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1.
Laser surface texturing (LST) was performed on the nickel-based composites by a Nd:YAG pulsed laser and the regular-arranged dimples with diameter of 150 μm were fabricated on their surfaces. The textured surfaces were smeared with molybdenum disulfide powder. The tribological properties of the textured and filled composites were investigated by carrying out sliding wear tests against an alumina ball as a counterface using a high temperature ball-on-disk tribometer. The tests were conducted at a sliding speed of 0.4 m/s and at normal loads ranging from 20–100 N and from room temperature to 600 °C. The friction coefficient of nickel-based composite textured and smeared with molybdenum disulfide was found to reduce from 0.18 to 0.1 at the temperature range from 200 to 400 °C. The texture with a dimple density of 7.1% was observed to prolong wear life of MoS2 film by more than four times in comparison to the texture with other dimple densities. The lubricious oxide particles stored in the dimples reduce friction coefficient at elevated temperatures and compensate for the extra lubricant owing to the degradation of MoS2 caused by its oxidation at high temperatures.  相似文献   

2.
Prospective beneficial effects of mixtures of temperature-adaptive solid lubricants (ZnO–MoS2) on mechanical and tribological properties of M50 alloy steel were investigated at temperatures from 25 to 800 °C. ZnO and MoS2 were mixed with M50 (designated as M) to create composites MZ (M50 steel plus ZnO), MM (M50 steel plus MoS2), and MZM (M50 steel plus both additives). Sliding friction and wear experiments were performed at different temperatures using a pin-on-disk at a sliding speed of 0.2 m s?1 and a load of 12 N. Silicon nitride and M50 steel were used as the pin materials. In order to understand the friction and wear behavior of composites, analyses of their surfaces were done using XRD, EPMA, FESEM, EDS line/mapping, and XPS tests. A dynamic simulation model based on the finite element method was built to simulate the different stresses on the contact pairs. Results elucidated that MZM attained the least friction (0.17), compared to M (0.40), MZ (0.26), or MM (0.29) at 800 °C. The increase in surface roughness of MZM due to sliding was reduced by 37.3% compared to that of MZ (11.9%) or MM (22.7%). The good lubricating behaviors were referred to the synergetic effects of ZnO, MoS2, and formed lubricating components on worn surfaces.  相似文献   

3.
Due to their thermal stability and high strength, polyimides are an aromatic type of polymer that is used in sliding equipment functioning under high loads and elevated temperature. However, its tribological behaviour under high temperature and atmospheric conditions is not fully understood. It has been reported that a transition from high towards lower friction occurs ‘somewhere’ in the temperature region between 100°C and 200°C; however, a correlation with changes in the polyimide molecular structure remains difficult to illustrate and it is not certain whether or not this transition is correlated to lower wear. In the present work sliding experiments under controlled bulk temperatures between 100°C and 260°C are performed. A transition is observed in both friction and wear at 180°C which is further explained by microscopic analysis of the transfer film on the steel counterface and Raman spectroscopy of the worn polymer surfaces. A close examination of the spectra reveals transitions in relative intensity of certain absorption bands, pointing to different orientation effects of the molecular conformation at the polymer sliding surface at 180°C. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

4.
This study was undertaken to investigate the effect of heat treatments on the high-temperature wear behavior of 60Nitinol. The samples were hot-worked, aged at two temperatures of 400 and 700°C for 1 h and then water quenched. The microstructure of the alloys was investigated by scanning electron microscopy and X-ray diffraction. Sliding wear tests were performed at two temperatures of 25 and 200°C using three types of 60Nitinol disks: hot-worked, aged at 400°C, and aged at 700°C. All wear tests were performed at a speed of 0.3 m/s under a normal load of 60 N for a total sliding distance of 1,000 m using WC-Co pins sliding against 60Nitinol disks. The worn surfaces and microstructure of the subsurfaces were studied by scanning electron microscopy. Compression and hardness tests were also performed to characterize the mechanical properties of the alloys. The highest fracture strain and lowest hardness were obtained for the sample aged at 700°C that contained Ni3Ti2 precipitants. This sample also showed the maximum wear resistance at a wear testing temperature of 200°C. This was attributed to the formation of a more compact and stable tribological layer on the worn surface of the softer sample.  相似文献   

5.
In this study, we investigated the effect of temperature on the friction and wear of rice bran (RB) ceramics, a hard porous carbon material made from rice bran, sliding against alumina, stainless steel, and bearing steel balls under dry conditions. Friction tests were performed using a ball-on-disk-type friction tester wherein a ceramic heater was installed in the rotational stage. The surface temperature of the RB ceramic disk specimens was controlled at 20, 100, 150, or 200°C. The normal load was 1.96 N, sliding velocity was 0.1 m/s, and number of cycles was 20,000. The effect of surface temperature on the friction and wear of RB ceramics substantially differed among the ball material types. The friction coefficient for the RB ceramics sliding against an alumina ball decreased with increasing temperature and exhibited an extremely low value (0.045) at 200°C. The friction coefficient in the case of the RB ceramics sliding against a stainless steel ball exhibited a stable value as the temperature was increased to 150°C and slightly decreased as the temperature was increased further, reaching a low value of 0.122 at 200°C. The friction coefficient for the RB ceramics sliding against bearing steel ball drastically increased with increasing temperature, reaching 0.381 at 200°C. The specific wear rate of the RB ceramics increased with increasing temperature; it was lowest when sliding against alumina and highest when sliding against bearing steel. The wear of the alumina ball was the lowest and that of the bearing steel ball was the highest under all investigated temperature conditions. On the basis of these results, we concluded that alumina is a promising counterpart material for RB ceramics sliding at high temperatures (≤200°C).  相似文献   

6.
Abstract

Tribological systems working under severe conditions like high pressures, sliding velocities and temperatures are subjected to different phenomena such as wear, oxidation and changes in mechanical properties. In many cases, there are several mechanisms occurring simultaneously. The predominating type(s) of wear mechanism(s) presented will depend on the materials in contact, operating parameters and surrounding environment. In this work, high temperature tribological studies of boron steel sliding against tool steel were conducted using a pin-on-disc machine under unlubricated conditions at five different temperatures ranging from 25 to 400°C, three different loads: 25, 50 and 75 N (contact pressures of 2, 4 and 6 MPa respectively) and a sliding speed of 0·2 ms?1. Scanning electron microscopy/energy dispersive spectroscopy and X-ray techniques were used for analysing the resulting damage and tribolayers of the worn surfaces. Additionally, hardness measurements were carried out in a special hot hardness rig in the same temperature range as that used in pin-on-disc tests. The results have shown that for a given load, the wear rate of boron steel decreased as the temperature increased, reaching its lowest value at 400°C at 50 N. In the case of the tool steel, it could be observed that at 200°C and above, the wear rate decreased as the load increased. This behaviour is consistent with the formation of a protective oxidised layer initiated at 100°C. At higher temperatures, such layers become more pronounced. The obtained data were finally used to construct a friction and wear mechanism map for this material pair that takes temperature and pressure into account.  相似文献   

7.
Ionic liquids have properties that make them attractive as solvents for many chemical synthesis and catalysis reactions. Consequently, research has focused on their application as advanced solvents. Recently, ionic liquids were shown to have promise as a lubricant due to many of the same properties that make them useful as solvents. The focus of this paper is to study the surface chemistry of ionic liquid lubricated steel in sliding contact to temperatures from room to 300 °C. Tribological properties were evaluated using a pin on disk tribometer with high temperature capability (up to 800 °C). Chemistry was studied using Mössbauer spectroscopy and X-ray photoelectron spectroscopy. Samples used for tribological evaluation were 1 inch diameter polished M50 disks. Samples used for studying the surface chemistry were enriched 57Fe grown via thermal evaporation. Some 57Fe samples were oxidized to Fe2O3 and Fe3O4 prior to treatment with ionic liquids. The metallic and oxidized 57Fe samples were then reacted with ionic liquids at elevated temperatures. Three ionic liquids were used in this study; 1-n-ethyl-3-methylimidazolium tetrafluoroborate (BF4), 1,2-di-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide (TFMS), and 1,2-di-methyl-3-butylimidazolium hexafluorophosphate (PF6). This study was focused on understanding the high temperature stability of the liquids in contact with metal and under tribological stress. Therefore, the friction data was collected in the boundary (or mixed boundary/EHL) lubrication region to enhance surface contact. BF4 provided a friction coefficient of 0.04 for both the room and 100 °C tests and varied between 0.07 and 0.2 for the 300 °C test. The results from TFMS lubrication showed a friction coefficient of 0.025 at room temperature and 0.1 at 100 °C. The 300 °C test friction coefficient ranged between 0.1 and 0.3. Chemical analysis of the surface revealed corrosion of the surface due to reaction between the ionic liquids and steel/iron substrates.  相似文献   

8.
Semi-interpenetrating network composites containing 40 vol.% ceramics (5Al2O3·8SiO2) and 60 vol.% Al-alloy were fabricated in place of cast iron available for automotive brake rotors. The friction and wear performances of brake pads dry sliding against the composites were measured using a SRV testing machine. The test procedures include friction fade and recovery, load sensitivity at 100 and 250°C, and wear. The friction was found to increase first and then decrease with increasing temperature, followed by the inverse recovery upon cooling. Wear showed an incremental tendency over a wide temperature range. For loads from 40 to 160 N, the friction decreased at 100 and 250°C. At load below 128 N, the former friction was inferior to the latter while at load above 128 N the friction exhibited an inverse tendency. Wear mildly increased with load at 100 °C and decreased dramatically at 250 °C. SEM and EDS investigations revealed that the worn pad surfaces at 250 °C were covered by more tribofilms, including more coke and graphite with friction-reducing action as well as fewer compounds (corresponding to Si and Al) with friction-increasing action in comparison with those at 100 °C. The compression of the tribofilms contributed to a large decrease in the friction and wear with increasing load. However, at 100 °C E-glass fibers exposed at the worn surfaces inhibited the excessive wear of the pad despite lack of more tribofilms. Their glossy surfaces decreased the friction. The proposed friction models explain some friction and wear behaviour better.  相似文献   

9.
The influence of only water addition on the hot metal forming process has not yet been reported in regard to tribological performance. In the present study, simulation tests were carried out on a pin-on-disc tribometer to evaluate the effects of water lubrication on the wear and friction behaviors of interstitial free (IF) steel sliding against different countersurface materials at 800°C in comparison with those in dry sliding. The opposing materials were selected as GCr15 steel and ceramic-based compounds including ZrO2, SiC, and Si3N4. It has been found that Si-based component–IF steel pairs exhibit the lowest wear losses despite achieving relatively high friction. Water addition adversely impairs the friction and wear characteristics on steel-steel tribopairs, whereas it shows insignificant effects on the pair involving ceramic-based components except ZrO2. Varying tribological responses can be found among different mated surfaces under water lubrication. X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy were utilized to examine the worn surface. The acting mechanism of water addition for different rubbing pairs was further discussed from the aspects of oxide tribochemistry.  相似文献   

10.
The antiwear properties of five zinc dialkyldithiophosphates, which differed in thermal stability, were evaluated in a 4-ball machine by a preliminary wear track formation method. After testing the additives, the wear resistance of the films formed was measured by the increase in preliminary wear scar diameter over that of the additive-free oil. IR spectroscopy was then used to study the transformation products of additives after thermostatic testing at between 100 and 240°C on steel surfaces, where the interaction products were evaluated by electrode potential method. The interaction of the decomposition products of dithi-ophosphates with metal surfaces was found to be followed by a change in electrode potential. For the tested additives, a relationship is shown between antiwear effectiveness of the film on a friction track during tribological tests and the electrode potential value of the steel sample. Different parts of the relationship between the electrode potential and temperature relate to different stages of dithiophosphate decomposition measured by IR spectroscopy. It can be said that chemical modification of the steel surface which produces an improvement of antiwear properties, starts at the decomposition temperature of the dithiophosphate neutral salt.  相似文献   

11.
A sputter-deposited bilayer coating of gold and chromium was investigated as a potential solid lubricant to protect alumina substrates in applications involving sliding at high temperatures. The lubricant was tested in a pin-on-disk tribometer with coated alumina disks sliding against uncoated alumina pins. Three test parameters—temperature, load and sliding velocity—were varied over a wide range in order to determine the performance envelope of the Au/Cr solid lubricant film. The tribo-tests were run in air at temperatures of 25° to 1000°C, under loads of 4.9 to 49.0 N and at sliding velocities from 1 to 15 ms?1. Posttest analyses included surface profilometry, wear factor determination and SEM/EDS examination of worn surfaces.

Compared to unlubricaled Al2O3 sliding, the use of the Au/Cr film reduced friction by 30 to 50 percent and wear by one to two orders of magnitude. Increases in test temperature resulted in lower friction and the Au/Cr film continued to provide low friction, about 0.3, even at 1000°C. Pin wear factors and friction were largely unaffected by increasing loads up to 29.4 N. Sliding velocity had essentially no effect on friction, however, increased velocity reduced coaling life (total sliding distance). Based upon these research results, the Au/Cr film is a promising lubricant for moderately loaded, low-speed applications operating at temperatures as high as 1000°C.  相似文献   

12.
Semi-interpenetrating network composite containing 33 vol% ceramics (5Al2O3·8SiO2) and 67 vol% Al-alloy dry sliding against Cr12 cold-work die steel was measured on a SRV4 testing machine. The test procedures include the load sensitivities of the friction and wear at 70 °C and 270 °C. Test results show that the friction and wear decreased with the increase of load, whereas the specific energy conversion per countermaterial surface unit increased. The friction level and the specific energy conversion at 70 °C were superior to those at 270 °C. Scanning electron microscopy and energy dispersive X-ray spectroscopy analysis revealed at 270 °C the existence of the thicker tribofilms and, with them, more Fe oxides and less Al oxide at the worn composite surfaces in comparison with those at 70 °C. A good accordance was obtained between test and analysis results.  相似文献   

13.
In this present work, the in situ Al (A380)/5 wt%TiB2 composites were fabricated through salt–melt reaction using halide salts such as potassium hexafluorotitanate (K2TiF6) and potassium tetra fluoroborate (KBF4) salts as precursors. The composites were produced at four different melt temperatures (700, 750, 800, 850 °C). The formation of particle was confirmed from XRD results. The wear behaviour of Al/5 wt% TiB2 composite was investigated by varying the wear test parameters such as sliding temperature (25, 100, 150, 200 °C), applied load (10, 20, 30, 40 N), sliding velocity (0.4, 0.7, 1, 1.3 m/s). The microstructure of Al/5 wt% TiB2 composite was correlated with the wear characteristics of the composites. The wear resistance of Al/5 wt% TiB2 composite was significantly improved due to the presence of TiB2 particle in Al matrix material. The composite produced at melt temperature 800 °C showed a higher wear resistance at applied load: 10 N, sliding temperature: 25 °C and sliding velocity: 0.7 m/s. The wear mechanism for each of the tested condition was identified from the worn surfaces using scanning electron microscopy (SEM). ANOVA test was carried out to find out significant factor for the wear resistance of composite. The checking of adequacy of experimental value for the wear behaviour of composite for different testing condition was analysed by residual plots using statistical software.  相似文献   

14.
SEM tribometric experiments were performed with Si(100) vs. Si(100) interfaces in mode-rate vacuum to 850°C. The results are compared with similar tests previously completed with fine-cauliflowered PCD (PCDfcf) mated against itself, and polished C(100)-textured polycrystalline diamond (PCDC(100)) sliding against Si(100). All data agree with a hypothesis connecting the thermal desorption of adsorbates and wear with the generation of dangling bonds on the sliding surfaces. Linking of the counterfaces by the free radicals appears to be the main cause of high adhesion and friction. The high friction can be drastically reduced by dissociative chemisorption of certain passivating gaseous species condensing at sufficiently low surface temperatures. Strong circumstantial evidence continues to mount for the incremental reduction in high temperature friction being caused by surface reconstruction. Deconstruction of the sliding surfaces and the reemergence of high friction eventually occurs on discontinued heating, until the adsorbates chemisorb on the cooled surfaces. There, the friction drops to a level determined by the characteristic shear strength of the interfaces and the wear-induced increase in the real area of contact. The maximum friction measured at high temperatures in vacuum, indicative of the most intensive interaction of dangling bonds at the interface, scaled only approximately with the 1.8 times strength of the C-C versus the Si-Si bonds. The 1.6 experimental ratio is lower than the theoretical, reflecting the broad distribution of dangling bond energies (densities of surface trap states) for PCD and even for polished Si(100). The wear rate of Si(100) sliding against itself is about four-orders-of-magnitude higher (~ 2 × 10-12 m3/(Nm)) than that of unpolished PCDfcf vs. itself (4 × 10-16 m3/(Nm)) or rough and unpolished PCDC(100) wearing its polished version (8.5 × 10-16 m3/(Nm)).  相似文献   

15.
The effect of 10 wt% VC addition on the friction and sliding wear response of WC–12 wt% Co cemented carbides produced by spark plasma sintering (SPS) was studied. The SPS of WC–12 wt% Co alloys with and without 10 wt% VC, at 1100 and 1130°C, respectively, yielded dense materials with minimal porosity. No eta phase was found in any of the alloys. The WC–12 wt% Co–10 wt% VC alloy showed the formation of a hard WV4C5 phase, which improved the alloy's hardness. Friction and dry sliding wear tests were done using a ball-on-disk configuration under an applied load of 10 N and sliding speed of 0.26 m.s?1, and a 100Cr-steel ball was used as the counterface. A significant improvement in the sliding wear response of the harder and more fracture tough WC–12 wt% Co–10 wt% VC alloy compared to the WC–12 wt% Co alloy was found. Analysis of the worn surfaces by scanning electron microscopy showed that the wear mechanisms included plastic deformation, preferential binder removal, adhesion, and carbide grain cracking and fragmentation.  相似文献   

16.
Sliding friction tests of pin-on-disc type were carried out for carbon steel, pure iron and pure copper, and the microstructure and hardness near the sliding surfaces were investigated in detail. It was found that patchy transfer layers with ultra-fine (<200 nm) structures were produced on the disc surfaces. Nanocrystalline grains of 30–50 nm were identified for carbon steel, and submicron sized grains of 100–150 nm were observed in pure copper. The thicknesses of the ultra-fine structures were in the range of 10–50 μm, depending on the specimen material, sliding speed and applied load. The hardness near the sliding surface of pure iron was increased compared with the matrix. It was suggested that the hardening was due to the very fine structure formed by severe plastic deformation, but not due to phase transformation caused by thermal effects.  相似文献   

17.
The ability to tune friction by tailoring surface topographies at micron length scales and by changing the relative orientation of crystallites at the atomic scale is well established. Here, we investigate if the two concepts combine, i.e. if the relative orientation of surfaces affects dry friction between laser-textured surfaces. Laser patterning was used on austenitic stainless steel substrates and on tribometer testing balls made of 100Cr6 to create linear periodic arrays with different structural wavelengths or periodicities (5, 9 and 18 ??m). Pairing each substrate with a ball of the same periodicity, the different arrays were subjected to dry sliding tests at 0°/90° relative alignment between the linear patters. We observe that the patterning reduces friction after running-in. The reduction increases with decreasing wavelength and also depends sensitively on the relative alignment and the chemistry of the sliding surfaces. Our results highlight the possibility to create tailored contacting surface geometries leading to tunable frictional properties.  相似文献   

18.
In this study, the authors investigated the tribological properties of hard diamondlike carbon (DLC) films on magnesia-partially stabilized zirconia (MgO-PSZ) substrates over a wide range of bads, speeds, temperatures, and counterface materials. The films were 2 μm thick and produced by ion-beam deposition at room temperature. Tribological tests were conducted on a ball-on-disk machine with MgO-PSZ balls, in open air of 30 to 50% relative humidity under contact loads of 1 to 50 N, at sliding velocities of 0.1 to 6 m/s, and at temperatures of 400°C. Al2O3 and Si3N4 balls were also rubbed against the DLC-coaled MgO-PSZ disks, primarily to assess their friction and wear performance and to compare it with that of MgO-PSZ balls. A series of long-duration lifetime tests was run at speeds of 1, 2, and 6 m/s under a 5 N load to assess the durability of these DLC films. Results showed that the friction coefficients of MgO-PSZ balls sliding against MgO-PSZ disks were 0.5-0.8, and the average specific wear rates of MgO-PSZ balls ranged from 1 × 10?5 to 5 × 10?4 mm3/N·m, depending on sliding velocity, contact load, and ambient temperature. The friction coefficients of MgO-PSZ balls sliding against the DLC-coaled MgO-PSZ disks ranged from 0.03 to 0.1. The average specific wear rates of MgO-PSZ, balls were reduced by three to four orders of magnitude when rubbed against the DLC-coaled disks. These DLC films could last 1.5 to 4 million cycles, depending on sliding velocity. Scanning electron microscopy and micro-laser Raman spectroscopy were used to elucidate the microstructural and chemical nature of the DLC films and worn surfaces.  相似文献   

19.
A test program to determine the relative slitting durability of an alumina-silica candidate ceramic fiber for high temperature sliding seal applications is described. Pin-on-disk tests were used to evaluate the potential seal material by sliding a tow or bundle of the candidate ceramic fiber against a superalloy test disk. Friction was measured during the tests and fiber wear, indicated h the extent of fibers broken in the tow or bundle, was measured at the end of each test. Test variables studied included ambient temperature from 25° to 900°C, loads from 1.3 to 21.2 N, and sliding velocities from 0.025 to 0.25 m/sec. In addition, the effects of fiber diameter and elastic modulus on friction and wear were measured. Thin gold films deposited on the superalloy disk surface were evaluated in an effort to reduce friction and wear of the fibers.

In most cases, wear increased with test temperature. Friction ranged from 0.36 at 500°C and low velocity (0.025 miser) to over 1.1 at 900°C and high velocity (0.25 m/sec). The gold films resulted in satisfactory lubrication of the fibers at 25°C. At elevated temperatures diffusion of substrate elements degraded the films. These results indicate that the alumina-silica (Al2O3SiO2) fiber is a good candidate material system for high temperature sliding seal applications. More work is needed to reduce friction.  相似文献   

20.
The results of experimental investigations on the effect of the oil pockets existence on seizure resistance of sliding elements are presented. Seizure tests were conducted with block-on-ring apparatus at increasing pressure. The stationary block (counter specimen) contacted the rotating steel ring (specimen). The tested assemblies were lubricated by oil L-AN 46, which was heated to 30 °C before each experiment. The sliding was unidirectional. The block was a part of a bearing sleeve-hardened EN-GJS 400-15 cast iron with a hardness value of 50 HRC. The ring samples, 35 mm in diameter, were made from hardened 42CrMo4 steel of hardness 32 HRC. The friction force and temperature near the contact zone were measured during the tests. Some variants of specimen surfaces were created by burnishing technique. They were characterised by the oil pocket density, the holes depth, length, and width. The oil pockets existence of area density of 10% on the ring surface improved seizure resistance of the sliding pair steel-cast iron for speed of 0.27 m/s. The pit shape and orientation are very important, too.  相似文献   

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