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Tao Li Yulei Zhang Yanqin Fu Jia Sun Jie Li 《Journal of the European Ceramic Society》2021,41(10):5046-5055
Carbon/carbon (C/C) composites have a wide application as the thermal structure materials because of their excellent properties at high temperatures. However, C/C composites are easily oxidized in oxygen-containing environment, which limits their potential applications to a great degree. Silicon carbide (SiC) ceramic coating fabricated via pack cementation (PC) was considered as an effective way to protect C/C composites against oxidation. But the mechanical properties of C/C composites were severely damaged due to chemical reaction between the molten silicon and C/C substrate during the preparation of SiC coating by PC. In order to eliminate the siliconization erosion, a pyrolytic carbon (PyC) coating was pre-prepared on C/C composites by the chemical vapor infiltration (CVI) prior to the fabrication of SiC coating. Due to the retardation effect of PyC coating on siliconization erosion, the flexural strength retention of the SiC coated C/C composites with PyC coating increased from 46.27 % to 107.95 % compared with the specimen without PyC coating. Furthermore, the presence of homogeneous and defect-free PyC coating was beneficial to fabricate a compact SiC coating without silicon phase by sufficiently reacting with molten silicon during PC. Therefore, the SiC coated C/C composites with PyC coating had better oxidation resistances under dynamic (between room temperature and 1773 K) and static conditions in air at different temperatures (1773?1973 K). 相似文献
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《Ceramics International》2017,43(11):8208-8213
In order to improve the oxidation behavior of carbon/carbon composites in a wide range of temperature, a new SiC/glaze-precursor coating was developed.The SiC layer was produced by slurry and sintering, while the glaze precursor layer was prepared by slurry and drying. The microstructures and phase compositions of the coating were analyzed by SEM and XRD, respectively. The oxidation resistance of the coated composites was investigated using both isothermal and temperature-programmed thermogravimetric analysis in the temperature range from room temperature to 1600 °C. The results showed that the oxidation behavior of the coating was mainly controlled by the diffusion of oxygen during the test.The coating showed excellent oxidation resistance and self-healing ability in a wide range of temperature. 相似文献
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Xuanru Ren Hejun Li Qiangang Fu Yanhui Chu Kezhi Li 《Journal of the European Ceramic Society》2013,33(15-16):2953-2959
To improve the oxidation resistance of the carbon/carbon (C/C) composites, a TaB2–SiC–Si multiphase oxidation protective ceramic coating was prepared on the surface of SiC coated C/C composites by pack cementation. Results showed that the outer multiphase coating was mainly composed of TaB2, SiC and Si. The multilayer coating is about 200 μm in thickness, which has no penetration crack or big hole. The coating could protect C/C from oxidation for 300 h with only 0.26 × 10?2 g2/cm2 mass loss at 1773 K in air. The formed silicate glass layer containing SiO2 and tantalum oxides can not only seal the defects in the coating, but also reduce oxygen diffusion rates, thus improving the oxidation resistance. 相似文献
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《Journal of the European Ceramic Society》2021,41(13):6151-6159
To improve the oxidation resistances of SiC coated C/C composites by a pack cementation (PC) method at high temperature and alleviate the siliconization erosion of molten silicon on C/C substrate during the preparation of SiC coating, a SiO2-SiC reticulated layer with SiC nanowires was pre-prepared on C/C composites through combined slurry painting and thermal treatment before the fabrication of SiC coating. The presence of porous SiO2-SiC layer with SiC nanowires was beneficial to fabricate a compact and homogeneous SiC coating resulting from synergistic effect of further reaction between SiO2 and pack powders and the reinforcement of SiC nanowires. Therefore, the results of thermal shock and isothermal oxidation tests showed that the mass loss of modified SiC coating was only 0.02 % after suffering 50-time thermal cycles between room temperature and 1773 K and decreased from 5.95 % to 1.08 % after static oxidation for 49.5 h in air at 1773 K. Moreover, due to the blocking effect of SiO2-SiC reticulated layer on siliconization erosion during PC, the flexural strength of SiC coated C/C composites with SiO2-SiC reticulated layer increased by 64.8 % compared with the untreated specimen. 相似文献
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《Ceramics International》2018,44(10):11448-11455
In order to improve the interlaminar shearing strength of carbon fiber/pyrolytic carbon (Cf/PyC) composites, SiC nanowires (SiCNWs) growing at different positions were introduced into carbon fiber/pyrolytic carbon composites to generate carbon fiber-SiC nanowire/pyrolytic carbon (Cf-SiCNWs/PyC) composites. Cf-SiCNWs/PyC composites were prepared by sol-gel and isothermal chemical vapor infiltration (ICVI) method. The morphology, microstructure and compositions of composites were investigated by SEM, TEM, XRD and XPS. The interlaminar shearing strength was tested and the effect of SiCNWs growth positions on the interlaminar shearing strength was investigated. The results showed that SiCNWs were consisted of perfect single crystalline structure of β-SiC with diameter of 160–200 nm. The SiCNWs could grow at four kinds of positions to combine with carbon fibers to form multi-scaled reinforcements (micro-scaled carbon fibers and nanoscaled SiCNWs). The interlaminar shear strength of Cf-SiCNWs/PyC composites were increased by 78% compared with Cf/PyC composites without SiCNWs. The improvement of interlaminar shear strength was attributed to bridging and pull-out of multi-scaled reinforcements composed of carbon fibers and SiCNWs as well as the enhancement of fiber/matrix interface bonding generated by SiCNWs growing at different positions. 相似文献
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Xiaofei Zhu Yulei Zhang Yangyang Su Yanqin Fu Pei Zhang 《Journal of the European Ceramic Society》2021,41(1):114-120
To improve the oxidation resistance of carbon/carbon (C/C) composites at high temperatures, a SiC-Si coating with micro-pores was prepared by slurry and heat-treatment on the surface of C/C composites with SiC-Si inner coating acquired by pack cementation (PC). The microstructure, phase composition, element distribution, and anti-oxidation properties of the dual-layer SiC-Si coating were investigated. The results show that a SiO2-SiC inlay structure was formed during the oxidation process, due to a large amount of SiO2 rapidly generated by the oxidation of SiC particles in the porous coating. The coating with this structure could inhibit the cracking of SiO2 glass and had a good resistance to oxygen diffusion. Moreover, the crack propagation was blocked by the remaining micro-pores of the coating. The coating could protect C/C composites against oxidation for 846 h only with the mass loss of 0.16 % at 1773 K in air. 相似文献
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SiC coating was deposited on carbon/carbon (C/C) composites by chemical vapor deposition (CVD). The effects of elevated temperatures on tribological performance of SiC coating were investigated. The related microstructure and wear mechanism were analyzed. The results show that the as-deposited SiC coating consists of uniformity of β-SiC phase. The mild abrasive and slight adhesive wear were the main wear mechanisms at room temperature, and the SiC coating presented the maximum friction coefficient and the minimum wear rate. Slight oxidation of debris was occurred when the temperature rose to 300?°C. As the temperature was above 600?°C, dense oxide film formed on the worn surface. The silica tribo-film replaced the mechanical fracture and dominated the frication process. However, the aggravation of oxidation at elevated temperatures was responsible for the decrease of friction coefficient and the deterioration of wear rate. The SiC coating presented the minimum friction coefficient and the maximum wear rate when the temperature was 800?°C. 相似文献
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To reduce the residual thermal stress between the carbon fiber-reinforced carbon (C/C) composites and the SiC coating layer, functionally graded materials (FGM) consisting of a C/SiC compositionally graded layer (C/SiC interlayer) were adopted. After designing the compositional distribution of the C/SiC interlayer which can relieve the thermal stress effectively, the deposition conditions of the entire compositional range of the C/SiC composites were determined using a thermodynamic calculation. According to the design and calculation the C/SiC interlayer and the SiC outer layer were deposited on the C/C composites by a low pressure chemical vapor deposition (LPCVD) method at deposition temperatures of 1100 and 1300 °C. The stress calculation and the experimental results suggested that the SiC-rich compositional profile in the FGM layer is the most effective for relieving the thermal stress and increasing the oxidation resistance. 相似文献
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In order to exploit the unique high temperature mechanical properties of carbon/carbon (C/C) composites, a new type of oxidation protective coating has been produced by a two-step pack cementation technique in an argon atmosphere. XRD analysis showed that the internal coating obtained from the first step was a gradient SiC layer that acts as a buffer layer, and the multi-layer coating formed in the second step was an Al2O3-mullite layer. It was found that the as-received coating characterized by excellent thermal shock resistance on the surface of C/C composites during exposure to an oxidizing atmosphere at 1873 K, could effectively protect the C/C composites from oxidation for 45 h. The failure of the coating is due to the formation of bubble holes on the coating surface. 相似文献
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《Ceramics International》2017,43(2):1722-1730
To protect carbon/carbon composites (C/Cs) against oxidation, SiC coating toughened by SiC nanowires (SiCNWs) and carbon nanotubes (CNTs) hybrid nano-reinforcements was prepared on C/Cs by a two-step technique involving electrophoretic co-deposition and reactive melt infiltration. Co-deposited SiCNWs and CNTs with different shapes including straight-line, fusiform, curved and bamboo dispersed uniformly on the surface of C/Cs forming three-dimensional networks, which efficiently refined the SiC grains and meanwhile suppressed the cracking deflection of the coating during the fabrication process. The presence of SiCNWs and CNTs contributed to the formation of continuous glass layer during oxidation, while toughed the coating by introducing toughing methods such as bridging effect, crack deflection and nanowire pull out. Results showed that after oxidation for 45 h at 1773 K, the weight loss percentage of SiC coated specimen was 1.35%, while the weight gain percentage of the SiCNWs/CNTs reinforced SiC coating was 0.03052% due to the formation of continuous glass layer. After being exposed for 100 h, the weight loss percentage of the SiCNWs/CNTs reinforced SiC coating was 1.08%, which is relatively low. 相似文献
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《Ceramics International》2017,43(18):16512-16517
In order to improve the thermal shock resistance of the coated carbon/carbon (C/C) composites, a mullite whisker toughened mullite coating was fabricated on the surface of SiC pre-coated C/C composites (SiC-C/C) by molten-salt method with a later hot dipping process. The phase compositions, surface and cross-section microstructures, high temperature thermal shock resistance of the as-prepared multi-layer coatings were investigated. Results show that the introduction of mullite whiskers can effectively improve the density of the mullite outer coating and decrease the cracking of the coating during the thermal shock cycle process. After 100 times thermal shock cycles between 1773 K and room temperature, only 1.87 × 10−3 g cm−2 weight loss has been detected, indicating the achievement of the excellent thermal shock resistance. 相似文献
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《Ceramics International》2017,43(12):8989-8998
Cobalt (Co) was chosen as an additive to improve the ablation resistance of WC coating for SiC coated C/C composites, SiC modified WC coating and pure WC coating which were prepared and tested for comparative purposes. Results showed that the thermal shock resistance of WCC (WC-10%Co) coating was better than pure WC coating and WCS (WC-10%SiC) coating. Furthermore, the produced oxide layer on WCC coating was found to be more stable due to the reaction of CoO and WO3. As a result, during oxyacetylene torch ablation test, compared with pure WC coating and WCS coating, WCC coating keeps excellent dimensional stability with the linear ablation rate decreased by 67% and 62%, respectively, showing a significant improvement of the ablation resistance. 相似文献
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Peipei Wang Mingde Tong Hanhui Wang Hejun Li Yujun Jia Bo Li Yulei Zhang Zhigang Zhao 《Ceramics International》2018,44(17):20968-20973
The gradient HfB2 modified SiC coating was prepared on the surface of SiC-coated C/C composites by in-situ synthesis. Anti-oxidation behaviors of the coated C/C samples at 1773, 1873 and 1973?K were investigated. The results show that the gradient HfB2 modified SiC coatings possess excellent oxidation resistance, which can protect C/C substrates from oxidation for 800, 305 and 100?h at 1773, 1873 and 1973?K, respectively. In addition, with the oxidation temperature increasing, the evaporation of the Hf-Si-O glass layer and the active oxidation of SiC were accelerated, which is the reason for the worst oxidation resistance of the sample at 1973?K among the three temperatures. 相似文献
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《Ceramics International》2017,43(15):12005-12012
To improve the ablation resistance of SiC coating, HfB2-SiC coating was prepared on SiC-coated carbon/carbon (C/C) composites by in-situ reaction method. Owing to the penetration of coating powders, there is no clear boundary between SiC coating and HfB2-SiC coating. After oxyacetylene ablation for 60 s at heat flux of 2400 kW/m2, the mass ablation rate and linear ablation rate of the coated C/C composites were only 0.147 mg/s and 0.267 µm/s, reduced by 21.8% and 60.0%, respectively, compared with SiC coated C/C composites. The good ablation resistance was attributed to the formation of multiple Hf-Si-O glassy layer including SiO2, HfO2 and HfSiO4. 相似文献
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For extending application of TaSi2 in complex coating system, the ablation behavior and thermal protection performance of TaSi2 coating is studied to evaluate its potential applications for anti-ablation protection of C/C composites. TaSi2 coating is prepared by supersonic atmospheric plasma spraying (SAPS) on the surface of SiC coated carbon/carbon (C/C) composites. Phase variation and microstructure are characterized by XRD and SEM, respectively. During the ablation process, the coating is quickly oxidized to SiO2 and Ta2O5 accompanied by a lot of heat consumption. The linear and mass ablation rates are 0.9?µm?s?1 and ??0.4?mg?s?1 after ablation for 80?s, respectively Results show that the prepared coating possesses optimal ablation performance under the heat flux of 2.4?MW/m2. Moreover, the TaSi2 coating and SiC inner coating have good chemical and physical compatibility during the ablation process. Therefore, the excellent performance of TaSi2 coating during the ablation process makes it a candidate for anti-ablation protection for C/C composites. 相似文献
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《Ceramics International》2016,42(13):14518-14525
To improve the oxidation resistance of carbon/carbon (C/C) composites, a dense HfC nanowire-toughened Si-Mo-Cr/SiC multilayer coating was prepared by chemical vapor deposition (CVD) and pack cementation. The microstructure, thermal shock and isothermal oxidation resistance of the coating were investigated. HfC nanowires could improve the toughness of the coating and suppress the coating cracking. After incorporating HfC nanowires in the coating, both of the thermal shock and isothermal oxidation resistance of the coating were obviously improved. The multilayer coating with HfC nanowires could effectively protect C/C composites at 1773 K for 270 h, whose weight loss is only 0.19%. The good oxidation resistance is mainly attributed to the formation of a compound glass layer containing SiO2 and Cr2O3. 相似文献