suggests that vapor pressures can attain high enough levels to drive the voids to grow to rupture, thereby causing package failure. Under other conditions, residual/thermal stresses assisted by vapor pressure can cause crack growth within the polymeric materials as well as along interfaces. Vapor pressure effects on void growth have been incorporated into the Gurson model for porous ductile material. Using this model, a finite element study shows that the combination of high vapor pressure and high porosity is very detrimental to fracture toughness.  相似文献   

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The fracture behaviour of two-phase titanium aluminide alloys was characterized by fracture toughness tests performed in a wide temperature range on chevronnotched three point bending bars. Temperature and rate dependent deformation processes were characterized by temperature and strain rate cycling tests. The alloy investigated had compositions and microstructures which are currently being considered for engineering applications. The paper considers the effects of microstructure and crack tip plasticity on the crack growth resistance. The temperature dependence of the fracture toughness was rationalized in terms of micro-processes which determine the glide resistance of the dislocations in the plastic zone of crack tips. The implications of such observations for the engineering application of the materials are addressed briefly.  相似文献   

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While previous studies have reported that nanocrystalline materials exhibit poor resistance to fatigue crack growth (FCG), the electro-deposited nanocrystalline Ni–Co alloys tested in this paper show superior resistance to FCG. The high damage tolerance of our alloy is attributed to the following: alloying with Co, low internal stresses resulting in stability of the microstructure, and a combination of high strength and ductility. The high density of grain boundaries interact with the dislocations emitted from the crack tip, which impedes FCG, as predicted by the present model and measured experimentally by digital image correlation. Further, the addition of Co increases the strength of the material by refining the grain size, reducing the fraction of low angle grain boundaries, and reducing the stacking fault energy of the material, thereby increasing the prevalence of twinning. The microstructure is stabilized by minimizing the internal stress during a stress relief heat treatment following the electro-deposition process. As a result grain growth does not occur during deformation, leaving dislocation-mediated plasticity as the primary deformation mechanism. The low internal stresses and nanoscale twins preserve the ductility of the material, thereby reaching a balance between strength and ductility, which results in a superior resistance to FCG.  相似文献   

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《Acta Materialia》2004,52(8):2395-2406
Micromechanics analyses of the dominant energy-dissipating mechanisms responsible for the resistance to catastrophic fracture of the aragonitic shell of the giant Queen conch, Strombus gigas, are presented. The crossed lamellar microstructure of the shell is associated with a work of fracture that is three orders of magnitude higher than that of non-biogenic aragonite [J. Mater. Sci. 6 (1996) 6583]. Previous energy-based models predict that multiple “tunnel” cracks in the weak layers of the shell account for a factor of 20 of this increase in fracture energy. We show that the additional factor of ⪞300 results from the synergy between the tunnel cracking and crack bridging mechanisms, analogous to multiple energy dissipating mechanisms observed in brittle matrix composites. The theoretical models demonstrate that the microstructure of the shell of S. gigas is such that potential cracks evolve towards the desirable non-catastrophic ACK (Aveston–Cooper–Kelly) [Properties of fiber composites, Conference Proceedings 15, National Physical Laboratory, IPC Science and Technology Press, 1971] limit, a situation in which all bridging ligaments remain intact along the crack wakes. Load–deflection experiments at temperatures ranging from −120 to 200 °C suggest that a glass transition occurs within the organic (proteinaceous) phase at ∼175 °C, and demonstrate the critical role that this organic “matrix” plays in the resistance of the shell to catastrophic crack propagation.  相似文献   

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F.M. Song   《Corrosion Science》2009,51(11):2657-2674
A fundamentally based mathematical model was developed with the goal to predict, as a first step, the crack growth rate (CGR) of high pH stress corrosion cracking (SCC) of buried steel pipelines. Two methods were used to predict CGRs and for both methods the model has included the film rupture and repassivation mechanism. The two methods are distinguished by the expression used to determine the active anodic current density at the crack tip. In the first method, this current density is expressed by the anodic polarization curve with a large peak current density and the prediction tends to yield a larger CGR and a lower pH at the crack tip. By contrast, when the Butler–Volmer equation is used to express the crack tip anodic current density, with a predicted low CGR the chemistry at the tip does not appear to have any significant change due to the high buffer of the solution.The predicted mechanism responsible for the steady-state crack growth is shown to be the balance between the increasing stress intensity factor as the crack grows, which tends to increase the crack tip strain rate and thus the CGR, and the change of the crack tip condition, which, for large CGRs, is the significant shift in the more negative direction of the crack tip potential, and for low CGRs, the increase of ferrous ion concentration, and either tends to decrease CGR.Limitations currently existing in the model and proposal for further development of the model are discussed.  相似文献   

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The slow crack growth (SCG) resistance (V–KI diagrams) of magnesium aluminate spinel and its tungsten composites with different metallic content (7, 10, 14 and 22 vol.%) is reported. It is found that tungsten plays a crucial role in the composite by increasing crack resistance: the higher the W content, the higher the stress intensity factor needed for crack extension at a given rate. The reinforcement is due to the bridging mechanism performed by metal particles, as it strongly affects the compliance of cracked specimens. Its magnitude is estimated by a compliance function Φ(a) from a double torsion test. From the compliance function, R-curve behaviour is predicted for the composite with highest tungsten content. It explains the effect of metal particles on SCG curves. The W–MgAl2O4 interface is believed to influence the reinforcement mechanism.  相似文献   

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An analysis of the cyclic crack growth rate data generated so far for pressure vessel materials in simulated light water reactor environments suggests a strong dependence on frequency, load ratio, waveform, temperature and material composition. To account for these observations a mechanistic crack growth model has been advanced based on hydrogen-induced cracking, where anodic dissolution creates the conditions for hydrogen absorption at the crack tip. Hydrogen-induced cracking starts from the manganese sulfide inclusions, which act as strong hydrogen traps. The hydrogen-induced crack growth around the manganese sulfide inclusions generally spans several prior austenite grains. At high hydrogen input rates brittle crack growth also occurs, this being unrelated to inclusions. When the crack growth exposes manganese sulfide inclusions, these dissolve and the crack tip environment becomes aggressive and conducive to hydrogen absorption. This hydrogen-induced cracking model explains why inclusions form a preferred crack path, and accounts for the effect of sulfur on crack growth rate both in PWR and BWR conditions. Based on the model, the observed crack growth rate dependence on different testing variables can also be explained.  相似文献   

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In the very high cycle regime (Nf > 107 cycles) cracks can nucleate on inclusions, “supergrains” and pores, which leads to fish-eye propagation around the defect. The initiation from an inclusion or other defect is almost equal to the total crack growth lifetime, perhaps much more than 99% of this lifetime in many cases. Integration of the Paris law allows one to predict the number of cycles to crack initiation. A cyclic plastic zone around the crack exists, and recording the surface temperature of the sample during the test may allow one to follow crack propagation and determine the number of cycles to crack initiation. A thermo-mechanical model has been developed. In this study several fish-eyes from various materials have been observed by scanning electron microscopy, and the fractographic results analyzed as they related to the mechanical and thermo-mechanical models.  相似文献   

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应用断裂力学物理量和有限元方法,分析并揭示焊缝弧坑热裂纹开裂力学机理. 通过应力的无量纲化和正交变换,将热—弹塑性有限元分析获得的节点应力等效为应力强度因子计算模型的外载荷,建立了基于应力强度因子参量的焊缝弧坑热裂纹数值分析模型. 计算并比较焊接热应力作用下焊缝含裂纹单元的张开、剪切和撕裂三类应力强度因子,揭示弧坑裂纹断裂机制并断口试验验证. 结果表明,弧坑热裂纹以拉裂模式主导,在热裂纹敏感区间1100~1000 ℃扩展速度最快,且呈“之”字形开裂取向.  相似文献   

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The influence of the amount of retained austenite on short fatigue crack growth and wear resistance in carburized SAE 8620 steel was studied in this article. Different amounts of retained austenite in the microstructure of the carburized case were obtained through different heat treatment routes applied after the carburizing process. The wear tests were carried out using pin on disk equipment. After every 200 turns the weight loss was registered. Four point bend fatigue tests were carried out at room temperature, using three different levels of stress and R=0.1. Crack length versus number of cycles and crack growth rate versus mean crack length curves were analyzed. In both tests the results showed that the test pieces with higher levels of retained austenite in the carburized case exhibited longer fatigue life and better wear resistance.  相似文献   

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It has been generally recognized that the fatigue life of welded joints is little influenced by the strength of steels owing to the high-stress concentration and the tensile residual stress near the weld toe. In this paper, improvement of the fatigue life of welded joints using steel with high resistance to fatigue crack growth (ferrite/martensite (F/M) steel) is investigated. F/M steel has a microstructure with an elongated and banded martensite phase distributed in a ferrite matrix and a fatigue crack growth rate of about one-half to one-tenth in the thickness direction, compared with conventional steel. As a result, the fatigue life of an out-of-surface gusset-welded joint increases with the decrease of the fatigue crack growth rate. The fatigue life of welded joints using F/M steel with the highest resistance to fatigue crack growth increases to about twice that of joints using conventional steel. Whereas the fatigue crack growth rate decreases significantly, the fatigue life of welded joints increases only slightly. This can be attributed to the stress ratio independent of the fatigue crack growth rate. In other words, the fatigue crack growth rate of F/M steel increases with the increase of the stress ratio, approaching that of conventional steel. In the case of welded joints, even if a fatigue test is carried out at a low-stress ratio, the region near the weld toe is under a high-stress ratio due to tensile residual stress. Therefore, improvement of the fatigue life of welded joints becomes comparatively small so that the effect of fatigue crack retardation of F/M steel decreases.  相似文献   

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