共查询到18条相似文献,搜索用时 125 毫秒
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丙烯酸酯无皂乳液的研究 总被引:4,自引:1,他引:4
在甲基丙烯酸甲酯和丙烯酸丁酯的无皂乳液体系中,加入适量的自制聚氨酯型反应性乳化剂(URE),考察单体配比和有机溶剂对乳胶膜性能的影响,并研究了聚合物乳液的稳定性。结果表明:与传统乳液聚合体系相比,所合成的胶乳耐电解质、耐酸碱、耐有机溶剂的性能均好。 相似文献
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用AMPS合成高耐水性丙烯酸乳液压敏胶的研究 总被引:15,自引:3,他引:12
运用可聚合乳化剂AMPS和极少量低分子化剂CO-436相配合,采用特殊工艺的半连续无皂乳液聚合方法,研制出了一种耐水性较好的丙烯酸乳液压敏胶,并就其各种性能及影响因素进行了考查,结果表明,聚合工艺对AMPS乳液的聚合稳定性有较大影响,用可聚合乳化剂AMPS合成的丙烯酸乳液压敏胶具有较好的耐水性。 相似文献
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高性能无皂硅丙乳液合成的研究 总被引:6,自引:0,他引:6
本文在无乳化剂下合成了硅丙乳液。利用丙烯酸丁酯与甲基丙烯酸(钠)制备低聚物P(BA/MANa)代替乳化剂,由于低聚物P(BA/MANa)与合成的硅丙乳液P(BA/MMA)结构中都有PBA链段,有利于两者互容,因此,在硅丙乳液合成中虽不使用乳化剂,但乳化效果更好。研究了丙烯酸丁酯与甲基丙烯酸单体配比、pH值变化对低聚物性能的影响;研究了低聚物用量、软硬单体配比、有机硅单体种类与用量、有机硅单体(KH-570)加入方式等对合成硅丙乳液性能的影响,找出了合成无皂种子乳液与无皂硅丙乳液的最佳工艺参数,合成的无皂硅丙乳液的耐候性、耐水性等性能更加优良,硅丙乳液应用范围更加广泛。 相似文献
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Yuhong Zhang Shanshan Pan Shulun Ai Hang Liu Haiping Wang Peixin He 《Iranian Polymer Journal》2014,23(2):103-109
The emulsifier-free emulsion polymerization of vinyl acetate (VAc) and butyl acrylate (BA) in the presence of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) was carried out by a semi-continuous process. AMPS was a reactive surfactant in the aqueous emulsion, due to its amphiphilic structure and the unsaturated double bonds. Potassium persulfate (KPS) was used as initiator. The following factors were mainly examined: quantity of AMPS, BA and KPS concentrations, which could significantly affect the particle size and its distribution, conversion, gel content, minimum film-forming temperature, etc. The particle size and its distribution were characterized by dynamic laser particle size analyzer, and morphology of the latex particles was characterized by transmission electron microscopy (TEM). Fourier transform infrared spectroscopy was used to characterize chemical structure of copolymers. The results indicated that AMPS was successfully reacted onto the resulted copolymer of vinyl acetate and butyl acrylate. A hydrophilic sulfonic acid group in the molecular structure of AMPS tended to be distributed in particles surface after polymerization. As a result, an electrostatic repulsion between the particles was produced in order to maintain stability of the system. Thermogravimetric analysis curves suggested that as BA content increased, thermal stability of the polymer increased accordingly. The conversion-time plots with varying AMPS and initiator contents were obtained, which illustrated that the initiator concentration could greatly influence the polymerization rate and the final conversion. The TEM micrographs of the final emulsifier-free latex particles for P(VAc/BA/AMPS) system revealed small particle size in monodisperse polymer latex. The particles of the latex were measured as about 150 nm. 相似文献
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Víctor M. Ovando‐Medina Paola E. Díaz‐Flores René D. Peralta Eduardo Mendizábal Gladis Y. Cortez‐Mazatan 《应用聚合物科学杂志》2013,127(4):2458-2464
Vinyl acetate (VAc) and butyl acrylate (BuA) were copolymerized in heterophase by a semicontinuous process (unseeded) and compared with the seeded semicontinuous microemulsion polymerization of the same monomers. A mixture of sodium dodecyl sulfate (SDS) and poly(ethylene oxide) dodecyl ether (Brij‐35®) were used as surfactants. The effects of monomer addition rate (Ra) and surfactants concentrations (4 or 1 wt % with respect to the initial mixture of reaction) on polymer and latex properties were studied. High copolymer content latexes (24–36 wt %) with average particle diameters (Dp) from 38 to 55 nm and relatively narrow particle size distributions, high polymerization rates, weight ratios of polymer to surfactant (P/S) from 13.3 to 32.8 were obtained. The number‐average molecular weights (Mn) were between 96,000 and 188,000 g/mol. Homogeneous copolymer compositions were obtained throughout the reaction for both, seeded and unseeded processes, which is not possible by the usual batch microemulsion process. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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The concentrated emulsion copolymerization of butyl acrylate and vinyl acetate with an ammonium persulfate/sodium hydrogen sulfate mixture as a redox initiator, with a sodium dodecyl sulfate/cetyl alcohol mixture as a compound surfactant, and with poly(vinyl alcohol) as a liquid film reinforcer was carried out at lower temperature. In less than 3 h, the polymerization conversion was greater than 95%. The effects of the surfactant, the initiator, the volume fraction of the monomer, and the temperature on the stability of the concentrated emulsion, the kinetic process, and the average size of the latices were examined. The morphology of the polymer particles was observed by transmission electron microscopy, and the average size and distribution of the particle diameter were measured by photon correlation spectroscopy. The kinetic equation was Rp = k[M]0.38[I]0.89[E]?0.80 at 30°C (where Rp is the polymerization rate, [I] is the initiator concentration, [M] is the monomer concentration, and [E] is the concentration of the compound surfactant), and the apparent activation energy was 22.69 kJ/mol. The thin‐layer polymerization of the concentrated emulsions, which enabled the removal of the heat of polymerization, was performed first. In comparison with test‐tube polymerization, thin‐layer polymerization provided a more regular morphology of the polymer particles. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 570–576, 2004 相似文献
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丙烯酸(酯)改性聚醋酸乙烯酯乳液的研制 总被引:1,自引:1,他引:1
采用半连续种子乳液聚合法,使用丙烯酸(AA)功能性单体和丙烯酸丁酯(BA)软单体对醋酸乙烯酯(VAc)进行了共聚改性,制备出高固含量(50.2%)的聚醋酸乙烯酯(PVAc)改性乳液。该乳液适合用于喷雾干燥法制备可再分散聚合物粉末,并且其耐水性和耐碱性等都得到了明显地改善。对影响共聚物的诸多因素进行了较为全面地考察,得出最佳的工艺条件为:AA用量为主单体质量的3%~4%,BA用量为主单体质量的5%~10%,保护胶体用量为混合单体质量的7.5%~15%,引发剂用量为混合单体质量的0.4%~0.5%,阴/非离子型复合乳化剂的质量比为1∶2~1∶3、用量为混合单体质量的2%~3%,分散剂、消泡剂和酸碱缓冲剂等助剂均为适量,加料时间为3~4h,反应温度为70~75℃。 相似文献
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A series of butyl acrylate (BA) and vinyl acetate (VAc) homopolymerizations in toluene was conducted to investigate the effect of solvent at different solvent and chain transfer agent (CTA) concentrations. Because the experimental determination of the individual propagation and termination rate constants for these systems is challenging, experimental observations were limited to the lumped rate constant (kp/k). Differences in the lumped rate constant, at different solvent and CTA concentrations, were assumed to be attributed to the effect of solvent on the termination rate constant. Our hypothesis was that the termination rate constant kt was affected by the presence of solvent. At higher solvent concentrations, chain transfer to solvent occurs more frequently and leads to the formation of shorter chains, which move more easily and are able to terminate more quickly compared to longer chains. Thus, kt will increase, leading to a decrease in the lumped rate constant. The experimental results confirmed the presence of a solvent effect on the lumped rate constant. This effect was more pronounced in the case of VAc compared to BA solution homopolymerizations. Under the investigated conditions, increased CTA concentrations did not substantially affect the rate of BA homopolymerizations, whereas a slight synergistic effect between the CTA and solvent at higher CTA and solvent concentrations was apparent for VAc homopolymerizations. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 871–876, 2004 相似文献
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No alternating copolymers of vinyl acetate (VAc) and butyl acrylate (BA) were obtained by free radical copolymerization in the presence of GeCl4 and BCl3 (compared with the acrylic acid–vinyl acetate copolymerization system). By ultraviolet spectral analysis, it was concluded that both BCl3 and GeCl4 can form complexes with butyl acrylate. The BA–BCl3 complex constants were determined by 1H NMR; KB=33·2 (25°C). The reason for the gel formation in the BA–Vac–BCl3 copolymerization system was discussed. When vinyl acetate reacted with BCl3, cationic polymerization probably occurred. A white gel product probably resulted from the polymerization of the BA–BCl3 complex. © 1998 SCI. 相似文献