共查询到19条相似文献,搜索用时 78 毫秒
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研究了单种溶剂、混合溶剂对3,4-苯并芘的溶解选择性及煤沥青溶解量。并以顺丁烯二酸酐为改性剂、硫酸为催化剂,考察了溶剂效应对降低煤沥青中3,4-苯并芘的影响。研究表明,环己烷、甲苯,环己烷、乙酸丁酯组成的混合溶剂具有较好的3,4-苯并芘溶解选择性和合适的煤沥青溶解量。当环己烷∶甲苯=2∶1(体积比)和环己烷∶乙酸丁酯=2∶1(体积比)为反应溶剂时,能够高效地脱除煤沥青中3,4-苯并芘,煤沥青中3,4-苯并芘降低率分别达到88.26%和90.83%。其原因认为是此类溶剂能使包裹在沥青颗粒内部的3,4-苯并芘释放出来,且3,4-苯并芘与改性剂能够形成均相反应体系,大部分不具有致癌性的高相对分子质量环芳烃与改性剂之间形成两相体系,从而提高了改性剂与3,4-苯并芘的有效反应。 相似文献
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孙颖 《合成材料老化与应用》2022,(5):101-102+15
为了提升石油沥青的基本性能,研究向石油沥青中加入不同种类及掺量的煤沥青进行改性。通过对改性石油沥青进行性能试验,分析获得改性石油沥青的软化点、针入度等性能指标的变化规律。性能测试结果表明:不同种类的煤沥青均可降低石油沥青的针入度,有利于改善石油沥青的流变性能;随着煤沥青掺加比例的不断增加,可大幅度提高混合沥青的抗高温性能。将掺加煤沥青的改性石油沥青应用于路面施工建设,可延长路面的使用寿命。 相似文献
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环氧改性煤沥青防腐材料的研制 总被引:1,自引:0,他引:1
1概述在煤化工业中,煤焦油分馏的残余物即煤沥青。煤沥青的沸程约36OC以上,占煤焦油分馏量的半数以上,主要含葱、菲、素类稠环化合物。长期以来,由于人们对它的认识不够而未加以好好利用,有的弃之荒郊,污染环境,有的即使利用,也只能做些低性能,低档次的涂料,用在一些无关紧要的场合,这样大大限制了煤沥青的综合利用范围。煤沥青有优异的防腐性能,对于大多数的酸、碱、盐、油类化合物及醛、醇类化学溶剂都具有较好适应性,煤沥青有较好的成膜性,生成的膜,表面光亮。煤沥青的主要缺点是强度差,耐气候性差。选择耐蚀性能优良,… 相似文献
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考察了不同添加量的煤沥青四氢呋喃萃取物(THFS)对石油沥青的改性,随着THFS添加量的增多,改性沥青针入度降低,软化点升高,延度下降,参照英国标准(BSI BS—3690)得出最佳添加量为8%。利用TG-FTIR、FTIR对改性沥青进行了表征,结果表明:THFS、改性沥青的失重率大于基质沥青70的失重率; THFS在700~900cm-1处芳香烃类的透射峰强度明显强于基质沥青与改性沥青;沥青老化后在2953cm-1和1377cm-1(—CH3)、1461cm-1和2924cm-1(—CH2—)处透射峰逐渐增强;1600cm-1(C=O和苯环C=C)透射峰逐渐增强;沥青热解半焦中的脂肪烃类物质含量较少,主要以高度缩合的稠环芳香烃类物质为主;沥青在老化过程中主要发生了氧化、裂解、加成、聚合、缩合等反应。 相似文献
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Modified characteristics of mesophase pitch prepared from coal tar pitch by adding waste polystyrene
The toluene soluble of coal tar pitch was carbonized with waste polystyrene. The properties of mesophase pitches were characterized using polarized light optical microscope, apparent viscometer, FT-IR, 1H NMR and X-ray diffractometer. After adding the waste polystyrene into the toluene soluble of coal tar pitch, the soluble mesophase were was increased from about 9% to 52% and the mesophase pitches were changed from 74% with coarse mosaic texture to 100% with flow domain texture. The mesophase pitches were transformed from thixotropy to unthixotropy. By waste polystyrene added into the toluene soluble of coal tar pitch, the methylene group was increased a lot. The presence of more alkyl groups modified the characteristics of mesophase pitches and improved the assembly of mesophase pitch molecules. 相似文献
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以煤沥青为原料,采用直接热聚合工艺制备出优质中间相沥青。研究了热聚合温度及保温时间对中间相沥青族组成及光学组织结构等性能的影响,并对反应机理进行了深入研究,得到了制备中间相沥青的最佳工艺条件。研究表明,在一定条件下,通过热聚合,在低温、长时间或高温、短时间都能制备优质中间相沥青。在360℃、5 h条件下制备的中间相球晶较小,分布较分散;而在380℃、4 h条件下制备的球晶较大,分布较集中。制备的中间相可作为高级炭材料的优质前躯体,为制取高质量的新型炭材料提供了一条新的途径,对煤炭资源的综合利用具有十分重要的意义。 相似文献
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A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m~(-1) ·K~(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building. 相似文献
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