添加CaF2的Ni-Cr-Cu基固体自润滑材料的研究

由于加入脆性的CaF2而使材料的机械性能稍有下降，在室温、载荷50N，滑动速度1．5m/s的情况下使材料的磨损率下降28％，在600℃时下降40．4％。对4#材料在不同温度下的摩擦磨损性能分析结果显示：随着温度的升高，材料的摩擦系数逐渐减小，材料的磨损率先减少后升高。载荷对材料的摩擦系数影响很小，但是使材料的磨损率不断上升。     

Tribochemical Processes and Wear Resistance of Polymeric Materials

Tribochemical transformations of polyphenylquinoxaline (PPQ) and a composite material on its basis containing graphite are investigated. A mass-spectrometric analysis shows that in the polymer surface layers the destructive-structurizing processes occur on friction that changes the structure and properties of the surface layer. It is shown that, in the presence of a graphite filler, the tribochemical transformation character also changes. Based on the investigation data, a general scheme of tribochemical changes of PPQ is proposed and their relation to wear is suggested.     

拉深模激光毛化表面的磨损性能研究

为提高拉深模的磨损性能和使用寿命,利用激光毛化技术在模具钢试样表面分别加工出不同直径和间距的微单元体。对比研究毛化表面试样和非毛化表面试样的磨损性能,结果表明,毛化试样表面耐磨性均优于非毛化表面试样。通过激光毛化可提高拉深模寿命,改善板料成形时的流动性。     

钢铜摩擦副摩擦磨损特性的试验研究

本文试验分析了ＺＱＡ１９－４和ＺＱＺｎ６－６－３两种铜合金材料在不同的表面粗糙度下对摩擦系数和出口区油温的影响，以及改变载荷和相对滑动速度时，摩擦系数的变化状况。结果表明；铜合金成分不同时具有不同的硬度。     

Friction and Wear Behavior of Steels under Different Reciprocating Sliding Conditions

The friction and wear behavior of ISO 100Cr6 steel ball sliding against conventionally hardened carbon and low-alloy steels was studied. The effect of hardness, hardening capacity, normal load, and sliding speed on the coefficient of friction and friction energy was investigated. Friction tests were carried out, without lubrication and under ambient conditions, on a reciprocating friction tester in which a ball-on-flat contact configuration was adopted. The results showed that there is a relative tendency for the friction properties to decrease with increased hardening capacity and decreased hardness. The results showed that increasing normal load decreases the coefficient of friction for the two steel nuances. However, increasing sliding speed increases the coefficient of friction of low-alloy steel and decreases the coefficient of friction of carbon steel. The oxidation of wear debris influences the wear mechanisms and friction behavior.     

干摩擦状态下动载荷特性对磨损的影响

在自行研制的环一块磨损试验装置上研究了干摩擦状态下矩形波载荷特性对磨损的影响,结果表明。1)矩形波载荷和静载荷作用下试件的磨损过程一样,存在跑合期和稳定磨损期;2)矩形波载荷的占空比愈小,跑合期磨损量愈少,跑合期愈长。     

Impact of Plateaued Surfaces on Tribological Performance

Plateaued surfaces are surfaces that have been machined to simulate those that result from normal running in and are said to have advantages over conventional or non-plateaued surfaces. However, the evidence is lacking. This study evaluates the tribological performance of plateaued and non-plateaued surfaces on a pin-on-disk tribometer. The honing pattern of an engine cylinder bore was simulated on the disks. These disks have similar average surface heights with either plateaued or non-plateaued surface finish. Friction, wear and scuffing resistance of plateaued and non-plateaued disks were evaluated. Results from the pin-on-disk tribometer show that in the hydrodynamic lubrication regime plateaued and non-plateaued disks have the same friction, while in the mixed lubrication regime the plateaued surface has less friction. The author's findings also reveal that plateaued surfaces tend to have higher wear resistance but lower scuffing resistance. It also confirms the conventional wisdom that plateaued surfaces have shorter running-in wear period.     

Experimental Study on the Effect of Microstructure on Dry Sliding Wear Behavior of Titanium Alloy Using Taguchi Experimental Design

The present article depicts the influence of independent control factors such as microstructural variation, normal load, sliding velocity, and test duration on the dry sliding wear behavior of titanium alloy at room temperature using a statistical approach. Different heat treatments were carried out in a controlled manner to produce various microstructural features (i.e., lamellar, bimodal, and equiaxed) in this alloy. A lamellar microstructure is found to be harder than bimodal microstructure followed by an equiaxed microstructure in this alloy. Dry sliding wear tests were carried out using a multiple tribotester following a well-planned experimental schedule based on Taguchi's orthogonal arrays. The dry sliding wear behavior of this alloy consisting of various microstructural features is related to their hardness values. The results indicated that a lamellar microstructure has the lowest sliding wear resistance followed by bimodal and equiaxed microstructures. Using signal-to-noise ratios and analysis of variance (ANOVA), an optimal combination of control factors that minimize the dry sliding wear in this alloy were determined. Among all four control factors, normal load is the most significant control factor influencing the dry sliding wear behavior of the investigated titanium alloy, followed by microstructural variation, sliding velocity, and test duration. Normal load has a greater static influence of 39.53%, microstructural variation has an influence of 31.55%, sliding velocity has an influence of 21.6%, and test duration has an influence of 5.7% on the dry sliding wear of this alloy. Two wear mechanisms were identified: oxidative wear occurs at the lowest sliding velocity and delamination wear occurs at the highest sliding velocity. Optical microscopy, scanning electron microscopy, and Rockwell hardness measurements were used to characterize the microstructures in order to correlate the results obtained.     

Comparative Study of Wear Behaviors of a Selected Titanium Alloy and AISI H13 Steel as a Function of Temperature and Load

A comparative study of the wear behaviors of a selected titanium alloy and AISI H13 steel as a function of temperature and load was performed on a high-temperature wear tester. The titanium alloy and H13 steel presented totally different wear behaviors with the variation in temperature and load. Their behaviors are suggested to be attributed to the protective ability of tribo-oxides and the thermal softening resistance of the matrix. Compared to H13 steel, the titanium alloy presented poor room-temperature wear resistance, excellent high-temperature wear resistance, and an extremely protective function of tribo-oxides.     

SiCp颗粒复合对ZA27合金滑动摩擦条件下耐磨性能的影响

用铸造法制备了SiC_p/ZA27复合材料,用MM200磨损试验机,测定和对比了基体合金和不同颗粒含量复合材料在不同载重下滑动摩擦的磨损量,结果表明:在重载条件下,复合材料的耐磨性远高于基体材料。此外.还初步分析了不同条件下的磨损机理。     

The Effect of Laser Texturing of Steel Surfaces and Speed-Load Parameters on the Transition of Lubrication Regime from Boundary to Hydrodynamic

Laser surface texturing (LST) is an emerging, effective method for improving the tribological performance of friction units lubricated with oil. In LST technology, a pulsating laser beam is used to create thousands of arranged microdimples on a surface by a material ablation process. These dimples generate hydrodynamic pressure between oil-lubricated parallel sliding surfaces. The impact of LST on lubricating-regime transitions was investigated in this study. Tribological experiments were carried out on pin-on-disk test apparatus at sliding speeds that ranged from 0.15 to 0.75 m/s and nominal contact pressures that ranged from 0.16 to 1.6 MPa. Two types of oil with different viscosities (54.8 cSt and 124.7 cSt at 40°C) were evaluated as lubricants. Electrical resistance between flat-pin and laser-textured disks was used to determine the operating lubrication regime. The test results showed that laser texturing expanded the range of speed-load parameters for hydrodynamic lubrication. LST also reduced the measured friction coefficients of contacts that operated under the hydrodynamic regime. The beneficial effects of laser surface texturing are more pronounced at higher speeds and loads and with higher viscosity oil.     

Effects of Environment on Friction and Wear of Al-Si Alloy Impregnated Graphite Composite

Pin-on-disk-type wear experiments for an Al-Si alloy impregnated graphite composite (pin) in contact with a bearing steel (disk) were conducted at 100N normal load (100 Newtons) in air, argon, and deionized water to investigate the effects of environment on the tribological characteristics of the composite. The friction and wear behavior and the pin-lifting phenomenon due to wear particle ingress into the contact surfaces were continuously measured during the experiments. At low relative humidity (RH) levels, the friction coefficients in air and argon are high (0.32 to 0.39) and decrease with increasing RH to values around 0.2. The friction coefficients in air have reached a minimum of 0.15 to 0.17 between 50 and 70% RH and increased slightly at 80% RH. The friction coefficients in argon are constant at about 0.2 between 10 and 80% RH. Because of the lubricating action of a water film, the friction coefficient in deionized water is slightly lower (0.1 to 0.17) than that in air. The mean wear rate of 10^?4 to 8 × 10^?4 mm ³ /mm (specific wear rate; w _s = 10 ^?6 to 8 × 10^{? 6} mm ² /N) is very high in a severe wear regime at RH levels lower than 10% in air, decreases with increasing RH to a minimum in the middle RH range (30 to 60%), and increases slightly at RH levels higher than 70%. Although the mean contact pressure is very high (31.8 MPa), mild wear with the rates of 10^?8 to 10^?7 mm ³ /mm (w _s = 10^?10 to 10^?9 mm ² /N) occurs in the middle RH range. The same change in wear with RH as that in air is found in argon but the wear rate in argon is slightly lower than the wear rate in air. The height of the pin-lifting, having a wear reduction effect, is greater in argon than in air over almost the whole RH range. The wear rate in deionized water is nearly equal to the rate at 70% RH in air and argon.     

Effect of Tribofilm Formation on the Dry Sliding Friction and Wear Properties of Magnetron Sputtered TiAlCrYN Coatings

Nano-structured TiAlCrYN coatings, grown by unbalanced magnetron sputtering on various steel substrates, exhibited friction coefficients 0.6–0.8 and wear coefficients 10⁻¹⁶–10⁻¹⁵ m³ N⁻¹ m⁻¹ in dry sliding wear tests. This article reports comprehensive worn surface analyses using SEM, TEM, EDX, EELS and Raman spectroscopy. A ~80 nm thick tribofilm formed on the TiAlCrYN worn surface was found to have dense amorphous structure and homogeneous oxide composition of Cr_0.39Al_0.19Ti_0.20Y_0.01O_0.21. Viscous flow of the amorphous tribofilm was dominant in causing the high friction coefficient observed. The coatings showed combined wear mechanisms of tribo-oxidation and nano-scale delamination.     

Friction and Wear of Low-Phosphorus Engine Oils with Additional Molybdenum and Boron Compounds,Measured on a Reciprocating Lubricant Tester

Previous research has already extensively characterized the effects of a variety of engine oils on engine performance. However, low-phosphorus engine oils, which are of growing importance due to the reduction of automotive emissions, have not been studied much. This paper sets forth the results of an initial investigation involving the effects of low-phosphorus engine oils on the friction and wear characteristics of typical engine cylinder kit components from a 3.8-liter, four-cylinder engine. For these tests, sections of molybdenum-coated piston rings were oscillated against segments of production cast iron cylinder bores. The oils were evaluated under two sets of conditions; i.e., the frequency of 20 Hz and a load of 60 N and a frequency of 40 Hz and a load of 120 N. The friction coefficients were continuously recorded, and the wear depths on the cylinder bore segments were measured at the conclusion of each experiment. The oils consisted of low-phosphorus prototype oil (LPPO) containing 0.05 wt% phosphorus, which is half the amount of ZDDP in GF–3 oils, and the LPPO treated with six different supplemental antiwear, anti-friction additives. The remaining additives in the LPPO were present in the amount required for full GF–3 formulation. The supplemental additives were selected to lower friction and replace and/or enhance antioxidant and antiwear properties lost due to lower zinc dithiophosphate (ZDDP) content. The results of low phosphorus concentration oils were compared to the results obtained with formulated ILSAC GF-3 engine oil. The oils that contained organomolybdenum ester showed the greatest benefit in friction reduction in the two different operating conditions. SEM/EDS/XPS surface analyses on the surfaces run with oils containing organomolybdenum ester showed evidence of molybdenum compound formation on the cylinder bore surface. In addition, antiwear film formation mechanisms due to surface interaction among the ZnDTP, organomolybdenum compounds, and metal oxides are discussed.     

转速对三元硼化物基金属陶瓷覆层耐磨性的影响

以Mo粉、FeB合金粉和Fe粉为基本原料,同时加入Cr、Ni、C合金元素成分,采用原位反应真空液相烧结工艺,在Q235钢基体上制备三元硼化物基金属陶瓷覆层材料。利用摩擦磨损试验测试了不同转速下三元硼化物基金属陶瓷覆层材料的耐磨损性能,研究了转速对该覆层材料耐磨性的影响。     

Study of the Influence of Contact Geometry and Contact Pressure on Sliding Distance to Galling in the Slider-on-Flat-Surface Wear Tester

One of the major causes of tool failure in sheet metal forming is wear in the form of galling. Galling is gradual buildup of adhered sheet material on the tool and leads to unacceptable scratches on the sheet surface and to components that fail to meet tolerances. Because it is difficult to reproduce operational and interactional conditions in laboratory test equipments it is hard to test, model, and predict galling initiation.

Here the authors examine how changes from elliptical to line contact geometry influenced galling initiation under dry sliding by using a slider-on-flat surface (SOFS) wear tester. A micro clean tool steel was tested against ferritic low-strength and martensitic high-strength steel sheets.

The sliding distance to galling initiation was extracted from friction data and verified by scanning electron microscopy (SEM) observations. The presence of adhesive wear on worn tools after completed tests was used as a criterion. Experimental results showed that the elliptical contact causes galling quicker than the line contact.

Applicability of experimental results depends on the relevance of test conditions, so contact pressures calculated for the described tests were compared to calculated contact pressures in a semi-industrial U-bending test and to literature data relevant to industrial applications. Good agreement between values observed for SOFS and for most selected industrial applications was found, which assume that contact pressures typical for most common industrial applications can be successfully simulated by selection of tool geometry and normal load in the SOFS tester.     

Effect of Normal Load and Sliding Distance on the Wear Behavior of NiTi Alloy

Effect of normal load and sliding distance on the room temperature dry sliding wear behavior of a Ti-50.3 at% Ni alloy against a bearing steel was studied. The wear tests were conducted using a pin-on-disk tribometer under normal loads of 20, 40, 50, 60 and 80 N for sliding distances up to 1000 m. The wear results showed that the wear rate of NiTi alloy decreased as the normal load increased from 40 N to 60 N. Formation of iron rich tribological oxide layers under the higher loads could be the main reason of decrease in the wear of NiTi alloy. Increasing the sliding distance decreased the wear rate of NiTi alloy under normal loads of 60 N and 80 N, which was attributed to the formation of more stable iron rich tribological oxide layers on the worn surfaces of NiTi alloy.     

超高速滑动电接触CuCrZr合金轨道表面磨损机制及电接触性能

电磁轨道发射具有典型超高速滑动电接触特性（出口速度大于等于2 000 m/s）,电磁轨道表面会发生磨损。为研究轨道表面磨损状态与接触电阻之间关系,通过开展电磁轨道发射试验,研究发射后的CuCrZr轨道表面沉积层的形成与磨损机制,揭示枢轨间静态接触电阻的演变规律,总结沉积层的形成与接触电阻的关联关系。结果表明：沿着发射方向,轨道表面沉积层覆盖面积逐渐增大,沉积层的形成机制由摩擦材料转移变为电枢表面熔化飞溅,表面磨损特征由机械磨损向电气磨损转变;由于轨道不同位置沉积层形成原因不同,导致表面粗糙度分布不一致,枢轨间静态接触电阻随接触沉积层形貌特征改变呈现上升、下降及波动3个变化阶段;并且枢轨间静态接触电阻随着接触压力的增大而减小。研究成果对电磁轨道发射装备的研究及发射动力学研究具有理论价值。     

Impacts of Friction-Modified Fully Formulated Engine Oils on Tribological Performance of Nitrided Piston Rings Sliding against Cast Iron Cylinder Bores

The tribochemical interaction in a nitrided piston ring/cast iron cylinder bore sliding contact with two commercial fully formulated engine oils (ILSAC GF-2 and GF-3 category, referred to as modified GF-2 and modified GF-3, respectively) supplemented with molybdenum dithiocarbamate (MoDTC) friction modifier was investigated in a laboratory bench test. Test results indicated that the modified GF-2 oil could produce a rapid friction reduction while the modified GF-3 oil maintained a stable and lower coefficient of friction (μ = 0.03) for a longer testing time. The modified GF-3 oil also generated a lower wear rate compared with the modified GF-2 oil under the same tribotest conditions. Based on SEM/EDX analyses of wear tracks on the tested tribo-components, it appears that the better formed tribofilm on both the lower and upper specimens by the modified GF-3 oil made a significant contribution to its tribological performance compared with the modified GF-2 oil when sliding under the same test conditions.     

The Effect of Temperature on Tribological Properties of Chemically Modified Bio-Based Lubricant

Vegetable oil has several characteristics that provide advantages for use as lubricant. This includes a high viscosity index, high flash point, high biodegradability, and friction and wear reduction properties. However, vegetable oil has some disadvantages such as low oxidation stability and low thermal stability. The transesterification process of palm oil using trimethylolpropane (TMP) alcohol has been proven to reduce the oxidation stability of vegetable oil. However, little research has been carried out on the effect of TMP ester as a lubricant in term of friction and wear. Therefore, this study investigated the effect of temperature on the tribological properties of TMP ester using a four-ball machine. The load and speed of the sample were set at 40 kg and 1,200 rpm, respectively. Temperature was varied between 50 and 100°C. It was found that TMP ester improved the friction properties by around 15–20%. At low temperature, TMP esters have a higher coefficient of friction (COF) compared to paraffin oil. However, as the temperature increased higher than 80°C, paraffin oil had a highere COF value. This is because at high temperature, the lubricant filmed formed by fatty acids tends to be less stable and breaks down more easily.