ICT and environmental sustainability: A global perspective

The positive and negative environmental impacts of information and communication technologies (ICTs) are widely debated. In theory, ICT is among the sources contributing to the increasing levels of CO₂ emissions in terms of production of ICT machinery and devices, energy consumption, and recycling of electronic waste. However, ICT is also expected to reduce CO₂ emissions on a global scale by developing smarter cities, transportation systems, electrical grids, industrial processes, and energy saving gains. These two effects work in opposite direction, creating an inverted-U relationship between ICT and CO₂ emissions. The aim of this study is to investigate this non-linear relationship between ICT and CO₂ emissions on a global scale. Given that global warming is a global issue, it is necessary to look at this relationship in countries at all levels of development. To this end, we use a panel data set consisting of 142 economies, split into 116 developing and 26 developed countries, over the period 1995–2010. The results of our empirical study confirm that the relationship between ICT and CO₂ emissions is an inverted U-shaped relationship. Moreover, while for the sample of developing countries, the ICT turning point is well above the mean value, the opposite is true for the sample of developed countries. This implies that many developed countries have already attained the level of ICT development, at which CO₂ emissions decreases as the level of ICT development improves further.     

Proton Turnover Dominated Cascade Route for CO2 Photoreduction

Photoreduction carbon dioxide (CO₂) and water (H₂O) into valuable chemicals is a huge potential to mitigate immoderate CO₂ emissions and energy crisis. To date, tremendous attention is concentrated on the improvement of independent CO₂ reduction or H₂O oxidation behaviors. However, the simultaneous control of efficient electron and hole utilization is still a huge challenge due to the complex cascade redox reactions. Here, a proton turnover exists in the whole CO₂ photoreduction process is discovered, which is defined as the pivot to concatenate the hole and electron behaviors. As a demonstration of the concept, the efficient activated hydrogen (*H) production centers of copper (Cu) and rapid hydrogenation centers of nickel (Ni) are coupled by an alloying strategy, and the proton turnover behaviors could be directly determined by adjustment of the molar ratios of Cu_xNi_y. Moreover, Cu₃Ni₁–TiO₂ exhibits the highest electron selectivity of 93.7% for methane (CH₄) production with a rate of 175.9 µmol g⁻¹ h⁻¹, while Cu₁Ni₅–TiO₂ reaches up to the highest carbon monoxide (CO) electron selectivity and generation rate at 84.4% and 164.6 µmol g⁻¹ h⁻¹, respectively. Consequently, the experimental and theoretical analysis all clarify the predominate proton turnover effect during the overall CO₂ photoreduction process, which directly determines the categories and generated efficiency of C-based products by regulating variable reaction pathways. Therefore, the revelation of the proton turnover pivot could broaden the new sights by bidirectional optimization of dynamics during the overall CO₂ photoreduction system, which favors the efficient, selective, and stable photocatalytic CO₂ reduction with H₂O.     

A fast approach for bitcoin blockchain cryptocurrency mining system

The growth of the blockchain-based cryptocurrencies has attracted a lot of attention from a variety of fields, especially in academic research. One of them is Bitcoin, the most popular and highest valued cryptocurrency on the market. The SHA256 is the main processing part in Bitcoin mining, to date the difficulty of which is extremely high and still increases relentlessly. Hence, it is essential to improve the speed of the SHA256 cores in the Bitcoin mining system. In this paper, we propose a two-level pipeline hardware architecture for the SHA256 processing. The first-level pipeline helps the system reduce the number of operating cycles. Besides, the maximum frequency of the system is boosted by the second-level pipeline. The proposed hardware is implemented on FPGA Xilinx Virtex 7-VC707 (28 nm technology). The mining hash rate using the proposed pipeline SHA256 cores reaches 514.92 MH/s that improves 2.4 times compared to the FPGA based conventional technique. The throughput of SHA core of current study is 296.108 Gbps that is 240 times higher compared to the standard technique. The proposed architecture is also implemented in an ASIC design using ROHM 180 nm CMOS technology, which resulted in a throughput of 69.28 Gbps that is 18 times higher than that of conventional work implemented in Intel 14 nm process.     

Projected photovoltaic energy impacts on US CO2 emissions: an integrated energy environmental–economic analysis

The potential role of photovoltaic technologies in reducing carbon dioxide (CO₂) emissions in the USA was evaluated using an energy–environment–economic systems model. With a range of assumptions about future scenarios up to 2030, the model results provide an objective quantitative assessment of the prospects for photovoltaics in a competitive market. With the projected improvements in cost and efficiency, photovoltaics will compete favorably as a general source of electricity supply to the grid by about 2010 in southwestern USA. This analysis indicates that photovoltaics has the potential to reach a total installed capacity of 140 GW by the year 2030, and to displace a cumulative 450 million metric tons of carbon emissions from 1995 to 2030. At the projected 2030 capacity, photovoltaics could displace over 64 million metric tons of carbon emissions a year. Under constraints on carbon emissions, photovoltaics becomes more cost effective and would further reduce carbon emissions from the US energy system. © 1997 John Wiley & Sons, Ltd.     

Does information and communication technology and financial development lead to environmental sustainability in India? An empirical insight

This paper examines the relationship between CO₂ emissions, electricity consumption, financial development, Economic growth, Informational Communication Technology (ICT) from 1990 to 2018 in India. We have applied the structural break co-integration approach like Gregory Hansen approach to check long-term relations between the variables. ARDL bounds testing approach is used to know the long run and short-run elasticity. We find that electricity consumption is positively contributing CO₂ emissions or reducing environmental sustainability in India. However, ICT has negative and significantly improving environmental sustainability or reducing emissions when measured in both ICT internet connection (ICT_INT) and ICT mobile Phones (ICT_MOB). Similarly, financial development and CO₂ emissions are negatively related. The result indicates the existence of Environmental Kuznets Curve in India's case. Overall, environmental sustainability achieved in ICT and financial development sectors. Therefore govt. needs to focus more on the stringent policy in electricity production by investing more in the renewable energy sector to curb environmental degradation.     

Selective activation of failure mechanisms in packaged double-heterostructure light emitting diodes using controlled neutron energy irradiation

This paper demonstrates the feasibility of creating specific defects in double-heterostructure AlGaAsGaAs commercial light emitting diode by neutron irradiation. Using controlled neutron energy, only one failure mechanism can be activated. Defects are located in the side of the chip and increase the leakage current driven by the well-known Pool–Frenkel effect with E_c ? E_T = 130 meV electron trap energy level. The maximal amplitude of optical spectrum also reveals a drop about 20% associated to the rise of leakage current.     

Understanding Boosted Selective CO2-to-CO Photoreduction with Pure Water Vapor over Hierarchical Biomass-Derived Carbon Matrix

Solar-driven CO₂ reduction reaction (CO₂RR) with water into carbon-neutral fuels is of great significance but remains challenging due to thermodynamic stability and kinetic inertness of CO₂. Biomass-derived nitrogen-doped carbon (N-C_b) have been considered as promising earth-abundant photocatalysts for CO₂RR, although their activities are not ideal and the reaction mechanism is still unclear. Herein, an efficient catalyst is developed for CO₂-to-CO conversion realized on diverse N-C_b materials with hierarchical pore structures. It is demonstrated that the CO₂-to-CO conversion preferentially takes place on positively charged carbon atoms next to pyridinic-N using two representatives treated pollens with the largest difference in pyridinic-N density and N content as model photocatalysts. Systematic experimental results indicate that surface local electric field originating from charge separation can be boosted by hierarchical pore structures, doped N, as well as pyridinic-N. Mechanistic studies reveal that positively charged carbon atoms next to pyridinic-N serve as active sites for CO₂RR, reduce the energy barrier on the formation of CO*, and facilitate the CO₂RR performance. All these benefits cooperatively contribute to treated chrysanthemum pollen catalyst exhibiting excellent CO formation rate of 203.2 µmol h⁻¹ g⁻¹ with 97.2% selectivity in pure water vapor. These results provide a new perspective into CO₂RR on N-C_b, which shall guide the design of nature-based photocatalysts for high-performance solar-fuel generation.     

Pre-Activation of CO2 at Cobalt Phthalocyanine-Mg(OH)2 Interface for Enhanced Turnover Rate

Cobalt phthalocyanine (CoPc) anchored on heterogeneous scaffold has drawn great attention as promising electrocatalyst for carbon dioxide reduction reaction (CO₂RR), but the molecule/substrate interaction is still pending for clarification and optimization to maximize the reaction kinetics. Herein, a CO₂RR catalyst is fabricated by affixing CoPc onto the Mg(OH)₂ substrate primed with conductive carbon, demonstrating an ultra-low overpotential of 0.31 ± 0.03 V at 100 mA cm⁻² and high faradaic efficiency of >95% at a wide current density range for CO production, as well as a heavy-duty operation at 100 mA cm⁻² for more than 50 h in a membrane electrode assembly. Mechanistic investigations employing in situ Raman and attenuated total reflection surface-enhanced infrared absorption spectroscopy unravel that Mg(OH)₂ plays a pivotal role to enhance the CO₂RR kinetics by facilitating the first-step electron transfer to form anionic *CO₂⁻ intermediates. DFT calculations further elucidate that introducing Lewis acid sites help to polarize CO₂ molecules absorbed at the metal centers of CoPc and consequently lower the activation barrier. This work signifies the tailoring of catalyst-support interface at molecular level for enhancing the turnover rate of CO₂RR.     

Photo-electrochemical characterization of porous material Fe-FSM-16. Application for hydrogen production

We describe in the present work the photo-electrochemical characterization of iron/folded-sheets mesoporous materials (Fe-FSM-16, Si/Fe=60) synthesized by microwave-assisted hydrothermal (M-H) method and its application for the hydrogen evolution upon visible light. The mesoporous catalyst consists of small Fe₂O₃ particles (～2 nm) spread on SiO₂ with specific surface area of ～800 m² g^?1. The capacitance measurements reveal an iron deficiency and the oxide exhibit p type conductivity with activation energy of 0.07 eV. The optical gap of the hematite (α-Fe₂O₃) is evaluated at 3.24 eV from the diffuse reflectance spectrum. The flat band potential V_fb (?0.54 V_SCE) and the holes density N_D (9.56×10¹⁴ cm^?3) of the hematite are obtained respectively by extrapolating the linear part to C^?2=0 and the slope of the Mott Schottky plot. At pH=7, the conduction band (?0.47 V_SCE) is suitably positioned with respect to the H₂O/H₂ level (?0.59 V_SCE) leading to a spontaneous water reduction. The oxide is stabilized by hole consumption involving SO₃^2? and S₂O₃^2? species and spectacular improvement of the hydrogen evolution is reported with evolution rates of ～461 and 163 μ mol respectively.     

Boosting Industrial-Level CO2 Electroreduction of N-Doped Carbon Nanofibers with Confined Tin-Nitrogen Active Sites via Accelerating Proton Transport Kinetics

The development of highly efficient robust electrocatalysts with low overpotential and industrial-level current density is of great significance for CO₂ electroreduction (CO₂ER), however the low proton transport rate during the CO₂ER remains a challenge. Herein, a porous N-doped carbon nanofiber confined with tin-nitrogen sites (Sn/NCNFs) catalyst is developed, which is prepared through an integrated electrospinning and pyrolysis strategy. The optimized Sn/NCNFs catalyst exhibits an outstanding CO₂ER activity with the maximum CO FE of 96.5%, low onset potential of −0.3 V, and small Tafel slope of 68.8 mV dec⁻¹. In a flow cell, an industrial-level CO partial current density of 100.6 mA cm⁻² is achieved. In situ spectroscopic analysis unveil the isolated Sn N site acted as active center for accelerating water dissociation and subsequent proton transport process, thus promoting the formation of intermediate *COOH in the rate-determining step for CO₂ER. Theoretical calculations validate pyrrolic N atom adjacent to the Sn N active species assisted reducing the energy barrier for *COOH formation, thus boosting the CO₂ER kinetics. A Zn-CO₂ battery is designed with the cathode of Sn/NCNFs, which delivers a maximum power density of 1.38 mW cm⁻² and long-term stability.     

Thermoelectrics: Impacts on the Environment and Sustainability

Energy saving in power generation, industry, transport, and residential applications by using waste heat with thermoelectrics (TE) may be important for an environmentally sound and sustainable energy system. It is probable that operable TE generators (TEG) will be developed for numerous applications and will save energy and reduce CO₂ emissions from plants. However, the environmental profile of a technology is not sufficiently described by just the energy and CO₂ inputs and outputs of the core process. Necessary preceding and subsequent processes, other environmental impacts, and competing technologies have to be considered as well. Furthermore, sustainability covers aspects beyond environmental soundness. So far, comprehensive studies on TE and the environment/sustainability have not been available. In this paper, the following selected aspects are discussed: resource availability, specific energy consumption of TEG production, specific energy and CO₂ savings in different application fields by TE and competing technologies, and the global potential of TE.     

Band offsets at interfaces of (1 0 0)InxGa1−xAs (0 ⩽ x ⩽ 0.53) with Al2O3 and HfO2

The electron energy band alignment at interfaces of In_xGa_1?xAs (0 ? x ? 0.53) with atomic-layer deposited insulators Al₂O₃ and HfO₂ is characterized using combined measurements of internal photoemission of electrons and photoconductivity. The measured energy of the In_xGa_1?xAs valence band top is found to be only marginally influenced by the semiconductor composition. This result suggests that the observed bandgap narrowing from 1.42 to 0.75 eV when the In content increases from 0 to 0.53 occurs mostly through downshift of the semiconductor conduction band bottom. Electron states originating from the interfacial oxidation of In_xGa_1?xAs lead to reduction of the electron barrier at the semiconductor/oxide interface.     

Hollow NiSe Nanocrystals Heterogenized with Carbon Nanotubes for Efficient Electrocatalytic Methanol Upgrading to Boost Hydrogen Co-Production

Electro-oxidative organic upgrading, as an ideal alternative to sluggish oxygen evolution reaction (OER) performance, can effectively decrease energy consumption to boost hydrogen evolution reaction (HER) performance. However, developing highly active electrocatalysts for long-term durable organic upgrading with high selectivity at large and steady current density remains challenging. Herein, hollow NiSe nanocrystals heterogenized with carbon nanotubes (h-NiSe/CNTs) are fabricated via a facile one-pot approach. The highly dispersed h-NiSe/CNTs 3D network can efficiently facilitate rapid mass/electron diffusion, thus achieving highly active and long-term stable electrocatalysis for catalyzing methanol to value-added formate at high and steady current density (≈345 mA cm⁻²) with high Faradaic efficiency (>95%). This reaction replaces sluggish OER performance to reduce the energy consumption for boosting H₂ generation by six times. The critical active species and methanol activation mechanism are systematically studied using X-ray photoelectron spectroscopy, X-ray absorption fine structure analysis, in situ Raman, and density functional theory calculations, indicating that the non-ignorable SeO_x collaborated with in situ formed Ni OOH species can synergistically modulate the d band center to achieve an optimal adsorption for methanol selective oxidation and suppress the further oxidation to CO₂, thus leading to active and stable electrolysis for producing value-added formate with high selectivity and co-generating H₂ with less energy consumption.     

Additive-Free Self-Presodiation Strategy for High-Performance Na-Ion Batteries

The irreversible consumption of sodium at the anode side during the first cycle prominently reduces the energy density of Na-ion batteries. Different sacrificial cathode additives have been recently reported to address this problem; however, critical issues such as by-products (e.g., CO₂) release during cycling and incompatibility with current battery fabrication procedures potentially deteriorate the full-cell performance and prevent the practical application. Herein, an additive-free self-presodiation strategy is proposed to create lattice-coherent but component-dependent O3-Na_xTMMnO₂ (TM  =  transition metal ion(s)) cathodes by a quenching treatment rather than the general natural cooling. The quenching material preserves higher Mn³⁺ and Na⁺ content, which is able to release Na⁺ via Mn³⁺ oxidation to compensate for sodium consumption during the initial charge while adopting other TM to provide the capacity in the following cycles. Full cells fabricated with hard carbon anode and this material as both cathode and sodium supplement reagent have a nearly 9.4% cathode mass reduction, around 9.9% energy density improvement (from 233 to 256 Wh kg⁻¹), and 8% capacity retention enhancement (from 76% to 84%) after 300 cycles. This study presents the route to rational design cathode materials with sodium reservoir property to simplify the presodiation process as well as improve the full-cell performance.     

A New Strategy for Accelerating Dynamic Proton Transfer of Electrochemical CO2 Reduction at High Current Densities

Developing single-atom electrocatalysts with high activity and superior selectivity at a wide potential window for CO₂ reduction reaction (CO₂RR) still remains a great challenge. Herein, a porous Ni N C catalyst containing atomically dispersed Ni N₄ sites and nanostructured zirconium oxide (ZrO₂@Ni-NC) synthesized via a post-synthetic coordination coupling carbonization strategy is reported. The as-prepared ZrO₂@Ni-NC exhibits an initial potential of −0.3 V, maximum CO Faradaic efficiency (F.E.) of 98.6% ± 1.3, and a low Tafel slope of 71.7 mV dec⁻¹ in electrochemical CO₂RR. In particular, a wide potential window from −0.7 to −1.4 V with CO F.E. of above 90% on ZrO₂@Ni-NC far exceeds those of recently developed state-of-the-art CO₂RR electrocatalysts based on Ni N moieties anchored carbon. In a flow cell, ZrO₂@Ni-NC delivers a current density of 200 mA cm⁻² with a superior CO selectivity of 96.8% at −1.58 V in a practical scale. A series of designed experiments and structural analyses identify that the isolated Ni N₄ species act as real active sites to drive the CO₂RR reaction and that the nanostructured ZrO₂ largely accelerates the protonation process of *CO₂⁻ to *COOH intermediate, thus significantly reducing the energy barrier of this rate-determining step and boosting whole catalytic performance.     

Investigation of deep level defects in copper irradiated bipolar junction transistor

Commercial bipolar junction transistor (2N 2219A, npn) irradiated with 150 MeV Cu¹¹⁺-ions with fluence of the order 10¹² ions cm^?2, is studied for radiation induced gain degradation and deep level defects. I–V measurements are made to study the gain degradation as a function of ion fluence. The properties such as activation energy, trap concentration and capture cross-section of deep levels are studied by deep level transient spectroscopy (DLTS). Minority carrier trap levels with energies ranging from E_C ? 0.164 eV to E_C ? 0.695 eV are observed in the base–collector junction of the transistor. Majority carrier trap levels are also observed with energies ranging from E_V + 0.203 eV to E_V + 0.526 eV. The irradiated transistor is subjected to isothermal and isochronal annealing. The defects are seen to anneal above 350 °C. The defects generated in the base region of the transistor by displacement damage appear to be responsible for transistor gain degradation.     

Fabrication of single crystal field-effect transistors with phenacene-type molecules and their excellent transistor characteristics

Single crystal field-effect transistors (FETs) using [6]phenacene and [7]phenacene show p-channel FET characteristics. Field-effect mobilities, μs, as high as 5.6 × 10^?1 cm² V^?1 s^?1 in a [6]phenacene single crystal FET with an SiO₂ gate dielectric and 2.3 cm² V^?1 s^?1 in a [7]phenacene single crystal FET were recorded. In these FETs, 7,7,8,8-tetracyanoquinodimethane (TCNQ) was inserted between the Au source/drain electrodes and the single crystal to reduce hole-injection barrier heights. The μ reached 3.2 cm² V^?1 s^?1 in the [7]phenacene single crystal FET with a Ta₂O₅ gate dielectric, and a low absolute threshold voltage |V_TH| (6.3 V) was observed. Insertion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F₄TCNQ) in the interface produced very a high μ value (4.7–6.7 cm² V^?1 s^?1) in the [7]phenacene single crystal FET, indicating that F₄TCNQ was better for interface modification than TCNQ. A single crystal electric double-layer FET provided μ as high as 3.8 × 10^?1 cm² V^?1 s^?1 and |V_TH| as low as 2.3 V. These results indicate that [6]phenacene and [7]phenacene are promising materials for future practical FET devices, and in addition we suggest that such devices might also provide a research tool to investigate a material’s potential as a superconductor and a possible new way to produce the superconducting state.     

Effect of doping of cesium carbonate on electron transport in Tris(8-hydroxyquinolinato) aluminum

Electron transport studies in Tris(8-hydroxyquinolinato) aluminum (Alq₃) is hindered due to lack of efficient electron injecting electrode. We demonstrate that an electron injection layer of Cs₂CO₃ forms ohmic contact with Alq₃, which enables the observation of SCLC. This allows us to directly determine the electron mobility in Alq₃, which was found to be 1 × 10^?9 m²/V s at room temperature. Doping of Cs₂CO₃ leads to increase in conductivity as well as mobility. Mobility has increased to 1 × 10^?7 m²/V s for 33% doping of Cs₂CO₃.     

Efficient Electrocatalytic Reduction of CO2 to Ethanol Enhanced by Spacing Effect of Cu?Cu in Cu2-xSe Nanosheets

It is highly desired yet challenging to strategically steer carbon dioxide (CO₂) electroreduction reaction (CO₂ER) toward ethanol (EtOH) with high activity, which provides a promising way for intermittent renewable energy reservation. Controlling spatial distance between the adjoining active centers and promoting the C C coupling progress are crucial to realize this purpose. Herein, ultrathin 2D Cu_2-xSe is prepared with abundant Se vacancies, where the spatial distance between the Cu Cu around the Se vacancies is effectively shortened because of the lattice stress. Besides, the moderate spatial distance induced by Se vacancies can significantly decrease the Gibbs free energy of asymmetric *CO *CHO coupling progress, effectively change the local charge distribution, decrease the valence state of Cu atoms and increase the electron-donating capacity of the dual active sites. Combining experimental observations and density functional theory   simulations, the Cu Cu dual sites with spatial distance of 2.51 Å in V_Se-Cu_2-xSe sample can catalyze CO₂ER to EtOH with high selectivity in a potential range from −0.4 to −1.6 V, and reach the highest faradaic efficiency of 68.1% at −0.8 V. This work reveals the influence of spacing effect on ethanol selectivity, and provides a new idea for future design of catalysts with chain elongation reaction, which can bring extensive attention.     

Assignment of laser lines in an optically pumped submillimeter and near millimeter laser: (H2CO)3

A large number of emissions is obtained in the submillimeter and near millimeter range with the (H₂CO)₃ laser optically pumped by a CO₂ laser. A study of the microwave absorption spectrum of the molecule carried out simultaneously with the submm analysis allows us to assign six of the laser lines in thev ₅ excited state of the molecule and to determine the rotational constants and vibrational energy ofv ₅.