Montmorillonite KSF and K10 were used as precursor materials for synthesis of aluminum pillared K10 and KSF (Al-K10 and Al-KSF) which characterized by TGA, XRD, SEM and FT-IR spectroscopic analysis. The sorption of trimethoprim (TMP) which is commonly employed as an antibiotic onto Al-K10 and Al-KSF was also investigated as a function of adsorbent dosage, solution pH, contact time and temperature. The adsorption kinetics was interpreted using pseudo-first-order, pseudo-second-order kinetic models and intraparticle diffusion model. The pseudo-second-order model provided the best correlation. Adsorption isotherm parameters were obtained from Freundlich, Langmuir and Dubinin–Radushkevich (DR) isotherm models. Adsorption of TMP onto Al-K10 and Al-KSF was physical in nature and ion-exchange mechanism for DR equation, respectively. Al-K10 exhibits higher removal capacity at lower adsorbent dosages in comparison with Al-KSF. The removal capacity was increased by increasing pH. ΔH0, ΔS0 and ΔG0 showed that adsorption of trimethoprim was endothermic, increasing randomness and not spontaneous in nature. 相似文献
Nanocomposite superabsorbents were synthesized by graft copolymerization of mixture of acrylamide (AAm) and acrylic acid (AA)
onto collagen using potassium persulfate (KPS) as a free radical initiator and methylenebisacrylamide (MBA) as a crosslinker.
Nanoclay sodium montmorillonite (MMt) was introduced as filler into superabsorbent. The chemical structure of the Collagen-g-poly(Sodium
Acrylate-co-Acrylamide)/MMt nanocomposite was characterized by means of FTIR spectroscopy, XRD patterns, and TGA thermal methods.
Morphology of the sample was examined by scanning electron microscopy (SEM). The effects of reaction variables were systematically
optimized to achieve a superabsorbent with swelling capacity as high as possible. Under the optimized conditions concluded,
the maximum swelling capacity in distilled water was 950 g/g. Dewatering of nanocomposite and clay-free superabsorbent revealed
that inclusion of nanoclay into superabsorbents can improve water retention of superabsorbent under heating. The swelling
ratio in various salt solution and kinetic of dewatering was also determined and additionally, the swelling of nanocomposite
superabsorbent was measured in solution with pH ranged 1–13. The synthesized nanocomposite exhibited a pH-responsive characteristic. 相似文献
A series of clay-based superabsorbent composite from acrylamide (AM) and various clays, such as attapulgite, kaolinite, mica, vermiculate and Na+-montmorillonite, was prepared by free-radical aqueous polymerization, using N,N′-methylenebisacrylamide (MBA) as a crosslinker and ammonium persulfate (APS) as an initiator, and then saponified with sodium hydroxide solution. In this paper, the reaction mechanism and thermal stability of the superabsorbent composites incorporated with various clays were characterized by FTIR, XRD and TGA, respectively. The effects of clay kind and clay content on equilibrium water absorbency of these composites were also investigated and compared. In addition, the influences of clay kind on comprehensive swelling behaviors of the PAM/clay superabsorbent composites were studied. The results indicated that the introduced clays could influence physicochemical properties of obtained superabsorbent composites. Mica could improve thermal stability of corresponding superabsorbent composites to the highest degree comparing with the other clays. The PAM/clay superabsorbent composites incorporated with 10 wt% clay of various kinds were all endowed with equilibrium water absorbency of more than 1300 g g−1. The equilibrium water absorbency decreases with increasing clay content and correlates with the kind of clay. Attapulgite-based superabsorbent composite was endowed with higher water absorbency in univalent cationic saline solution, however, the vermiculite- and the kaolinite-based ones acquired the highest water absorbency in CaCl2 and FeCl3 aqueous solution, respectively. Moreover, the superabsorbent composites incorporated with Na+-montmorillonite have higher swelling rate and that of doped with mica was endowed with higher reswelling capability. 相似文献
A series of novel copolymer superabsorbents based on acrylamide (AM), acrylic acid(AA) were prepared
by inverse microemulsion copolymerization using ammonium persulfate (APS) as the initiator and N,N-methylenebisacrylamide
(MBA) as the crosslinking agent and OP-10 and SDS as complex surfactants. The synthetic variables (amount
of crosslinking agent and initiator, water/oil ratio, monomer/surfactant ratio and AA/ Am ratio) and their
effects on the absorbencies of the synthesized superabsorbents were investigated. The experimental results
of superabsorbent polymers (SAPs) showed the maximum saline solution absorbency of 130 g/g within
75 min, and the saline solution absorbency of 111 g/g within 30 min. FTIR indicated the
structure of the acrylic acid and acrylamide copolymer. SEM indicated that the particles prepared with
higher crosslinker content (0.03%) showed smaller pore sizes and less porous structures compared with those
with less crosslinker content (0.01%) and the number of the micropores largely decreased with the water/oil
ratio increasing from 8% to 14%. 相似文献
Summary: A novel fast‐swelling porous superabsorbent hydrogel was prepared by grafting acrylic acid onto corn starch through free‐radical polymerization in aqueous solution using N,N′‐methylenebisacrylamide as a crosslinker, ammonium persulfate as an initiator, sodium dodecyl sulfate and p‐octyl poly(ethylene glycol)phenyl ether as pore‐forming agents. The graft polymerization and surface morphology of the porous superabsorbents were characterized by FTIR and SEM. The results indicate that the porous superabsorbents were endowed with higher equilibrium water absorbency and faster swelling rate (they needed only 10 min to reach 90% of their equilibrium water absorbency) compared with the nonporous superabsorbents. The dewatering method employed had a significant influence on the swelling behavior of the superabsorbents and dewatering agents were useful to preserve the pores formed during the polymerization process.
The equilibrium water absorbency in distilled water, for the porous and non‐porous starch‐g‐poly(acrylic acid‐co‐sodium acrylate) superabsorbent hydrogels dried through different procedures. 相似文献
ABSTRACTThe mechanical strength of superabsorbents is an important practical factor that can be characterized by measuring the absorbency of the superabsorbent under load. In the last decades, many efforts have been devoted to enhancing the mechanical strength of superabsorbents. Herein, as an attempt to increase the superabsorbent mechanical strength, two types of star-shaped bio-based modifiers were designed and synthesized via condensation reaction between acids and alcohols. The chemical structures of the bio-based modifiers were characterized via FT-IR and 1H NMR analysis. Glycerin, lactic acid, succinic acid, and itaconic acid used for the synthesis of the star-shaped modifier, which further used in different ratios in the bulk of the superabsorbent. Moreover, another modifier was synthesized from glycerin, lactic acid, and methacrylic anhydride, and successfully used as a surface modifier for superabsorbents in different ratios. The absorption analysis showed that the employment of the optimum amount of the bulk modifier (4.75 wt.%) increases the AUL almost 4 units, without significant impacts on the water and NaCl solution absorbencies. Also, the incorporation of the optimum amount of the surface modifier increases the AUL about 3 units. As a result, the AUL value of the acrylic acid- sodium acrylate superabsorbent enhanced ~7 units by the incorporation of these bio-based modifiers-from 17.3 for the pristine superabsorbent to 24.2. 相似文献