电感耦合等离子体原子发射光谱法测定高碳除尘灰中11种元素

实验重点探讨了高含量碳对除尘灰样品中镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌等元素测定的影响,并解决了除碳的问题。样品使用马弗炉高温除碳,采用盐酸-硝酸-氢氟酸-高氯酸消解样品灰分,选择了镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌等元素的分析谱线和扣背景模式,建立了使用电感耦合等离子体原子发射光谱法(ICP-AES)测定高碳除尘灰中镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌等元素的方法。在仪器最佳工作条件下,各元素校准曲线线性相关系数r均大于0.999 5,方法检出限在1.08～26.01 mg/kg之间。方法应用于除尘灰实际样品中镁、铝、钾、钙、铬、锰、铜、钡、铅、镉、锌的测定,结果的相对标准偏差(RSD,n=11)为0.90%～7.1%,目标元素的加标回收率为90%～117%;按照实验方法测定除尘灰中镁、铝、钾、钙、锌,结果与火焰原子吸收光谱法(FAAS)的测定结果相吻合。     

熔炼次数对M17返回料合金成分、组织和性能的影响

实验结果表明,M17铸造高温合金(%:0.16C、8.79Cr、5.79A1、4.93Ti、3.29Mo、15.20Co、0.78V、0.015B、0.073Zr、0.002S、0.001P、0.001 1O、0.001 0N)经25 kg真空感应炉返回重熔后,Si含量随重熔次数的增加而略有增加,合金中主要元素和其它杂质元素S、P、H的含量变化不大,而氧、氮略有增加;合金中初生碳化物由新合金中的草书体逐渐向返回合金块状转变,初生碳化物的遗传性堵塞合金凝固时的补缩通道,使返回料合金的疏松倾向增大,高温塑性下降较大。     

Review of Alcoholism: A bio-psycho-social approach.

Reviews the book, Alcoholism: A bio-psycho-social approach by Jerome David Levin (1990). This small volume sets its task as providing counseling students with a comprehensive knowledge base "summarizing biochemical, pharmacological, physiological, anthropological, sociological, epidemiological, historical, and psychological findings on alcohol and its use and abuse" (Preface, p. xi). It treats each of these, in varying degrees of depth, in seven chapters. Perhaps the greatest strength of the book is its thorough presentation of the medical consequences of alcoholism, the mechanisms involved, and the interplay between biological and psychological factors. Unfortunately, this volume does not provide sufficient coverage of treatment-related issues. It may serve as an introductory overview of the alcoholism field for undergraduate or graduate students, or professionals from other fields. It is too advanced, however, in its use of concepts and language, for paraprofessional students. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Recent books.

Reviews the books The art of being, by Erich Fromm (1992); Basic writings, by Martin Heidegger (1993); History of the concept of time: Prolegomena, by Martin Heidegger (1992); Complexity: Life at the edge of chaos, by Roger Lewin (1992); The future of an illusion: Film, feminism, and psychoanalysis, by Constance Penley (1989); Human inquiry: A sourcebook of new paradigm research, by Peter Reason and John Rowan (1990); Reading Heidegger: Commemorations, edited by John Sallis (1993); and Truth and existence, by Jean-Paul Sartre (1992). Brief synopses of each book are presented, rather than full reviews. In The art of being, Fromm presents his synthesis of spiritual teachings from Zen to existentialism, as well as a synopsis of his earlier critiques of consumer capitalism. Basic writings is a collection of essays, lectures, and sections from Heidegger's major works. Of special interest to psychologists interested in Heidegger's methodology is the re-translation of the introduction to Being and Time. In History of the concept of time: Prolegomena, Heidegger elaborates the methodological and foundational connection of his work to Brentano, Dilthey, and Husserl, thus providing for the first time an authoritative understanding of the relationship of his uniquely hermeneutic phenomenology to the ideas of his predecessors. In Complexity: Life a the edge of chaos, Roger Lewin discusses the search for the set of rules that underly complexity theory and the "grand unification" of the life sciences. The future of an illusion: Film, feminism, and psychoanalysis, by Constance Penley, is a collection of essays on the sexual politics of representation. In Human inquiry: A sourcebook of new paradigm research, Reason and Rowan cover the philosophy, methodology, practice, and prospects of what the editors call "new paradigm research": alternative approaches to human science research that are both collaborative and experiential. Reading Heidegger: Commemorations is a richly provocative book of essays by an impressive list of 23 Heidegger scholars around the world. This text celebrates, reconsiders, and sometimes pokes fun at one of the most controversial and most important thinkers of our century. Finally, written in response to Heidegger's The essence of truth, Jean-Paul Sartre's Truth and existence provides a bridge between Sartre's Being and nothingness and his Critique of dialectical reason. It is a philosophical as well as psychological study of epistemology, based on his phenomenological ontology, that becomes a work on morality. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Measuring students' connectedness to school, teachers, and family: Validation of three scales.

Connectedness to school, teachers, and family are all significant protective factors in adolescents' lives, yet the measurement of each varies considerably. This article describes the measurement properties of three composite scales of adolescent connectedness, adapted from the Add Health study and the California Healthy Kids Survey. These composite scales are created by either summing or taking the mean of all individual items, measured on an ordinal scale. This approach fails to account for the ordinal, non-normal nature of the data. Using a covariance approach, this article describes the measurement properties of the latent constructs of connectedness to school, teachers, and family and the contribution of each of the items used to compile the relevant composite score. The outcomes of this study will provide researchers and practitioners with information about the validity, reliability, and overall usefulness of each of the measures of adolescents' perception of their connectedness to school, teachers, and family. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

分光光度-遗传算法同时测定锌、镉、钴、镍、锰

在pH9.3,乳化剂OP存在下,Zn2+,Cd2+,Co2+,Ni2+,Mn2+与5-Br-PADAP发生灵敏的显色反应,所形成的三元胶束络合物的吸收光谱严重重叠,单独测定相互干扰严重。本文将分光光度法与遗传算法相结合,对同一混合体系的总吸光度值进行解析,实现了5种组分的同时测定。模拟样品测定的相对误差一般小于±10%。     

应用于碱性土壤上重金属污染的超积累植物种植研究

以调查区的严格管控区土壤为研究对象,挑选了酸模、龙葵、月季、金盏菊、万寿菊、油牡丹、凤仙花7种植物进行了大田试验,考察超积累植物对土壤中Cd、Pb富集的影响。结果表明,不同植物体内或同种植物体内各部位重金属的含量存在较大差异;酸模、金盏菊、龙葵、月季地上部分重金属含量明显高于地下部分,说明重金属在这几种植物的茎叶里积累较多。金盏菊、凤仙花、万寿菊、龙葵对Cd的富集较强,有利于修复Cd污染的土壤。除凤仙花外,其他6种植物对Cd的转运系数均大于1,对Cd的转移能力由强到弱的顺序依次为酸模、金盏菊,龙葵、油牡丹、月季、万寿菊。就单株而言,积累生物量从大到小依次是酸模、金盏菊、万寿菊、月季;就每亩而言,积累生物量从大到小依次是金盏菊、酸模、月季、万寿菊。综合植物对重金属的富集系数、植物自身的转运系数、整株生物量以及植物的经济价值等考量,万寿菊、金盏菊、月季在修复土壤重金属污染的同时还可兼顾提升经济效益,酸模作为有效降低Cd、Pb含量的重金属修复植物,可推广应用于碱性耕地的重金属污染修复。综上所述,从植物对重金属的富集系数、植物自身的转运系数、整株生物量以及植物的经济价值等综合考量,万寿菊、金盏菊、月季作为修复土壤重金属污染的同时兼顾提升经济,酸模作为有效降低Cd、Pb含量的重金属修复植物,可推广应用于碱性耕地的重金属污染修复。     

火焰原子吸收光谱法测定合金结构钢中铬、锰

利用火焰原子吸收光谱法测定合金结构钢中铬、锰,此方法快速、准确、灵敏度高、精密性好,方法简便,并充分反应了现代仪器的高科技分析手段。合金结构钢使用较为广泛,因此利用原于吸收光谱法测定铬、锰,能迅速有效的达到检测目地的需要。本方法改变了以往化学法操作时间长、步骤多、消耗试剂多的弊病,解决了高氯酸氧化铬对人体的危害及对环境的严重污染。通过对各项做条件试验,优选了最佳仪器测试条件。对干扰元素铁、镍抑制铬的吸收,采用硫酸钠做干扰消除剂,彻底消除了干扰,测定数据稳定可靠。经过对标准样品的测定,重复性好,误差小,回收率达到99～102%,效果令人满意。     

电感耦合等离子体原子发射光谱法测定铍中11种杂质元素

铍中铝、钴、铬、铜、铁、镁、锰、镍、铅、硅和锌等11种杂质元素含量的准确测定,是判定铍材是否合格的重要指标。目前,上述杂质元素的测定标准为GJB 2513A—2008《铍化学分析方法》,方法分别采用光度法和原子吸收光谱法对各元素逐一测定,测定周期很长。试验采用盐酸-硝酸溶解样品,选择Al 308.215nm、Co 230.786nm、Cr 284.325nm、Cu 324.754nm、Fe 261.187nm、Mg 285.213nm、Mn 260.569nm、Ni 221.647nm、Pb 182.205nm、Si 250.690nm、Zn 213.856nm为分析谱线,采用标准加入法(MSA)配制标准溶液系列消除基体效应的影响,使用电感耦合等离子体原子发射光谱法(ICP-AES)测定铝、钴、铬、铜、铁、镁、锰、镍、铅、硅和锌,从而建立了铍中11种元素的测定方法。各待测元素校准曲线的线性相关系数均大于0.9995;各元素的定量限为0.001%~0.002%。实验方法用于测定铍样中铝、钴、铬、铜、铁、镁、锰、镍、铅、硅和锌,结果的相对标准偏差(RSD,n=10)为0.63%~8.6%,回收率为90%~110%。按照实验方法测定铍样中上述11种元素,测定结果与采用GJB 2513A—2008测定的结果吻合。     

银含量对方铅矿浮选的影响及其机理研究进展

为了阐明银含量对方铅矿浮选的影响,提高含银方铅矿中伴生银的综合回收效率,通过全面梳理前人研究成果,对含银方铅矿的资源状况、工艺流程和药剂制度进行了总结。首先,从不同维度和层面（从试验到模拟、从宏观到微观）综述了银含量对方铅矿的影响,其中包括银含量对方铅矿浮选行为及表面接触角的影响。然后,评述了前人利用红外光谱、微热动力学、电化学和量子化学等分析方法开展的有关银含量对方铅矿浮选行为影响机理的研究进展,上述分析方法相互验证,均证实银矿物对方铅矿的浮选有促进作用,且银含量与促进程度呈正相关。最后,针对含银方铅矿今后研究方向和银铅锌矿资源开发,提出科学、合理的建议,如：在现场生产中应尽量避免使用石灰调浆,如必须使用时,应控制好石灰用量,从而减少伴生银的损失。