Hydrothermal systems in tengchong, West Yunnan, China and their evolution during the past 400 years

The active hydrothermal activity in Tengchong, West Yunnan province is more intense than in other areas of the Chinese hinterland. Based on the comparison with records reported in “Travel Notes on Xu Xiake”, the features of the Hot Sea in Tengchong have changed considerably during the past 400 years.     

Chemical geothermometers and mixing models for geothermal systems

Qualitative chemical geothermometers utilize anomalous concentrations of various “indicator” elements in groundwaters, streams, soils, and soil gases to outline favorable places to explore for geothermal energy. Some of the qualitative methods, such as the delineation of mercury and helium anomalies in soil gases, do not require the presence of hot springs or fumaroles. However, these techniques may also outline fossil thermal areas that are now cold.Quantitative chemical geothermometers and mixing models can provide information about present probable minimum subsurface temperatures. Interpretation is easiest where several hot or warm springs are present in a given area. At this time the most widely used quantitative chemical geothermometers are silica, Na/K, and Na-K-Ca.     

Dislocation mechanism of hydrogen embrittlement of metals and alloys with HCP and FCC crystal structure

The results of the experimental study of the mechanism of hydrogen embrittlement were generalized on the basis of a theory of thermally activated (quasi-brittle) fracture, developed by the authors to predict the nature of gradual quasi-brittle transition of Me-H solid solutions. It was established that development of hydrogen brittleness for polycrystals appeared to be controlled at low (cryogenic) temperature by thermally activated sliding screening dislocations overcoming segregated H atoms at the microcrack tips with activation energy of 0.05-0.07 eV at the critical (hard-activated) stage of fracture propagation. If the concentration of excess (hydrogen- and deformation-induced) vacancies of 2–3 orders exceeds that for thermal equilibrium vacancies, the structure's clusterization of Me-H solid solutions was observed within the thermally activated area of dynamic deformational aging (in the host metal and at the boundaries). Hereby the formation of strong “H atom-excess vacancy” clusters with a binding energy of 0.2-0.5 eV, being large in comparison with “H atom-screening dislocation” binding energy, prevent the H atom's segregation at the structure defects. The methods for elimination of hydrogen brittleness, restoration of plasticity and strength properties of Me-H systems are suggested on the basis of the formation of the new barriers for propagating microcracks—the disoriented cellular structures in clusterized solid solutions with large numbers of active sliding systems of screening dislocations. Ti---H, Zr---H and Al---H or superdisperse granular structures in superplastic and plastic states of clusterized substitution alloys with a lack of active sliding systems of screening dislocations (Mg---Ba---H, Be---Co---H).     

K-Ar age and strontium isotopic composition of the tengchong volcanic rocks, West Yunnan province, China

Dating of 47 samples of the Tengchong volcanic rocks gave K-Ar ages ranging between 0.09 and 17.84 My. Thθ ⁴⁰Ar/³⁶Ar vs ⁴⁰K/³⁶Ar plot was made on the basis of those data in which radiogenic ⁴⁰Ar is more than 2%. Four isochrones at 2.93, 0.81, 0.31 and 0.13 My were then obtained. The eruption time was from the Miocene to Pleistocene, with the climax occurring in the Late Pleistocene. The K-Ar ages were determined by statistical analysis and the probability of eruptions indicates that the Tengchong volcanoes are not to be considered extinguished but dormant volcanoes.Rb and Sr contents and the strontium isotopic compositions were determined on 20 samples of Tengchong volcanic rocks. The initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.70578 to 0.71437. It would appear that the “parent magma” is of deep origin (⁸⁷Sr/⁸⁶Sr near 0.706) and that it underwent a progressive contamination by crustal material rich in radiogenic ⁸⁷Sr.     

Volcano–tectonic structures, gravity and helium in geothermal areas of Tuscany and Latium (Vulsini volcanic district), Italy

Since the early 1980s, geological and structural mapping, gravity, and helium soil–gas studies have been performed in the eastern sector of the Vulsini Volcanic District (Roman Magmatic Province) in an attempt to locate potential geothermal reservoirs. This area is characterised by an anomalous geothermal gradient of >100°C/km, and by widespread hydrothermal mineralization, thermal springs, high gas fluxes, and fossil and current travertine deposits. The results of these surveys indicate the existence of a number of fault systems, with N–S and E–W structures that appear to be superimposed on older NW–SE and NE–SW features. Comparison of the results of the various studies also reveals differences in permeability and potential reservoir structures at depth.     

Geophysical investigations of the Seferihisar geothermal area, Western Anatolia, Turkey

Self-potential (SP), magnetic and very low frequency electromagnetic (EM-VLF) surveys were carried out in the Seferihisar geothermal area to identify major and minor fault zones and characterize the geothermal system. The SP study provided useful information on the local faults and subsurface fluid flow. The main SP anomalies appear mostly along and near active fault zones in the area of the Cumalı, Tuzla and Doğanbey hot springs. Two of these anomalies near the Tuzla hot springs were further evaluated by SP modelling. Total magnetic field values increase from the Doğanbey to the Cumalı hot springs. Modelling performed on the magnetic data indicates that between these two spring areas are four different regions or units that can be distinguished on the basis of their magnetic susceptibility values. Fraser filtering of EM-VLF data also indicates that there are three significant conductive zones in the regions around the Cumalı, Tuzla and Doğanbey hot springs, and that they lie between important fault systems. The EM-VLF and total (stacked) SP data show that the conductive tilt anomalies obtained by Fraser filtering generally coincide with negative SP areas.According to our geophysical investigations, new exploratory wells should be drilled into the conductive zones located between the Cumalı and Tuzla hot springs. We further recommend that resistivity and magnetotelluric methods be carried out in the area to obtain additional information on the Seferihisar geothermal system.     

Geoelectric study of some indian geothermal areas

The electrical resistivity technique has been used extensively in the Indian sub-continent for the exploration of geothermal areas. The first systematic application of the resistivity method for locating the geothermal reservoir was made in the Puga area, which is situated very close to the collision junction of the Indian and the Asian plates and has numerous hot springs with temperatures varying from 30 to 84°C (boiling point at that altitude). The resistivity depth probes indicated the presence of a conductive zone, with a value of 10–25 ohm·m and a thickness varying from 50 to 300 m over an area of 3 km², which was inferred to correspond to a shallow thermal reservoir. Thermal surveys also revealed a significant anomaly corresponding to this zone, which, when drilled, encountered a reservoir of wet steam with a temperature of up to 135°C, thus confirming the results of the resistivity surveys. Somewhat similar results have been obtained in the adjoining area, where much thicker zones with moderate electrical conductivity have been mapped.Another significant application of the electrical resistivity method has been made in the NNW-SSE extending West Coast geothermal belt of India, which is covered by Traps (Basalts) of the Cretaceous-Eocene. The area is characterized by the existence of a number of hot springs, with temperature up to 70°C, along a 400 km long alignment, associated with steep gravity gradients and an isolated occurrence of native mercury in the zone of a gravity “high”. The enigmatic geology of this area has been mapped, giving quantitative estimates of the thickness of the Traps and inferring the structural features. In addition, the electrical resistivity depth probes have also been used to identify the pre-Trappean geology, thereby locating the probable areas which could act as geothermal reservoirs.This paper presents the results of the electrical resistivity surveys in the form of geoelectric sections for some of the geothemal fields in the Indian sub-continent.     

Evolution of hydrothermal explosions at Rehai geothermal field, Tengchong volcanic region, China

During the period 1993–2003 over 20 hydrothermal eruptions occurred at Rehai geothermal field, in Tengchong volcanic region, Yunnan Province, southwestern China. Initially, the explosions occurred on the bed of the Zaotang River, and later along a NW–SE striking fault cross-cutting the river. The explosion activity intensified with time. The free gas samples collected from springs created by the explosions show ³He/⁴He ratios of 1.17, 2.22 and 4.05 Ra (Ra = 1.4 × 10⁻⁶) for the three distinguishable stages of ever-increasing magnitude of the explosions, respectively. Data on helium isotopes and gas chemistry indicate that the source of the gases feeding the explosions has progressively shifted from shallower to greater depth. Following this trend, larger hydrothermal explosions will probably occur in the future, so that this hazard must be taken into serious consideration.     

Gravity survey and interpretation of bouguer anomalies in the campidano geothermal area (Sardinia, Italy)

A gravity survey of the Campidano geothermal fields and surrounding region was conducted in 1981. It covered an area of 1900 km² and included 952 uniformly distributed stations. The Bouguer anomaly is generally negative within the Campidano graben, reaching −10 mgal in the central zone, whereas a positive Bouguer anomaly prevails outside the graben, exceeding 20 mgal in several areas. The gravity data were interpreted using spectral analysis and two-dimensional models, to determine the thickness of sediments and andesitic volcanics within the graben. The total thickness of these formations reaches 3000 m in the centre, but is reduced elsewhere, especially towards the sides of the graben. The thermal springs on both the eastern and western sides of the graben are associated with residual positive anomalies and are near very steep gradients in the Bouguer anomaly.     

Geochemistry of thermal waters in the Tengchong volcanic geothermal area, West Yunnan Province, China

The Tengchong volcanic geothermal area is one of the areas in China which has powerful geothermal energy potential. The chemical compositions of the thermal waters discharged in this area were studied to obtain information on boiling and mixing relationships and average reservoir temperatures. Then a conceptual model of the Tengchong volcanic geothermal area was formulated. Hydrothermal areas have reservoir temperatures ranging from 90 to 150°C; such temperatures can be found in up to 60% of the 58 hydrothermal areas. Five hydrothermal areas have high temperatures, with an average reservoir temperature of more than 150°C, and occupy less than 10% of the total. The Hot Sea geothermal field is one of the five high temperature hydrothermal areas where a more detailed investigation was made.     

Fluid geochemistry of the San Vicente geothermal field (El Salvador)

The volcano Chichontepeque (San Vicente) is one of the nine recent volcanoes making up the El Salvador sector of the WNW-ESE-trending active Central American volcanic belt. Thermal activity is at present reduced to a few thermal springs and fumaroles. The most important manifestations (Agua Agria and Los Infernillos Ciegos) are boiling springs and fumaroles located on the northern slope of the volcano (850 m a.s.l.) along two radial faults. The chloride acid waters of the Los Infernillos area are partly fed by a deep hydrothermal aquifer (crossed at 1100–1300 m by a geothermal exploration well), which finds a preferential path to the surface through the radial fault system. C0₂ is the most important gas (>90%) of the Los Infernillos Ciegos and Agua Agria fumaroles. Part of the Los Infernillos gases may also come from a deeper, hotter source, given their high HCl/S_tot. ratio and their more reducing conditions. The application of geothermometric and geobarometric methods to the gases and thermal waters suggests that both thermal areas are linked to the identified 1100–1300 m reservoir, whose temperature (250°C), lateral extension and chemical composition, as resulting from this study, are of interest for industrial development.     

Geophysical exploration of the Boku geothermal area, Central Ethiopian Rift

The Boku central volcano is located within the axial zone of the Central Ethiopian Rift near the town of Nazareth, Ethiopia. An integrated geophysical survey involving thermal, magnetic, electrical and gravimetric methods has been carried out over the Boku geothermal area in order to understand the circulation of fluids in the subsurface, and to localize the “hot spot” providing heat to the downward migrating groundwaters before they return to the surface. The aim of the investigations was to reconstruct the geometry of the aquifers and the fluid flow paths in the Boku geothermal system, the country's least studied. Geological studies show that it taps heat from the shallow acidic Quaternary volcanic rocks of the Rift floor. The aquifer system is hosted in Quaternary Rift floor ignimbrites that are intensively fractured and receive regional meteoric water recharge from the adjacent escarpment and locally from precipitation and the Awash River. Geophysical surveys have mapped Quaternary faults that are the major geologic structures that allow the ascent of the hotter fluids towards the surface, as well as the cold-water recharge of the geothermal system. The shallow aquifers are mapped, preferred borehole sites for the extraction of thermal fluids are delineated and the depths to deeper thermal aquifers are estimated.     

The thermal springs of bockfjord, svalbard: occurrence and major ion hydrochemistry

The Troll and Jotun thermal springs of northern Svalbard, with temperatures of up to 25.6°C, are derived from a major fault forming the junction between Devonian sandstones and Proterozoic marbles, mica schists and gneisses. The Troll waters are dominated by Na–HCO₃ compositions and the Jotun waters by Na–Cl compositions. The pristine thermal water source has a sub-neutral pH and is highly reducing. Taken at face value, common geothermometers suggest temperatures at depth of 130–180°C for the Troll springs (corresponding to a depth of 1.6–2.3 km), with 10–30% thermal water diluted by 70–90% cold water. Such geothermometers may, however, be inappropriate to the cool, high CO₂ waters of Bockfjord, and real temperatures at depth and dilution factors are probably considerably lower. The salinity of the thermal water appears to be only partially derived from water–rock interaction; Br\Cl ratios suggest that seawater or possibly evaporites may be a source of chloride salinity.     

Oxygen and hydrogen isotopes in deep thermal waters from the south meager creek geothermal area, british columbia, canada

Deuterium and oxygen-18 (¹⁸O) have been measured in deep thermal, shallow thermal and non-thermal water samples collected at various times between 1982 and 1989 from the Meager Creek area, with the aim of assessing the origin of the thermal waters. The isotopic composition of the reservoir waters (δ¹⁸O = −13‰ and δD = −114.8‰) was calculated from data on post-flash deep thermal waters, using a two-stage steam loss model. The reservoir composition shows an oxygen shift of 2.4‰ relative to the local meteoric water line. The composition of the recharge, obtained by removing the oxygen shift, is isotopically heavier than the average local meteoric waters, suggesting that the recharge may be from an area to the west of Mt Meager where isotopically heavier ground-waters are likely to be found. The small δ¹⁸O shift of the deep high-temperature waters is indicative of dominance of fracture-related permeability in the reservoir. Analysis of the chemistry and the temperature of the waters from hot springs and shallow thermal wells suggests that these waters have evolved from the deep geothermal waters through dilution by meteoric waters and about 40°C adiabatic cooling (steam loss).     

Isotopic and chemical evidence for water sources and mixing in the Cerro Pando geothermal area, Republic of Panama

The Cerro Pando geothermal area in Chiriqui Province is situated just to the south of the continental divide in western Panama. Three groups of thermal springs are associated with lineations in a complex of late Tertiary and Quaternary extrusives. Spring temperatures reach maximum values of 66°C at Los Pozos, 67°C at Cotito and 41°C at Catalina; flow-rates are low, ranging up to 1.5 l/s. However, total heat output is estimated at around 7 MW from calculations incorporating measured spring discharges with river-bed discharges inferred from stream conductivity anomalies. In all cases the spring hydrochemistries become of a more dominantly Na-Cl character as mineralization increases; the highest salinities are found in samples from test boreholes in which 4500 mg/l Cl⁻ has been measured. ¹⁸O/¹⁶O and ²H/¹H data for all thermal springs are roughly colinear, plotting on the δ-diagram with a slope around 3.6 and intersecting the meteoric water line within the compositional range of local surface water. Moreover, δ¹⁸O data are found to correlate with Cl⁻ concentrations, although separate linear trends represent the Los Pozos/Cotito and the Catalina groups of springs. These data are interpreted as indicating that deep thermal ground water feeds the thermal spring systems, with differing isotopic compositions and/or salinities in the Los Pozos/Cotito and Catalina groups. These end-member compositions have evolved by sub-surface steam loss, possibly without any δ ¹⁴O shift due to water - rock exchange. The observed spring compositions are all mixtures between the deep thermal and shallow cool end-member ground waters. The importance of resolving mixing relationships before applying geothermometric calculations is illustrated.     

Hydrogeochemical exploration of geothermal prospects in the Tecuamburro Volcano region, Guatemala

Chemical and isotopic analyses of thermal and nonthermal waters and of gases from springs and fumaroles are used to evaluate the geothermal potential of the Tecuamburro Volcano region, Guatemala. Chemically distinct geothermal surface manifestations generally occur in separate hydrogeologic areas within this 400 km² region: low-pressure fumaroles with temperatures near local boiling occur at 1470 m elevation in a sulfur mine near the summit of Tecuamburro Volcano; non-boiling acid-sulfate hot springs and mud pots are restricted to the Laguna Ixpaco area, about 5 km NNW of the sulfur mine and 350–400 m lower in elevation; steam-heated and thermal-meteoric waters are found on the flanks of Tecuamburro Volcano and several kilometers to the north in the andesitic highland, where the Infernitos fumarole (97°C at 1180 m) is the primary feature; neutral-chloride hot springs discharge along Rio Los Esclavos, principally near Colmenares at 490 m elevation, about 8–10 km SE of Infernitos. Maximum geothermometer temperatures calculated from Colmenares neutral-chloride spring compositions are 180°C, whereas maximum subsurface temperatures based on Laguna Ixpaco gas compositions are 310°C. An exploration core hole drilled to a depth of 808 m about 0.3 km south of Laguna Ixpaco had a bottom-hole temperature of 238°C but did not produce sufficient fluids to confirm or chemically characterize a geothermal reservoir. Hydrogeochemical data combined with regional geologic interpretations indicate that there are probably two hydrothermal-convection systems, which are separated by a major NW-trending structural boundary, the Ixpaco fault. One system with reservoir temperatures near 300°C lies beneath Tecuamburro Volcano and consists of a large vapor zone that feeds steam to the Laguna Ixpaco area, with underlying hot water that flows laterally to feed a small group of warm, chloriderich springs SE of Tecuamburro Volcano. The other system is located beneath the Infernitos area in the andesitic highland and consists of a lower-temperature (150–190°C) reservoir with a large natural discharge that feeds the Colmenares hot springs.     

Geochemical evidence of chemical equilibria in the South Meager Creek geothermal system, British Columbia, Canada

Meager geothermal reservoir appears to be in “thermochemical” equilibrium as indicated by constant ion-concentration ratios (B/Li, B/K, Na/Li, Na/CI etc.). The Na/Li ratio describes the thermal conditions of the first and the deepest equilibrium reached by the thermal waters, whereas the Na/K indicates a secondary and shallower equilibrium. Analysis of the correlations between K, Na and CI indicate that discharge from well MC1 is probably a mixture between a single brine and high-chloride cool waters.     

Interpretation of magnetic anomalies over the Waimangu geothermal area, Taupo volcanic zone, New Zealand

The study area is located on the eastern side of the Taupo volcanic zone in central North Island of New Zealand. It lies a few kilometres to the southwest of Mt Tarawera, the site of the biggest New Zealand volcanic eruption in historical times (the June 1886 Tarawera eruption). The study area includes the Waimangu geothermal field and a small part of Waiotapu and Waikite fields. The extensive surface thermal expressions (boiling springs, hot lakes, craters, and sinter terraces) occurring at the Waimangu field were all formed following the 1886 Tarawera eruption. Another large area of less intense thermal manifestations (thermal ground and hydrothermally altered rocks) exists about 5 km southwest of Waimangu, extending towards the Waiotapu field in the south. In 1993 an aeromagnetic survey was conducted over the study area at an average altitude of about 350 m above the ground. The results show a subdued negative residual anomaly (about −100 nT) over the Waimangu field, which can be interpreted by near-surface hydrothermal demagnetisation of rhyolitic host rocks. The lateral distribution of the demagnetised rocks is much greater than the thermal area of Waimangu, and is consistent with the extent of low resistivity rocks across the study area. The magnetic interpretation also shows that two-high standing dacite domes situated about 5 and 7 km to the southwest of Waimangu have been affected by hydrothermal demagnetisation. There are negative residual anomalies outside the low resistivity zone that could be associated with reversely magnetised rocks (age >0.78 Ma). A strong positive residual anomaly (up to 450 nT) occurs to the east of the Waimangu field. Results from 3-D magnetic interpretation indicate some alternative models for this positive anomaly: (1) southwest–northeast trending, vertical basalt dykes (magnetisation 10 A/m), tops between −0.1 and −0.65 km RL (reduced LEVEL=relative to sea level), (2) a thick ( 1 km) sequence of rhyolites (magnetisation 2.5 A/m) extending from the surface down to about −0.8 km RL, and (3) a rather thin (0.35 km) sequence of rhyolites (from surface to sea level) underlain by basalt bodies similar to those of model (1).     

Optimum performance of thermal trap collectors

The “thermal trap effect” in semitransparent material and the trapping system in the conventional flat-plate collectors with two, three or four glass or plastic covers with air-gaps in between are analysed under a common heading of “thermal trap collectors”. In general, a thermal trap collector consists of one or many slabs of semitransparent material of finite thickness with air-gaps in between, and an ideal withdrawal mechanism at the base of the trapping system to withdraw all available energy. This approach makes a comparative study of the two types of collectors possible, and provides data to design the appropriate withdrawal mechanism and operating conditions. A steady state analysis which neglects internal reflections and body radiation shows the existance of an optimum performance in single-layer thermal trap collectors and its dependence on thickness. A model which includes internal reflections is then analysed and the existance of the optimum performance and its dependence on thickness is demonstrated by taking the example of a single slab of methylmethacrylate plastic. The model is extended to multilayer thermal trap collectors and two examples are considered; a multilayer methylmethacrylate thermal trap collector and a multilayer “glass” thermal trap collector. The results show that the two-layer methyl methacrylate thermal trap collector has, in general, a better performance than the corresponding single or three and four-layer systems. But at high withdrawal efficiencies of about 60 per cent, the single layer methyl methacrylate shows its uniqueness and becomes competitive with the two-layer system. But the three and four-layer “glass” thermal trap collectors perform better than the corresponding single and two-layer ones, with the three-layer system having an overall better performance. These results show that the number of slabs in addition to thickness are important parameters in the study of the performance of thermal trap collectors.