我国生物质能源现代化应用前景展望(三)——生物质能源转化技术经济评估

秸秆、动植物油脂、微藻等生物质原料可以生产液体运输燃料,生物燃料的化学成分包括醇、酯、烃三类。燃料乙醇主要替代汽油,受到各国重视,其中纤维素乙醇技术发展较快。脂肪酸甲酯是第一代生物柴油的主要成分,价格主要受油脂原料价格的影响,由于和柴油相容性差,低温流动性不好,将逐渐被加氢生产的第二代生物柴油取代。相比醇、酯等含氧燃料,烃类生物燃料在使用性能上有很多优势。有多条技术路线可以生产烃类燃料,其中油脂加氢制喷气燃料已接近商业应用,热解油加氢可将木质生物质原料中的"木质素"组分转化为生物油,大型快速热解工厂可以和热电联产装置组成联合系统,从而提高工厂综合热效率,降低生物燃料生产成本。因此,快速热解生产汽柴油将成为主要的生物燃料生产路线。生物质与煤共气化技术通过提高气化温度,不仅可以提高生物质气化效率,减少焦油的生成,还可以解决生物质供给的季节性问题,为生物质的高效利用提供了一条新的技术途径。微藻高压液化生产柴油是最具发展潜力的第三代生物燃料技术,我国需要加强微藻养殖及加工技术攻关。     

我国生物质能源现代化应用前景展望(二)——生物质制备液体燃料的转化途径

利用可再生生物质资源转化制备液体燃料已成为全球关注的热点。常见的生物质能源原料主要有草本植物、木本植物、微藻和脂肪类生物质资源,丰富的生物质资源为生物质液体燃料的生产提供了广泛的原料来源,也为生物质能源的多样性发展提供了坚实的物质基础。不同的生物质原料种类和转化方式可生产出性能各异的多种液体燃料,主要包括醇类燃料(乙醇、丁醇等)、烃类燃料和生物柴油等,由此构建出生物质转化制备液体燃料的转化途径网络。醇类燃料的生物质转化途径主要包括生物质直接发酵、生物质合成气发酵、生物质合成气化学合成等;烃类燃料的生物质转化途径主要有生物质液化加氢、微藻热化学途径、生物质合成气费托合成、生物质发酵脂肪酸加氢及油脂类加氢途径等;生物柴油的转化途径主要有油脂酯交换和微藻萃取酯交换。在这些液体燃料的转化途径中,只有生物质发酵制乙醇途径和油脂酯交换途径基本实现了商业化应用,其他大部分转化途径仍处于开发阶段。     

An analytical framework for siting and sizing biomass fuel plants

A generalized framework is presented for analyzing the relative attractiveness of biomass fuel production investments on a disaggregate level, using a systems approach to integrate sitespecific considerations. A model based on this approach may be used to site and size prospective biomass fuel plants and to identify and specify critical factors that threaten or enhance the viability of investments. Rather than providing a single mean value for each critical factor, structural relationships have been formulated. Generalized feedstock supply curves, processing cost functions and modal transportation cost functions are formulated to specify feedstock-production and fuel transport sub-systems. This analytical framework may be applied in any area with abundant biomass. Local costs and conditions and fuel demand patterns would be used to calibrate the model for each local area.     

Studies of biomass fuelled MCFC systems

In the present work, the methods, techniques and results obtained during the studies of biomass fuelled molten carbonate fuel cell (MCFC) systems within the Swedish national fuel cell program are presented. The power plants are 60 MW class, utilising biomass (i.e. wood chips) as the primary fuel. The biomass is converted via pressurised gasification into a gaseous form that, after subsequent cleaning, can be used in the fuel cells. An investigation of the effects of gasification pressure, temperature and the influence of internal reforming on the overall system performance is presented.All studies were carried out using the Aspen Plus™ with Model Manager™ simulation package.     

Technological learning in bioenergy systems

The main goal of this article is to determine whether cost reductions in different bioenergy systems can be quantified using the experience curve approach, and how specific issues (arising from the complexity of biomass energy systems) can be addressed. This is pursued by case studies on biofuelled combined heat and power (CHP) plants in Sweden, global development of fluidized bed boilers and Danish biogas plants. As secondary goal, the aim is to identify learning mechanisms behind technology development and cost reduction for the biomass energy systems investigated. The case studies reveal large difficulties to devise empirical experience curves for investment costs of biomass-fuelled power plants. To some extent, this is due to lack of (detailed) data. The main reason, however, are varying plant costs due to differences in scale, fuel type, plant layout, region etc. For fluidized bed boiler plants built on a global level, progress ratios (PRs) for the price of entire plants lies approximately between 90–93% (which is typical for large plant-like technologies). The costs for the boiler section alone was found to decline much faster. The experience curve approach delivers better results, when the production costs of the final energy carrier are analyzed. Electricity from biofuelled CHP-plants yields PRs of 91–92%, i.e. an 8–9% reduction of electricity production costs with each cumulative doubling of electricity production. The experience curve for biogas production displays a PR of 85% from 1984 to the beginning of 1990, and then levels to approximately 100% until 2002. For technologies developed on a local level (e.g. biogas plants), learning-by-using and learning-by-interacting are important learning mechanism, while for CHP plants utilizing fluidized bed boilers, upscaling is probably one of the main mechanisms behind cost reductions.     

Hydrocarbons via photosynthesis

Photosynthesis is examined as a possible annually renewable resource for material and energy. the production of fermentation alcohol from sugar cane as a major component of materials for chemical feedstocks is examined as well as the direct photosynthetic production of hydrocarbon from known plant sources. Experiments are underway to analyse the hydrocarbons from Euphorbias. Asclepis and other hydrocarbon-containing plants with a view toward determining their various chemical components. In addition, experimental plantings of plants of this type have begun to obtain data on which species would be the most successful. Work is also underway on the development of chemical process techniques for the extraction of plant materials after harvesting. In addition, efforts are underway to construct synthetic systems on the basis of our knowledge of the natural photosynthetic processes. These systems could be used to produce fuel, fertilizer and power. As a result of studies of the natural quantum conversion process in green plants, we can envisage several photoelectron transfer processes, some of which have already been demonstrated in synthetic systems. Methods of constructing systems of this type and the principles of their use are described.     

An economic assessment of the use of short-rotation coppice woody biomass to heat greenhouses in southern Canada

This study explores the economic feasibility of fossil fuel substitution with biomass from short-rotation willow plantations as an option for greenhouse heating in southern Ontario, Canada. We assess the net displacement value of fossil fuel biomass combustion systems with an integrated purpose-grown biomass production enterprise. Key project parameters include greenhouse size, heating requirements, boiler capital costs and biomass establishment and management costs. Several metrics have been used to examine feasibility including net present value, internal rate of return, payback period, and the minimum or break-even prices for natural gas and heating oil for which the biomass substitution operations become financially attractive. Depending on certain key assumptions, internal rates of return ranged from 11-14% for displacing heating oil to 0-4% for displacing natural gas with woody biomass. The biomass heating projects have payback periods of 10 to >22 years for substituting heating oil and 18 to >22 years for replacing a natural gas. Sensitivity analyses indicate that fossil fuel price and efficiency of the boiler heating system are critical elements in the analyses and research on methods to improve growth and yield and reduce silviculture costs could have a large beneficial impact on the feasibility of this type of bioenergy enterprise.     

Tracer-LIF diagnostics: quantitative measurement of fuel concentration,temperature and fuel/air ratio in practical combustion systems

The safe, clean, and reliable operation of combustion devices depends to a large degree on the exact control of the fuel/air mixing process prior to ignition. Therefore, quantitative measurement techniques that characterize the state of the fresh gas mixture are crucial in modern combustion science and engineering. This paper presents the fundamental concepts for how to devise and apply quantitative measurement techniques for studies of fuel concentration, temperature, and fuel/air ratio in practical combustion systems, with some emphasis on internal combustion engines. The paper does not attempt to provide a full literature review of quantitative imaging diagnostics for practical combustion devices; rather it focuses on explaining the concepts and illustrating these with selected examples. These examples focus on application to primarily gaseous situations.The photophysics of organic molecules is presented in an overview followed by discussions on specific details of the temperature-, pressure-, and mixture-dependence of the laser-induced fluorescence strength of aliphatic ketones, like acetone and 3-pentanone, and toluene. Models that describe the fluorescence are discussed and evaluated with respect to their functionality. Examples for quantitative applications are categorized in order of increased complexity. These examples include simple mixing experiments under isothermal and isobaric conditions, fuel/air mixing in engines, temperature measurements, and mixing studies where fuel and oxygen concentrations vary.A brief summary is given on measurements of fuel concentrations in multiphase systems, such as laser‐induced exciplex spectroscopy. Potentially adverse effects that added tracers might have on mixture formation, combustion, and the faithful representation of the base fuel distribution are discussed. Finally, a brief section describes alternative techniques to tracer-based measurements that allow studies of fuel/air mixing processes in practical devices.The paper concludes with a section that addresses key issues that remain as challenges for continued research towards the improvement of quantitative, tracer-based LIF measurements.     

The use of biomass syngas in IC engines and CCGT plants: A comparative analysis

This paper studies the use of biomass syngas, obtained from pyrolysis or gasification, in traditional energy-production systems, specifically internal combustion (IC) engines and combined cycle gas turbine (CCGT) plants. The biomass conversion stage has been simulated by means of a gas–solid thermodynamic model. The IC and CCGT plant configurations were optimised to maximise heat and power production. Several types of biomass feedstock were studied to assess their potential for energy production and their effect on the environment. This system was also compared with the coupling between biomass gasification and fuel cells.     

Chemicals from biomass—the U.S. prospects for the turn of the century

Historically, chemicals from biomass have been and are expected to be economical in three major areas: byproducts, specialty items and polymers. Assessments of producing major chemicals from biomass in a processing plant based on the available conversion techniques indicate that they are not economically attractive, with the possible exception of conversion to ammonia and ethanol. The deterrents are the heavy capital investments, dependability of raw material supply and transportation costs for large plants, lack of operation experience, inadaptability to market variations, and competition from petroleum and coal. More importantly, it is also shown that even if chemicals from biomass were economical today, the resultant savings in petroleum would be far less than those achieved through other options available for the utilization of biomass as fuel and structural material. Thus, it is concluded that near-term research and development must be toward improved conversion processes, recovery of valuable products from waste streams at existing plants, more efficient use of biomass for energy and more efficient production of superior material products.     

Political,economic and environmental impacts of biomass-based hydrogen

The purpose of this study is to assess the political, economic and environmental impacts of producing hydrogen from biomass. Hydrogen is a promising renewable fuel for transportation and domestic applications. Hydrogen is a secondary form of energy that has to be manufactured like electricity. The promise of hydrogen as an energy carrier that can provide pollution-free, carbon-free power and fuels for buildings, industry, and transport makes it a potentially critical player in our energy future. Currently, most hydrogen is derived from non-renewable resources by steam reforming in which fossil fuels, primarily natural gas, but could in principle be generated from renewable resources such as biomass by gasification. Hydrogen production from fossil fuels is not renewable and produces at least the same amount of CO₂ as the direct combustion of the fossil fuel. The production of hydrogen from biomass has several advantages compared to that of fossil fuels. The major problem in utilization of hydrogen gas as a fuel is its unavailability in nature and the need for inexpensive production methods. Hydrogen production using steam reforming methane is the most economical method among the current commercial processes. These processes use non-renewable energy sources to produce hydrogen and are not sustainable. It is believed that in the future biomass can become an important sustainable source of hydrogen. Several studies have shown that the cost of producing hydrogen from biomass is strongly dependent on the cost of the feedstock. Biomass, in particular, could be a low-cost option for some countries. Therefore, a cost-effective energy-production process could be achieved in which agricultural wastes and various other biomasses are recycled to produce hydrogen economically. Policy interest in moving towards a hydrogen-based economy is rising, largely because converting hydrogen into useable energy can be more efficient than fossil fuels and has the virtue of only producing water as the by-product of the process. Achieving large-scale changes to develop a sustained hydrogen economy requires a large amount of planning and cooperation at national and international alike levels.     

Recovery and use of olive stones: Commodity,environmental and economic assessment

At the present time biomass (together with sunlight) is the most equally distributed and easily exploited energy resource. Of the various types of biomass, that deriving from agricultural by-products is proving to be of growing interest thanks to the ease with which it can be accessed and processed, its energy concentration and the “ethical” acceptability of this fuel (that does not derive from specifically grown crops but from the by-products of the agricultural industries). In addition, a number of potential environmental problems may be resolved.In particular, during the production of olive oil it is possible to recover olive pits as a by-product for energy production for use as fuel in domestic boilers or in large industrial plants for cogeneration.This study evaluates the commodity, environmental and economic aspects linked to different techniques for the pit recovery from olive pulp and olive pomace. The economic and environmental viability of these new “best practices” has been demonstrated both at the level of production (increased income for olive extraction plants) and at the level of environmental sustainability (use of renewable fuels).     

利用低温碳化技术生产清洁固体燃料

介绍了一种利用低温碳化技术开发出的低成本、高效率的劣质固体燃料(结合生物能、褐煤、煤、原煤)预处理技术。这种预处理过程在燃烧之前的小规模的还原性气氛中除去有害的气体污染物(如氮、硫、氯、汞)，从而提高燃料效率。它主要应用在小于50MW的小型电厂和热电联产机组，以及小于300MW的中型电厂。     

Turkey's Renewable Energy Facilities in the Near Future

In this work, renewable energy facilities of Turkey were investigated. Electricity is mainly produced by thermal power plants, consuming coal, lignite, natural gas, fuel oil and geothermal energy, and hydro power plants in Turkey. Turkey has no large oil and gas reserves. The main indigenous energy resources are lignite, hydro and biomass. Turkey has to adopt new, long-term energy strategies to reduce the share of fossil fuels in primary energy consumption. For these reasons, the development and use of renewable energy sources and technologies are increasingly becoming vital for sustainable economic development of Turkey. The most significant developments in renewable production are observed hydropower and geothermal energy production. Renewable electricity facilities mainly include electricity from biomass, hydropower, geothermal, and wind and solar energy sources. Biomass cogeneration is a promising method for production bioelectricity.     

Commercial-scale rapid thermal processing of biomass

Rapid Thermal Processing (RTP) utilizes proprietary reactor systems to convert both biomass and petroleum-based materials to high yields of chemical and liquid fuel products. The essential feature is the ability to transfer heat rapidly with precise control of short contact times. The process involves thermal or thermocatalytic refining of biomass, and is somewhat analogous to the refining of petroleum materials. Nevertheless, the chemical and fuel products from biomass are unique, and not similar to petroleum-derived products. Furthermore, RTP is not to be confused with conventional pyrolysis, from which it differs fundamentally with respect to product yield and quality, and process conditions and chemistry. Short-term applications include the production of specialty chemicals, fuel oil substitutes and engine fuels for both diesel and turbine applications. Research in support of these applications is in progress and is briefly reviewed. The paper focuses primarily on the status of RTP hardware, including the operation of a 2.5 tonne day⁻¹ plant and a 25 tonne day⁻¹ commercial plant.     

Biomass and district-heating systems

New technologies for biomass gasification are being developed which increase the potential to cogenerate electricity and may reduce costs compared with steam turbine technology. Cogeneration is a more energy-efficient way to convert biomass into heat and electricity than separate electricity and heat production. The potential to cogenerate electricity in the Swedish district-heating systems is estimated to be 20% of current electricity production when using combined cycle technology. The electricity and heat costs from cogeneration with biomass are higher than the costs from fossil fuel plants at current fuel prices when external costs are excluded.     

Feasibility assessment of Brassica carinata bioenergy systems in Southern Europe

A detailed reliability assessment was made of electricity generation systems in Spain that are based on Brassica carinata cultivation. The assessment considers the following chain of energy generation: biomass cultivation and harvesting, transportation and electricity generation in biomass power plants (10, 25 and 50 MW). Flue gas desulphurisation systems have been included for larger plants following the criteria of the Spanish legislative framework. Six scenarios were analysed in accordance with the following aspects: two crop distributions around the power plant and three power plant sizes. The results show that the cost of biomass delivered at the power plants ranges from 107.81 to 112.54 € Mg⁻¹ dry basis.Sensibility analysis shows that variation in biomass production in the field demonstrates that biomass cost delivered at the plant is notably affected and consequently so is the system's feasibility.Furthermore, the increase of the price of CO₂ emission credits, also considered in sensibility analysis, can help to improve the reliability of systems because of the increase of gross profit for each scenario.This study clears up the Economic uncertainty of B. carinata biomass energy systems based on the single use of this renewable energy resource. Higher crop productivities are needed to ensure an economic reliability of the analysed systems. On the other hand biomass mix can solve SO₂ emission cleaning cost for large power plants, improving the reliability of B. carinata application as fuel.     

Biofuel production: Challenges and opportunities

It is increasing clear that biofuels can be a viable source of renewable energy in contrast to the finite nature, geopolitical instability, and deleterious global effects of fossil fuel energy. Collectively, biofuels include any energy-enriched chemicals generated directly through the biological processes or derived from the chemical conversion from biomass of prior living organisms. Predominantly, biofuels are produced from photosynthetic organisms such as photosynthetic bacteria, micro- and macro-algae and vascular land plants. The primary products of biofuel may be in a gas, liquid, or solid form. These products can be further converted by biochemical, physical, and thermochemical methods. Biofuels can be classified into two categories: primary and secondary biofuels. The primary biofuels are directly produced from burning woody or cellulosic plant material and dry animal waste. The secondary biofuels can be classified into three generations that are each indirectly generated from plant and animal material. The first generation of biofuels is ethanol derived from food crops rich in starch or biodiesel taken from waste animal fats such as cooking grease. The second generation is bioethanol derived from non-food cellulosic biomass and biodiesel taken from oil-rich plant seed such as soybean or jatropha. The third generation is the biofuels generated from cyanobacterial, microalgae and other microbes, which is the most promising approach to meet the global energy demands. In this review, we present the recent progresses including challenges and opportunities in microbial biofuels production as well as the potential applications of microalgae as a platform of biomass production. Future research endeavors in biofuel production should be placed on the search of novel biofuel production species, optimization and improvement of culture conditions, genetic engineering of biofuel-producing species, complete understanding of the biofuel production mechanisms, and effective techniques for mass cultivation of microorganisms.     

Highly efficient electricity generation from biomass by integration and hybridization with combined cycle gas turbine (CCGT) plants for natural gas

Integration/co-firing with existing fossil fuel plants could give near term highly efficient and low cost power production from biomass. This paper presents a techno-economical analysis on options for integrating biomass thermal conversion (optimized for local resources ∼50 MW_th) with existing CCGT (combined cycle gas turbine) power plants (800–1400 MW_th). Options include hybrid combined cycles (HCC), indirect gasification of biomass and simple cycle biomass steam plants which are simulated using the software Ebsilon Professional and Aspen Plus. Levelized cost of electricity (LCoE) is calculated with cost functions derived from power plant data. Results show that the integrated HCC configurations (fully-fired) show a significantly higher efficiency (40–41%, LHV (lower heating value)) than a stand-alone steam plant (35.5%); roughly half of the efficiency (2.4% points) is due to more efficient fuel drying. Because of higher investment costs, HCC options have cost advantages over stand-alone options at high biomass fuel prices (>25 EUR/MWh) or low discount rates (<5%). Gasification options show even higher efficiency (46–50%), and the lowest LCoE for the options studied for fuel costs exceeding 10 EUR/MWh. It can be concluded that clear efficiency improvements and possible cost reductions can be reached by integration of biomass with CCGT power plants compared to stand-alone plants.     

Sustainability improvement in combined electricity and freshwater generation systems via biomass: A comparative emergy analysis and multi-objective optimization

For energy systems, sustainability is a major concern that must be carefully considered when designed and established. Emergy analysis is an effective technique to scrutinize the sustainability of these systems. On the other hand, water shortage is seen to become a big problem in the close future; however, this problem can be effectively alleviated by combined electricity/water production plants, where waste heat is recovered to generate freshwater. This study applies emergy analysis to evaluate and improve the sustainability, renewability, environmental impacts, and economic aspect of such a plant, in which a multi-stage desalination (MSF) system is employed to recover the waste heat from a gas turbine (GT). The plant is fueled by biomass/natural gas (system I), natural gas (system II), and biomass (system III), and the above-mentioned features are compared for the different fuel types. To estimate chemical equilibrium state inside the gasifier, Lagrange's method of undetermined multipliers is applied. Also, considering exergy efficiency and emergy sustainability index as objective functions, biomass/natural gas-fueled system is optimized by adopting a multi-objective optimization approach based on the non-dominated sorting genetic algorithm II (NSGA II). To predict the optimized points' behavior, the Pareto optimal frontier of the system is utilized. The results reveal that using biomass as inlet fuel remarkably improves the sustainability index and reduces environmental impacts. The optimization results show that as sustainability index increases, exergy efficiency decreases. Also, the two optimized points of the system are found to have exergy efficiencies of 20.14% and 25.09% and sustainability indices of 24.67% and 13.60%.