Design and thermodynamic analysis of supercritical CO2 reheating recompression Brayton cycle coupled with lead‐based reactor

A reheating process is generally incorporated in a supercritical CO₂ (S‐CO₂) Brayton cycle to enhance its efficiency. The heat transfer process from the reactor coolant to the working fluid of the power cycle is a key issue encountered when designing reheating power systems for the lead‐based reactor. The traditional reheating system, called RH‐1, utilizes an intermediate coolant circuit. In this paper, a novel reheating system, called RH‐2, is proposed. It eliminates the intermediate coolant circuit and combines the processes of the primary heating and reheating in a single heat exchanger. A thermodynamic analysis of three different systems for the lead‐based reactor integrated with the S‐CO₂ power cycle with or without reheating was conducted to evaluate the performance of the proposed system. The results confirmed that the performance of RH‐2 was the best of all the three systems. Under the same reactor conditions, the system efficiency of RH‐2 was greater than those of RH‐1 and the recompression (no reheating) system by 1.2% and 1.7%, respectively. RH‐2 could also maintain higher efficiency when the main operating parameters varied. The efficiency of RH‐2 was higher at different core outlet temperatures and split ratios. The maximum efficiency at optimal maximum pressure of RH‐2 was greater than those of the other two systems. RH‐2 was less sensitive to the variations in the isentropic efficiencies of the components than the other two systems, while the turbine isentropic efficiency demonstrated a significantly higher impact on the system efficiency than the two compressors (approximately 3.8 times).     

Performance optimisation of solar receivers that use oil as a heat transfer fluid

This article presents the use of a wire mesh in optimising the performance of two volumetric solar receivers that use oil as a heat transfer fluid. Computational fluid dynamics models have been used to optimise the receivers. Varied parameters (including the use of a wire mesh) of the receiver models were changed in the optimisation process. Based on the models, prototype receivers were developed and tested. After that, the models were validated against experiments and the results compare well. The results indicate that the use of a wire mesh placed inside a receiver improves its performance. An optimal wire mesh porosity was found as ≈0.95 mainly because the efficiency is increased without inducing an adverse pressure drop inside the receiver.     

Thermodynamic optimisation of the integrated design of a small‐scale solar thermal Brayton cycle

The Brayton cycle's heat source does not need to be from combustion but can be extracted from solar energy. When a black cavity receiver is mounted at the focus of a parabolic dish concentrator, the reflected light is absorbed and converted into a heat source. The second law of thermodynamics and entropy generation minimisation are applied to optimise the geometries of the recuperator and receiver. The irreversibilities in the recuperative solar thermal Brayton cycle are mainly due to heat transfer across a finite temperature difference and fluid friction. In a small‐scale open and direct solar thermal Brayton cycle with a micro‐turbine operating at its highest compressor efficiency, the geometries of a cavity receiver and counterflow‐plated recuperator can be optimised in such a way that the system produces maximum net power output. A modified cavity receiver is used in the analysis, and parabolic dish concentrator diameters of 6 to 18 m are considered. Two cavity construction methods are compared. Results show that the maximum thermal efficiency of the system is a function of the solar concentrator diameter and choice of micro‐turbine. The optimum receiver tube diameter is relatively large when compared with the receiver size. The optimum recuperator channel aspect ratio for the highest maximum net power output of a micro‐turbine is a linear function of the system mass flow rate for a constant recuperator height. For a system operating at a relatively small mass flow rate, with a specific concentrator size, the optimum recuperator length is small. For the systems with the highest maximum net power output, the irreversibilities are spread throughout the system in such a way that the internal irreversibility rate is almost three times the external irreversibility rate. Copyright © 2011 John Wiley & Sons, Ltd.     

Dual Loop line-focusing solar power plants with supercritical Brayton power cycles

This study is focused on proposing the combination of a Dual Loop solar field, with Dowtherm A and the Solar Salt as heat transfer fluids in parabolic or linear Fresnel solar collectors, coupled to supercritical Carbon Dioxide (s-CO₂) Brayton power cycle. The Dual-Loop justification relies on gaining the synergies provided by the different heat transfer fluids properties. The oils advantages are related with the operating experience accumulated in numerous solar power plants deployed around the World, assuring the commercial equipment availability. Also the pipes metal corrosion with oil is much lower than with molten salt. The pipes material cost saving is significant with the oil alternative. The thermal oil main constraint is imposed by the maximum operating temperature (around 400 °C) for avoiding chemical decomposition and degradation, stablishing the plant threshold efficiency 37% due to Carnot principle. On the other hand the Solar Salt mixture (60%NaNO₃40%KNO₃) maximum operating temperature goes up to 550 °C, but the freezing point is stablished around 220 °C requiring pipes and equipment electrical heating for avoiding salts solidification at low temperature. Regarding the balance of plant, the s-CO₂ power cycle is the most promising alternative to the actual Rankine power cycle for increasing the plant energy efficiency, reducing the solar collector aperture area and minimizing the equipment dimensions and civil work. Three Brayton cycles configurations with reheating were assessed integrated with the line-focusing Dual-Loop solar field: the simple Brayton cycle (SB), the Recompression cycle (RC), the Partial Cooling with Recompression cycle (PCRC), and the Recompression with Main Compression Intercooling (RCMCI). The power cycle operating thermodynamic parameters (split flow, reheating pressure, mass flow and pressure ratio) were optimized with unconstrained multivariable algorithms: SUBPLEX, UOBYQA and NEWUOA. The main conclusion deducted is the significant efficiency improvement when adopting the s-CO₂ Brayton cycle in comparison with the Rankine legacy solution. The Dual-Loop solar field integrated with a Rankine cycle provides a gross efficiency around 41.8%, but when coupling to s-CO₂ Brayton RC or RCMCI the plant efficiency goes up to ≈50%. It was also demonstrated the beneficial effect of increasing the total heat exchangers (recuperators) conductance (UA) for optimizing the Brayton cycles efficiency and minimizing the solar field aperture area for a fixed power output, only limited by the minimum pinch point temperature in heat exchangers.     

Review of supercritical CO2 power cycles integrated with CSP

Increasing demand of electricity and severer concerns to environment call for green energy sources as well as efficient energy conversion systems. SCO₂ power cycles integrated with concentrating solar power (CSP) are capable of enhancing the competitiveness of thermal solar electricity. This article makes a comprehensive review of supercritical CO₂ power cycles integrated with CSP. A detailed comparison of four typical CSP technologies is conducted, and the cost challenge of currently CSP technologies is pointed out. The thermophysical properties of sCO₂ and the corresponding two real gas effects are analyzed elaborately to express the features of sCO₂ power cycles. An extensive review of sCO₂ layouts relevant for CSP including 12 single layouts and 1 combined layout is implemented logically. Strengths and weaknesses of sCO₂ power cycles over traditional steam-Rankine cycle generally adopted in current CSP plants are concluded, followed by metal material degration summary in CSP relevant temperature sCO₂ environment, which shows that the nickel-based alloy is a proper structural material candidate for sCO₂-CSP integration. Thermodynamic analyses of sCO₂ power cycles when integrated with CSP are divided into three level of which design-point analysis and off-design modeling are conducted and compared, more researches into the off-design point analysis, dynamic modeling, especially the transient behavior are suggested. Economic analysis of the integrated system is concluded and presents a considerable levelized cost of electricity reduction of 15.6% to 67.7% compared to that of state of art CSP. Taking the thermodynamic and economic analysis into consideration, target designs of sCO₂ power cycles for CSP are summarized in three aspects. Finally, current theoretical and experimental researches of sCO₂ power cycles integrated with CSP for market penetration are introduced. The strengths, weaknesses, and potential solutions to the gaps of three potential pathways (molten salt pathway, particle pathway, and gas phase pathway) to realize the integration of sCO₂ power cycles in the next CSP generation plants up to 700°C are reviewed. In general, the integration of sCO₂ power cycles with CSP technologies exhibits promising expectations for facilitating the competitiveness of thermal solar electricity.     

Two novel high-porosity materials as volumetric receivers for concentrated solar radiation

This article reports on two novel porous materials, which have been foreseen as volumetric receivers for concentrated solar radiation: a double-layer silicon carbide foam and a screen-printed porous silicon carbide material. Volumetric receivers are used in the solar tower technology. In this technology ambient air flows through the porous solid, which is heated by concentrated solar radiation. A heat exchanger then transfers the energy to a conventional steam turbine process. The general thermophysical and permeability properties of materials required for this application are reviewed. Experimental set-up and results of pressure loss and laboratory scale tests in concentrated solar radiation are reported. For the foam, efficiency data could be determined from the test results. Finally, a comparison is presented between the efficiency properties of the foam and those of materials used for the same application until now. This comparison shows, that the efficiency of the double-layer foam material is significantly higher. Up to now, porous materials consisting of a parallel channel geometry with thin walls showed disadvantageous permeability properties. By applying a new manufacturing process and modifying the channel geometry, the permeability properties of the printed material could be significantly changed, so that it now meets the requirements for an application as a volumetric receiver.     

Development of thermodynamic cycles for concentrated solar power plants

Solar thermal power is a promising ‘green’ technology that could contribute significantly – in countries where it may be applicable due to available resources – towards meeting the 2020 and 2050 targets for the free energy production of emissions [Viebahn, P., Lechon, Y., and Trieb, F., 2011. The potential role of concentrated solar power (CSP) in Africa and Europe – a dynamic assessment of technology development, cost development and life cycle inventories until 2050. Energy Policy, 39 (8), 4420–4430]. Especially for the regions where solar radiation is significant, the technology of concentrated solar power (CSP) plants seems to have a great potential, once cost-related issues are resolved. The thermodynamic process, on which the component design of the plant is based, plays a significant role in the optimisation of the efficiency of the derived configuration. This paper aims to present a route for the design of thermodynamic cycles for a CSP, starting from the simplest processes and heading towards more complicated ones. For a reference output capacity, the obtained efficiencies are presented, illustrating the technical benefits of shifting to more advanced thermodynamic processes.     

Innovative biomass to power conversion systems based on cascaded supercritical CO2 Brayton cycles

In the small to medium power range the main technologies for the conversion of biomass sources into electricity are based either on reciprocating internal combustion or organic Rankine cycle engines. Relatively low energy conversion efficiencies are obtained in both systems due to the thermodynamic losses in the conversion of biomass into syngas in the former, and to the high temperature difference in the heat transfer between combustion gases and working fluid in the latter. The aim of this paper is to demonstrate that higher efficiencies in the conversion of biomass sources into electricity can be obtained using systems based on the supercritical closed CO₂ Brayton cycles (s-CO₂). The s-CO₂ system analysed here includes two cascaded supercritical CO₂ cycles which enable to overcome the intrinsic limitation of the single cycle in the effective utilization of the whole heat available from flue gases. Both part-flow and simple supercritical CO₂ cycle configurations are considered and four boiler arrangements are investigated to explore the thermodynamic performance of such systems. These power plant configurations, which were never explored in the literature for biomass conversion into electricity, are demonstrated here to be viable options to increase the energy conversion efficiency of small-to-medium biomass fired power plants. Results of the optimization procedure show that a maximum biomass to electricity conversion efficiency of 36% can be achieved using the cascaded configuration including a part flow topping cycle, which is approximately 10%-points higher than that of the existing biomass power plants in the small to medium power range.     

Development and thermodynamic assessment of a novel solar and biomass energy based integrated plant for liquid hydrogen production

In this paper, a combined power plant based on the dish collector and biomass gasifier has been designed to produce liquefied hydrogen and beneficial outputs. The proposed solar and biomass energy based combined power system consists of seven different subplants, such as solar power process, biomass gasification plant, gas turbine cycle, hydrogen generation and liquefaction system, Kalina cycle, organic Rankine cycle, and single-effect absorption plant with ejector. The main useful outputs from the combined plant include power, liquid hydrogen, heating-cooling, and hot water. To evaluate the efficiency of integrated solar energy plant, energetic and exergetic effectiveness of both the whole plant and the sub-plants are performed. For this solar and biomass gasification based combined plant, the generation rates for useful outputs covering the total electricity, cooling, heating and hydrogen, and hot water are obtained as nearly 3.9 MW, 6584 kW, 4206 kW, and 0.087 kg/s in the base design situations. The energy and exergy performances of the whole system are calculated as 51.93% and 47.14%. Also, the functional exergy of the whole system is calculated as 9.18% for the base working parameters. In addition to calculating thermodynamic efficiencies, a parametric plant is conducted to examine the impacts of reference temperature, solar radiation intensity, gasifier temperature, combustion temperature, compression ratio of Brayton cycle, inlet temperature of separator 2, organic Rankine cycle turbine and pump input temperature, and gas turbine input temperature on the combined plant performance.     

Theoretical and numerical investigation of flow stability in porous materials applied as volumetric solar receivers

This article reports results of a theoretical analysis as well as a numerical study investigating the occurrence of flow instabilities in porous materials applied as volumetric solar receivers. After a short introduction into the technology of volumetric solar receivers, which are aimed to supply heat for a steam turbine process to generate electricity, the general requirements of materials applied as solar volumetric receivers are reviewed. Finally, the main methods and results of the two studies are reported. In the theoretical analysis it is shown that heat conductivity as well as permeability properties of the porous materials have significant influence on the probability of the occurrence of flow instabilities. The numerical study has been performed to investigate the occurrence of unstable flow in heated ceramic foam materials. In the simulations a constant heat flow of radiation, that is absorbed in a defined volume, and constant permeability coefficients are assumed. Boundary conditions similar to those of the 10 MW Solucar Solar project have been chosen. In a three dimensional, heterogeneous two phase heat transfer model it was possible to simulate local overheating of the porous structure. The parameters heat conductivity, turbulent permeability coefficient and radial dispersion coefficient have been varied systematically. Consequently, for a heat flux density of 1 MW/m² a parameter chart could be generated, showing the possible occurrence of “unstable” or “stable” thermal and fluid mechanical behaviour. These numerical results are beneficial for the design of optimized materials for volumetric receivers.     

A thermodynamic analysis of a simple open-flow solar regenerator

Simple expressions have been developed for important variables of the flow in an open-flow solar regenerator (with applications in absorption cooling systems) through a first- and second-law analysis of the system. In particular, expressions for the regenerator figure of merit, the exergetic or rational efficiency and the entropy production rate have been given and applied to some available data with reasonably good results.     

High temperature oxidation of ZrC-20%MoSi2 in air for future solar receivers

This article reports on the study of the oxidation of ZrC-20 vol% MoSi₂ in the temperature range 1800-2400 K in air, in order to partially reproduce the operating conditions of a high-temperature receiver for concentrated solar radiation. Such receivers are used in solar tower power plants, this technology being likely to grow in scale in the future due to environmental concerns. A thermodynamic calculation showed the existence of a limit temperature at about 1600 K, above which CO formation is significantly increased. During oxidation experiments carried out in a solar furnace, Bubble Burst Events appeared around 2000 K. The formation of these bubbles was accompanied by an increase in oxidation damage for the material. It was assumed that these bubbles formed because of the surface melting of samples in addition to an increased release of CO. However ZrC was found to undergo less oxidation damage than SiC under same conditions, as demonstrated in this study. Two different ZrC surface states were studied, but no major differences were observed in terms of oxidation behavior. Results of the thermodynamic calculation and characterization of the oxide layer let us think that the addition of such a high amount of MoSi₂ was detrimental to the oxidation behavior above 1800 K, because of its dissociation and its role in the surface melting.     

Solar flux distribution on central receivers: A projection method from analytic function

This paper presents a methodology to project the flux distribution from the image plane into the panels of any central receiver in Solar Power Tower plants. Since analytic functions derived from the convolution approach are conveniently defined on the image plane, its oblique projection solves the distorted spot found in actual receivers. Because of its accuracy describing the flux distribution due to rectangular focusing heliostats, we make use of the analytic function on the image plane by Collado et al. (1986). Based on the projection method, we have developed a computer code successfully confronted against PSA measurements and SolTrace software, either for flat plate or multi-panel cylindrical receivers. The validated model overcomes the computation time limitation associated to Monte Carlo technique, with a similar accuracy and even higher level of resolution. For each heliostat in a field, the spillage is computed besides the rest of optical losses; parallel projection is used for shading and blocking. The resulting optical performance tool generates the flux map caused by a whole field of heliostats. A multi-aiming strategy is investigated on the basis of the radius of the reflected beams, estimated from error cone angles.     

Comparative performance analysis of solar powered supercritical-transcritical CO2 based systems for hydrogen production and multigeneration

CO₂ based power and refrigeration cycles have been developed and analyzed in different existing studies. However, the development of a CO₂ based comprehensive energy system and its performance analysis have not been considered. In this study, the integration of a CO₂ based solar parabolic trough collector system, a supercritical CO₂ power cycle, a transcritical CO₂ power cycle, and a CO₂ based cascade refrigeration system for hydrogen production and multigeneration purpose is analyzed thermodynamically. This study aims to analyze and compare the difference in the thermodynamic performance of comprehensive energy systems when CO₂ is used as the working fluid in all the cycles with a system that uses other working fluids. Therefore, two comprehensive energy systems with the same number of subsystems are designed to justify the comparison. The second comprehensive energy system uses liquid potassium instead of CO₂ as a working fluid in the solar parabolic trough collector and a steam cycle is used to replace the transcritical CO₂ power cycle. Results of the energy and exergy performance analysis of two comprehensive energy systems showed that the two systems can be used for the multigeneration purpose. However, the use of a steam cycle and potassium-based solar parabolic trough collector increases the comprehensive energy systems’ overall energy and exergy efficiency by 41.9% and 26.7% respectively. Also, the use of liquid potassium as working fluid in the parabolic trough collectors increases the absorbed solar energy input by 419 kW and 2100 kW thereby resulting in a 23% and 90.7% increase in energetic and exergetic efficiency respectively. The carbon emission reduction potential of the two comprehensive energy systems modelled in this study is also analyzed.     

Design and analysis of a solar tower power plant integrated with thermal energy storage system for cogeneration

In the current study, a solar tower–based energy system integrated with a thermal energy storage option is offered to supply both the electricity and freshwater through distillation and reverse osmosis technologies. A high‐temperature thermal energy storage subsystem using molten salt is considered for the effective and efficient operation of the integrated system. The molten salt is heated up to 565°C through passing the solar tower. The thermal energy storage tanks are designed to store heat up to 12 hours. The temperature variations in the storage tanks are studied and compared accordingly for evaluation. The effect of operating temperatures on the freshwater production and overall system efficiency is determined. About 24.46 MW electricity is generated in the steam turbine under sunny conditions. Furthermore, the storage subsystem stores heat during sunny hours to utilize later in cloudy hours and night time. The produced power decreases to 20.17 MW in discharging hours due to temperature decrease in the tank. The electricity generated by the system is then used to produce freshwater through the reverse osmosis units and also to supply electricity for the residential use. A total flowrate of 240.02 kg/s freshwater is obtained by distillation and reverse osmosis subsystems.     

Wind effect on the performance of solid particle solar receivers with and without the protection of an aerowindow

The wind conditions affect the performance of a solid particle solar receiver (SPSR) by convection heat transfer through the existing open aperture. Aerowindows have the potential of increasing the efficiency of an SPSR. In the present paper, the wind effect on the performance of an SPSR is investigated numerically with and without the protection of an aerowindow. The independence of the calculating domain in a wind field has been studied in order to select a proper domain for the numerical simulation. The cavity thermal efficiencies and the exiting temperature of the solid particles have been calculated and analyzed for different wind conditions. The numerical investigation of the SPSRs’ performance can provide a guide in optimizing the prototype design, finding out the suitable working condition and proposing efficiency enhancing techniques for SPSRs.     

Comparison of three different solar collectors integrated with geothermal source for electricity and hydrogen production

In this study, an integrated system is proposed for mainly electricity and hydrogen production. Energy and exergy analyses of the system are also examined by using Engineering Equation Solver (EES, version 2019) under solar radiation during day time on 1st July. The proposed system consists of a middle-temperature geothermal source with fluid temperature 93 °C, three solar collectors (SCs of 300 m²) namely parabolic trough solar collectors (PTSCs), evacuated tube solar collectors (ETSCs), flat plate solar collectors (FPSCs), an organic Rankine cycle (ORC), proton exchange membrane (PEM), a compressor, hot water storage tank and a mushroom cultivation room. The temperature of the geothermal fluid is upgraded via solar collectors by harvesting solar radiation to operate the ORC. Thus the generated electricity is used in the PEM electrolysis system for producing hydrogen. When the PTSCs, ETSCs, and FPSCs are integrated with the geothermal source separately, it is found that 2758.69 g, 1585.27 g, and 634.42 g of hydrogen can be produced, respectively for a day. The highest overall energetic and exergetic performance of the system is calculated as to be 5.67% and 7.49%, respectively.     

Thermal performance analysis of small-sized solar parabolic trough collector using secondary reflectors

ABSTRACT

In this paper, theoretical analysis of receiver tube misalignment, the design of secondary reflector and experimental analysis of a small-sized solar parabolic trough collector (PTC) with and without secondary reflectors are represented. Experimental analysis of PTC has been done using a parabolic secondary reflector (PSR) and triangular secondary reflector (TSR) and compared with PTC without secondary reflector (WSR). The maximum outlet temperature of heat transfer fluid is observed as 49.2°C, 47.3°C and 44.2°C in the case of PSR, TSR and WSR conditions, respectively. The maximum thermal efficiency of 24.3%, 22.5% and 17.8% is observed in the case of PSR, TSR and WSR conditions, respectively. The circumferential temperature difference on the outer surface of the receiver tube is obtained more uniform in the case of PSR and TSR than WSR condition. This indicates that the use of a secondary reflector can improve the performance of a solar PTC system.     

Heat transfer performance of an external receiver pipe under unilateral concentrated solar radiation

The heat transfer and absorption characteristics of an external receiver pipe under unilateral concentrated solar radiation are theoretically investigated. Since the heat loss ratio of the infrared radiation has maximum at moderate energy flux, the heat absorption efficiency will first increase and then decrease with the incident energy flux. The local absorption efficiency will increase with the flow velocity, while the wall temperature drops quickly. Because of the unilateral concentrated solar radiation and different incident angle, the heat transfer is uneven along the circumference. Near the perpendicularly incident region, the wall temperature and absorption efficiency slowly approaches to the maximum, while the absorption efficiency sharply drops near the parallelly incident region. The calculation results show that the heat transfer parameters calculated from the average incident energy flux have a good agreement with the average values of the circumference under different boundary conditions. For the whole pipe with coating of Pyromark, the absorption efficiency of the main region is above 85%, and only the absorption efficiency near the parallelly incident region is below 80%. In general, the absorption efficiency of the whole pipe increases with flow velocity rising and pipe length decreasing, and it approaches to the maximum at optimal concentrated solar flux.     

A novel integrated simulation approach couples MCRT and Gebhart methods to simulate solar radiation transfer in a solar power tower system with a cavity receiver

An integrated simulation approach, which couples Monte Carlo ray tracing (MCRT) and Gebhart methods, is proposed to simulate solar radiation transfer in a solar power tower system with a cavity receiver. The MCRT method is used to simulate the solar radiation transfer process from the heliostat field to interior surfaces of the cavity receiver, and the Gebhart method is used to simulate the multiple reflections process of solar radiation within the cavity. This integrated simulation method not only reveals the cavity effect on receiver performance but also provides real-time simulation results. Based on this method, the reflection loss of the cavity receiver and solar flux distributions are discussed in detail. The results indicate that the cavity effect can significantly reduce the reflection loss and homogenize the concentrated solar energy distributed on interior surfaces to some extent. Moreover, the surface absorptivity has less effect on the reflection loss when cavity effect is considered. The cavity effect on homogenizing solar flux distributions is greater with lower surface absorptivity. In addition, although the concentrated solar energy is distributed on the cavity aperture with similar shapes at different times, the shape of the solar flux distribution on interior surfaces varies greatly with time.