Current research on environmentally assisted cracking in light water reactor environments

The effect of dissolved oxygen level on fatigue life of austenitic stainless steels is discussed and the results of a detailed study of the effect of the environment on the growth of cracks during fatigue initiation are presented. Initial test results are given for specimens irradiated in the Halden reactor. Impurities introduced by shielded metal arc welding that may affect susceptibility to stress corrosion cracking are described. Results of calculations of residual stresses in core shroud weldments are summarized. Crack growth rates of high-nickel alloys under cyclic loading with R ratios from 0.2 to 0.95 in high-purity water that contains <5 and 300 ppb dissolved oxygen at 240, 289, and 320°C, are summarized.     

Fracture toughness of narrow-gap welded joints in the nuclear pressure vessel steel 22 NiMoCr 37

The mechanical testing of narrow-gap welded joints in 100 and 200 mm thick sections of the steel 22 NiMoCr 37 has revealed that the weld metal, and not the heat affected zone (HAZ) or the weld metal-parent metal boundary. is the critical region. This modified gas-shielded welding process operates with a very low heat input of the order of 6.500 J cm⁻¹ pass⁻¹ and the combination of small diameter welding wires and high welding speeds contributes to the excellent joint properties in the as-welded condition.To investigate the effect of preheating and post-welding heat treatment on the mechanical properties of narrow-gap welds, tensile, notch impact, flat bend and fracture toughness test specimens were extracted from joints welded with the following conditions: (1) no preheating: no post-weld heat treatment; (2) no preheating: soaking at 300°C: (3) no preheating: stress-relief heat treatment at 600°C; (4) preheating 200–250°C; no post-weld heat treatment; (5) preheating 200–250°C; soaking at 300°C; (6) preheating 200–250°C; stress relief heat treatment at 600°C. Tensile testing at room temperature and at 250°C of round specimens oriented across the seam revealed the ultimate fracture to be always located in the base material remote from the welded zone. Although pores or slag inclusions had an influence on bend-test results of specimens in the as-welded condition, the results generally show failure free bends to 180°C with no evidence of cracking in the HAZ or at the fusion boundary.Using sharp-notched impact bend specimens with the notch located in the centre of the seam as well as in and across the HAZ, absorbed energy-test temperature curves have been determined for each welding condition. In comparison with the base material impact toughness, the weld exhibits superior toughness in the temperature range − 60 – 0°C, but yielded lower values at room temperature. After stress relieving at 600°C, the impact toughness of the weld reduced significantly, apparently due to precipitations occurring in the weld-metal microstructure. Test results from welded specimens with the no notch in the HAZ show this region to have superior notch impact toughness to the base material.Crack opening displacement (COD) specimens 45 × 90 × 380 mm with the fatigue crack located in the weld metal and in the HAZ were tested at 0 and 20°C using both the recommendation in BS DD 19: 1972 as well as acoustic emission measurements for the determination of COD values. For this method of fracture toughness testing it has been shown that the occurrence of a critical event must be clearly defined as corresponding to stable crack growth or alternatively to unstable crack propagation.     

Pressure vessel nozzle repair

The dissimilar metal weldment joining Boiling Water Reactor (BWR) nozzles to safe-ends is one of the more complex configurations in the entire recirculation system. Field installation techniques typically specify that a special shop weld deposit (butter) be placed on the end of the nozzle prior to final shop post-weld heat treatment (PWHT) in order to facilitate field welding without PWHT. The shop weld deposit is normally an Inconel or stainless steel and does not require additional field heat treatment after welding. Soon BWR vessels used Inconel 182 manual shielded metal arc electrodes to weld deposit the butter. This manual process produces a deposit which is now known to be susceptible to intergranular stress corrosion cracking (IGSCC), especially under severe conditions such as crevices and/or cold work.Recently two BWRs have experienced, IGSCC of I-182 weld deposits in which axially oriented cracking progressed into the low alloy steel nozzle material. Although IGSCC extension from weld butter into nozzle material has been observed in other BWRs, these cases appeared to be the deepest. At Taiwan Power Company's Chinshan Unit 2 a repair has been completed in which the defect was verified visually, the old butter and defect removed by machining, the butter restored with PWHT and a new safe-end installed. At Carolina Power and Light's Brunswick Unit 1 a large number of deep axial indications have been identified on nine nozzles by ultrasonic examination. Weld overlay repairs using a temperbead procedure have been completed as a temporary measure while preparing for a permanent repair at the next refueling outage.Details of the cracking observations and repair activities are discussed. Concurrent repairs/replacements of safe-ends will also be described.     

Residual stresses and stress corrosion effects in cast steel nuclear waste overpacks

In the concepts for final disposal of high-level radioactive waste in Switzerland, one engineered barrier consists of an overpack made out of cast steel GS-40. Whenever tensile stresses are expected in the overpack, the issue of stress corrosion cracking must be expected. A low-strength steel was chosen to minimize potential problems associated with stress corrosion cracking. A series of measurements on stress corrosion cracking under the conditions as expected in the repository confirmed that the corrosion allowance of 50 mm used for the design of the reference overpack is sufficient over the 1000 years design lifetime. Tensile stresses are introduced by the welding process when the overpack is closed. For a multipass welding, the evolution of deformations, strains and stresses were determined in a finite-element calculation. Assuming an elastic-plastic material behavior without creep, the residual stresses are high; considering creep would reduce them. A series of creep tests revealed that the initial creep rate is important for cast steel already at 400°C.     

Materials aspects of BWR plant life extension

Considerable experience with plant equipment performance in nuclear power stations has indicated that the principal factors limiting the life of BWRs and PWRs are materials related. Specifically, for LWRs it is known that these materials issues generally include parameters related to stress corrosion cracking, corrosion fatigue, wear and radiation embrittlement. Not only do these parameters affect and limit the actual useful design life of plant components but also affect the plant's operating availability. In all these cases, the elimination or control of one or more of these critical parameters should improve the plants availability and significantly extend the useful service life.In the present paper, research performed to address the intergranular stress corrosion cracking (IGSCC) area is described. Specific emphasis is placed on Type 304 stainless steel which has suffered IGSCC in piping in the heat-affected-zone (HAZs) adjacent to the welds in the BWR primary system. Research has developed and qualified a number of techniques which address the three necessary conditions for IGSCC in BWRs: (1) sensitized microstructure, i.e., chromium depletion at the grain boundaries during welding; (2) over yield tensile stress; and (3) oxygenated (200 ppb) high temperature (288Another potential life-limiting IGSCC phenomenon for certain components, irradiation assisted stress corrosion cracking (IASCC) of stainless steel exposed to a high neutron flux, is also discussed. Unlike the IGSCC, IASCC results in intergranular cracking of annealed material at low stress. Fortunately, preliminary research has indicated that some of the techniques utilized for IGSCC control in piping as well as new controlled impurity level stainless steel alloys may reduce the future potential IASCC concern to an insignificant level.     

High temperature strength and inelastic behavior of plate–fin structures for HTGR

In this paper, both high temperature strength and inelastic behavior of plate–fin structures were discussed for applying these structures to the compact heat exchangers such as recuperative and intermediate heat exchangers for high-temperature gas-cooled reactors (HTGR). Firstly tensile, creep and fatigue tests of the brazed plate–fin model of small size were carried out to obtain the rupture strength and inelastic behavior. The influence of the braze filler metal thickness on the tensile strength was experimentally studied and a possibility of predicting both the tensile and creep strength was discussed using the data of base material of plates and fins. Secondly, we demonstrated the fabrication of large-size core with a dimension of 1000 mm, and also demonstrated that the bonding ratio in this core was improved up to almost 100% by adopting the pressurized tank system in the brazing process. Finally, we proposed the stress analysis method of plate–fin structures on the basis of the equivalent-homogeneous-solid concept, and carried out the elastic–plastic analysis of recuperative heat exchanger for HTGR. Characteristics of stress–strain behavior were discussed together with a possibility of predicting the fatigue life of the structure.     

Prediction of residual stress distributions due to surface machining and welding and crack growth simulation under residual stress distribution

In nuclear power plants, stress corrosion cracking (SCC) has been observed near the weld zone of the core shroud and primary loop recirculation (PLR) pipes made of low-carbon austenitic stainless steel Type 316L. The joining process of pipes usually includes surface machining and welding. Both processes induce residual stresses, and residual stresses are thus important factors in the occurrence and propagation of SCC. In this study, the finite element method (FEM) was used to estimate residual stress distributions generated by butt welding and surface machining. The thermoelastic-plastic analysis was performed for the welding simulation, and the thermo-mechanical coupled analysis based on the Johnson-Cook material model was performed for the surface machining simulation. In addition, a crack growth analysis based on the stress intensity factor (SIF) calculation was performed using the calculated residual stress distributions that are generated by welding and surface machining. The surface machining analysis showed that tensile residual stress due to surface machining only exists approximately 0.2 mm from the machined surface, and the surface residual stress increases with cutting speed. The crack growth analysis showed that the crack depth is affected by both surface machining and welding, and the crack length is more affected by surface machining than by welding.     

Random cyclic stress–strain responses of a stainless steel pipe-weld metal II — a modeling

This paper pays special attention to an issue that there is a significant scatter of the stress–strain responses of a nuclear engineering material, 1Cr18Ni9Ti stainless steel pipe-weld metal. Efforts are made to reveal the random fatigue damage character by fracture surface observations and to model the random responses by introducing probability-based stress–strain curves of Ramberg–Osgood relation and its modified form. Results reveal that the fatigue damage is subjected to, 3-D interacting and involved microcracks. The three stages, namely microstructural short cracks (MSC), physical short cracks (PSC) and long cracks (LC) subdivided by Miller and de los Rios, can give a good characterization of the damage process. Both micro- and macro-behaviour of the material have the character of three stages. The 3-D effects are strong in the MSC stage, tend to a gradual decrease in the PSC stage, and then show saturation after going to the LC stage. Intrinsic causes of the random behaviour are the difference and evolution of the microstructural conditions ahead of the dominant crack tips. The ‘effectively short fatigue crack criterion’ introduced by Zhao et al. in observing the material surface short crack behaviour could facilitate an understanding of the mechanism of interaction and evolution. Based on the previous obtained appropriate assumed distribution, normal model, for the cyclic stress amplitude, the probability-based curves are approximated by the mean value and standard deviation cyclic stress–strain curves. Then, fatigue analysis at arbitrarily given reliability can be conveniently made according to the normal distribution function. To estimate these curves, a maximum likelihood method is developed. The analysis reveals that the curves could give a good modeling of the random responses of material.     

Numerical weld modeling — a method for calculating weld-induced residual stresses

In the past, weld-induced residual stresses caused damage to numerous (power) plant parts, components and systems (Erve, M., Wesseling, U., Kilian, R., Hardt, R., Brümmer, G., Maier, V., Ilg, U., 1994. Cracking in Stabilized Austenitic Stainless Steel Piping of German Boiling Water Reactors — Characteristic Features and Root Causes. 20. MPA-Seminar 1994, vol. 2, paper 29, pp.29.1–29.21). In the case of BWR nuclear power plants, this damage can be caused by the mechanism of intergranular stress corrosion cracking in austenitic piping or the core shroud in the reactor pressure vessel and is triggered chiefly by weld-induced residual stresses. One solution of this problem that has been used in the past involves experimental measurements of residual stresses in conjunction with weld optimization testing. However, the experimental analysis of all relevant parameters is an extremely tedious process. Numerical simulation using the finite element method (FEM) not only supplements this method but, in view of modern computer capacities, is also an equally valid alternative in its own right. This paper will demonstrate that the technique developed for numerical simulation of the welding process has not only been properly verified and validated on austenitic pipe welds, but that it also permits making selective statements on improvements to the welding process. For instance, numerical simulation can provide information on the starting point of welding for every weld bead, the effect of interpass cooling as far as a possible sensitization of the heat affected zone (HAZ) is concerned, the effect of gap width on the resultant weld residual stresses, or the effect of the ‘last pass heat sink welding’ (welding of the final passes while simultaneously cooling the inner surface with water) producing compressive stresses in the root area of a circumferential weld in an austenitic pipe. The computer program (finite element residual stress analysis) was based on a commercially available code (Hibbitt, Karlsson, Sorensen, Inc, 1997. user's manual, version 5.6), and can be used as a 2-D or 3-D FEM analysis; depending on task definition it can provide a starting point for a fracture mechanics safety analysis with acceptable computing times.     

Numerical models for prestressing tendons in containment structures

Two modified stress–strain relations for bonded and unbonded internal tendons are proposed. The proposed relations can simulate the post-cracking behavior and tension stiffening effect in prestressed concrete containment structures. In the case of the bonded tendon, tensile forces between adjacent cracks are transmitted from a bonded tendon to concrete by bond forces. Therefore, the constitutive law of a bonded tendon stiffened by grout needs to be determined from the bond–slip relationship. On the other hand, a stress increase beyond the effective prestress in an unbonded tendon is not section-dependent but member-dependent. It means that the tendon stress unequivocally represents a uniform distribution along the length when the friction loss is excluded. Thus, using a strain reduction factor, the modified stress–strain curve of an unbonded tendon is derived by successive iterations. In advance, the prediction of cracking behavior and ultimate resisting capacity of prestressed concrete containment structures using the introduced numerical models are succeeded, and the need for the consideration of many influencing factors such as the tension stiffening effect, plastic hinge length and modification of stress–strain relation of tendon is emphasized. Finally, the developed numerical models are applied to prestressed concrete containment structures to verify the efficiency and applicability in simulating the structural behavior with bonded and/or unbonded tendons.     

The feasibility of small size specimens for testing of environmentally assisted cracking of irradiated materials and of materials under irradiation in reactor core

Environmentally assisted cracking (EAC) or, in other words, stress corrosion cracking (SCC) of in-core materials has become an increasingly important reason for the downtime and maintenance costs of nuclear power plants (NPPs). Use of small size specimens for stress corrosion testing of irradiated materials is necessary because handling of high dose rate materials is difficult and the availability of these materials is limited. A drawback of using small size specimens is that they do not in some cases fulfil the requirements of the relevant testing standards and sometimes their limited load-bearing capacity prevents corrosion fatigue tests and tests with static loading at reasonable K_I values. The test results show that the ductile fracture resistance curves of a Cu–Zr–Cr alloy are, to some extent, independent of the specimen geometry and size. However, the curves of small specimens deviate from the curves of larger specimens at high J values (large plastic zone relative to the remaining ligament) or when the crack growth exceeds about 30% of the remaining ligament. The size dependency of the tested Cu–Zr–Cr alloy seems to be a consequence of decreasing stress triaxiality as the size of the specimen is decreased. The results of the SCC tests of sensitized SIS 2333 stainless steel (equal to AISI 304) specimens in simulated boiling water reactor (BWR) water show that the plastic deformation of the remaining ligament of the specimen has no significant effect on the environmentally assisted crack growth rate. This indicates that stress corrosion testing is not limited by the specimen size. The size dependency in SCC tests should be further studied by conducting tests using various specimen sizes.     

CEA and JNC approaches for creep–fatigue evaluation of weldments and inter-comparison through benchmark analyses

Creep–fatigue is an important failure mode in elevated temperature components especially for weldments. To establish rational design-by-analysis methods for weldments, the CEA and JNC have developed creep–fatigue evaluation methods. Both organizations have compared data and ideas through two kinds of benchmark analyses. The CEA benchmark is fatigue and creep–fatigue evaluation of welded plates under reverse bending at 550 °C. The JNC benchmark is creep–fatigue evaluation of a welded vessel under cyclic thermal transients. The main differences in the methods are the strain concentration factors for base metal fatigue strength reduction factors of weldments. To evaluate inferior performance of weldments to base metal, the CEA pays attention to material strength reduction in the weld metal, while the JNC examines strain redistribution between the base and weld metals. Both the CEA and JNC calculations gave good results for welded plates. Both methods obtained conservative results for a welded vessel because evaluation methods for base metal are conservative.     

贯穿件J形坡口焊接残余应力分析

核电站反应堆压力容器(RPV)顶盖控制棒驱动机构(CRDM)管座J形坡口焊缝在一回路高温高压水环境下存在应力腐蚀开裂(SCC)的风险,而焊接残余应力是SCC的主要驱动力。使用二维轴对称模型有限元方法对CRDM中心管座J形坡口进行焊接残余应力分析。为了探索一种简单、高效和保守的方法,研究了热源简化、焊缝形状简化、屈服强度、相变和强化行为对焊接残余应力的影响。结果表明:双椭球热源与均匀热源得到的残余应力结果基本一致;焊缝形状由鱼鳞状简化为方块模型对焊接残余应力结果影响不大,但是与合并焊道的结果相差较大;采用低屈服强度得到的残余应力结果并不保守;在ANSYS软件中,固液相变对残余应力结果影响不大;等向强化模型的结果比随动强化模型的结果保守;在工程上,建议采用均匀热源、方块焊道模型和等向强化模型进行焊接模拟。     

反应堆压力容器内部大尺寸环形异种金属焊缝残余应力分布研究

获得反应堆压力容器内部大尺寸环形异种金属焊缝残余应力分布可为反应堆压力容器结构设计和制造工艺优化提供指导,通过设计和制造能够代表产品焊接结构形式的镍基合金和低合金钢异种金属焊接结构模拟件,采用轮廓法测试焊接结构模拟件内部纵向残余应力,采用有限元法模拟计算焊接结构模拟件横向和纵向残余应力,获得了整个异种金属焊接接头残余应力分布特征。结果表明:焊缝区域内部纵向残余应力为拉伸应力,峰值应力达到500 MPa左右,并且表层应力大于内部应力,峰值应力出现在距下表面3 mm和24 mm位置;横向残余应力在焊缝区域从上表面到下表面的分布为拉应力-压应力-拉应力,压缩横向残余应力峰值达到?300 MPa,出现在距下表面约18 mm位置。本文研究可为焊接结构设计提供理论指导。      

焊接残余应力对316LN不锈钢应力腐蚀裂纹扩展速率的影响

核电站不锈钢管道焊接过程中引入的残余应力对焊接接头的应力腐蚀开裂性能有较大影响。本文针对一AP1000主管道316LN不锈钢焊接模拟件进行残余应力分析和应力腐蚀裂纹扩展速率测量,得到了焊后原始状态和去应力热处理状态的焊接热影响区材料在高温高压水中的应力腐蚀裂纹扩展速率。实验结果表明,焊接残余应力明显提高了热影响区的应力腐蚀裂纹扩展速率,且在含氢的压水堆一回路正常水化学下焊接残余应力的影响更加显著。     

Properties of heavy components of steel grade 91 and their welds

The use of the modified 9% Cr1% Mo steel grade (grade 91) for the manufacturing of heavy products (forgings, plates) for pressure vessels is evaluated on the following aspects: (i) possibility to produce heavy components (base material) with the required properties, (ii) conditions for welding without cracking, and (iii) availability of welding products and determination of their mechanical properties. Heavy plates with thickness ranging from 20 to 300 mm have been manufactured and tested. All mechanical properties (tensile, Charpy V notch impact, creep…) have been obtained in conformity with the requirements of ASTM specifications and literature data on thinner materials. Some laboratory tests have been carried out to determine the sensitivity of this material to cracking phenomena during welding (cold cracking) or during the postweld heat treatment (reheat cracking). They show that this material does not present major welding difficulties in comparison with more conventional materials used for the manufacture of pressure vessels. To obtain high toughness properties of the weld metal and low residual stresses, the postweld heat treatment temperature was found to be high (750 to 770°C). A significant modification of the weld metal deposit chemistry was found to be necessary to achieve the convenient level of impact properties, but correlatively, a decrease of its creep resistance may be expected for this very low Nb weld material.     

Age-related degradation of boiling water reactor vessel internals

Researchers at the Idaho National Engineering Laboratory performed an assessment of the aging of the reactor internals in boiling water reactors (BWRs), and identified the unresolved technical issues related to the degradation of these components. The overall life-limiting mechanism is intergranular stress corrosion cracking (IGSCC). Irradiation-assisted stress corrosion cracking, fatigue, and thermal aging embrittlement are other potential degradation mechanisms. Several failures in BWR internals have been caused by a combination of factors such as environment, high residual or preload stresses, and flow-induced vibration. The ASME Code Section XI in-service inspection requirements are insufficient for detecting aging-related degradation at many locations in reactor internals. Many of the potential locations for IGSCC or fatigue are not accessible for inspection.     

Piping Cracks in JPDR, (IV)

Circumferential cracks detected in the JPDR (BWR) near welded joints connecting the nozzle safe-end to pipe (austenitic stainless steel) were studied in reference to the stresses applied in service, the conditions of welding, environment (O₂ and Cl^? concentration, water flow, temperature etc.), metallurgical structure and operating records, to determine the cause of cracking. Fatigue tests were also undertaken with simulated welded pipe of size to examine possible contribution of fatigue to the cracking.

The analysis indicated stress corrosion to be the principal cause of cracking, and that it had initiated in the heat-affected zone which had been sensitized by the excess heat input of welding. The factors contributing to the stress corrosion were the presence of oxygen in the fluid, which had at times attained a level exceeding 0.2 ppm, and which combined with stress, at times exceeding the yield strength. This had caused the cracks once initiated, to propagate along the grain boundary.     

Prediction of residual stress in the welding zone of dissimilar metals using data-based models and uncertainty analysis

Since welding residual stress is one of the major factors in the generation of primary water stress-corrosion cracking (PWSCC), it is essential to examine the welding residual stress to prevent PWSCC. Therefore, several artificial intelligence methods have been developed and studied to predict these residual stresses. In this study, three data-based models, support vector regression (SVR), fuzzy neural network (FNN), and their combined (FNN + SVR) models were used to predict the residual stress for dissimilar metal welding under a variety of welding conditions. By using a subtractive clustering (SC) method, informative data that demonstrate the characteristic behavior of the system were selected to train the models from the numerical data obtained from finite element analysis under a range of welding conditions. The FNN model was optimized using a genetic algorithm. The statistical and analytical uncertainty analysis methods of the models were applied, and their uncertainties were evaluated using 60 sampled training and optimization data sets, as well as a fixed test data set.     

Environmentally-assisted cracking behaviour in the transition region of an Alloy182/SA 508 Cl.2 dissimilar metal weld joint in simulated boiling water reactor normal water chemistry environment

The stress corrosion cracking (SCC) and corrosion fatigue behaviour perpendicular and parallel to the fusion line in the transition region between the Alloy 182 Nickel-base weld metal and the adjacent SA 508 Cl.2 low-alloy reactor pressure vessel (RPV) steel of a simulated dissimilar metal weld joint was investigated under boiling water reactor normal water chemistry conditions. A special emphasis was placed to the question whether a fast growing interdendritic SCC crack in the highly susceptible Alloy 182 weld metal can easily cross the fusion line and significantly propagate into the adjacent low-alloy RPV steel. Cessation of interdendritic SCC crack growth was observed in high-purity or sulphate-containing oxygenated water under constant or periodical partial unloading conditions for those parts of the crack front, which reached the fusion line. In chloride containing water, on the other hand, the interdendritic SCC crack in the Alloy 182 weld metal very easily crossed the fusion line and further propagated with a very high rate as a transgranular crack into the heat-affected zone and base metal of the adjacent low-alloy steel. The observed SCC cracking behaviour at the interface correlates excellently with the field experience of such dissimilar metal weld joints, where SCC cracking was usually confined to the Alloy 182 weld metal.