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1.
热致液晶高分子聚酯醚砜及其共混物变行为的研究 总被引:3,自引:0,他引:3
利用平板流变仪及熔融指数仪研究了一种新型热致液晶高分子材料酯醚砜(PEES0的流变行为,测定了该聚合物的熔体粘度-温度,粘度-剪切速率关系。以及聚合物的熔融指数-温度关系。实验结果表明,该聚合物具有热致液晶的流变特性。同时研究了该液晶聚合物与含酚酞基的降芳醚砜(PES-C)组成的不同组分含量的原位复合材料在360℃下的熔融指数变化,表明该液晶聚合物能降低PES-C的熔体粘度,进一步说明此液晶聚合物 相似文献
2.
PES与热致液晶高分子共混物的流变性能 总被引:1,自引:0,他引:1
研究了PES与热致液晶聚合物(LCP)HBA/PET(60/40)共混物的转矩流变和剪切流变性能。加入2%~5%HBA/PET(60/40)可使PES熔体在低剪切速率下的表观粘度下降2~4倍。共混物的粘流活化能也低于纯PES的活化能。加入少量LCP(5%以下)可望大大改善PES的加工性能。 相似文献
3.
SPES-C与PI共混材料膜的气体除湿性能 总被引:6,自引:0,他引:6
以浓硫酸为磺化试剂对聚芳醚砜(PES-C)进行了磺化改性,得到一系列磺化度不同的产物。采用磺化聚芳醚砜(SPES-C)与可溶性聚酰亚胺(PI)的共混材料制备中空纤维用于空气除湿,研究了磺化度及不同的操作条件对膜除湿性能的影响。结果表明,磺化度适当的SPES-C与PI共混体系不但具有良好的成膜性能,而且膜对水蒸汽具有很高的脱除能力,在操作压力较低(0.25MPa)的情况下除湿率可达95%以上。同时,提高回扫比和操作压力在一定范围内也可以改善这类膜的除湿性能。 相似文献
4.
磺化聚芳醚砜与可溶性聚酰亚胺共混材料制备气体除湿膜 总被引:7,自引:2,他引:5
在不同反应条件下制备了一系列磺化聚芳醚砜(SPES-C)样品,采用磺化程度较高的产物与可溶性聚酰亚胺(PI)进行共混并纺制成中空纤维膜,研究了磺化条件对材料磺化程度、共混相容性及成膜性能的影响,通过测试膜对空气中水蒸汽的脱除效果得到了一些规律性的结论。 相似文献
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以4,4′-二氯二苯砜和4-(4-羟基苯基)-2,3-二氮杂萘-1-酮为原料,经亲核取代逐步聚合反应制分子主链中含二氮杂萘酮结构的聚芳醚砜低聚物(PPES),然后与环氧氯丙烷反应制得所需分子量的含环氧端基的聚代醚砜(E-PPES)。用FT-IR和^1H-NMR表达了分子链结构,考察了不同的反应温度、反应时间和反应单体配比对环氧化效果的影响,并测试了聚合物的溶解性能。 相似文献
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以棉纤维为原料,制备了一种纤维素芳族酯(CAE)。用FT-IR表征了CAE的化学结构,用DSC及热台偏光显微观察证实了CAE具有热致液晶性,液晶态温度范围为210~280℃。结晶速度测试表明,CAE对PET有明显的成核和促进结晶作用。 相似文献
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以棉纤维为原料,制备了一种纤维素芳族酯(CAE)。用FT-IR表征了CAE的化学结构,用DSC及热台偏光显微观察证实了CAE具有热致液晶性,液晶态温度范围为210 ̄280℃。结晶速度测试表明,CAE对PET有明显的成核和促进结晶作用。 相似文献
10.
研究了含酚酞聚苯醚酮(PEK-C)、液晶聚合物(LCP)及其共混物的流动性能,测定了ηa-γ曲线及流动活化能(△E)。结果表明,(1)PEK-C、LCP及其共混物均属假塑性流体;(2)LCP可增加PEK-C的流动性;(3)它们的粘度均随温度的升高而降低;(4)共混物的△E随LCP含量的增加而下降。 相似文献
11.
《International journal for numerical methods in engineering》2018,113(9):1488-1506
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method. 相似文献
12.
Standards are the basis for production enterprises to organize production ex-factory inspection trade 《中国标准化(英文版)》2008,25(1):24-25
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.…… 相似文献
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A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa. 相似文献
15.
On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.…… 相似文献
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Zusammenfassung Bei der Gestaltung von Ernteprozessen — beispielsweise des Prozesses Mähdrusch, Körnertransport und -abnahme — als transportverbundene Fließarbeitsverfahren mit mindestens zwei verschiedenen Arbeitsmitteln gibt es einen großen Optimierungsspielraum. Solche Prozesse sind mehrstufige Bedienungsprozesse mit gemischter Anordnung der Bedienungseinrichtungen. Außerdem besitzen sie stark ausgeprägte räumliche Aspekte. Es wird vor allem gezeigt, welche Merkmale solcher Prozesse in Simulationsmodellen abgebildet sein müssen, welche Zielgrößen in Abhängigkeit von welchen Einflußgrößen unter Berücksichtigung welcher Prozeßbedingungen ermittelt werden sollten und wie der Bewertungsprozeß zur Ermittlung der gewünschten Informationen gestaltet werden muß. 相似文献
17.
C. Qihong W. Zhan‐Wen J. Yi J. Yehua L. Fei F. Hanguang 《Materialwissenschaft und Werkstofftechnik》2014,45(7):582-590
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill. 相似文献
18.
《中国标准化(英文版)》2014,(4)
正Responding to ISO’s appeal for survey for the to-be-developed ISO Strategy Plan for 2016-2020,SAC hosted a special workshop over the needs and comments of various fi elds on June 8 in Beijing.The workshop was attended by ISO President-elect and Ansteel General Manager Zhang Xiaogang,SAC Vice-Administrator Yu Xinli,and 30 experts from 相似文献
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《中国标准化(英文版)》2014,(5)
正The review group of Asia Pacific Laboratory Accreditation Cooperation(APLAC)carried out a 4-day peer review of the proficiency testing provider(PTP)for China National Accreditation Service for Conformity Assessment(CNAS)from July 28 to 31,2014.CNAS passed the PTP review with excellent performance.Two senior peer reviewers of APLAC made a comprehensive,rigorous and detailed review of CNAS’s PTP accreditation activities,and made the on-spot inspection of the review groups in Shanghai and Shenzhen respectively. 相似文献
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《中国标准化(英文版)》2014,(4)
正China and Greece Sign the Standardization Cooperation Agreement Witnessed by Chinese Premier Li Keqiang and Greek Prime Minister Antonis Samaras,AQSIQ Minister Zhi Shuping and ELOT Chairman and Executive Director Angelos Tolkas signed the SAC-ELOT Standardization Cooperation Agreement.The Agreement is one of the critical cooperation documents signed during Li Keqiang’s visit in Greece,encouraging China and Greece to 相似文献