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纪逸之 《化学工业与工程技术》2011,32(1):53-55
介绍了厌氧预处理+初沉+好氧组合工艺在处理可发性聚苯乙烯(EPS)及PET化纤生产废水上的应用,设计处理规模2 000 m~3/d。通过该工艺处理后,出水水质符合国家相关标准规定的三级要求。 相似文献
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采用气浮预处理-厌氧-好氧系统处理某化纤废水,介绍了各处理构筑物、运行参数及经济技术指标。实际运行结果表明,用该工艺处理化纤废水,其出水水质可达到GB 8978-1996中的二级排放要求。 相似文献
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采用物化+生化组合工艺处理旧汽车发电机、起动机翻新废水,经工程竣工验收监测结果表明:各项污染物指标达到GB 8978—1996(污水综合排放标准》中一级排放标准;采用该工艺可实现良好的表面活性剂去除效果。 相似文献
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某工业区污水处理厂采用A+A^2/O工艺,对其工艺流程,设计参数和设计特点作了介绍。并对该工艺的优点和注意事项等进行了总结。 相似文献
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采用微波辐射法制备了La^3+/Y、Co^2+/Y、Cu^2+/Y和Zn^2+/Y离子交换型沸石催化剂。通过考察交换原液浓度、加热时间、微波功率等因素对交换度的影响,得出交换反应的适宜工艺条件为:交换原液浓度0.12 mol·L^-1(La^3+)、0.06 mol·L^-1(Co^2+)、0.08 mol·L^-1(Cu^2+)和0.10 mol·L^-1(Zn^2+),加热时间6 min(Co^2+和Zn^2+)、12 min(La^3+和Cu^2+),微波辐射功率520 W(La^3+,Co^2+,Cu^2+和Zn^2+)。La^3+,Co^2+,Cu^2+和Zn^2+与Y沸石的一次交换度分别为80.8%(La^3+)、69.6%(Zn^2+)、67.5%(Cu^2+)和63.8%(Co^2+)。对比实验结果表明,在相同工艺条件下,微波辐射加热法所需时间仅为传统加热法的1/40~1/80。XRD结果表明,微波辐射对沸石晶体结构无破坏作用。采用“二交二焙”法可使La^3+与Y沸石的交换度由80.8%提高到91.6%。 相似文献
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卤代硅烷的相平衡数据为硅烷生产所需,而这方面的研究又较缺乏,尤其是甲基乙烯基二氯硅烷生产中所需的汽液相平衡数据尚未见报道.今用新型泵式沸点仪测定了常压(101.325 kPa)下甲基二氯硅烷 甲基三氯硅烷 二甲基二氯硅烷 苯四元系及其四个三元体系和六个二元体系在不同液相组成时的泡点.由所测的二元系数据,用过量自由焓Q函数间接法推算了与之平衡的汽相组成.再用最小二乘法求出二元体系的最佳配偶液相活度系数模型参数.所得的六组最佳二元系Wilson模型参数符合热力学一致性,并用于该体系三元和四元系汽液相平衡数据的预测,将计算的泡点与实验测得的泡点作了比较,其拟合精度良好,关联结果令人满意,硅烷二元系、多元系的热力学模型及VLE数据可为该体系的分离设计提供必要的理论依据. 相似文献
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应用水热技术制备了二元Ni2+-Fe3+-CO23- LDHs和三元Co2+-Ni2+-Fe3+-CO32- LDHs,以十二烷基磺酸根离子作为插层客体,通过离子交换反应在酸性溶液中实现了十二烷基磺酸根插层Ni2+-Fe3+ LDHs和Co2+-Ni2+-Fe3+-LDHs。十二烷基磺酸根在Ni2+-Fe3+LDHs层间出现了2种空间导向和排列:即十二烷基磺酸根以单层垂直方向排布和以双层垂直方向排布在层间;十二烷基磺酸根在三元组分Co2+-Ni2+-Fe3+-LDHs层间只有一种空间排列方式,即十二烷基磺酸根以单层垂直方向排布于Co2+-Ni2+-Fe3+-LDHs层间。 相似文献
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Erevan. Translated from Fizika Goreniya i Vzryva, Vol. 26, No. 5, pp. 33–36, September–October, 1990. 相似文献
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The partition coefficients of ethylene between hydrate and vapor for methane + ethylene + water and methane + ethylene + SDS + water systems 总被引:1,自引:0,他引:1
The hydrate formation of CH4+C2H4 mixture was studied experimentally in two different cases, with and without the presence of sodium dodecyl sulfate (SDS) in water. The results manifested that the presence of SDS could not only accelerate the hydrate formation process, but also increase the partition coefficient of ethylene between hydrate and vapor drastically. The partition coefficients of ethylene between hydrate and vapor for methane + ethylene + water with the presence of 500 ppm SDS in water were then systematically measured. The experimental temperature ranged from 273.15 to 278.15 K, the pressure ranged from 2.5 to 5.5 MPa, the initial gas-liquid volume ratio ranged from 95 to 240 standard volumes of gas per volume of liquid, and the mole percentage of ethylene in feed gas mixture ranged from 5.28% to 79.36%. The results demonstrated that ethylene could be enriched in hydrate phase and partition coefficients were increased with the presence of SDS in water. This conclusion is of industrial significance; it implies that it is feasible to recover ethylene from gas mixture, e.g., various kinds of refinery gases or cracking gases in ethylene plant, by forming hydrate. 相似文献
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研究了Na+-Ca2+-Mg2+与钠型斜发沸石和NH4+-Ca2+-Mg2+与铵型斜发沸石的离子交换平衡,分别测定出2个体系的离子交换平衡数据,并利用三维坐标绘制出三元离子交换平衡等温面,计算出改型沸石对体系中离子的分离因数. 结果表明,在Na+-Ca2+-Mg2+溶液体系中,Na+的分离因数>10,Ca2+的在0.4~10之间,Mg2+的小于0.4,斜发沸石离子交换顺序为Na+>Ca2+>Mg2+,且温度升高Ca2+和Mg2+的交换能力增强,而低温则有利于沸石对Na+的选择;在NH4+-Ca2+-Mg2+溶液体系中,NH4+的分离因数>15,Ca2+的在0.2~1.5之间,Mg2+的小于0.2,斜发沸石离子交换顺序为NH4+>Ca2+>Mg2+,且温度升高Ca2+和Mg2+的交换能力增强,NH4+的选择性降低. 相似文献
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W. E. Blake J. Randle 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1967,17(12):358-360
Very dilute solutions containing zinc sulphate, sodium and sulphuric acid were passed down a column of Zeo-Karb 225 cation-exchange resin, and the volume at which zinc first appeared in the effluent (breakthrough volume), together with the volume at which the concentration of zinc in the effluent became equal to its concentration in the influent (equivalent volume), were determined. 相似文献
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Erevan. Translated from Fizika Goreniya i Vzryva, Vol. 26, No. 6, pp. 120–124, November–December, 1990. 相似文献
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A chemical model,based on Pitzer activity coefficient model,is developed with a speciation approach to describe the solubility and chemistry of nesquehonite in concentrated chloride solutions.The chemical equilibrium constants for nesquehonite and aqueous species,i.e.0 3 MgCO,3 MgHCO,and MgOH +,are precisely calculated as a function of temperature according to the Van’t Hoff equation by use of standard Gibbs free energy,standard formation enthalpy and heat capacity.The most recent solubility data are regressed to obtain new Pitzer parameters with good agreement.The predictive ability of the new model is improved significantly in comparison with previous models.The behavior of speciation chemistry for nesquehonite in various chloride media is explained through this modeling work on the basis of the 2 3 Mg /CO bearing species distribution,activity coefficient and pH changes. 相似文献
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高聚物萃取分离光度法测定Pb2+ 总被引:5,自引:0,他引:5
《化学世界》2003,44(4):185-187
利用非挥发性水溶性高聚物的水溶液在无机盐存在下可分成两相的特点,讨论了Pb2+、Cd2+、Co2+、Cu2+、Fe3+、Ni2+、Zn2+混合液中Pb2+的分离和测定条件,实现了Cd2+、Co2+、Cu2+、Fe3+、Ni2+、Zn2+与Pb2+的定量分离和测定,结果表明方法简便、可靠、快速,在Pb2+含量0~4.0μg/mL范围内有良好的线性关系.回收率在95%~105%. 相似文献