共查询到19条相似文献,搜索用时 78 毫秒
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付雪琴 《四川化工与腐蚀控制》2000,3(3):12-13
在硝酸,硝酸锌介质中,用硝酸银自动电位滴定法测定亚铁氰化钾,亚铁氰化钠中微量氯化物,其测定结果的准确度,精密度均符合国家标准要求。 相似文献
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在硝酸、硝酸锌介质中 ,用硝酸银自动电位滴定法测定亚铁氰化钾、亚铁氰化钠中微量氯化物 ;其测定结果的准确度、精密度均符合国家标准要求 相似文献
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以HG/T3607—2000为基础,研究了用Metrohm 798 MPT Titrino全自动电位滴定仪测定氢氧化镁中镁离子质量分数的方法,铜电极为指示电极,银/氯化银为参比电极。与人工滴定比较,具有操作简便、分析速度快、终点判断准确的特点,受环境及溶液温度的影响小。并用基准氧化镁对该方法进行了验证。 相似文献
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探讨自动电位滴定法测定氯化物的检出限、精密度与准确度以及适宜测定的pH值范围。实验结果:方法检出限0.2 mg/L;对浓度分别为50 mg/L和200 mg/L的样品测定的相对标准偏差分别为1.3%和0.4%;加标回收率分别在97.8%~102.5%、99.0%~100.5%之间;适宜测定的pH范围为3~12。 相似文献
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A modified determination of iodine value in fats, fatty acids, and fatty acid derivatives is reported. The described procedures,
visual and potentiometric, have wide applicability and generate less solvent waste. These analytical procedures are based
on a nonchlorinated solvent system. The performance of the new procedures was evaluated in a multiple-laboratory study. 相似文献
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R. G. Ackman E. Macpherson A. Timmins 《Journal of the American Oil Chemists' Society》1998,75(9):1223-1225
Squalene has six ethylenic bonds, but the experimental iodine values in two different solvent systems—chloroform and cyclohexane/acetic
acid—were 25% higher than the theoretical values. We propose that this results from an additional halogen adding at each of
the two terminal ethylenic bonds carrying two methyl groups. In the solvent system of cyclohexane alone, the excess is only
3–4% greater than the theoretical. Mixtures of squalene in seal oil confirmed the additivity of the experimental squalene
high iodine value and the seal oil fatty acid iodine value with reasonable accuracy but depended on the skill of the operator
in obtaining the titration end point for cyclohexane/acetic acid. This observation has particular relevance for shark liver
oils and olive oils. 相似文献
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R. G. Ackman E. Macpherson A. Timmins 《Journal of the American Oil Chemists' Society》1998,75(12):1223-1225
Squalene has six ethylenic bonds, but the experimental iodine values in two different solvent systems—chloroform and cyclohexane/acetic
acid—were 25% higher than the theoretical values. We propose that this results from an additional halogen adding at each of
the two terminal ethylenic bonds carrying two methyl groups. In the solvent system of cyclohexane alone, the excess is only
3–4% greater than the theoretical. Mixtures of squalene in seal oil confirmed the additivity of the experimental squalene
high iodine value and the seal oil fatty acid iodine value with reasonable accuracy but depended on the skill of the operator
in obtaining the titration end point for cyclohexane/acetic acid. This observation has particular relevance for shark liver
oils and olive oils. 相似文献
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本实验采用常量、微型滴定法对市售碘盐中碘的含量进行测定。结果表明:两种方法对同一样品的测定结果无显著差异,同样准确可靠。但因微型滴定法耗时短、成本低、仪器携带方便,所以推荐基层食品检验、经营等单位使用微型滴定法进行碘盐中碘含量的测定。 相似文献
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T. Haryati Y. B. Che Man A. Asbi H. M. Ghazali L. Buana 《Journal of the American Oil Chemists' Society》1997,74(8):939-942
Iodine value (IV) is used as a parameter in process control as well as a quality parameter in traded palm oil products. IV
measures the number of double bonds in the molecular structure of an oil. To form a double bond, carbon requires more energy
(615 kJ/mol) than to form a single bond (350 kJ/mol). Therefore, the thermal behavior of an oil could reflect its iodine value.
This study was conducted to demonstrate the use of a differential scanning calorimeter (DSC) to determine the IV of palm oil
and its products as an attempt to reduce the use of chemicals in the analysis. The DSC thermograms of palm oil showed a clear
separation of the substances that have low melting points (low-T), consisting of triunsaturated, monosaturated and disaturated
triglycerides, from the high ones (high-T), consisting of trisaturated triglycerides. Regression analysis showed that the
peak characteristics, namely, area and height of the low-T group and height of the high-T group in the heating thermogram
and also the height of the high-T group in the cooling thermogram, can predict the IV of palm oil with R
2 higher than 0.99. This study concludes that DSC can be used to determine the IV of palm oil and its products. 相似文献
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Discrimination of edible oil products and quantitative determination of their iodine value by Fourier transform near-infrared spectroscopy 总被引:3,自引:0,他引:3
Hui Li F. R. van de Voort A. A. Ismail J. Sedman R. Cox C. Simard H. Buijs 《Journal of the American Oil Chemists' Society》2000,77(1):29-36
This work demonstrates the application of partial least squares (PLS) analysis as a discriminant as well as a quantitative tool in the analysis of edible fats and oils by Fourier transform near-infrared (FT-NIR) spectroscopy. Edible fats and oils provided by a processor were used to calibrate a FT-NIR spectrometer to discriminate between four oil formulations and to determine iodine value (IV). Samples were premelted and analyzed in gass vials maintained at 75°C to ensure that the samples remained liquid. PLS calibrations for the prediction of IV were derived for each oil type by using a subset of the samples provided as the PLS training set. For each oil formulation (type), discrimination criteria were established based on the IV range, spectral residual, and PLS factor scores output from the PLS calibration model. It was found that all four oil types could be clearly differentiated from each other, and all the validation samples, including a set of blind validation samples provided by the processor, were correctly classified. The PLS-predicted IV for the validation samples were in good agreement with the gas chromatography IV values provided by the processor. Comparable predictive accuracy was obtained from a calibration derived by combining samples of all four oil types in the training set as well as a global IV calibration supplied by the instrument manufacturer. The results of this study demonstrate that by combining the rapid and convenient analytical capabilties of FT-NIR spectroscopy with the discriminant and predictive power of PLS, one can both identify oil type, as well as predict IV with a high degree of confidence. These combined capabilities provide processors with better control over their process. 相似文献