共查询到20条相似文献,搜索用时 15 毫秒
1.
Processes involving particles, are known to exhibit extremely unpredictable behaviour, mainly due to the mesoscopic nature of granular media. Understanding particulate processes, not only for intellectual satisfaction, but also for process design and operation, basically requires a systems approach in modelling. Because they combine simplicity and flexibility, the stochastic models based on the Markov chain theory are very valuable mathematical tools to this respect. However, they are still largely ignored by the whole core of chemical engineering researchers. This motivates the existence of this review paper, in which we examine the three traditional issues: mixing and transport, separation and transformation. 相似文献
2.
We consider a generalized autoregressive conditionally heteroskedastic (GARCH) equation where the coefficients depend on the state of a nonobserved Markov chain. Necessary and sufficient conditions ensuring the existence of a stationary solution are given. In the case of ARCH regimes, the maximum likelihood estimates are shown to be consistent. The identification problem is also considered. This is illustrated by means of real and simulated data sets. 相似文献
3.
Abstract. Backward and forward moving average (MA) representations are established for multivariate stationary processes. It is observed that in the multivariate case, in contrast to the univariate case, the backward and forward MA coefficients correspondingly, in general, are different. A method is presented to adopt the known techniques in deriving the backward MA to obtain the forward ones. 相似文献
4.
In this article, we propose a nonparametric procedure for validating the assumption of stationarity in multivariate locally stationary time series models. We develop a bootstrap‐assisted test based on a Kolmogorov–Smirnov‐type statistic, which tracks the deviation of the time‐varying spectral density from its best stationary approximation. In contrast to all other nonparametric approaches, which have been proposed in the literature so far, the test statistic does not depend on any regularization parameters like smoothing bandwidths or a window length, which is usually required in a segmentation of the data. We additionally show how our new procedure can be used to identify the components where non‐stationarities occur and indicate possible extensions of this innovative approach. We conclude with an extensive simulation study, which shows finite‐sample properties of the new method and contains a comparison with existing approaches. 相似文献
5.
为了更有效的对汕头市空气质量进行预测,我们将基于Markov链理论的空气质量的统计预报模型进行了改进,加入了气象因素对模型进行修正,并作实例验证其可行性及准确率检验。证明了该模型具有较好的短期预测正确率,有一定的实用价值。 相似文献
6.
We consider a time series model where the variance of the underlying process depends on the state of a non-observed Markov chain. Maximum likelihood estimates are shown to be consistent. Estimators with asymptotic Gaussian distribution are proposed. Prediction and identification are also mentioned. This is illustrated by means of real and simulated data sets 相似文献
7.
8.
9.
This paper develops an efficient approach to modeling and analyzing the overall dynamics of polydisperse particulate systems, exemplified using a rotating drum with horizontal axis, under both constant and time-varying operating conditions. This approach captures the collective dynamics using stochastic models in the form of Markov chains. The characteristics of such dynamics can be obtained from the Markov chains operator. It provides a systematic way to the analysis of collective dynamical features of particle movements. The obtained operators are used to estimate the spatial particle distribution and the degree of particulate mixing as examples of collective dynamic features of polydisperse particulate systems. In this paper, Markov chains models were developed from discrete element method simulation results to show the effectiveness of the proposed approach. 相似文献
10.
Simulation of Real Discrete Time Gaussian Multivariate Stationary Processes with Given Spectral Densities 下载免费PDF全文
In this article we establish a simulation procedure to generate values for a real discrete time multivariate stationary process, based on a factor of spectral density matrix. We prove the convergence of the simulator, at each time epoch, to the actual process, and provide the corresponding rate of convergence. We merely assume that the spectral density matrix is continuous and of bounded variation. By using the positive root factor, we provide an extended version for the Sun and Chaika ( 1997 ) simulator, for real univariate stationary processes. 相似文献
11.
12.
The main goal of this review is to provide an overview of the trends in the technological development of complexation gas chromatography. This kind of chromatography, despite the passage of years, continues to offer new opportunities. The authors would like to show how complexation gas chromatography evolved over the years, due to the variety of stationary phases with complexation properties, their ability to separate, very specifically, the structures of the molecules and chemical compounds, improving the quality of the obtained results, and continuously lowering the detection limits of the analysed compounds in very complex matrices, including environmental and medical samples. The work is dedicated to the memory of Professor E. Gil-Av, whose scientific achievements were the inspiration for the improvement and widening of the research on the use of complexing metal ions and coordination metal compounds for selective separation in gas chromatography. 相似文献
13.
A new time-frequency model and a method to classify time series data are proposed in this article. By viewing the observed signals as realizations of locally dyadic stationary (LDS) processes, a LDS model can be used to provide a time-frequency decomposition of the signals, under which the evolutionary Walsh spectrum and related statistics can be defined and estimated. The classification procedure is as follows. First choose a training data set that comprises two groups of time series with a known group. Then compute the time frequency feature (the energy) using the training data set, and use a best tree method to maximize the discrepancy of this feature between the two groups. Finally, choose the testing data set with the unknown group as validation data, and use a discriminant statistic to classify the validation data to one of the groups. The classification method is illustrated via an electroencephalographic dataset and the Ericsson B transaction time dataset. The proposed classification method performs better for integer-valued time series in terms of classification error rates in both simulations and real-life applications. 相似文献
14.
15.
Pierre Boulard Valrie Gouilleux-Gruart Herv Watier 《International journal of molecular sciences》2022,23(18)
For twelve years, the oncology field has been revolutionized by antibodies targeting immune checkpoints. They must be considered as a heterogenous family of immunostimulatory antibodies displaying very different mechanisms of action, not only depending on the target or on the cells expressing it, but also on the IgG subclass or IgG variant that has been chosen. To dissect this complex landscape, the clinical experience has been confronted with a precise analysis of the heavy chain isotypes, referred as new Ge nomenclature. For antibodies targeting inhibitory receptors, anti-CTLA-4 antibodies (whose main effect is to kill regulatory T cells) will be distinguished from anti-PD-1 antibodies and other true antagonistic antibodies. Antibodies targeting ligands of inhibitory receptors (PD-L1, CD47) represent another different category, due to the antigen expression on tumors and a possible beneficial killing effect. The case of agonistic antibodies targeting lymphocyte activatory receptors, such as CD40 or 4-1BB, is still another “under construction” category because these products are less advanced in their clinical development. Altogether, it appears that choosing the right heavy chain is crucial to obtain the desired pharmacological effect in patients. 相似文献
16.
17.
18.
Abstract. The innovations algorithm can be used to obtain parameter estimates for periodically stationary time series models. In this paper, we compute the asymptotic distribution for these estimates in the case, where the innovations have a finite fourth moment. These asymptotic results are useful to determine which model parameters are significant. In the process, we also develop asymptotics for the Yule–Walker estimates. 相似文献
19.
The spherical truncation of electrostatic field with different functions break down long-range interactions at a given cutoff distance (roff) resulting in short-range ones. Consequently, a Markov Chain model may approach to the entropies of spatial distribution of charges within the polymer backbone. These entropies can be used to predict polymers properties [González-Díaz H, Molina RR, Uriarte E. Polymer 2004; 45: 3845 [53]]. Herein, we explore the effect of abrupt, shifting, force shifting, and switching truncation functions on QSAR models classifying 26 proteins with different function: lysozymes, dihydrofolate reductases, and alcohol dehydrogenases. Almost all methods have shown overall accuracies higher than 85% instead of 80.8% for models based on physicochemical parameters. The present result points to a acceptable robustness of the Markov model for different truncation schemes and roff values. The results of best accuracy 92.3% with abrupt truncation coincides with our recent communication [Bioorg Med Chem Lett 2004; 14: 4691-4695]. Nonetheless, the simpler model with three variables and high accuracy (88%) was derived with a shifting function and roff=10 Å. 相似文献
20.
Stationary processes are a natural choice as statistical models for time series data, owing to their good estimating properties. In practice, however, alternative models are often proposed that sacrifice stationarity in favour of the greater modelling flexibility required by many real‐life applications. We present a family of time‐homogeneous Markov processes with nonparametric stationary densities, which retain the desirable statistical properties for inference, while achieving substantial modelling flexibility, matching those achievable with certain non‐stationary models. A latent extension of the model enables exact inference through a trans‐dimensional Markov chain Monte Carlo method. Numerical illustrations are presented. 相似文献