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1.
许静  谢凯  龙永福  肖加余 《材料导报》2005,19(11):115-117
报道了一种新的调节二氧化硅光子晶体带隙的方法;通过化学镀向SiO2胶体晶体中填充半导体材料Se,获得了Se-SiO2两种介质复合的三维光子晶体;采用扫描电子显微镜(SEM)、X射线衍射和紫外-可见光谱仪(UV-VIS)等对Se-SiO2三维光子晶体的形貌、结构和光学性能进行了观察测试.研究结果表明,Se以纳米晶粒的形式均匀地包覆在SiO2微球表面,形成了Se壳层,与相同晶格周期的SiO2光子晶体相比,Se-SiO2光子晶体的带隙发生了明显的红移.  相似文献   

2.
CdSe-SiO2光子晶体的垂直沉积及近红外变频特性   总被引:1,自引:1,他引:0  
在氧化铟锡玻璃上电化学合成了CdSe薄膜,采用垂直沉积法首次在CdSe薄膜上制备了SiO2胶体晶体, 实现了CdSe表面介电常数的调节.扫描电镜观察表明,500nm微球在CdSe薄膜上呈面心立方密堆结构排列,在微米尺度上胶体晶体显示出一定的多晶序.与SiO2胶体晶体相比,CdSe-SiO2光子晶体的UV-vis-NIR透射谱只有一个较宽的光子带隙,带隙在近红外波段随入射角减小向短波方向移动.所得CdSe-SiO2光子晶体样品可作为地面目标针对红外卫星成像的伪装材料.  相似文献   

3.
近红外光学带隙硅三维光子晶体的制备   总被引:2,自引:0,他引:2  
李宇杰  谢凯  许静  龙永福 《材料导报》2006,20(6):129-131
用溶剂蒸发法将单分散SiO2微球组装成三维有序结构的胶体晶体模板,用低压化学气相沉积法填充高折射率材料硅,酸洗去除SiO2模板,获得了硅反蛋白石三维光子晶体.通过扫描电镜、X射线衍射仪和紫外-可见-近红外光谱仪对硅反蛋白石三维光子晶体的形貌、成分、结构和光学性能进行了表征.研究结果表明:Si在SiO2微球空隙内具有较高的结晶质量,填充致密均匀;通过控制沉积条件,可控制硅的填充率;制备的硅反蛋白三维光子晶体在近红外区(1.4μm左右)具有明显的光学反射峰,表现出光学带隙效应,测试的光学性能与理论计算基本吻合.  相似文献   

4.
光子晶体是由具有不同介电常数的物质,在空间按照周期性排列形成具有光子带隙的介电结构材料.光子带隙中的慢光子和带隙反射可以促进光子的捕获和控制光与物质之间的相互作用.基于光子晶体独特的光学特性和较大的比表面积,将光子晶体结构引入到半导体光催化材料的设计中,可以有效地增强光催化反应活性.本文介绍了三维光子晶体的制备方法及慢光子效应,总结了光子晶体特别是反蛋白石结构的光子晶体作为光催化剂在废水净化、制氢、二氧化碳的转化等领域的研究进展,并针对光子晶体光催化剂面临的挑战,提出了开发具有不同折射率和周期性的多层三维光子晶体,促进光子晶体在光催化领域的应用.  相似文献   

5.
赵荻  汪晨怿  钱达兴 《材料导报》2008,22(4):119-124
光子晶体是一种具有光子带隙的新型功能材料.利用垂直沉积自组装法制成SiO2胶体晶体,并利用扫描电子显微镜和紫外分光度计对胶体晶体的显微形貌和光学特征进行了研究.结果表明,利用垂直沉积法自组装得到的SiO2胶体晶体具有面心立方结构;在可见光波段,胶体晶体在<111>面方向存在光子带隙.  相似文献   

6.
对传统的"Stober-Fink"合成SiO2微球的工艺进行了改进,运用"籽晶生长法"合成了单分散SiO2微球,该法可以准确地控制微球尺寸,提高微球的球形度.采用垂直沉积法制备了胶体晶体,并对样品的结构和光学性能进行了表征.研究了微球尺寸对垂直沉积SiO2胶体晶体光子带隙的影响,结果表明,通过控制微球粒径,可调节光子晶体的带隙位置.  相似文献   

7.
光子晶体用二氧化硅胶体球的改性制备及其自组装   总被引:1,自引:0,他引:1  
采用一步法制备了表面接枝甲基丙烯酰氧基三甲氧基硅烷(MPS)的单分散SiO2胶体球,并通过垂直沉积法在40℃、60%相对湿度下组装出有序性较好的密排结构的SiO2光子晶体.傅立叶红外光谱(FT-IR)和X射线光电子能谱(XPS)结果证明SiO2胶体球表面接枝上了MPS;扫描电子显微镜(SEM)结果表明改性后SiO2胶体球平均粒径为284nm,单分散性较高,平均标准偏差<5%;制备出的光子晶体是面心立方(fcc)紧密堆积结构;吸收光谱表明,所制备的光子晶体在(111)方向具有光子晶体的带隙特性,带隙中心波长为646nm.  相似文献   

8.
为提高SiO2微球的表面电荷密度,通过改进Stober法,引入电解质NaCl合成SiO2微球,并采用垂直沉积法制备出光子晶体.通过Zeta电位粒度仪、带EDS能谱仪的场发射扫描电子显微镜(SEM)和紫外-可见-近红外光谱仪对其电学性能、显微形貌和光学性能进行测试分析.Zeta电位测试结果显示改性SiO2:微球的Zeta电位平均提高11.39mV;EDS能谱分析表明微球中含有钠元素;SEM照片表明样品平均粒径为334 nm,平均标准偏差小于5%,所得光子晶体为面心立方密排结构;吸收光谱表明在725nm处具有光子晶体带隙.  相似文献   

9.
贾瑛  王幸运  许国根  徐虎 《纳米科技》2013,(2):23-26,31
以Zn(Ac)2和DEG为原料,采用胶体自组装工艺制备了不同胶粒尺寸的ZnO光子晶体,探索了胶体自组装ZnO光子晶体的制备工艺,研究了自组装温度、溶剂、悬浮液浓度、热处理温度等因素对光子晶体排布平整度、周期性和空间紧密度的影响规律,对各种工艺条件下光子晶体的带隙特征进行了研究,试验结果表明,通过自组装工艺条件选择可实现对光子晶体带隙结构的可控性制备。  相似文献   

10.
徐键  赵文娟  方刚  徐清波 《材料导报》2017,31(24):169-173
单分散胶体球可自组装出面心立方结构(周期常数为a)的三维光子晶体材料,进一步用高折射率光学材料填充其间隙再除去胶体球则可制得高折射率差、反蛋白石结构的三维光子晶体材料,从而应用于集成光子器件。了解其光子带隙以及光在缺陷中的传输性质是设计与制造该光子晶体材料与器件的基础,因此采用时域有限差分法仿真,研究不同波长λ的光在完整与含直线、L形线缺陷的反蛋白石结构光子晶体材料中的传输性质。研究结果表明该材料光子禁带的归一化频率a/λ在0.45~0.55之间,光在直线缺陷和L形线缺陷中传输的透过系数分别为~65%和~72%。  相似文献   

11.
We report a hybrid approach for photonic systems that combines chemically synthesized single nanowire emitters with lithographically defined photonic crystal and racetrack microresonator structures. Finite-difference time-domain calculations were used to design nanowire photonic crystal structures where the photonic band gap overlaps the electronic band gap of the nanowire. Photoluminescence (PL) images of cadmium sulfide (CdS) nanowire photonic crystal structures designed in this way demonstrate localized emission from engineered defects and light suppression in regions of the photonic crystal. PL spectroscopy studies of defect-free nanowire photonic crystal structures further demonstrate the photonic band gap or stop band that spans most of the CdS band edge emission spectrum. In addition, single CdS nanowire-racetrack microresonator structures were fabricated, and PL imaging and spectroscopy measurements show good coupling of the nanowire to the microcavity including efficient feedback and amplified spontaneous emission. These hybrid structures exploit unique strengths of bottom-up and top-down approaches and thereby open new opportunities in nanophotonics from efficient and localized light sources to integrated optical processing.  相似文献   

12.
The effect of temperature on a two-dimensional square lattice photonic crystal composed of Si rods arranged in an air background was investigated theoretically using the plane-wave expansion method. Both the thermal expansion effect and thermo-optical effect are considered simultaneously. We have discussed the role of temperature in creating the complete photonic band gap as a function of temperature. Two different shapes of rods, i.e. square and circular, are considered in the presence of the two polarization states, i.e. TE and TM waves. The numerical results show that the photonic band gap can be significantly enlarged compared to the photonic band gap at room temperature. The effect of temperature on the complete photonic band width in the cylindrical rods case is more significant. Cylindrical and square Si rods may work as a temperature sensor or filter, among many other potential applications.  相似文献   

13.
We use first order perturbation theory to study the effect of surface plasmon polaritons on the photonic band structure of plasmonic photonic crystals. Our results are based on a simple numerical tool that we have developed to extend the standard frequency domain methods to compute the photonic band structure of plasmonic photonic crystals. For a two-dimensional honeycomb photonic crystal with a lattice constant of 500 nm placed on an aluminium substrate, we show that the band gap for TM modes is enhanced by 13%. Thus a slight variation in the effective dielectric function results in a plasmonic band structure that is not scale-invariant, which is reminiscent of the inherent non-linear properties of the effective dielectric constant.  相似文献   

14.
一维光子晶体是指介质只在一个方向成周期性排列的材料。利用薄膜光学的特征矩阵法研究了一维光子晶体的禁带特性,分析了填充率变化、厚度的随机扰动对光子带隙的影响。结果表明,随着填充率的变化,各能级的带隙率变化,并且存在一个极大值;厚度的随机扰动对光子带隙也有一定的影响,随机度不同,对光子带隙的影响也不一样。本研究对一维光子晶体的设计与制备有一定的参考价值。  相似文献   

15.
二氧化硅胶体晶体的制备及其光子带隙特性   总被引:9,自引:0,他引:9  
利用胶体颗粒悬浊液的自组织生长技术制备了两种二氧化硅胶体晶体.透射光谱表明:所制备的胶体晶体的光子带隙位于近红外波段,带隙的位置随胶体晶体中胶粒的尺寸而变化;且放置时间延长,带隙将发生蓝移.  相似文献   

16.
The optical properties of a graphene based annular photonic crystal (APC) are theoretically investigated. The proposed structure is a hollow core cylindrical shell consists of the alternate dielectric layer and graphene monolayer immersed in free space. In order to study the photonic band structures of the APC, we obtained the optical spectra of the graphene based APC by employing the transfer matrix method in the cylindrical waves for both TE and TM polarizations. In this work we study the effect of different geometrical and optical parameters of the structure on the low loss high reflectance graphene induced band gap. It is found that the graphene induced band gap which appeared in the frequency below 10 THz is polarization independent and remains almost invariant with the change in the period number, the radius of the inner core region and the refractive indices of the inner core region and the surrounding medium. However, its width increases by increasing the azimuthal mode number and the chemical potential of the graphene monolayers and decreases by increasing the refractive index and the thickness of the dielectric layers.  相似文献   

17.
Abstract

In this study, we analyse the evolution of complete photonic band gap in two-dimensional photonic structures by arranging the 12-fold symmetric quasicrystalline unit cells on square and triangular lattices. The unit cells composed of circular air holes in anisotropic tellurium background and the air holes are infiltrated with liquid crystal. Using the supercell method based on plane wave expansion, we study the variation of complete band gap by changing the optical axis orientation of liquid crystals.  相似文献   

18.
We study transmission properties of one-dimensional photonic crystals consisting of mu-negative and positive index materials by using transfer matrix methods. The results show that transmission properties of the transverse electric waves depend on permittivity (?), while transmission properties of the transverse magnetic waves depend on permeability (μ); there exists a transmission band inside the single-negative gap in this periodic structure without defects, and the transmission band is insensitive to the incident angle for the transverse electric waves but sensitive for the transverse magnetic waves. This property can be used to make polarization-dependent angle filters.  相似文献   

19.
The three-dimensional (3D) photonic crystals with face-centered cubic (fcc) structure was fabricated on polyester fabrics, a kind of soft textile materials quite different from the conventional solid substrates, by gravitational sedimentation self-assembly of monodisperse P(St-MAA) colloidal microspheres. The optical properties of structural colors on polyester fabrics were investigated and the position of photonic band gap was characterized. The results showed that the color-tuning ways of the structural colors from photonic crystals were in accordance with Bragg’s law and could be modulated by the size of P(St-MAA) colloidal microspheres and the viewing angles. The L1a1b1 values of the structural colors generated from the assembled polyester fabrics were in agreement with their reflectance spectra. The photonic band gap position of photonic crystals on polyester fabrics could be consistently confirmed by reflectance and transmittance spectra.  相似文献   

20.
A binary genetic algorithm with floating crossover and mutation probabilities is used to design two-dimensional photonic crystals for large absolute band gaps under a light line. The unit cell is composed of a small number of round rods and is arranged in a square lattice. The photonic band structure of each chromosome is calculated by the plane-wave expansion method. Starting from randomly generated photonic crystals, the genetic algorithm finally yielded a photonic crystal with an absolute common band gap of 0.0618(2πc/a) at the mid-frequency of 0.4084(2πc/a).  相似文献   

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