共查询到20条相似文献,搜索用时 140 毫秒
1.
2.
淀粉以其绿色环保的优点在胶黏剂领域中的应用占有举足轻重的地位,但是单一的淀粉胶黏剂有很多不足之处。满足不了各个领域的多方面需求,因此在一定条件下经过物理、化学或者生物方法对其进行有限度的改性,研制出了各种具有优良性能的改性淀粉胶黏剂并且在各个领域中都有很好的推广应用。根据淀粉胶黏剂在改性方面的研究和开发概况,综合介绍了几种改性淀粉胶黏剂的产物性能及其在包装行业中的推广应用情况,最后指出了淀粉胶黏剂改性的优势及未来发展的方向。 相似文献
3.
4.
在皮肤、内脏、心血管、骨和软/硬组织伤口的再生修复方面,医用胶黏剂具有广泛的应用需求。但在人体内潮湿环境中,生物医用胶黏剂的黏附力较弱是临床上一直面临的挑战。为此,从物理、化学以及生物角度出发,通过模拟自然界中各种动、植物的黏附机制,各种聚合物基仿生医用胶黏剂得到了研发与应用,有效解决了潮湿环境中黏附力较弱的问题。文章总结了各种聚合物基仿生医用胶黏剂的黏附机制及其在创口黏合、止血及软/硬组织再生修复中的应用,并展望了医用胶黏剂的未来发展方向。 相似文献
5.
以天然可再生资源替代传统化石资源开发绿色环保、性能优异的木材胶黏剂是人造板行业研究的热点。木质素来源广泛、价格低廉,且分子结构中含有羟基、甲氧基、羧基等活性基团,易于功能化修饰,是合成木材胶黏剂的理想原料。本文重点综述了木质素及其衍生物在酚醛树脂、脲醛树脂、环氧树脂、聚氨酯等合成树脂木材胶黏剂中的应用与研究现状,介绍了化学改性、降解、溶剂分级纯化等预处理方式对木质素化学反应活性及合成树脂胶黏剂力学性能的影响,探讨了木质素基木材胶黏剂目前发展面临的困难和挑战,并展望了未来应用及研究方向,以期为木质素资源的高效、高值化综合利用及高性能生物基木材胶黏剂的开发提供理论与技术参考。 相似文献
6.
生物基胶黏剂拥有环境优良且可再生等方面的特点,在使用方面应用较为广泛。在分析生物油淀粉胶黏剂时,对其固化过程中的热行为、固化反应、固化工艺等方面进行了探讨,并有效运用了复合固化剂和单一固化剂胶黏剂热行为,可从中发现复合固化反应热较大,且固化特征温度较低,其复合固化剂体系固化更为充分有效。文章主要分析了生物油淀粉胶黏固化特征,旨在进一步推动胶黏剂固化。 相似文献
7.
胶黏剂在陶瓷的修复、生产和连接等许多方面起着重要的作用,综述了陶瓷用胶黏剂的研究现状,在简要介绍陶瓷结构性能的基础上,重点介绍了应用于陶瓷领域的磷酸盐类胶黏剂、硅酸盐类胶黏剂、氧化物类胶黏剂等无机胶黏剂和环氧树脂胶黏剂、酚醛树脂胶黏剂、丙烯酸脂类胶黏剂等有机胶黏剂近年来国内外的研究情况,以促进陶瓷用胶黏剂的发展。 相似文献
8.
9.
10.
11.
树皮是一种丰富的可再生天然高分子材料,随着石油资源的日趋短缺,研究并合理利用树皮制备高分子材料具有积极意义。首先在复合酸存在下采用高温苯酚液化法将落叶松全树皮进行液化处理,然后以此作为部分苯酚的替代物,制备耐水环保型树皮胶(即苯酚液化落叶松全树皮-甲醛胶粘剂)。重点研究了不同加碱次数对树皮胶主要性能的影响。结果表明:加碱次数对树皮胶的理化性能影响较大;采用2次加碱工艺制成的树皮胶具有相对最好的综合性能,其胶接性能及游离甲醛释放量均与纯酚醛树脂(PF)胶相当;苯酚液化落叶松全树皮对苯酚的替代量达到30%,但所得系列树皮胶的储存期较短。 相似文献
12.
Thermosetting plastic composites have been prepared with phenol–formaldehyde resins as well as unsaturated polyesters as binders and coconut hair as fibrous reinforcement. Using resole-type phenol–formaldehyde resins, the effect of coconut fiber pretreatment by NaOH, the precondensation time of the impregnated fibrous press material, the resin–fiber ratio, and pressing parameters have been studied. Especially advantageous press-material has been obtained using 60–65 wt % linear novolac type phenol-formaldehyde resin as binder and 35–40 wt % of coconut hair. Applying unsaturated polyester (UP) as binder, BMC (bulk molding compound)-type press material can be prepared using coconut fiber reinforcement instead of glass fibers. To achieve better coupling between coconut fiber and UP matrix, coconut fiber was pretreated by NaOH and/or gamma-preirradiation. It has been found that in glass-fiber-reinforced UP press materials a significant part of glass fiber could be changed for short-cut coconut fiber. 相似文献
13.
竹焦油是竹炭产业的副产物之一,富含酚类物质,可部分替代昂贵苯酚合成竹焦油酚醛树脂(BPF)。以n(苯酚)/n(甲醛)、竹焦油替代率、n(NaOH)/n(苯酚)和反应时间为试验因素,以BPF的黏度和游离酚含量、相应胶合板的胶接强度和甲醛释放量为考核指标,采用正交试验法优选合成高替代率环保型BPF的最佳工艺条件。结果表明:当n(苯酚)/n(甲醛)=2.0、竹焦油替代率为50%、n(NaOH)/n(苯酚)=0.35和反应时间为60 min时,由BPF胶粘剂压制而成的胶合板,其胶接强度和甲醛释放量分别达到GB/T 9846.3—2004标准中Ⅰ类胶合板和E0级的指标要求。 相似文献
14.
Condensed tannins are phenolic in nature and undergo reaction with formaldehyde to form resins. Tannin/formaldehyde condensates tend to have a low degree of condensation resulting in bonds lacking strength and water resistance. Small amounts of short-length phenol/resorcinol/formaldehyde, phenol/formaldehyde, and urea/formaldehyde polymers are used to increase the degree of polymerization of tannin-formaldehyde resins, decreasing brittleness and increasing water resistance. Furfural is used to plasticize tannin/formaldehyde resins to improve the distribution of stress forces on the glueline, overcoming weakness due to stress concentration. Exterior plywood panels were prepared using these modified tannin/formaldehyde resins as adhesives. The modified tannin/formaldehyde adhesives perform well, have similar characteristics to and are as easy to use as phenol/formaldehyde adhesives, and also have a few advantages, especially tolerance to faster pressing times. 相似文献
15.
The kinetics of phenol–formaldehyde prepolymers catalyzed by sodium hydroxide at various temperatures was studied. Several reactions were conducted with different phenol to formaldehyde as well as phenol to sodium hydroxide molar ratios. The React‐IR system was used to monitor the reaction as well as to determine residual free phenol and formaldehyde. The changes in the concentrations of phenol and formaldehyde with the reaction time were determined. The value of the concentration of the hydroxide ion, [OH?], was obtained by measuring the pH value of reaction mixture. The concentration of the hydroxide ion, [OH?], expressed as a function of reaction time, was fitted by the six‐order polynomial to the experimental data. On the basis of the proposed reaction scheme the kinetic model was developed. The kinetic parameters were obtained by adjusting the experimental evolution of phenol and formaldehyde during the synthesis. Using this method the changes in the concentrations of five species of hydroxymethyl phenols with the reaction time was also been calculated. The activation energy and preexponential factor have been calculated for individual reactions. The accuracy of the kinetic model was confirmed by comparing experimental concentration profiles of formaldehyde and phenol with the calculated ones for different molar ratios. The experimental tendencies are in agreement with the results of the model. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
16.
Yongsheng Zhang Xiaomeng Yang Jinpan Bao Hang Qian Dong Sui Jianshe Wang Chunbao Charles Xu Yanfang Huang 《Frontiers of Chemical Science and Engineering》2023,17(5):504
Phenolic resins were employed to prepare electrospun porous carbon nanofibers with a high specific surface area as free-standing electrodes for high-performance supercapacitors. However, the sustainable development of conventional phenolic resin has been challenged by petroleum-based phenol and formaldehyde. Lignin with abundant phenolic hydroxyl groups is the main non-petroleum resource that can provide renewable aromatic compounds. Hence, lignin, phenol, and furfural were used to synthesize bio-based phenolic resins, and the activated carbon nanofibers were obtained by electrospinning and one-step carbonization activation. Fourier transform infrared and differential scanning calorimetry were used to characterize the structural and thermal properties. The results reveal that the apparent activation energy of the curing reaction is 89.21 kJ·mol–1 and the reaction order is 0.78. The activated carbon nanofibers show a uniform diameter, specific surface area up to 1100 m2·g–1, and total pore volume of 0.62 cm3·g–1. The electrode demonstrates a specific capacitance of 238 F·g–1 (0.1 A·g–1) and good rate capability. The symmetric supercapacitor yields a high energy density of 26.39 W·h·kg–1 at 100 W·kg–1 and an excellent capacitance retention of 98% after 10000 cycles. These results confirm that the activated carbon nanofiber from bio-based phenolic resins can be applied as electrode material for high-performance supercapacitors. 相似文献
17.
酚醛树脂热降解动力学研究 总被引:8,自引:2,他引:6
用热失重非等温法对不同甲醛,苯酚魔鬼洋比的酚树脂进行了热降解动力学研究。结果表明,甲醛,苯酚摩尔比为1.5时,酚醛树旨的热发活化能最高。耐热性最好。 相似文献
18.
Technical lignin and condensed tannins have been combined with soy flour as model of no-added-formaldehyde adhesive binders for veneer wood products to understand their impacts on volatile organic compounds (VOCs) produced during panel manufacture. VOC emissions captured on manufacturing lauan hardwood plywood at 170?C were dominated by acetaldehyde, hexaldehyde, acetone, and terpenes in both the condensate and gaseous fractions of press emissions. Other aldehydes including formaldehyde, valeraldehyde, and propionaldehyde were produced in relatively lower quantity during panel manufacture. Compared to using soy flour alone, lignin, and tannin reduced the formaldehyde and acetaldehyde contents in press emissions. These reductions in VOCs had a dependency on adhesive resin pH with an alkaline formulation proving to also decrease longer chain aldehydes such as valeraldehyde and hexaldehyde. Chamber testing plywood panels found the composition of VOC emissions initially released from panels to be prominent compounds released in press emissions formed on panel manufacture. Use of soy flour alone as binder produced relatively high acetaldehyde emissions from panels, whereas incorporating lignin and tannin with soy flour as adhesive binders reduced both acetaldehyde and formaldehyde emissions from panelboards post-manufacture. 相似文献
19.
In Yang Gyu-Seong Han Sye Hee Ahn In-Gyu Choi Yong-Hyun Kim 《The Journal of Adhesion》2013,89(4):279-295
This study examined the adhesive properties of adhesives formulated with rapeseed flour (RSF), a by-product of edible oil and bio-diesel manufacture, for medium-density fiberboards (MDFs). The RSF was hydrolyzed by sulfuric acid (AC-RSFH) and sodium hydroxide (AK-RSFH) solutions of 3%, 5%, and 7%. Phenol–formaldehyde (PF) prepolymers were prepared with formaldehyde to phenol molar ratios of 1.5, 1.8, and 2.1 (1.5-, 1.8-, and 2.1-PF). RSF-based adhesives were formulated by cross-linking 35% AC-RSFH, 35% AK-RSFH, and 30% PF prepolymers on a solid weight basis. The mechanical strength and dimensional stability of the MDFs were improved by decreasing the concentration of RSF-hydrolytic agents. The properties of the MDFs bonded with RSFH/1.8-PF resins were superior to those of RSFH/1.5- or 2.1-PF resins. These results suggest that RSF can be used as a raw material for environment-friendly adhesives used in MDF production. 相似文献