共查询到17条相似文献,搜索用时 312 毫秒
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聚氧乙烯醚类表面活性剂生物降解度测定方法的改进 总被引:1,自引:2,他引:1
对聚氧乙烯醚类非离子表面活性剂生物降解度的测定方法———硫氰酸钴法进行了改进:三氯甲烷取代苯作为萃取剂;萃取次数从1次增加到3次;硫氰酸钴与表面活性剂的络合反应时间为15 min。实验结果表明:重复性实验的相对标准偏差<6.0%;对AEO7、Tween85和AEO30的平均回收率在97%~104%,相对标准偏差<4.0%。对原方法不宜测定的一些类型的聚氧乙烯醚类非离子表面活性剂的生物降解度进行测定,结果表明:对单EO链、单烷基链非离子表面活性剂,EO数从3~12可扩大到3~30,并能测定多个EO链、多个烷基链聚氧乙烯醚类非离子表面活性剂的生物降解度。 相似文献
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《中国洗涤用品工业》2017,(8)
简述了表面活性剂对环境的影响及研究进展。着重讨论了表面活性剂的研究方法及表征,各种生物降解过程、降解机理和影响表面活性剂生物降解的因素。并对表面活性剂的安全性及毒性、温和性及对皮肤和黏膜的刺激性进行了简要介绍。 相似文献
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Torben Madsen Gitte Petersen Connie Seierø Jens Tørsløv 《Journal of the American Oil Chemists' Society》1996,73(7):929-933
The environmental properties of three glycoside surfactants and one alcohol ethoxylate were examined by standardized laboratory
methods. All of the surfactants biodegraded extensively in aerobic screening tests and may be assumed to approach 100% removal
in aerobic wastewater treatment plants, except in cases of high loadings or otherwise exceptional conditions. Anaerobic biodegradability
tests showed that an ethyl glycoside monoester (EGE) and a linear alkyl polyglycoside (APG) were both mineralized (>70%) under
methanogenic conditions. In contrast, a branched APG resisted anaerobic degradation, while the alcohol ethoxylate was partially
mineralized by anaerobic bacteria. The EGE surfactant was most rapidly mineralized in aerobic and anaerobic biodegradability
tests. None of the surfactants inhibited respiration in activated sludge at the highest concentration tested (200 mg/L). Tests
with aquatic organisms showed increasing toxicity in the following order: branched APG<EGE<linear APG<alcohol ethoxylate.
Negligible aquatic toxicity was observed for the branched APG, while the alcohol ethoxylate was highly toxic to examined organisms.
This evaluation demonstrates that considerable variation in biodegradability and toxicity responses can be seen within structurally
related glucose-based surfactants. 相似文献
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烷基苯磺酸盐的生物降解性与其结构及降解时间的关系研究 总被引:5,自引:0,他引:5
运用拓扑指数研究方法,证明阴离子表面活性剂烷基苯磺酸盐系列化合物的生物降解性与其结构及降解时间之间具有明显的相关性,通过回归分析得到降解性(Y)与分子二阶连接性指数(2Xn)及降解时间(T)的相关模型方程式,其复相关系数R>0.09,标准偏差E=1.131,平均标准偏差D=0.017,在传统的单变量QSBR-表面活性剂生物降解与其结构之间的定量关系研究中引入第二变量时间因子,是一种新的尝试,补充和完善了QSBR,提高了结果的合理性和准确性,也扩大了其适用范围,为众多的同名系列化合物生物降解性的预测和评价提供了一种新的方式和手段。 相似文献
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The primary aerobic biodegradation of several cationic and amphoteric surfactants has been studied by using the shaking-flask
degradation test and orange II spectrophotometric analysis. The results show that cationic and amphoteric surfactants can
be readily biodegraded, with their degradation exceeding 94%. The degradation kinetics can be accurately described by the
Boltzmann model. The relationship between structure and biodegradability is discussed. The presence of hydrophobic groups
has a strong effect on the biodegradability of these surfactants. Biodegradability decreases with increasing chain length.
The presence of hydrophilic groups mainly affects the degradation rate of these surfactants, but not their ultimate biodegradeability.
Bio-degradability is deterred and degradation is slowed as steric hindrance increases. Degradation rates increase markedly
when hydrophilic groups containing an amide bond are pres-ent. 相似文献
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R. N. Sturm 《Journal of the American Oil Chemists' Society》1973,50(5):159-167
Environmental water quality evaluations of raw materials in consumer products occupy a position of critical importance in
many industries throughout the world. The rapid growth and diversity of the household detergent market requires continuous
consideration of new materials needed to meet the demands of new, improved and modified products. As household cleaning products
are normally disposed of as a component of domestic sewage, surface active compounds, including nonionic surfactants, would
reach surface waters only as a part of a sewage effluent and would be subject to the same degree of biological treatment as
the balance of the waste. For this reason, evaluations of such new materials include an environmental assessment in which
biodegradability testing of organic materials is an important first step. Biodegradability characteristics of nonionic surfactants,
as a class, are generally more difficult to ascertain because of wide structural diversity and a usual lack of functional
groups. Such determinations usually involve intricate and laborious test methods which necessitate development of analytical
techniques for each degradation product of a given material. A method has been developed, modified and used in our laboratory,
that provides, after reasonable opportunity for biological acclimation, a measure of the rate and degree of ultimate biodegradation
(conversion to CO2 and H2O). This method, which uses simple equipment, has been used to assess the biodegradability of a wide variety of nonionic surfactants,
without necessitating the development of specific analytical methods for each surfactant under consideration. Additionally,
this method can be adapted to measure degradation under conditions of anaerobiosis or low temperature. 相似文献
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Qingbin Dong Yonghong Zhao Guangliang Zhang Yingjie Ren 《Journal of surfactants and detergents》2016,19(6):1327-1332
This investigation was performed to determine the anaerobic biodegradation of alkyl ethoxy glucoside (AEG) nonionic surfactants using the OECD 311 method. The influence of different initial concentrations of AEG on the primary biodegradation rate was investigated using the anthrone analysis method. The results show that different initial concentrations have similar good biodegradability and the biodegradation rate can reach more than 90 % even at the highest initial concentration of 100 mg/l. Alkyl polyglucoside (APG) surfactants have previously been confirmed as readily biodegradable. The profile of concentration changes over the incubation time of AEG and APG had similar trends. Therefore, AEG are also considered as readily biodegradable. The gas chromatograph‐mass spectrometer analytical method was used to identify the metabolites. The content of alcohol ethoxylate (AEO) increased with decrease in the number of AEG at the initial stage of degradation. It was found that AEO with longer EO chains disappeared first. Accordingly, a degradation pathway that accounts for the experiment results was proposed. 相似文献
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Soy protein concentrate, a potential alternative to petrochemical polymers, was cross‐linked with formaldehyde at 0.5, 1, 2.5, 5 and 7.5 % (w/w). The materials were then compression‐moulded into plastic tensile bars and tested for tensile and yield strength, percentage elongation and water absorption. The infrared spectra of the cross‐linked product were studied. The degradation pattern of the cross‐linked product was monitored by thermogravimetric analysis. A computerised LOTUS package method that we developed was used for evaluating the kinetic parameters. The biodegradability of the cross‐linked product was also investigated. Copyright © 2005 Society of Chemical Industry 相似文献