共查询到20条相似文献,搜索用时 31 毫秒
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C. P. Chen M. H. Leipold jr. D. Helmreich 《Journal of the American Ceramic Society》1982,65(4):c49-c49
Fracture toughness data is given for multicrystalline silicon which has been prepared by directional solidification. Results indicated a KIC of 0.8 to 0.87 MN /m3/2 , which is consistent with data for single-crystal silicon. 相似文献
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Kerkar Fouad Kheloufi Abdelkrim Dokhan Nahed Ouadjaout Djamel Belhousse Samia Medjahed Sidali Meribai Nadjib Laib Karim 《SILICON》2020,12(3):473-478
Silicon - Multicrystalline silicon (mc-Si) wafers produced by directional solidification still dominate the world market, due to the factor quality/price. The performance of solar cell depends... 相似文献
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High efficiency multicrystalline solar cells must improve performance while replacing higher cost monocrystalline silicon with lower cost multicrystalline silicon. Composite silicon dioxide-titanium dioxide (SiO2?TiO2) films are deposited on a large area of 15.6×15.6 cm2 textured multicrystalline silicon solar cells to increase the incident light trapped within the device. This is being achieved through new cell device structures that improve light trapping and energy conversion capability. These new structures depend on passivated thick and thin layers of silicon dioxide and titanum dioxide grown via wet and dry thermal oxidation. By replacing dry oxidation with wet oxidation the temperatures process can be lowered from 1050°C to 850°C to reduce both cycle time and wafer damage. 相似文献
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Silicon - In the production of multicrystalline silicon solar cell, diamond wire sawing method (DWS) is an important technique, which has already completely replaced multiwire slurry sawing (MWSS)... 相似文献
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Jiayan Li Mei Liu Yi Tan Lishi Wen 《International Journal of Applied Ceramic Technology》2013,10(1):40-44
Multicrystalline silicon ingots were fabricated via the directional solidification method in a vacuum induction furnace using silicon nitride (Si3N4) as quartz crucible coating. The effect of Si3N4 coating on the impurity content, transference, and distribution in Si ingots was investigated. The results can be summarized as follows: The impurities contained in Si ingots, including Fe, Ca, Mn, Cu, P, and B, were found to decrease at varying degrees when the inner surface of the quartz crucible was coated with Si3N4. A mixed layer composted by Si3N4 and Si was observed on the surface of the Si ingot. This mixed layer provided microdefects for the nucleation of metallic impurities. The Fe and N contents in the Si/Si3N4 mixed layer changed with the same tendency, and FeSi2 particles formed on the Si/Si3N4 crystalline boundary. Both Fe and Ca precipitated in the SiC particles near the Si ingot/Si3N4‐coating interface. 相似文献
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The defects of dislocations and grain boundaries (GBs) could significantly reduce the electrical properties of multicrystalline silicon (mc-Si) solar cells 相似文献
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Silicon - The quality of the multi-crystalline silicon ingot mainly depends on the defects and impurity distribution. The impurities originate from the various furnace parts and feedstock. The... 相似文献
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Doo J. Choi David B. Fischbach William D. Scott 《Journal of the American Ceramic Society》1989,72(7):1118-1123
Oxidation of {111} single-crystal silicon and dense, chemically-vapor-deposited silicon nitride was done in clean silica tubes at temperatures of 1000° to woo°C. The oxidation rates of silicon nitride under various atmospheres (dry O2 , wet O2 , wet inert gas, and steam) were several orders of magnitude slower than those of silicon under the identical conditions. The activation energy for the oxidation of silicon nitride decreased from 330 to 259 kJ/mol in going from dry O2 to steam while that for Si decreased from 120 to 94 kJ/mol. The parabolic rate constant for Si increased linearly as the water vapor pressure increased. However, the parabolic rate constant for silicon nitride showed nonlinear dependency on the water vapor pressure in the presence of oxygen. The oxidation kinetics of silicon nitride is explained by the formation of nitrogen compounds (NO and NH3 ) at the reaction interface and the counterpermeation of these reaction products. 相似文献
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研究的目的是完善工业硅检测方法,分析工业硅中的杂质来源和现有的工业硅检测方法,本次实验重点研究工业硅中杂质碳的检测方法,提出有必要修改现在的工业硅化学分析方法国家标准。 相似文献
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Electrical transport in Gold/porous silicon/crystalline silicon junctions has been studied. The junctions are found to improve when the porous silicon is exposed to a hydrogen plasma before depositing the top metal. The hydrogen passivated junctions exhibited higher current levels and emitted light at lower voltages as compared to the unhydrogenated ones. Internal photoemission measurements were carried out to investigate the gold/porous silicon barrier. The barrier height determined from the Fowler plot is independent of the top material. The temperature dependence of the barrier height is similar to that of the crystalline silicon energy gap. 相似文献
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Ethanolic silicon suspensions, with and without a polyethoxylated amine of low molecular weight, were studied by rheological, adsorption, electrophoretic, and sedimentation methods. Pellets were pressure-cast and nitrided to form reaction-bonded silicon nitride. Density and binding strength in the green state relate well to rheological behavior and other collodial aspects of the suspensions used, particularly the additive's role and distribution. Density and degree of nitridation in the final state are not importantly affected by the additive's use. Its greatest benefit is to modify the binding strength in the green state. The mode by which this small molecule affects the processing of silicon consists of adsorption, combined with an increased electrostatic interparticle repulsion which increases the suspension viscosity and that of undried pellets. Although the improved binding strength is accompanied by decreased green and nitrided densities, high degrees of conversion to silicon nitride are still achieved. 相似文献
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A simple defect interaction model was developed that explains the identical activation energies observed for carbon and silicon diffusion in single-crystal silicon carbide. In accord with experimental measurement of nonstoichiometry, the model requires a substantial concentration of silicon anti-site defects. The diffusion of silicon is limited by the motion of these defects; this is suggested to occur by their interaction with carbon vacancies. The model predicts that boron doping will increase both carbon and silicon diffusion coefficients. 相似文献
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The sequence of formation of silicon nitride phases inside the volume of an initial silicon grain heated in a gaseous nitrogen medium is studied. Technologies for making ceramics articles based on silicon nitride are proposed. 相似文献
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贺福 《高科技纤维与应用》2010,35(6):10-17
在生产PAN原丝过程中,干燥致密化之前要上油剂,使每根单丝表面形成油膜,防止单丝之间粘连和并丝等。目前,油剂种类主要是硅油剂。但是,硅油剂会带来硅污染,使碳纤维性能下降,这是上硅系油剂的负面影响。如何防止硅污染已提到议事日程,值得关注。本文就硅系油剂及其硅污染做一概述,以引起同仁们的重视。 相似文献
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Young-Soo Sohn Jinsung Park Gwonchan Yoon Jiseok Song Sang-Won Jee Jung-Ho Lee Sungsoo Na Taeyun Kwon Kilho Eom 《Nanoscale research letters》2010,5(1):211-216
Nanowires have been taken much attention as a nanoscale building block, which can perform the excellent mechanical function as an electromechanical device. Here, we have performed atomic force microscope (AFM)-based nanoindentation experiments of silicon nanowires in order to investigate the mechanical properties of silicon nanowires. It is shown that stiffness of nanowires is well described by Hertz theory and that elastic modulus of silicon nanowires with various diameters from ~100 to ~600 nm is close to that of bulk silicon. This implies that the elastic modulus of silicon nanowires is independent of their diameters if the diameter is larger than 100 nm. This supports that finite size effect (due to surface effect) does not play a role on elastic behavior of silicon nanowires with diameter of >100 nm. 相似文献
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研究了以煤油作为捕收剂和载体回收硅片切割废料中碳化硅的双液浮选工艺.研究捕收剂用量、pH值、固液比及粒度对回收碳化硅纯度的影响.通过单因素及正交试验,综合考虑极差分析和方差分析的结果,确定最优工艺条件为:捕收剂用量50mL·g-1、pH值为8.3、固液比为3∶400g·mL-1、粒度8.636μm,此条件下回收的碳化硅纯度达到99.08%.采用双液浮选工艺回收太阳能硅片切割废料中的碳化硅粉体具有显著的经济效益和社会效益. 相似文献
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Oxidation of Silicon, Silicon Carbide, and Silicon Nitride in Gases Containing Oxygen and Chlorine 总被引:1,自引:0,他引:1
PeiPei Hsu Sikyin Ip Chan Park Michael J. McNallan 《Journal of the American Ceramic Society》1993,76(6):1621-1623
Chlorine contamination accelerates the oxidation of silicon-based ceramics through the formation of volatile silicon chloride or silicon oxychloride species which degrade the protective character of the SiO2 film. Accelerated attack may occur by active corrosion or formation of bubbles in the oxide layer. Si3 N4 is much more resistant to this attack than either silicon or SiC. This resistance may be related to the presence of a thin silicon oxynitride layer below the SiO2 scale which forms on Si3 N4 . 相似文献