Printable phosphorescent organic light‐emitting devices

Abstract— A new approach to full‐color printable phosphorescent organic light‐emitting devices (P²OLEDs) is reported. Unlike conventional solution‐processed OLEDs that contain conjugated polymers in the emissive layer, the P²OLED's emissive layer consists of small‐molecule materials. A red P²OLED that exhibits a luminous efficiency of 11.6 cd/A and a projected lifetime of 100,000 hours from an initial luminance of 500 cd/m², a green P²OLED with a luminous efficiency of 34 cd/A and a projected lifetime of 63,000 hours from an initial luminance of 1000 cd/m², a light‐blue P²OLED with a luminous efficiency of 19 cd/A and a projected lifetime 6000 hours from an initial luminance of 500 cd/m², and a blue P²OLED with a luminous efficiency of 6.2 cd/A and a projected lifetime of 1000 hours from an initial luminance of 500 cd/m² is presented.     

Flexible high‐resolution full‐color top‐emitting active‐matrix organic light‐emitting diode display

We developed a high‐performance 3.4‐in. flexible active‐matrix organic light‐emitting diode (AMOLED) display with remarkably high resolution using an oxide semiconductor in a backplane, by applying our transfer technology that utilizes metal separation layers. Using this panel, we also fabricated a prototype of a side‐roll display for mobile uses. In these AMOLED displays, a white OLED combined with a color filter was used in order to achieve remarkably high resolution. For the white OLED, a tandem structure in which a phosphorescent emission unit and a fluorescent emission unit are serially connected with an intermediate layer sandwiched between the emission units was employed. Furthermore, revolutionary technologies that enable a reduction in power consumption in both the phosphorescent and fluorescent emission units were introduced to the white tandem OLED.     

Transflective device with a transparent organic light‐emitting diode and a reflective liquid‐crystal device

Abstract— A high‐transmittance transflective device based on a hybrid structure consisting of a transparent organic light‐emitting diode (OLED) stacked on top of a reflective liquid‐crystal device (RLCD) was conceptually demonstrated. By placing the transparent OLED on top of a vertically aligned LCD operated under normally black mode, a transmittance as high as 75.7% was obtained due to the asymmetric emission characteristics of a transparent OLED. To further improve the performance in the transmissive mode, a polarizer‐free LCD was used, which yielded an ultra‐high transmittance (82.2% overall).     

Highly efficient deep‐blue organic light‐emitting devices

Abstract— A highly efficient deep‐blue organic light‐emitting device (OLED) incorporating a novel composite hole‐transport layer (c‐HTL) and an emitter based on the new non‐symmetrical mono(styryl)amine fluorescent dopant in the stable host MADN, which achieved a luminance efficiency of 5.4 cd/A with a Commission Internationale d'Eclairage (CIEx,y) of (0.14, 0.13) and an external quantum efficiency of 5.1% at 20 mA/cm² and 6.8 V, is reported. The increased device efficiency is attributed to an improved balance between hole and electron currents in the recombination zone.     

Detailed analysis of exciton decay time change in organic light‐emitting devices caused by optical effects

Abstract— The exciton decay time in organic light‐emitting devices (OLEDs) depends on the optical environment, i.e., the thicknesses and refractive indices of all layers in a device. The decay of an exciton can occur through a radiative or a non‐radiative channel. Each of these channels has a probability, which is expressed by, respectively, the radiative and the non‐radiative decay rate. The radiative decay rate is influenced by the optical environment, i.e., the OLED's thin‐film layer structure. In this paper, a model for estimating the change of the exciton decay time (inverse of the decay rate) is presented. In addition, the decay time change in both top‐ and bottom‐emitting OLEDs as a function of the charge‐transport layer thicknesses has been investigated. Furthermore, the most important mechanism responsible for the exciton decay time change is outlined.     

Development of a liquid crystal with fine‐pitch light‐source display (LFD) using an organic light‐emitting diode (OLED)

Abstract— A novel display system, refered to as an LFD (liquid crystal with fine‐pitch light‐source display) is proposed. In an LFD, an auxiliary light source patterned with a fine pitch is attached to a reflective liquid‐crystal display (LCD), and a light shield is formed on the observer's side of the light source. A vertical‐alignment LCD (VA‐LCD) is attached as the reflective LCD, and an organic light‐emitting diode (OLED) is attached as the fine‐pitch light source. An LFD can produce bright, high‐contrast images under any ambient light. A test sample was built and its display characteristics confirmed.     

A novel electron‐transport material for organic light‐emitting devices

Abstract— A nanocrystalline electron‐transport material [ET68] was introduced into organic light‐emitting devices (OLEDs). By integrating a p‐doped transport system and phosphorescent emitters, a very bright and stable device could be obtained. Furthermore, 40% saving in power consumption can be achieved when the efficient pixels with ET68 were applied to AMOLEDs.     

Development of flexible organic light‐emitting diode on barrier film and roll‐to‐roll manufacturing

To come out with a successful organic light‐emitting diode (OLED) lighting business, it is very important to have clear differentiation of OLED from LEDs. Flexible OLED has merits, such as capability to be mounted on the curved wall, which is not easy for LEDs to achieve the feature. There are several approaches to make flexible OLEDs especially among those plastic barrier films that can bring high level of flexibility, which could not be achieved by any conventional lighting method. In this paper, barrier films with various water vapor transmission rate values, including 10^{? 6} order, are applied, and the conditions to have almost no dark spot growth under 85 °C and 85% high temperature/humidity test are shown. Flexible OLED panels are manufactured with the world's first roll‐to‐roll equipment using plastic barrier film.     

High resolution photolithography for direct view active matrix organic light‐emitting diode augmented reality displays

High‐resolution RGB organic light‐emitting diode frontplane is a key enabler for direct‐view transparent augmented reality displays. In this paper, we demonstrate 1250 ppi passive displays and semi‐transparent active displays. Organic light‐emitting diode photolithography can provide pixel density above 1000 ppi while keeping effective emission area high because of high aperture ratio. Patterns with 2 μm line pitch were successfully transferred to emission layers, indicating possible further pixel density scaling. Lifetime after patterning, key parameter enabling industrialization, is above 150 h (T90 at 1000 nit).     

Influence of the atmosphere on organic–organic interfacial layers and deterioration in organic light‐emitting diodes

The influence of organic–organic interfacial contaminants and deterioration in organic light‐emitting diodes (OLEDs) was investigated. There was deterioration of the device characteristics when atmospheric contamination was introduced to the emission site. We simultaneously observed a decrease of the maximum capacitance, C_max, of the OLEDs, implying that there was charge accumulation at the interface. Our study demonstrates that maintaining the interface adjacent to emission site free from contaminants is crucial to protect the device from deterioration.     

A 5291‐ppi organic light‐emitting diode display using field‐effect transistors including a c‐axis aligned crystalline oxide semiconductor

C‐axis‐aligned crystalline‐oxide semiconductor field‐effect transistor (CAAC‐OS FET) can be scaled down to a width and a length of 60 nm. We fabricated an organic light‐emitting diode (OLED) display with more than 5000 ppi, which is required in virtual reality (VR) display applications, using CAAC‐OS FETs as the backplane.     

A high image quality organic light‐emitting diode display with motion blur reduction for ultrahigh resolution and premium TVs

In this paper, we present a high image quality organic light‐emitting diode (OLED) display with motion blur reduction technology. Our latest work includes driving method that reduces motion blur using an adaptive black data insertion, brightness compensation technology, the simple structure pixel with low capacitance coupling for horizontal noise, and the multifunction integrated gate driver. The moving picture response time (MPRT) value of the OLED display panel with a fast response time was significantly affected by the frame frequency and the compensation driving method. The MPRT value of the large‐size OLED display panels was significantly decreased by using the integrated gate driver circuit with an MPRT reduction method. The decrease in the MPRT value originated from the turning of the emitting pixels off in advance resulting from providing black data. The integrated gate drivers were designed to achieve the normal display, the black data insertion, and the compensation mode. The MPRT value of the 65‐in. ultrahigh‐definition (UHD) OLED panels was decreased to 3.4 ms by using an integrated gate driver circuit. The motion blur of large‐size OLED display panels was significantly reduced due to a decrease in the MPRT value.     

Energy‐recycling high‐contrast organic light‐emitting devices

Abstract— It is reported that by integrating OLEDs with solar cells, ambient‐light reflection as low as 1.4% (even superior to that achieved with polarizers) can be achieved without compromising the EL efficiency for high‐contrast display applications. Furthermore, in such a configuration, the photon energies of both the incident ambient light and the portion of OLED emission not getting outside of the device can be recycled into useful electrical power via the photovoltaic action, instead of being wasted as in other reported contrast‐enhancement techniques. These features, we believe, shall make this present technique attractive for high‐contrast display applications and portable/mobile electronics that are highly power‐aware.     

High‐efficiency p‐i‐n organic light‐emitting diodes with long lifetime

Abstract— High‐performance organic light‐emitting diodes (OLEDs) are promoting future applications of solid‐state lighting and flat‐panel displays. We demonstrate here that the performance demands for OLEDs are met by the PIN (p‐doped hole‐transport layer/intrinsically conductive emission layer/n‐doped electron‐transport layer) approach. This approach enables high current efficiency, low driving voltage, as well as long OLED lifetimes. Data on very‐high‐efficiency diodes (power efficiencies exceeding 70 lm/W) incorporating a double‐emission layer, comprised of two bipolar layers doped with tris(phenylpyridine)iridium [Ir(ppy)₃], into the PIN architecture are shown. Lifetimes of more than 220,000 hours at a brightness of 150 cd/m² are reported for a red PIN diode. The PIN approach further allows the integration of highly efficient top‐emitting diodes on a wide range of substrates. This is an important factor, especially for display applications where the compatibility of PIN OLEDs with various kinds of substrates is a key advantage. The PIN concept is very compatible with different backplanes, including passive‐matrix substrates as well as active‐matrix substrates on low‐temperature polysilicon (LTPS) or, in particular, amorphous silicon (a‐Si).     

Thermally cross‐linkable copolymer and its evaluation as a hole transport layer in organic light‐emitting diode devices

This study reports on the synthesis of new thermally cross‐linkable copolymers containing a reactive cross‐linking comonomer. Synthesized polymers showed narrow molecular weight distribution (polydispersity) between 1.18 to 1.22 and 54 to 67% monomer conversion and incorporation of 2 to 7 mol% vinylbenzylcyclobutene comonomer. The polymer was soluble in nonpolar organic solvents such as chloroform, dichloromethane, toluene, and chlorobenzenes, and when cross‐linked, showed resistance to solubility in the previously listed solvents. The cross‐linked films exhibited uniform surface roughness below 1 nm. A polymer containing ~3.6 mol% vinylbenzylcyclobutene was thermally cross‐linked and evaluated as a hole‐transporting layer in green organic light‐emitting diode devices. The devices showed a maximum current efficiency of 39.5 cd/A at a current density of 2.7 mA/cm² and a brightness of 1000 cd/m² with an International Commission on Illumination coordinate (0.33, 0.62). The device performances are found comparable with the ones with the conventional hole‐transporting layer material, NPD.     

Displacement‐current analysis of organic light‐emitting diodes

Abstract— Organic light‐emitting diodes (OLEDs) having multiple organic layers were fabricated to analyze the physical phenomena occurring in an OLED according to the amplitude of the applied voltage. The staircase voltage with both an increasing period and a constant period was designed and applied to an OLED. The displacement current began to change at a voltage where the conduction current began to change, and partly originated from the formation of space charge due to the low mobility of the majority carrier. The displacement current was shown to be constant at low voltage and decreased after showing a maximum value as the applied voltage increased. The exact voltage for the injection of two types of carriers and light emission could be obtained from the variation in the displacement current.     

Composite silver electrode for double‐sided‐emitting stacked organic light‐emitting diode

Abstract— A reflective composite silver electrode is proposed and characterized as the middle electrode of a stacked organic light‐emitting diode (OLED) with double‐sided light emission. The proposed electrode is composed of a thermally evaporated stack of LiF (1 nm)/Al (3 nm)/Ag (70 nm) layers. The LiF/Al and the plasma‐treated Ag of the electrode function well as the respective cathode and anode of the bottom‐ and top‐emitting stacked OLEDs, with both being of the non‐inverted type. Power efficiencies of 10.3 and 12.1 lm/W at 100 cd/m² have been measured for bottom‐ and top‐emitting OLEDs, respectively, using dye doping. The stacked OLED having this bipolar middle electrode can be constructed as a two‐terminal‐only device, allowing for simpler driving schemes in double‐side‐emitting passive‐/active‐matrix OLED displays.     

Development of a high‐resolution RGBW flexible display using a white organic light‐emitting diode with microcavity structure and that of a side‐roll touch panel

In this study, white organic electroluminescent devices with microcavity structures were developed. A flexible high‐resolution active‐matrix organic light‐emitting diode display with low power consumption using red, green, blue, and white sub‐pixels formed by a color‐filter method was fabricated. In addition, a side‐roll touch display was developed in combination with a capacitive flexible touch screen.     

Performance enhancement of top‐ and bottom‐emitting organic light‐emitting devices using microcavity structures

Abstract— In order to improve the efficiency of top‐ and bottom‐emitting devices, metallic electrodes have been used to create microcavity effects within the OLED structure. Semi‐transparent Ag is used as the anode in bottom‐emitting microcavity structures, whereas various reflective opaque metallic anodes are used for the top emitters. The cathode used in both configurations is MgAg — thick and opaque in the case of the bottom emitter and thin and semi‐transparent in the case of the top emitter. Modeling and experiments show that for the top‐emitting structures, the device efficiency is roughly proportional to the reflectivity of the anode in the low reflectivity range and increases significantly more than predicted by reflectivity alone in the high‐reflectivity range. An ultrathin CF_x or MoO_x hole‐injecting layer allows for the use of many metals as anodes and is an important feature of the device structure. With an Ag anode, both the top‐ and bottom‐emitting microcavity devices are about twice as efficient (on axis) as the analogous nonmicrocavity bottom‐emitting device. Microcavity devices employing a C545T‐doped Alq emitter exhibit efficiencies of 21 cd/A at 6.4 V and 20 mA/cm², with operational stability equivalent to conventional bottom‐emitting structures.     

Solution‐processable double‐layered ionic p‐i‐n organic light‐emitting diodes

Abstract— Solution‐processed double‐layered ionic p‐i‐n organic light‐emitting diodes (OLEDs), comprised of an emitting material layer doped with an organometallic green phosphor and a photo‐cross‐linked hole‐transporting layer doped with photo‐initiator is reported. The fabricated OLEDs were annealed using simultaneous thermal and electrical treatments to form a double‐layered ionic p‐i‐n structure. As a result, an annealed double‐layered OLED with a peak brightness over 20,000 cd/m² (20 V, 390 mA/cm²) and a peak efficiency of 15 cd/A (6 V, 210 cd/m²) was achieved.