Urban Battery Litter

Consumer batteries littered in urban environments are generally littered on pavements. These batteries rapidly deteriorate by several physical and chemical mechanisms that breach their structural integrity and release a host of environmentally significant pollutants (Ag, Ba, Cd, Cr, Cu, Hg, Li, Mn, Ni, Pb, Ti, Zn) to storm-water runoff. Research on urban battery litter began at Case Western Reserve University in the summer of 2001. This paper presents much of what is currently known about the occurrence of urban battery litter. Data are presented on the number, type, and condition of over 6,100 littered batteries collected in field surveys conducted in urban areas around Cleveland. Methods are presented for estimating battery litter rates and for characterizing the size, structure, internal chemistry, deterioration status, life expectancy, and contaminant release potential of urban battery litter. Results from field study sites demonstrate that at “hot spot” locations, battery litter can be a significant source of contamination. Annual litter rates as high as 215?batteries/ha (nearly 90/acre) of parking lot pavement and 0.4?batteries/m of street curb (one battery for every 8?ft. of curb) have been measured. At some locations the Zn mass loading from batteries approaches 1?kg/ha and could be the most significant source of pavement-related Zn released to urban storm-water runoff.     

Corrosion Deterioration in Consumer Battery Litter

Recent studies have shown that the annual rates of consumer battery litter on urban pavements can be as high as 215 batteries per hectare of pavement and 0.4 batteries per meter of curb. As littered batteries deteriorate, they release components (Ag, Ba, Cd, Cr, Cu, Hg, Li, Mn, Na, Ni, Pb, Ti, and Zn) that can be significant sources of storm-water contamination. Results of ambient environmental and laboratory-accelerated corrosion studies are presented to quantify the mechanisms that yield chemical deterioration of littered batteries. The analysis concentrates on AA size alkaline and zinc chloride/zinc carbon (ZnCl/ZnC) cells since these are the most commonly littered batteries. Results indicate that littered batteries exposed to ambient well-drained environmental conditions for more than two months will develop surface corrosion over most of their surface but fewer than 10% will be ruptured by corrosion within the first 6 months. This agrees well with field observations. Exposure under poorly drained conditions yields more rapid deterioration but it requires exposure to more aggressive conditions such as those produced by road salts to reproduce the high degree of deterioration observed in some battery litter.     

Zinc Pollution Potential of Consumer Battery Litter

Consumer batteries in urban litter can be significant sources of storm-water pollution. Recent studies have reported annual urban battery litter rates as high as 215 batteries per hectare of pavement and 0.4 batteries per meter of street curb. On average, 75% of these batteries are leaking or have already discharged their internal reactants. However, many battery sizes, brands, and power chemistries are littered and this diversity makes it difficult to quantify their cumulative pollution potential. The amount of zinc released from AA size alkaline and zinc chloride/zinc carbon (ZnCl/ZnC) batteries which account for approximately 90% of urban battery litter is examined. Results are presented for batch rupture release extractions of 52 alkaline battery products yielding zinc releases of 20–40 mg/L and 57 ZnCl/ZnC products yielding zinc releases of 400–1,400 mg/L. Results of continuous flow column extractions are also presented to gauge releases following initial battery rupture. Disassembly analyses are used to bound the total zinc release potential of common battery products. Results indicate that ZnCl/ZnC batteries release more zinc when they are first ruptured, but if deterioration is complete, alkaline batteries can release approximately 25% more zinc. Therefore, the relative importance of these two classes of batteries depends on site-specific factors such as the proportion of each in litter, battery deterioration rates, and the length of time that battery litter remains unremediated by maintenance.     

Characterizing Physicochemical Quality of Storm-Water Runoff from an Urban Area in Calgary, Alberta

Understanding storm-water runoff quality is required to develop effective urban storm-water runoff management for regions of semiarid climate. In this study, the quality of storm-water runoff from a semiarid, urban residential catchment, draining through separated storm-water sewers was investigated in 2006 and 2007. Water temperature, conductivity, pH, dissolved oxygen, and turbidity were continuously measured during 16 storm events. Storm-water runoff quality was characterized in terms of event mean values (EMVs), loads, and first flush (FF) loads and their relationships with rainfall characteristics. Discharge of total suspended solids (TSSs) is in general governed by the flow magnitude in storms and no significant relationships exist between the FF loads of TSS and rainfall intensity. The discharge of dissolved solids is independent of the flow magnitude. Strong FF effect for dissolved solids and weak FF effect for TSS were observed. This semiarid region provided no relationship between the EMVs of both TSS and conductivity and the antecedent dry period. This raises doubts on storm-water runoff being more heavily loaded with pollutants after a longer dry period in semiarid regions.     

Trace Metal Pollutant Load in Urban Runoff from a Southern California Watershed

In order to implement efficient and effective management strategies for coastal water quality in Southern California, it is important to consider the relative pollutant contributions from urban dry-weather flow (DWF) and wet-weather flow (WWF). This study uses both historical flow coupled with water quality monitoring data and computer modeling to characterize the annual DWF and WWF discharges from an urban catchment in Los Angeles, Calif. The DWF and WWF pollutant loading of the trace metals copper, lead, nickel, and chromium for 6 water years dating from 1991 to 1996 is predicted. The results indicate that DWF contributes a considerable amount of flow and pollutants. Approximately, 9–25% of the total annual Ballona Creek flow volume is DWF. The simulations indicate DWF accounts for 54, 19, 33, and 44% of the average annual load of total chromium, copper, lead, and nickel, respectively. In the dry season, the simulations indicate DWF accounts for 89, 59, 58, and 90% of the load of total chromium, copper, lead, and nickel, respectively. This research suggests DWF controls may be an important part of pollution mitigation plans for urban stormwater drainage systems in Southern California.     

Investigation of Boundary Shear Stress and Pollutant Detachment from Impervious Surface during Simulated Urban Storm Runoff

Pollutant detachment rates have been determined for four chloride salts during simulated urban storm runoff. Under rainfall and/or overland flow conditions, chloride mass flux was measured and related to boundary shear stress of the test surface. Washoff coefficients, presumed to depend only on pollutant characteristics, were computed based on the slopes of dimensionless mass flux versus dimensionless time plots. Washoff coefficients were found to vary among and between the chloride compounds studied. In general, higher overland flow rates produced lower boundary shear and lower washoff coefficients. The combination of simulated rainfall and overland flow resulted in an increased boundary shear and an increased washoff coefficient. An empirical washoff coefficient based on a load characteristic curve derived from an exponential washoff relationship was also computed from the runoff data and compared with the previous washoff coefficient. A linear correlation between these two washoff coefficients was observed. The magnitude of the latter coefficient under simulated rainfall was consistent with reported values obtained from field data.     

Long-Term Simulation of a System for Catchment, Pretreatment, and Treatment of Polluted Runoff Water

The effects of pollutants in runoff on the environment have forced the development of several water treatment systems with the aim of reducing this kind of pollution before its final discharge. Nevertheless, many of these systems do not behave satisfactorily and, additionally, there is a low level of confidence in the treatment performance. This paper introduces the results of research on the long-term performance of a laboratory prototype of a system for catchment, pretreatment, and treatment (SCPT) designed to deal with the polluted runoff water. Solid and oil treatment efficiency were the focus of the study. After 14 consecutive simulated rain events, the treatment efficiency levels achieved by the prototype are higher than 80% of solids and 90% of oils.     

Load Resistance Factor Design of Axially Loaded Pile Based on Load Test Results

The present study proposes a procedure to determine partial factors in reliability based design format for pile foundations, considering bias as well as uncertainty in the parameters that represent soil-pile interaction. These issues are addressed using pile load-settlement test data from case studies obtained from the literature. The pile ultimate capacities are evaluated considering three different failure criteria. The uncertainties in the pile-soil interface parameters as well as pile ultimate capacity are quantified in Monte Carlo framework from the measured data by utilizing the closed form “t-z” method. Considering dead load to live load ratios as calibration points, the target reliability index is calculated based on existing code safety-checking format. The optimal partial factors are determined such that the difference between reliability index based on limit state equations expressed in terms of partial factors and target reliability index is minimum. Finally, it is observed that optimal partial factors enable rational choice of allowable load on pile foundation.     

Calibrating Resistance Factors of Single Bored Piles Based on Incomplete Load Test Results

This paper addresses a problem often encountered in calibrating resistance factors for the ultimate capacities of piles based on load test databases. In practice, many pile load tests are not conducted to failure but only to a multiple (e.g., 2) of the design load. This leads to a difficult situation of incomplete information: for these test results, the ultimate bearing capacities of the test piles are unknown. How can these test results still be used to calibrate resistance factors of piles? A full probabilistic framework is proposed in this research to resolve this problem. A local pile test database of Taipei (Taiwan) is presented for demonstration. The analysis results show that the inclusion of the incomplete pile load test data enhances the stability of the calibrated resistance factors. For a target reliability index of 3, the calibrated resistance factor is in the range of 0.4–0.66 for two design models adopted in the current Taiwan design code. Moreover, it is found that the safety factor adopted in the Taiwan design code corresponds to a reliability index larger than 3.5, which is reasonably conservative.     

Plate Load Test on Fiber-Reinforced Soil

This technical note discusses the load–settlement response from two steel plate load tests (0.3 m diameter, 25 mm thick) carried out on a thick homogeneous stratum of compacted sandy soil, reinforced with polypropylene fibers, as well as on the same soil without the reinforcement. In addition to the field test program, laboratory triaxial compression tests were performed to determine the static stress–strain response of the compacted sandy soil reinforced with randomly distributed polypropylene fibers. The laboratory test results showed that the reinforcement changed dramatically the stress–strain behavior at very large strains. The strength was found to increase continuously at a constant rate, regardless of the confining pressure applied, not reaching an asymptotic upper limit, even at axial strains as large as 25%. The plate load test on the soil–fiber stratum was performed to relatively high pressures, and gave a noticeable stiffer response than that carried out on the nonreinforced stratum.     

Improved Evaluation of Equivalent Top-Down Load-Displacement Curve from a Bottom-Up Pile Load Test

A modified procedure is presented in this study to evaluate the equivalent top-down load-displacement curve in a bottom-up pile load test considering elastic shortening. On the basis of the results of a parametric study on a bored pile in normally consolidated cohesive soils under undrained conditions, varying shear strength distribution and pile slenderness ratio, it was concluded that the pile shortening caused by the skin-friction component of the load in a top-down test can be related to the measured elastic shortening in a bottom-up test. A λ-factor is used to define this relationship, that is, the ratio of the top-down to bottom-up pile shortening. The factor λ = 1.0 is used for the case of a pile in soil with uniform shear strength profile, λ = 2.0 for linear profiles, 1.0<λ<2.0 for nonlinear profiles varying above linear, and λ>2.0 for nonlinear profiles varying below linear. In addition, the method suggests taking the corresponding readings of the skin-friction load component from the upward displacement curve of the top of the pile, which is a closer approximation to rigid pile displacement than the bottom when corrections for elastic pile shortening are to be applied. Assuming a fully mobilized skin-friction, a logarithmic relation for the factor λ to the normalized area under the shear strength profile was generally formulated and is limited to the assumptions on which they were derived. The suggested procedure in this study has produced the equivalent top-down load-displacement curves that are in close agreement with the measured top-down curve, as validated in the case studies.     

Computational Fluid Dynamics Simulation of Concentration Distributions from a Point Source in the Urban Street Canyons

Air pollution in big city areas resulting from exhaust emissions is a major urban problem. Often traffic pollution excess controls air pollution management decisions. There are a number of elaborate predictive models of pollutant dispersion and diffusion that address the effects of variable shapes of city buildings on pollutant concentrations, but few are fully validated. This paper presents ventilation behavior in different street canyon configurations. To evaluate dispersion in a model urban street canyon, a series of tests with various street canyon aspect ratios (B/H) are presented. Physical modeling in wind tunnels and numerical modeling can be used for dispersion simulation when investigating air quality. The flow and dispersion of gases emitted by a point source located between two buildings inside of the urban street canyons were determined by the prognostic model FLUENT using the four differences closure approximation [standard κ-ε, RNG κ-ε, Reynolds-stress, and large eddy simulation (LES)] and Fire Dynamics Simulator, LES methodology. Calculations are compared against fluid modeling in an industrial wind tunnel at Colorado State University. These buildings were arranged in various symmetric configurations with different separation distances and different numbers of surrounding buildings. The objective of this paper was to develop reliable computer models for the bluff body flow and transport of pollutants or chemical and biological agents in urban environments.     

Urban Runoff Quality Characterization and Load Estimation in Saskatoon, Canada

The improvement in the effluent quality of the treated sanitary sewage entering the South Saskatchewan River at Saskatoon, Canada, and the impending change in provincial legislation governing urban runoff, provided the impetus for Saskatchewan Environment to initiate the stormwater runoff quality study reported in this paper. Among others, the study involved a field program for characterizing the urban runoff water quality from four catchments, each representing a different type of land use. Both a site mean concentration approach and a multiple variable regression analysis approach were used to quantify the pollutant load contained within the runoff. Thereafter, using the runoff water quality characterizations developed in the study, rainfall–runoff pollutant loads from the entire city were estimated and compared with two local point sources to the receiving stream. On the basis of this analysis, it was found that urban runoff contributes more total suspended solids and total Kjeldahl nitrogen load, similar chemical oxygen demand load, and slightly less total phosphorus load than the two local point sources.     

Uncertainty Analysis of Micropile Pullout Based upon Load Test Results

Micropiles are applied in foundation rehabilitation projects to enhance the pullout capacity of the existing foundation system and minimize the vertical deflection of the structures. Consequently, the methods to calculate the pullout load–displacement behavior are important for the design of micropiles used for such rehabilitation projects. Production pullout load tests were performed on approximately 120 micropiles used for seismic retrofitting of the 580/980/24 freeway interchange in Oakland, Calif. These micropiles were required to satisfy the serviceability design capacity at a maximum deflection of 1.27?cm (0.5?in.), in addition to the ultimate design capacity. Because the existing structures varied in height and loading, micropiles of different pullout capacities were designed. In this paper, the measured data are using a closed-form “t–z” method to develop probability distribution functions for the model parameters. As the back-calculated model parameters are assumed to be random variables, the Monte Carlo simulation process is employed to develop a series of load–displacement curves. A method for determining the probability of micropile failure at the service limit state is developed using the results of the simulations. The method is utilized to obtain resistance factors that can be applied to LRFD based service limit- state design.     

Documenting Stormwater Quality on Texas Highways and Adjacent Vegetated Roadsides

The primary objective of this study is the documentation of stormwater quality of vegetated roadsides of two Texas highways (State Highway 6 in College Station and Loop 360 in Austin), both of which had high average daily traffic. Three sites each in Austin and College Station were monitored using passive “first flush” stormwater samplers for 16 months. Results from this study indicate that significant removal of sediment and heavy metals occurred over the width of vegetated roadsides, but no apparent nutrient (nitrogen and phosphorus) removal was observed. The results also show that vegetation density has a direct effect on the performance of vegetated roadsides. When roadsides are densely covered with grasses above 90%, significant sediment removal is expected, often within the first 4?m of the edge of pavement. A stepwise regression analysis identifies the antecedent dry period (ADP) as the most significant predictor to pollutant concentration. The pollutant event mean concentration was found to decrease with increasing ADP for all pollutants at the College Station sites, but not the Austin ones.     

Load Testing and Settlement Prediction of Shallow Foundation

The purpose of this study was to critically examine insitu test methods as a means for predicting settlement of shallow foundations. Accordingly, a 1.8?m (6?ft) diameter concrete footing was statically load tested. Prior to construction, insitu [standard penetration test (SPT), cone penetration test (CPT), dilatometer (DMT), and pressuremeter (PMT)] and laboratory tests were performed to determine engineering properties of the soil. Predictions of the footing settlement were made by traditional as well as finite element methods. The results of the static load test showed settlements were over predicted by all methods. However, the traditional methods provided reasonable settlement estimates using either SPT-N or back computed CPT(N) as input. Finite element analyses using either DMT or CPT derived input parameters provided reasonable settlement estimates. Finite element analyses using SPT or PMT derived input parameters provided poor settlement estimates. The Mohr–Coulomb (elastoplastic) model, accounting for overconsolidation, provided better estimates than the hardening soil (hyperbolic-cap) model for all insitu test derived parameters.     

Assessment of Load Transfer and Load Distribution in Bridges Utilizing FRP Panels

A primary means of demonstrating the feasibility and effectiveness of fiber-reinforced polymer (FRP) composite bridge materials is via in situ bridge load testing. For this study, the prescribed or assumed design factors for each of the study bridges were compared to those exhibited by the performance of the bridge. Specifically, the wheel load distribution factors and impact factors as defined by AASHTO were considered in order to assess the load transfer and distribution in structures utilizing FRP panels. The in situ testing configurations for the study bridges are outlined, including the truck and instrumentation placement to obtain the desired information. Furthermore, comparisons were drawn between the design values for deflection and those experienced by the structures during testing. It was found that although the deflections exhibited by the bridges were well within the design limits, further research is needed to be able to prescribe bridge design factors for FRP panels.     

In-Situ Evaluation of Two Concrete Slab Systems. I: Load Determination and Loading Procedure

The primary objective of in-situ load testing is to assess the safety and serviceability of an existing structural system with respect to a particular load effect. At this time, the most appropriate loading level and procedure, as well as the associated evaluation criteria are being reconsidered in light of technological advances in construction methods, analytical tools, and monitoring instrumentation. The in-situ load test method for reinforced concrete systems described in the ACI Building Code Requirements for Structural Concrete, namely the 24–h load test method and its evaluation criteria, has been in use for several decades, but may no longer serve the needs of contemporary construction and engineering practices. As a result, other load test methodologies and associated evaluation criteria are under development. This paper and a companion paper describe the rationale and application of an alternative approach to the determination of load level, loading procedure, instrumentation requirements, evaluation criteria and outcomes for two field projects. The first case study is relative to a posttensioned concrete slab where many areas were characterized by tendon and reinforcement misplacement, resulting in inadequate flexural strength and inadequate shear/flexure transfer at column/slab intersections. The second case study is the structural evaluation of a typical floor bay of a two-way reinforced concrete slab system, presenting distributed cracking at the positive and negative moment regions. Finite-element-method models were created for both structures to aid the load test design. The numerical models validated the field observations.     

Assessment of the Axial Load Response of an H Pile Driven in Multilayered Soil

Most of the current design methods for driven piles were developed for closed-ended pipe piles driven in either pure clay or clean sand. These methods are sometimes used for H piles as well, even though the axial load response of H piles is different from that of pipe piles. Furthermore, in reality, soil profiles often consist of multiple layers of soils that may contain sand, clay, silt or a mixture of these three particle sizes. Therefore, accurate prediction of the ultimate bearing capacity of H piles driven in a mixed soil is very challenging. In addition, although results of well documented load tests on pipe piles are available, the literature contains limited information on the design of H piles. Most of the current design methods for driven piles do not provide specific recommendations for H piles. In order to evaluate the static load response of an H pile, fully instrumented axial load tests were performed on an H pile (HP?310×110) driven into a multilayered soil profile consisting of soils composed of various amounts of clay, silt and sand. The base of the H pile was embedded in a very dense nonplastic silt layer overlying a clay layer. This paper presents the results of the laboratory tests performed to characterize the soil profile and of the pile load tests. It also compares the measured pile resistances with those predicted with soil property- and in situ test-based methods.     

Construction Effect on Load Transfer along Bored Piles

The load transfer behavior along bored piles is affected by details of pile construction particularly those imposing stress and moisture changes to the surrounding soils. An investigation involving moisture migration tests, in situ horizontal stress measurements, and borehole shear and pressuremeter tests shows clear effects of construction that lead to subsequent changes in soil properties. The construction of bored piles in Singapore and the region often involves casting of concrete either in unsupported “dry” boreholes or in “wet” boreholes filled with water. It is necessary to differentiate these two extreme construction conditions in bored pile design. Based on triaxial compression and pressuremeter tests on the residual soil of the Jurong Formation in Singapore, the variation of soil modulus with shear strain can be described by a hyperbolic function. A procedure is recommended for assessing the combined effect of stress relief and soaking on soil modulus by introducing a modulus reduction factor. Modulus degradation curves from pressuremeter tests with the borehole conditions properly simulated are found capable of producing load transfer curves that are comparable to those deduced in the field.