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1.
Determination of Sodium Dodecyl Sulfate by Means of Photometric Titration with o‐Toluidine Blue Dye
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Dorota Ziółkowska Jan Lamkiewicz Alexander Shyichuk 《Journal of surfactants and detergents》2018,21(5):751-756
A convenient technique for the determination of sodium dodecyl sulfate is titration with a metachromatic dye using in situ absorbance measurements. A suitable color reagent is ortho‐Toluidine Blue dye. Commercially available immersion optical probe Optrode® possesses a working wavelength of 640 nm, well matching the dye spectrum. The surfactant concentration is linearly related to the titrant volume at a certain solution absorbance. Optimal values of end point absorbance fall in the range from 0.7 to 2. The lower limit of quantitation is equal to 29 mg L?1. The highest concentration determined in this study was 52 g L?1. The required determination range may be adjusted by the appropriate selection of analyte volume and titrant concentration. The developed method is intended for routine process control in the surfactant industry. This method needs minimal manual efforts due to the lack of the dilution stage. Application of an automatic titrator looks to be a suitable solution for any industrial lab. 相似文献
2.
在用HCl溶液调节pH=12.0的NaOH溶液中,5-甲基-2-[3-(4-苯基-2-噻唑基)三氮烯基]苯磺酸(MPTTBSA)与氯化十六烷基吡啶(CPC)形成离子缔合物MPTTBSA-CPC。在该溶液中加入阴离子表面活性剂时,能定量置换出离子缔合物中的MPTTBSA,使缔合物在最大吸收波长556 nm处的吸光度下降,阴离子表面活性剂的浓度与溶液的褪色程度呈良好线性关系,从而建立了阴离子表面活性剂光度测定法。实验结果表明,十二烷基磺酸钠(SLS)和十二烷基苯磺酸钠(SDBS)的表观摩尔吸光系数分别为1.24×104 L·mol-1·cm-1和1.07×104 L·mol-1·cm-1,在0~2.5×10-5 mol·L-1范围内服从比尔定律。该方法应用于生活污水中微量阴离子表面活性剂(以SLS计)的测定,结果与亚甲基蓝法测定结果基本一致。 相似文献
3.
A direct, extraction‐free spectrophotometric method was developed for the determination of benzalkonium bromide (BAK). The method is based on the formation of mixed dye–surfactant aggregates between alizarin green (AG) and BAK in alkaline medium by measuring the decrease in absorbance of AG at 460 and 700 nm. Beer's law was obeyed in the concentration range 3–40 μg mL?1 with good precision and accuracy. The limits of detection were 0.4 μg mL?1 at 460 nm and 0.3 μg mL?1 at 700 nm, which reduced to 0.2 μg mL?1 by combining the absorbance at the two wavelengths. The proposed method was successfully applied to the determination of BAK in disinfectant solution and eye drops. The analytical results of the real samples were in good agreement with those of an HPLC method. 相似文献
4.
褪色光度法测微量CTMAB 总被引:1,自引:0,他引:1
利用阳离子表面活性剂十六烷基三甲基溴化铵(CTMAB)与偶氮兰形成离子缔合物,使染料发生明显的褪色,体系吸光度的降低与CTMAB浓度成正比,用分光光度法测定CTMAB含量,实验了最佳方法:波长选用554 nm处,CTMAB浓度在0~60μg/25 mL范围内符合比耳定律,方法的线性关系良好(r=0.998 3),检测限为0.18μg/mL(以3σ计),21种常见共存离子不影响CTMAB含量的测定。本法对环境水体中CTMAB含量进行了测定,稳定性和选择性较好,回收率较高(96.0%~103.0%),是一种良好的CTMAB测定方法。 相似文献
5.
Development of an Ultraviolet‐Spectrophotometric Method for Analysis of Esterquat‐Containing Flotation Collectors in Aqueous Solutions
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In this study, a rapid and simple ultraviolet‐spectrophotometric method was developed and validated for the quantitative determination of esterquat‐containing flotation collector FLOT 2015 in aqueous solutions. This method is based on the formation of an ion pair by FLOT 2015 and bromocresol purple, an anionic dye, and the subsequent measurement of the reduction in absorbance without extraction by organic solvents. The optimum conditions for FLOT 2015 detection and analysis were established. Sample solutions were stable up to 3 h. Maximum absorbance was obtained at 574 nm. The proposed method showed linearity in the range of 5–45 μg mL?1 with a correlation coefficient of 0.9917. Standard and relative standard deviation obtained by intraday and interday precision tests of the proposed method were within the permissible bias range and considered satisfactory. This method was found to be selective and specific for successful determination of FLOT 2015 in aqueous flotation systems. 相似文献
6.
Simple, rapid and precise determination of free sulfuric acid in unstabilized cellulose nitrate is accomplished by dissolving in 90 % v/v acetone–water solution and subsequent titration of sulfate by the lead nitrate–dithizone titration method. The method is proved accurately and sensitively for tracing very small amounts of free sulfuric acid present in all types of unstabilized cellulose nitrates. One more advantage of the method is that free nitric acid do not interfere in the determination, and, hence, there is no need to estimate its value and to correct the value for the free sulfuric acid content; the determination of free nitric acid, which is likely to be present with sulfuric acid in unstabilized cellulose nitrate is a very difficult problem. 相似文献
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This paper studies the interaction of anionic dye Phenol Red with cationic surfactant cetyltrimethylammonium bromide in aqueous solution and its influence on the formation of cetyltrimethylammonium bromide micelles for the first time. We obtain a series of thermodynamic parameters of the interaction by establishing a reasonable physical model of the association. Moreover, an in‐depth study on the variation in the absorption spectrum finds that the value of absorbance at the maximum absorption peak changes regularly with increase in the cetyltrimethylammonium bromide concentration. By establishing the micellisation models and measuring the changes in electrical conductivity with different cetyltrimethylammonium bromide concentrations, the critical micelle concentration values are obtained, which are essentially the same as the range of concentrations of regular change in absorbance, which shows that the formation of the cetyltrimethylammonium bromide micelles have an impact on the association interaction between Phenol Red and cetyltrimethylammonium bromide. All these data and phenomena illustrate a strong interaction between Phenol Red and cetyltrimethylammonium bromide. 相似文献
9.
Electrokinetic properties, namely, zeta potential (ζ), surface charge density (σ), and surface conductivity (Ks) of polyformaldehyde fibers [poly(oxymethylene) fibers] have been studied in the presence of direct dyes, with or without surfactants and an electrolyte. The anionic dyes increased the negative zeta potential of fibers. The increase in ζ was found to be a function of concentration and basicity of the dye in the streaming solution. Thus, the tetrabasic dye gave higher value of negative ζ than the equivalent concentration of the dibasic dye. The cationic surfactant brought about a decrease in negative ζ, giving a point of inflection, while the anionic surfactant increased it. The nonionic surfactant brought about a certain reduction in negative ζ, but failed to give a point of inflection. In the presence of a direct dye, the cationic surfactant brought about considerable reduction in negative ζ, to give a point of inflection. The presence of an electrolyte in the streaming dye solution progressively lowered the negative ζ. In general, σ increased with the increase in the concentration of either a dye or an electrolyte in the presence of a given concentration of the dye in the streaming solution. Results on Ks indicated that the surface conductivity of the fibers is a function of concentration of dye, surfactant, and electrolyte. It was, however, observed to be independent of the nature of the surfactant. Although both the dibasic and tetrabasic direct dyes brought about an increase in Ks, the extent of increase was dependent upon the basicity of the molecules. 相似文献
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浮选光度法测定饮用水中亚硝酸根 总被引:3,自引:0,他引:3
基于亚硝酸根在弱酸性的条件下重氮化反应 ,重氮化盐再与 N,N-二甲基苯胺进行偶合反应 ,生成黄色甲基橙 ,酸化后甲基橙变成红色 ,用十二烷基硫酸钠浮选富集 ,在正丁醇中收集浮选液 ,进行分光光度测定 ,从而求得亚硝酸根的含量。摩尔吸光系数ε为 9.7× 1 0 4L/ mol· cm(正丁醇为溶剂 ) ,亚硝酸根的浓度在 0 .0 4 1~ 0 .0 0 4 1μg/ m L与吸光度有良好的线性关系。该法可检出纯净水中痕量亚硝酸根的含量 相似文献
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Guoqiang Cai Liangxi Sun Jindan Wu Jiping Wang 《Journal of surfactants and detergents》2015,18(6):1127-1135
Nonionic surfactants are widely used in reactive dyeing processes, and the interaction between surfactants and reactive dyes affect the hydrolytic property of reactive dyes. In this study, reactive brilliant blue KN‐R (C.I. reactive blue 19) was employed as a model dye, and fatty alcohol polyoxyethylene ether (AEO‐9) was selected as a model nonionic surfactant. The interaction was first investigated in aqueous solutions by a UV‐spectrophotometry method, then the effect of surfactant concentration on the hydrolytic behavior of KN‐R was studied using high performance liquid chromatography method. Below the critical micelle concentration, the surfactant served as dispersant; the hydrolysis of reactive dye was accelerated. However, when the concentration of surfactant was above its critical micelle concentration, the dye was solubilized into the micellar phase, which was revealed from the changes in absorbance intensity and wavelength of the maximum absorbance. This led to slowed hydrolysis of reactive dye. These findings are useful in understanding the effect of concentration of nonionic surfactant on the hydrolysis of vinyl sulfone reactive dyes. 相似文献
15.
Interactions and Solubilization of Disperse Dye with Modified Gemini Surfactants: Investigation Using the Taguchi Method 总被引:1,自引:0,他引:1
Since the interaction of a disperse dye with a surfactant in micelles plays an important role in textile industry, the purpose of this study was to find out the optimal conditions that describe the dye?Csurfactant interaction. The effects of temperature, gemini surfactant concentration and ethylene-oxide chain length of gemini surfactants were investigated and optimized using the Taguchi method. First, this method was adopted to carry out the parameter design, and the interaction parameters that would affect the absorbance of UV?Cvisible spectrum were chosen as the control factors. After the selection of an appropriate orthogonal array, an analysis of variance was applied to decide upon the optimal conditions of solubilization parameters and determine the significant factors of the UV?Cvisible absorbance. The optimized conditions were as follow: surfactant concentration 5.6 × 10?4 M, length of ethylene oxide chain 20, and temperature 40 °C. Finally, the experimental results of confirmation tests with a confidence interval of 95%, indicated that the experiment is reliable and reproducible. Under these optimum conditions, it was also determined that the solubilization of disperse dye using modified gemini surfactants increased when the surfactant concentration and the ethylene oxide chain length increased. 相似文献
16.
Benzoylacetone, keto-enol tautomer, was dissolved in aqueous solutions of sodium dodecyl sulfate, dodecyl trimethyl ammonium
chloride, hexaethyleneglycol dodecyl ether, polyoxyethylene tert-octyl phenyl ether, and polyoxyethylene nonyl phenyl ether,
respectively. The effect of surfactants on this keto-enol equilibrium was examined by measuring the intensity of two spectral
bands at ca. 250 nm and 315 nm due to ketonic and enolic form of this compound. The existence of keto-enol equilibrium of
the benzoylacetone was indicated by an isosbestic point among the two bands. The absorbances of the two bands showed hardly
any change in the range of surfactant concentrations below the critical micelle concentration (cmc) but, in the concentration
range above the cmc, the absorbance of the enolic form increased and that of the ketonic form decreased abruptly. These changes
at cmc were very noticeable in the case of ionic surfactant solution. The concentrations corresponding to abrupt change of
the spectra used for the determination of cmc were in fair agreement with data obtained by other methods. However, in the
case of nonionic surfactant solutions, the absorbance due to the enolic form increased gradually with increase of the surfactant
concentration, and the distinct break point was not observed at cmc. 相似文献
17.
K. Gharanjig M. Sadeghi-Kiakhani A. R. Tehrani-Bagha A. Khosravi F. M. Menger 《Journal of surfactants and detergents》2011,14(3):381-389
The solubility of naphthalimide-based monoazo dyes containing N-ethyl and N-ethanoic acid groups was investigated in the presence of a conventional monomeric counterpart (DTAB) and two cationic gemini
surfactants (12-4-12 or 14-4-14) individually. The effective parameters on dye solubility such as temperature, time and concentration
of surfactants were investigated by UV–Visible spectrophotometry. The results demonstrate that the solubility of both dyes
was considerably increased at concentrations above the surfactant CMC. The wavelength for the maximum absorbance of dyes in
the aqueous solution shifts toward longer wavelengths with changes in the concentration of the cationic surfactants. A kinetic
study of solubilization of dyes in cationic surfactants solution showed that the rate of solubilization follows the pseudo-first-order
reactions. Rates of solubilization were in the range of 0.5 × 10−3 to 6.8 × 10−3 min−1 for both dyes. The disperse dye containing a carboxylic acid group (dye 2) has a higher solubility rate than the dye containing
an alkyl group (dye 1). The type of surfactant has a very low effect on adsorption of dye 1 onto the polyester fibers, whereas
changing the surfactant type from DTAB to 12-4-12 or 14-4-14 causes adsorption of dye 2 on polyester to decrease. 相似文献
18.
硫酸铵、羟基乙酸(GA)混合溶液中各组分定量分析时均存在另一组分的严重干扰。在甲醛法测定硫酸铵含量、酸碱滴定法测定羟基乙酸含量基础上,引入乙酰丙酮分光光度法,改进并建立了混合溶液中各组分定量分析方法。探讨了检测波长、羟基乙酸浓度、乙醇浓度、恒温时间、反应温度、p H值对3,5-二乙酰基-1,4-二氢二甲基吡啶(DDL)溶液吸光度的影响。该方法的适宜条件为:p H=5~7,ω(GA)90%,60℃恒温15 min,测定波长414 nm。线性方程Ar=0.242 5 C+0.004 0,线性范围0.05~4.00μg/m L,R2=0.999 9。方法测硫酸铵含量RSD1.5%,羟基乙酸含量RSD1.8%。此分析方法快捷、简便、灵敏、准确。 相似文献
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20.
Controlling the dispersion of multi-wall carbon nanotubes in aqueous surfactant solution 总被引:3,自引:0,他引:3
The sonication-driven dispersion of multi-wall carbon nanotubes (MWCNTs) in aqueous surfactant solution has been monitored by UV-vis spectroscopy and transmission electron microscopy. Time dependent sonication experiments reveal that the maximum achievable dispersion of MWCNTs corresponds to the maximum UV-vis absorbance of the solution. With higher surfactant concentration the dispersion rate of MWCNTs increases and less total sonication energy is required to achieve maximum dispersion. Dispersion of higher MWCNT concentrations requires higher total sonication energy. For effective dispersion the minimum weight ratio of surfactant to MWCNTs is 1.5-1. The surfactant molecules are adsorbed on the surface of the MWCNTs and prevent re-aggregation of MWCNTs so that a colloidal stability of MWCNT dispersions could be maintained for several months. The maximum concentration of MWCNTs that can be homogeneously dispersed in aqueous solution is about 1.4 wt%. 相似文献