Ultrasensitive, visible tunable diode laser detection of NO(2)

Recent advances in room-temperature visible diode lasers and ultrasensitive detection techniques have been exploited to create a highly sensitive tunable diode laser absorption technique for in situ monitoring of NO(2) in the lower troposphere. High sensitivity to NO(2) is achieved by probing the visible absorption band of NO(2) with an AlGalnP diode laser at 640 or 670 nm combined with a balanced ratiometric electronic detection technique. We have demonstrated a sensitivity of 3.5 × 10(10) cm(-3) for neat NO(2) in a 1-m path at 640 nm and have estimated a sensitivity for ambient operation of 5 ppbv m (l0 ppbv m at 670 nm), where ppbvm is parts in 10(9) by volume per meter of absorption path length, from measured pressure-broadening coefficients.     

Reflective attenuator for high-energy laser measurements

A high-energy laser attenuator in the range of 250 mJ (20 ns pulse width, 10 Hz repetition rate, 1064 nm wavelength) is described. The optical elements that constitute the attenuator are mirrors with relatively low reflectance, oriented at a 45 degrees angle of incidence. By combining three pairs of mirrors, the incoming radiation is collinear and has the same polarization orientation as the exit. We present damage testing and polarization-dependent reflectance measurements for 1064 nm laser light at 45 degrees angle of incidence for molybdenum, silicon carbide, and copper mirrors. A six element, 74 times (18 dB) attenuator is presented as an example.     

Correlation measurements using clipped laser speckle

Clipped laser speckle is used to measure the correlation of time-varying laser speckle. As with standard intensity correlation, clipped speckle is correlated to determine the magnitude of the correlation coefficient. The simple nature of clipped speckle permits high-speed measurements of correlation and velocity. A closed form approximation to the clipped correlation function valid for arbitrary clipping thresholds is presented. The approximation is used to make correlation measurements on speckle from a rotating diffuser using a 2-D random access detector array.     

Ultrasensitive nonlinear measurements of femtosecond pulses in the telecommunications band by aperiodically poled LiNbO3 waveguides

We have used aperiodically poled lithium niobate waveguides to perform intensity autocorrelation and frequency-resolved optical gating (FROG) measurements for ultraweak femtosecond pulses at 1.5 microm wavelength. The required pulse energies for intensity autocorrelation and FROG are as low as 52 aJ and 124 aJ, respectively. The corresponding sensitivities are 3.2 x 10(-7) mW(2) and 2.7 x 10(-6) mW(2), about 3-5 orders of magnitude better than the previous records. The high nonlinear conversion efficiency is attributed to the long waveguide structure, and the needed broad phase-matching bandwidth is realized by chirping the poling period. We discuss the theory of intensity autocorrelation and FROG measurements in the presence of different phase-matching bandwidths, and we show, for the first time to our knowledge, that the distorted intensity autocorrelation trace due to a delta-like phase-matching spectrum is described by a modified field autocorrelation function. We also report new experimental results comparing autocorrelation traces measured with chirped and unchirped waveguide samples and demonstrating high-quality FROG measurements for cubic phase waveforms generated in a programmable pulse shaper.     

Ultrasensitive leak detection

The objective of this investigation was to develop a method of detecting leaks to a sensitivity of 1.0 × 10^?13 std cm0^?3 s^?1 in vacuum devices and to develop a qualifiable standard leak to provide system calibration at this leak rate. The development work demonstrated that minimum detectable leak rates of 6.5 × 10^?14 and 5.5 × 10^?15 std cm^?3 s^?1 are possible for respective analog and digital measurement modes.     

Flow-velocity measurements with a laser diode array

To measure flow velocity, a new technique, laser diode array velocimetry, generates multiple laser spots (four or more) separated by short distances (20-100 mum) at the probe volume. Particles that pass through the probe volume generate a signal that is analyzed by a digital signal processor for frequency content. The product of frequency and laser-to-laser spot separation determines the velocity. Rotating wire and wind-tunnel experiments confirm the performance of the new technique. An error analysis showed that the uncertainties in the processed diode array velocimetry signal frequency were less than 0.3%, and uncertainties in the beam-to-beam separation were less than +/-0.05%.     

Real-time diode laser measurements of vapor-phase benzene

An absorption spectrometer equipped with a IV-VI semiconductor tunable mid-IR diode laser was used to make sensitive measurements of benzene (C(6)H(6)) gas in the 5.1-microm spectral range. Wavelength modulation coupled with second-harmonic detection achieved accurate real-time quantification of benzene concentrations down to a minimum detection limit of 1 ppmv with an integration time of 4 s. A variety of calibrated benzene-sensing measurements were made, including the determination of the benzene concentrations in vehicle exhaust and headspace vapors from unleaded gasoline and other liquids. Kinetic phenomena, including the monitoring of benzene evaporation and absorption/desorption by granulated activated carbon were observed with the instrument. Measurements were performed that allowed experimental determination of the activation energy for desorption of benzene from activated carbon, which was found to be 198 meV/molecule (19.0 kJ/mol).     

Metrologic foundations of laser satellite range measurements

Translated from Izmeritel'naya Tekhnika, No. 6, pp. 27–29, June, 1991.     

Gain measurements in the KrCl excimer laser

The single-pass/double-pass amplified spontaneous emission technique has been used to measure the net gain at 222.4 nm in a discharge-pumped UV-preionized KrCl laser. The net gain has been measured as a function of pump rate and total pressure in He- and Ne-based gas mixtures. A maximum net gain of 0.15 cm(-1) has been obtained in a 0.09% HC1/10.1% Kr/1.5% He/88.3% Ne mixture at a total pressure of 355 kPa and at a specific power loading of approximately 21 MW/cc. The data presented are compared with previous net gain measurements performed using the passive absorption cell method.     

A heterodyne laser interferometer for dilatometer measurements

A dilatometer measuring system based on heterodyne laser interferometry is described. An electrooptical light modulator based on the double transverse Pockels electrooptical effect in a crystal of lithium niobate and operating in the quarter-wave mode is used as the optical heterodyne. The electronic measuring system uses modern microelectronic components with a high degree of integration.     

Ultrasensitive dual-beam absorption and gain spectroscopy: applications for near-infrared and visible diode laser sensors

A dual-beam detection strategy with automatic balancing is described for ultrasensitive spectroscopy. Absorbances of 2 × 10(-7) Hz(-?) in free-space configurations and 5 × 10(-6) Hz(-?) in fiber-coupled configurations are demonstrated. With the dual-beam technique, atmospherically broadened absorption transitions may be resolved with InGaAsP, AlGaAs, and AlGaInP single-longitudinal-mode diode lasers. Applications to trace measurements of NO(2), O(2), and H(2)O are described by the use of simple, inexpensive laser and detector systems. Small signal gain measurements on optically pumped I(2) with a sensitivity of 10(-5) are also reported.     

Traceable laser power measurements of diode laser radiation in the near infrared

We report a new calibration setup for laser radiometry at the Physikalisch-Technische Bundesanstalt, the German National Metrology Institute. Measurements of laser diode power of free beam diode lasers in the near infrared spectral range at a wavelength of 808 nm for powers up to 250 W and at wavelengths of 915 nm, 940 nm, and 980 nm for laser powers up to 25 W have been established. The calibration setup, the standard detector, the uncertainty budget and first calibration results will be presented and discussed. The standard uncertainty of the HLR302 standard detector is 0.2%. This uncertainty might be the main contribution to the overall uncertainty in customer calibrations, depending on the quality of the transfer detectors.     

Ultrasensitive microarray detection of short RNA sequences with enzymatically modified nanoparticles and surface plasmon resonance imaging measurements

A novel multiplexed method for short RNA detection that employs an enzymatic capture reaction onto DNA-modified silica nanoparticles (SiNPs) followed by nanoparticle-enhanced surface plasmon resonance imaging (SPRI) is demonstrated. SiNPs functionalized with 5'-phosphorylated single stranded DNA (ssDNA) are used with T4 RNA ligase to capture various short 20-24 base single-stranded RNA (ssRNA) oligonucleotides from a target solution. The ssRNA-modified SiNPs are collected from the target solution, specifically adsorbed onto a cDNA microarray and then detected with SPRI. The use of DNA-modified SiNPs to capture ssRNA for profiling has several advantages as compared to a planar SPRI surface bioaffinity adsorption format: (i) the target solution is exposed to a larger total surface area for the RNA ligation reaction; (ii) the SiNPs enhance the diffusion rate of the ssRNA to the surface; (iii) the SiNPs can be collected, washed, and preconcentrated prior to detection; and (iv) the ssRNA-modified SiNPs give an enhanced SPRI signal upon hybridization adsorption to the microarray. Our initial measurements demonstrate that this detection method can be used to detect multiple ssRNA sequences at concentrations as low as 100 fM in 500 μL.     

Use of a ring laser for angle measurements

Measurement Techniques -     

Intracavity laser absorption measurements at ultrahigh spectral resolution

Intracavity laser absorption spectroscopy with ultrahigh sensitivity and enhanced spectral resolution is demonstrated. It entails use of an intracavity étalon that selects equally spaced modes of the cavity. These modes are reduced in intensity when they occur at spectral locations where absorption that is due to intracavity species also occurs. We obtained absorption spectra by tuning the étalon in small steps across its free spectral range, recording intracavity spectra at each step, and summing the result. The maximum resolution is determined by the width of the étalon peaks, which was ~0.01 cm(-1). When the finesse of the étalon is increased, the resolution equal to the width of a single laser mode can be achieved. With this technique, spectra at Doppler-free resolution such as that required for studies of high vibrational-overtone transitions of molecules in supersonic jets are possible.     

双激光二极管速度传感器设计

本文验证了基于自混合效应的速度传感器的可行性,并设计了单激光二极管速度传感器,其标准偏差为0.22%。为了提高其精度,消除入射角的非控制变化和速度垂直分量的影响,我们设计了双激光二极管速度传感器,其标准偏差为0.03%。