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1.
Ahmed Mohamed Mahmoud Ibrahim Xiaoliang Shi Ao Zhang Kang Yang Wenzheng Zhai 《摩擦学汇刊》2013,56(6):1076-1083
In this study, the tribological properties of NiAl matrix composites with 1.5 wt% graphene nanoplatelets (NAG) at elevated temperatures were simulated and tested. NAG exhibits excellent characteristics at 100 and 200°C due to the formation of metal oxides and graphene nanoplatelets lubrication film. Furthermore, the removed layer thickness, the stress distributions, and the high stresses of the affected layer have been estimated theoretically. At 400°C, the friction coefficient increased due to the absence of the lubrication layer. In addition, the wear rate increased due to the excessive stresses, the increased layer thickness removal, and the propagation of subsurface cracks. 相似文献
2.
Qingshuai Zhu Xiaoliang Shi Wenzheng Zhai Jie Yao Ahmed Mohamed Mahmoud Ibrahim Zengshi Xu Siyuan Song Abid Qamar ud Din Long Chen Yecheng Xiao Qiaoxin Zhang 《Tribology Letters》2014,55(2):343-352
Research on the friction layer is needed to minimize friction- and wear-related mechanical failures in moving mechanical assemblies. Dry sliding tribological tests of Ni3Al matrix composites (NMCs) with 1.5 wt% graphene nanoplatelets (GNPs) sliding against different counterface balls are undertaken at the condition of 10 N–0.234 m s?1 in this study. When sliding against GCr15 steel, a uniform and thick friction layer is formed, resulting in a lower friction coefficient (0.29–0.31) and wear rate (2.0–3.1 × 10?5 mm3 N?1 m?1). While sliding against Al2O3 and Si3N4, the formation and stability of the friction layers are restricted in the severe wear regime, and the NMCs exhibit higher friction coefficients and wear rates. Therefore, various counterface balls have a great effect on the stability and thickness of the friction layer, thus affecting the tribology performance of NMCs. The result also shows that GNPs exhibit enrichment and self-organized microstructures in the friction layer. In addition, the friction layer is also found to be divided into two layers, protecting the subsurface from further damage and reducing shear. 相似文献
3.
Ahmed Mohamed Mahmoud Ibrahim Xiaoliang Shi Wenzheng Zhai Jie Yao Zengshi Xu Long Cheng 《摩擦学汇刊》2013,56(6):1044-1050
The progress in aerospace field requires a new NiAl matrix composite that can stand against wear and decrease the energy dissipation through decreasing friction. In this study, the tribological behavior of NiAl–1.5 wt% graphene composite is investigated at room temperature under a constant load of 12 N and different sliding velocities. The results show that the friction coefficient and wear rate increase with increasing sliding velocity from 0.2 to 0.4 m/s due to the adhesion between the sliding bodies and tearing of the graphene layer. The friction coefficient and wear rate tend to decrease at a sliding velocity of 0.6 m/s as a result of severe plastic deformation and grain refinement of the worn surface. However, at 0.8 m/s the friction coefficient reaches a minimum value and the wear rate increases and changes the wear mechanism to fatigue wear. It can be concluded that various wear mechanisms lead to different tribological performance of NiAl–1.5 wt% graphene composite. 相似文献
4.
Ultra-high molecular weight polyethylene (UHMWPE)/ graphene nanoplatelets (GNPs) nanocomposite coatings were developed to reduce friction and wear in the absence of liquid lubrication. UHMWPE nanocomposite powders with different loadings (0.25, 1, and 2 wt.%) of GNPs were prepared and electrostatic spraying technique was then used to deposit the nanocomposite powders on aluminum alloy to form a thin coating. Friction and wear tests were conducted on the coatings against a flat-end pin, made of hardened tool steel to determine the best loading of GNPs. That was further tested to investigate the effect of sliding speed and contact pressure on its tribological properties and to establish coating operating limits. Results showed that UHMWPE nanocomposite coating reinforced with 1 wt.% GNPs showed the best tribological performance. It reduced wear rate by about 51% as compared to the pristine UHMWPE coating. The coating sustained a maximum sliding speed of 1 m/s at a contact pressure of 4 MPa equivalent to a pressure and velocity (PV) value of 4 MPa.m/s. 相似文献
5.
An investigation is conducted on the unexplored synergistic effects of multilayer graphene (MLG) and Ti3SiC2 in self-lubricating composites for use in high-temperature friction and wear applications. The tribological properties of TiAl matrix self-lubricating composites with different solid lubricant additions (Ti3SiC2-MLG, MLG) are investigated from room temperature to 800°C using a rotating ball-on-disk configuration. Tribological results suggest the evolution of lubrication properties of MLG and the excellent synergistic lubricating effect of MLG and Ti3SiC2 as the testing temperature changes. It can be deduced that MLG has great potential applications as a promising high-temperature solid lubricant within 400°C, and a combination of MLG and Ti3SiC2 is an effective way to achieve and maintain desired tribological properties over a wide temperature range. 相似文献
6.
Jiqiang Ma Fei Li Jun Cheng Licai Fu Zhuhui Qiao Weimin Liu Jun Yang 《Tribology Letters》2013,50(3):323-330
In this paper, we reported the tribological behavior of Ti3AlC2 disk sliding against SiC ball from room temperature (RT) to 1,000 °C. The tribological properties are highly dependent of testing temperature. At RT, the coefficient of friction (CoF) is as low as 0.34 in the steady state, but the wear rate is relative high (4.26 × 10?4 mm3/Nm). At 200 and 400 °C, the CoF is as high as 1.21, and the wear rates are very high, about on the order of 10?3 mm3/Nm. From 600 to 1,000 °C, however, Ti3AlC2 exhibits quite low wear rate on the order of 10?6 mm3/Nm and relative moderate CoF, 0.60–0.80. The compacted continuous oxide layer at 600 °C and above might be responsible for the outstanding wear resistance. 相似文献
7.
This study aimed to explore the possibility of improving the tribological performance of NiAl matrix composites by graphene addition. Friction and wear experiments of as-prepared specimens were conducted under different conditions using a pin-on-disk wear testing machine. NiAl matrix composites containing graphene showed satisfactory performance in friction coefficient and wear resistance compared to NiAl matrix composites without graphene. For the active effect of graphene, the friction coefficient and wear rate of NiAl matrix composites were maintained at relatively lower values. The beneficial antifriction and antiwear effects of graphene gradually failed when the applied load was above 8 N. Graphene in NiAl matrix composites played an active role in the formation of a friction layer, which was beneficial to the lower friction coefficient and wear rate. In light of this research, graphene plays an active role in reducing the friction coefficient and wear rate. Hence, graphene has great potential in applications as an effective solid lubricant to promote tribological behavior. 相似文献
8.
The friction and wear performance of WC-12Co air plasma–sprayed (APS) coating at temperatures of 25–650°C under loads of 8 and 28 N in at atmospheric environment have been studied by a ball-on-disc tribometer. The effect of temperature and load on the tribological behavior of WC-Co coating was investigated. The results show that under a load of 8 N, the wear volume of the coating increases at 250°C due to the coating splat delamination and then it gradually decreases at 350–500°C. The friction could promote the formation of double oxide (CoWO4), which is beneficial to reduce friction and wear. At higher temperatures, the wear volume increases again due to the removal of oxides. Under a load of 28 N, the wear volume of the coating increases enormously at 250°C due to the serious splat delamination. At 350°C, the load promotes double oxide formation, resulting in an early decrease in the coefficient of friction and a rapid reduction in wear volume. Although the wear volume decreases at 350–500°C, it is 10-fold higher than that under a load of 8 N. Above 500°C, the differences of the wear volumes of coatings under the two loads become less obvious, and similar trends also appear for the coefficients of friction. The synergistic effect between the load and temperature on the friction and wear mechanism of WC-12Co APS coating is discussed. 相似文献
9.
More durable, low-friction bearing materials over a wide temperature range are needed for turbine components and other high-temperature bearing applications. The current study reported the tribological properties of TiAl matrix self-lubricating composites (TMC) containing MoS2 (a low-temperature lubricant, below 500°C), hBN (a medium-temperature lubricant, below 600°C), and Ti3SiC2 (a high-temperature lubricant, above 600°C) designated as MhT against an Si3N4 counterface at temperatures ranging from 25 to 800°C in air. The load was 10 N and the sliding speed was 0.2 m/s for all tests. Tribological studies indicated that TMC containing MhT showed a lower friction coefficient and wear rate in comparison to TiAl-based alloy at all test temperatures, which was attributed to the excellent synergetic lubricating effect of MoS2, hBN, and Ti3SiC2. TMC containing 5 wt% MhT exhibited the best tribological properties over a wide temperature range. 相似文献
10.
TiAl matrix self-lubricating composites (TMC) with various weight percentages of Ti3SiC2 and MoS2 lubricants were prepared by spark plasma sintering (SPS). The dry sliding tribological behaviors of TMC against an Si3N4 ceramic ball at room temperature were investigated through the determination of friction coefficients and wear rates and the analysis of the morphologies and compositions of wear debris, worn surfaces of TMC, and the Si3N4 ceramic ball. The results indicated that TMC with 10 wt% (Ti3SiC2-MoS2) lubricants had good tribological properties due to the unique stratification subsurface microstructure of the worn surface. The friction coefficient was about 0.57, and the wear rate was 4.22 × 10?4 mm3 (Nm)?1. The main wear mechanisms of TMC with 10 wt% (Ti3SiC2-MoS2) lubricants were abrasive wear, oxidation wear, and delamination of the friction layer. However, the main wear mechanisms of TMC without Ti3SiC2 and MoS2 lubricants were abrasive wear and oxidation wear. The continuous friction layer was not formed on the worn surfaces. The self-lubricating friction layer on the frictional surface, different phase compositions and hardness, as well as density of TMC contributed to the change in the friction coefficient and wear rate. 相似文献
11.
Effect of Hardness Ratio on the Wear Performance and Subsurface Evolution of Ni3Al Matrix Composites
Wenzheng Zhai Ahmed Mohamed Mahmoud Ibrahim Zengshi Xu Kang Yang Qiaoxin Zhang 《摩擦学汇刊》2017,60(5):902-912
A favorable hardness ratio (Hdisk/Hpin = Hd/Hp) could lead to a transition to mild wear during sliding contact. To determine a more appropriate Hd/Hp value for the sliding wear, the dry sliding pin-on-disk wear tests of Ni3Al matrix composites (NMCs) with multilayer graphene (MLG) are undertaken at Hd/Hp values of 0.99, 0.83, 0.42, and 0.35 at sliding speeds of 0.1, 0.3, 0.5, and 0.7 m/s. It is found that the tribological properties of NMCs are strongly affected by the various hardness ratios. At 0.1 m/s, the friction coefficient decreases with a decrease in Hd/Hp value. The low friction coefficient is 0.14 and the wear rate is 0.9 × 10?5 mm3 N?1m?1 under the ceramic counterpart with Hd/Hp of 0.35. At 0.7 m/s, the tribological properties show the opposite trend with a decrease in Hd/Hp. At an Hd/Hp of 0.35, the smooth compact layer on the worn surface could decrease the friction at 0.1 m/s, and the improved hardness in the subsurface by strain hardening would play an important role in the improvement of wear resistance. Under the metal counterpart with Hd/Hp of 0.99, plastic deformation only occurs on the contact surface and the MLG could suppress further shear deformation in the subsurface, leading to a low wear rate (2.4 × 10?5 mm3 N?1m?1) and friction coefficient (0.15) at 0.7 m/s. 相似文献
12.
Jie Chen Xiaoqin Zhao Huidi Zhou Jianmin Chen Yulong An Fengyuan Yan 《Tribology Letters》2014,56(1):55-66
An adaptive NiMoAl–Ag composite coating was deposited by high-velocity oxy fuel spraying, and its tribological properties from 20 to 800 °C under unlubricated conditions were evaluated using a CSM high-temperature tribometer. Scanning electron microscopy, X-ray diffraction and Raman spectroscopy were used to characterize the coating and corresponding wear tracks to determine the lubrication mechanisms. The results showed that the friction coefficient of the NiMoAl–Ag composite coating was around 0.3 from 20 to 600 °C and reached the lowest value of 0.09 at 800 °C. Meanwhile, wear rates of the coating were maintained on the order of 10?5 mm3/N m at the test temperatures except for 400 and 600 °C. Characterization of the NiMoAl–Ag coating revealed that silver provided lubrication below 400 °C. Ag2Mo2O7 and Ag2MoO4, which were formed through tribochemical reactions, acted as high-temperature lubricants above 400 °C. It was especially proposed that silver in a nearly molten state was effective in reducing the friction of the NiMoAl–Ag coating at 800 °C. Moreover, a comprehensive lubrication mechanism model of an NiMoAl–Ag composite coating at 800 °C was established to explain the extremely low friction coefficient and wear rate of the coating. 相似文献
13.
This study was undertaken to investigate the effect of heat treatments on the high-temperature wear behavior of 60Nitinol. The samples were hot-worked, aged at two temperatures of 400 and 700°C for 1 h and then water quenched. The microstructure of the alloys was investigated by scanning electron microscopy and X-ray diffraction. Sliding wear tests were performed at two temperatures of 25 and 200°C using three types of 60Nitinol disks: hot-worked, aged at 400°C, and aged at 700°C. All wear tests were performed at a speed of 0.3 m/s under a normal load of 60 N for a total sliding distance of 1,000 m using WC-Co pins sliding against 60Nitinol disks. The worn surfaces and microstructure of the subsurfaces were studied by scanning electron microscopy. Compression and hardness tests were also performed to characterize the mechanical properties of the alloys. The highest fracture strain and lowest hardness were obtained for the sample aged at 700°C that contained Ni3Ti2 precipitants. This sample also showed the maximum wear resistance at a wear testing temperature of 200°C. This was attributed to the formation of a more compact and stable tribological layer on the worn surface of the softer sample. 相似文献
14.
The tribological behavior of self-mated Ti3SiC2 is investigated from ambient temperature to 800?°C at a sliding speed of 0.01?m/s in air. The results show that at the temperatures lower than 300?°C, friction coefficient and wear rates are as high as 0.95 and 10?3?mm3/N?m, respectively. With the temperature increasing to 600?°C, both the friction coefficient and wear rates show consecutive decrease. At 700 and 800?°C, friction coefficient and wear rates are 0.5 and 10?6 mm3/N?m, respectively. According to the wear mechanism, the tribological behavior of Ti3SiC2 can be divided into three regimes: mechanical wear-dominated regime from ambient temperature to 300?°C characterized by pullout of grains; mixed wear regime (mechanical wear and oxidation wear) from 400 to 600?°C; and tribo-oxidation-dominated wear regime above 700?°C. The tribo-oxides on the worn surfaces involve oxides of Si and Ti. And, species transformation occurs to these two oxides with the increasing temperature. In the competition oxidation of elements Ti and Si, Si is preferably oxidized because of its high active position in the crystal structure. Additionally, plastic flow is another notable characteristic for the tribological behavior of self-mated Ti3SiC2. 相似文献
15.
In this article, friction and wear characteristics of BaCr2O4 ceramics have been investigated using a high-temperature friction and wear tester from room temperature to 800?°C in dry sliding against sintered alumina ball. At room temperature, the friction coefficient and wear rate of BaCr2O4 ceramics are quite high. BaCr2O4 ceramics exhibit low friction coefficients and small wear rates with temperature increasing up to 400?C600?°C. The oxidation reaction of BaCr2O4 during high-temperature wear tests is responsible for the tribological properties. The oxidized product of BaCr2O4 is BaCrO4, which forms a smooth self-lubricating film on the worn surface to effectively reduce friction and wear. However, at 800?°C, severe oxidation reduces the relative density of sintered BaCr2O4 ceramics, and further expedites the materials removal process. 相似文献
16.
Tribological thermostability of carbon film with vertically aligned graphene sheets was studied with annealing temperatures up to 1,750 °C. The carbon film was deposited on silicon carbide substrate by electron cyclotron resonance plasma sputtering. Tribological thermostabilities of the carbon film in terms of friction coefficient, wear life, and nanoscratch depth were investigated by Pin-on-Disk tribometer and atomic force microscopy. The evolution of nanostructure of vertically aligned graphene sheets in the carbon film as a function of annealing temperature was examined by Raman spectroscopy and transmission electron microscopy. The results showed that the friction coefficient, wear life, and nanoscratch depth of the carbon film were thermally stable up to 1,250 °C. When the annealing temperature was 1,500 °C, the friction coefficient and the nanoscratch depth increased, the wear life decreased, but still all were of considerable values. These variations were attributed to the initiation of tubular-like structure originated from graphene sheets stacks. After annealing at 1,750 °C, tribological performances degraded catastrophically due to the abundant formation of tubular-like structures and the appearance of a graphitic interlayer between the film and the substrate. 相似文献
17.
The frictional and wear characteristics of nanostructured DLC films were investigated. The coatings were deposited on silicon substrates by irradiation of a mass-separated C60 ion beam with 5 keV of energy and a deposition temperature ranging from 100 to 450 °C. The effects of deposition temperature on the surface morphology, nano-structure, mechanical properties and tribological characteristics of the coatings were assessed. Results showed that deposition temperature strongly affects the nanostructure and surface morphology of the coatings. Coatings deposited at temperatures exceeding 350–400 °C exhibited an increase in surface roughness as well as compressive stress due to the formation of graphite, which led to a significant increase in the friction coefficient and wear rate. Coatings deposited at 300 °C showed the best tribological properties. 相似文献
18.
Adequate high-temperature lubrication between loaded surfaces in sliding contact can be one of the most challenging tribological problems confronting today's designers. In an attempt to provide a possible solution a test program was initiated to evaluate PS400, a recently patented, high-temperature solid lubricant coating. Made from nickel–molybdenum–aluminum, chrome oxide, silver, and barium fluoride–calcium fluoride, PS400 is a variant of the earlier coating, PS304, but is formulated for higher density, smoother surface texture, and greater dimensional stability. It was initially developed to minimize the start–stop wear in foil air bearings but is expected to perform well in other high-temperature applications where sliding friction and wear are a concern, such as variable inlet guide vanes and process control valve stems. To better define its operational capabilities, a series of tests was conducted to study the behavior of PS400 under reciprocating sliding contact at temperatures from 260 to 927°C. The tests were performed on stationary, uncoated cobalt-based superalloy bushings loaded against reciprocating PS400-coated shaft specimens in a flat-on-cylinder configuration at Hertz contact pressures from 14.1 to 20.1 MPa. For tests conducted below 927°C, friction coefficients ranged from 0.37 to 0.84 with wear factors on the order of 10?5 and 10?6 at the high temperatures but substantially increased at the lowest temperature. Data collected at 927°C were limited because the coating was found to be dimensionally unstable at this temperature. 相似文献
19.
The effect of reaction temperature on the formation of a carbon layer on the surface of SiC has been investigated. Subsequently, the tribological properties of the formed carbon layers were studied. The experimental procedure involved exposing reaction-bonded SiC balls to a flowing gas mixture of 5% Cl2, 2.5% H2, and Ar at a high temperature of 800, 1000, or 1200 °C. A ball-on disk tribometer was used to investigate the friction and wear behavior of the treated specimens. While partially unreacted SiC phases were observed in the layer modified at 800 °C, rhombohedral graphite crystals were formed in the layer modified at 1200 °C. Compared to untreated SiC, the treated SiC materials were found to have relatively low friction coefficients and better wear resistance. Increasing the treatment temperature was found to improve the tribological performance of the resulting surface-modified SiC balls. A possible reason for this tribological improvement has been discussed based on the observed carbon phases. 相似文献
20.
《Tribology - Materials, Surfaces & Interfaces》2013,7(3):100-106
AbstractThe use of surface coatings is emerging as one of the most important approaches in reducing friction and wear in various tribological applications. Even though single layer coatings have a wide range of applications, the performance of the single layer alone may not always be adequate to meet the desired tribological property requirements. Hence, coatings consisting of multilayers to meet different property requirements in demanding applications are required. In this study, the tribological properties of a graded composite multilayer coating, with a specific layer sequence of MoS2/Ti–MoS2/TiBN–TiBN–TiB2–Ti deposited on tool steel substrate, have been investigated at temperatures of 40 and 400°C respectively. The experimental results from the tests at 40°C have shown that the friction coefficient value ranges between 0·02 and 0·034. It was found that the deposition parameters influenced the friction and durability of the coatings. Higher substrate bias was found to result in higher friction, and the coating deposited at high substrate bias and low N2 flow showed the lowest durability. The friction coefficient and durability of the coatings were found to be highly dependent on temperature. At high temperature, the friction coefficient increases almost threefold, and the durability decreases significantly. 相似文献