Relationships between water attenuation coefficients derived from active and passive remote sensing: a case study from two coastal environments

Relationships between the satellite-derived diffuse attenuation coefficient of downwelling irradiance (K(d)) and airborne-based vertical attenuation of lidar volume backscattering (α) were examined in two coastal environments. At 1.1 km resolution and a wavelength of 532 nm, we found a greater connection between α and K(d) when α was computed below 2 m depth (Spearman rank correlation coefficient up to 0.96), and a larger contribution of K(d) to α with respect to the beam attenuation coefficient as estimated from lidar measurements and K(d) models. Our results suggest that concurrent passive and active optical measurements can be used to estimate total scattering coefficient and backscattering efficiency in waters without optical vertical structure.     

Chlorophyll biomass in the global oceans: satellite retrieval using inherent optical properties

In the upper layer of the global ocean, 2082 in situ chlorophyll biomass values (Chl) are retrieved by concurrent satellite-derived inherent optical properties (IOP). It is found that (1) the phytoplankton absorption coefficient IOP alone does not provide satisfactory (Chl) retrieval; (2) the chromophoric dissolved organic matter (CDOM) absorption coefficient IOP must also be used to obtain satisfactory retrieval through (Chl) alpha a ph + pa CDOM where p is a constant and a ph and aCDOM are, respectively, the phytoplankton and CDOM absorption coefficients; (3) the IOP-based (Chl) retrieval performance is comparable to standard satellite reflectance ratio retrievals (that have CDOM absorption intrinsically embedded within them); (4) inclusion of the total backscattering coefficient IOP does not contribute significantly to (Chl) retrieval; and (5) the new IOP-based algorithm may provide the possibility for future research to establish the actual role of extracellular CDOM from all sources in the intracellular production of chlorophyll biomass.     

Satellite retrieval of the absorption coefficient of phytoplankton phycoerythrin pigment: theory and feasibility status

Oceanic radiance model inversion methods are used to develop a comprehensive algorithm for retrieval of the absorption coefficients of phycourobilin (PUB) pigment, type I phycoerythrobilin (PEB) pigment rich in PUB, and type II PEB deficient in PUB pigment (together with the usual "big three" inherent optical properties: the total backscattering coefficient and the absorption coefficients of chromophoric dissolved organic matter (CDOM)-detritus and phytoplankton). This fully modeled inversion algorithm is then simplified to yield a hybrid modeled-unmodeled inversion algorithm in which the phycoerythrin (PE) absorption coefficient is retrieved as unmodeled 488-nm absorption (which exceeds the modeled phytoplankton and the CDOM-detritus absorption coefficients). Each algorithm was applied to water-leaving radiances, but only hybrid modeled-unmodeled inversions yielded viable retrievals of the PE absorption coefficient. Validation of the PE absorption coefficient retrieval was achieved by relative comparison with airborne laser-induced PEB fluorescence. The modeled-unmodeled retrieval of four inherent optical properties by direct matrix inversion is rapid and well conditioned, but the accuracy is strongly limited by the accuracy of the three principal inherent optical property models across all four spectral bands. Several research areas are identified to enhance the radiance-model-based retrievals: (a) improved PEB and PUB absorption coefficient models, (b) PE spectral shifts induced by PUB chromophore substitution at chromophore binding sites, (c) specific absorption-sensitive phytoplankton absorption modeling, (d) total constituent backscattering modeling, (e) unmodeled carotinoid and phycocyanin absorption that are not now accounted for in the chlorophyll-dominated phytoplankton absorption coefficient model, and (f) iterative inversion techniques to solve for six constituents with only five radiances. Although considerable progress has been made toward the satellite recovery of PE absorption, the maturity of the retrieval is presently insufficient for routine global application. Instead it must currently be used on a regional basis where localized ship and aircraft validation can be made available. The algorithm was developed for the MODIS (Moderate-Resolution Imaging Spectroradiometer) sensor but is applicable to any sensor having comparable band locations.     

Determination of the particulate extinction-coefficient profile and the column-integrated lidar ratios using the backscatter-coefficient and optical-depth profiles

A new method is considered that can be used for inverting data obtained from a combined elastic-inelastic lidar or a high spectral resolution lidar operating in a one-directional mode, or an elastic lidar operating in a multiangle mode. The particulate extinction coefficient is retrieved from the simultaneously measured profiles of the particulate backscatter coefficient and the particulate optical depth. The stepwise profile of the column-integrated lidar ratio is found that provides best matching of the initial (inverted) profile of the optical depth to that obtained by the inversion of the backscatter-coefficient profile. The retrieval of the extinction coefficient is made without using numerical differentiation. The method reduces the level of random noise in the retrieved extinction coefficient to the level of noise in the inverted backscatter coefficient. Examples of simulated and experimental data are presented.     

Optical properties of highly scattering media determined from changes in attenuation, phase, and modulation depth

The optical properties of scattering media determine the attenuation (A) and the transit time (?t?) of light reflected from the medium as well as the phase (?) and modulation depth (M) of an intensity-modulated lightwave. Our primary finding is that the ratio of changes in A, ?, and M is approximately independent of the scattering properties and gives a good estimate of the absorption coefficient. These changes can be induced either by small changes in the absorption coefficient of the medium, by the tuning of the wavelength, or by changes in the light source-detector distance. The application for the in vivo monitoring of hemoglobin and oxyhemoglobin concentrations in human tissue is discussed.     

Assessment of the ultraviolet radiation field in ocean waters from space-based measurements and full radiative-transfer calculations

Quantitative assessment of the UV effects on aquatic ecosystems requires an estimate of the in-water radiation field. Actual ocean UV reflectances are needed for improving the total ozone retrievals from the total ozone mapping spectrometer (TOMS) and the ozone monitoring instrument (OMI) flown on NASA's Aura satellite. The estimate of underwater UV radiation can be done on the basis of measurements from the TOMS/OMI and full models of radiative transfer (RT) in the atmosphere-ocean system. The Hydrolight code, modified for extension to the UV, is used for the generation of look-up tables for in-water irradiances. A look-up table for surface radiances generated with a full RT code is input for the Hydrolight simulations. A model of seawater inherent optical properties (IOPs) is an extension of the Case 1 water model to the UV. A new element of the IOP model is parameterization of particulate matter absorption based on recent in situ data. A chlorophyll product from ocean color sensors is input for the IOP model. Verification of the in-water computational scheme shows that the calculated diffuse attenuation coefficient Kd is in good agreement with the measured Kd.     

Lidar system model for use with path obscurants and experimental validation

When lidar pulses travel through a short path that includes a relatively high concentration of aerosols, scattering phenomena can alter the power and temporal properties of the pulses significantly, causing undesirable effects in the received pulse. In many applications the design of the lidar transmitter and receiver must consider adverse environmental aerosol conditions to ensure the desired performance. We present an analytical model of lidar system operation when the optical path includes aerosols for use in support of instrument design, simulations, and system evaluation. The model considers an optical path terminated with a solid object, although it can also be applied, with minor modifications, to cases where the expected backscatter occurs from nonsolid objects. The optical path aerosols are characterized by their attenuation and backscatter coefficients derived by the Mie theory from the concentration and particle size distribution of the aerosol. Other inputs include the lidar system parameters and instrument response function, and the model output is the time-resolved received pulse. The model is demonstrated and experimentally validated with military fog oil smoke for short ranges (several meters). The results are obtained with a lidar system operating at a wavelength of 0.905 microm within and outside the aerosol. The model goodness of fit is evaluated using the statistical coefficient of determination whose value ranged from 0.88 to 0.99 in this study.     

Nighttime measurements of atmospheric optical thickness by star photometry with a digital camera

Nighttime stellar photometric measurements have been carried out with a commercial digital single-lens reflex camera to determine the atmospheric optical thickness on large fields of view (FOV). Specific procedures of image analysis allow to extract an equivalent irradiance for a number of stars and for the sky light background; thus, a measure of the optical thickness in each star direction can be retrieved. A larger FOV is obtained by stitching several photographs shot in quick sequence on adjacent regions of the sky: such measurements provide almost instantaneous maps of optical thickness and skylight background that indicate the degree of homogeneity of the aerosol load. Additional information provided by the combined use of the camera and a lidar is presented. The zenithal optical thickness is used with values of the aerosol backscatter provided by a lidar system to obtain the aerosol extinction-to-backscatter ratio.     

Oceanographic lidar attenuation coefficients and signal fluctuations measured from a ship in the Southern California Bight

We measured the attenuation coefficient of the National Oceanic and Atmospheric Administration lidar from a ship in the Southern California Bight in September 1995. The region from approximately 5 to 30 m in depth was covered. The laser was linearly polarized, and the receiver was operated with the same polarization and the orthogonal polarization. The measured values were between 0.08 and 0.12 m(-1) and were highly correlated with in situ measurements of the beam attenuation coefficient. Fluctuations of the lidar signal were found to be induced primarily by surface waves whose wavelengths are approximately three times the lidar spot size at the surface.     

Distortion of particulate extinction profiles measured with lidar in a two-component atmosphere

Distortions of particular extinction-coefficient profiles measured with lidar in a two-component (molecular and aerosol) scattering atmosphere are analyzed. The error of the extinction coefficient measured at range r depends on the location of the point r(b), where a boundary value is specified, and the particulate optical depth of the atmosphere between r and r(b); the particulate backscatter-to-extinction ratio; and the ratio of particulate and molecular scattering extinction. If the near-end solution is used, small measurement errors can produce a significant divergence between the actual and the retrieved extinction-coefficient profiles, even if the boundary value and the particulate backscatter-to-extinction ratio are specified accurately. This effect is exacerbated at small values of the particulate scattering coefficient and the backscatter-to-extinction ratio. When reasonable criteria are used, feasible minimum and maximum boundary values can be specified to restrict the range of lidar equation solutions from below and from above.     

Deviation from the Lambert-Beer Law in the Transmittance of a Light Beam Through Diffusing Media: Experimental Results

Abstract

Attenuation measurements of an He-Ne laser beam in suspensions of polystyrene latex spheres are presented. Measurements were performed with a transmissometer having a receiver with a variable field of view (FOV) in a lenspinhole geometry. Attenuation measurements taken with different fields of view for any fixed optical depth, enabled us to separate the scattered received power P _s and the beam-attenuated power P ₀ from the total received power P. In this way the true value τ of the optical depth was obtained from P ₀ and compared with the apparent optical depth τ_A obtained from P. Thus the error ? = (τ ? τ_A)/τ due to the contribution of scattered received power in attenuation measurements was investigated. Many measurements were taken in order to see how τ_A and ? vary with the optical depth, with the size of the diffusing spheres and with geometric arrangement (radius and angular FOV of the receiver, distance between scattering cell and receiver).     

Frequency domain photothermoacoustic signal amplitude dependence on the optical properties of water: turbid polyvinyl chloride-plastisol system

Photoacoustic (more precisely, photothermoacoustic) signals generated by the absorption of photons can be related to the incident laser fluence rate. The dependence of frequency domain photoacoustic (FD-PA) signals on the optical absorption coefficient (micro(a)) and the effective attenuation coefficient (micro(eff)) of a turbid medium [polyvinyl chloride-plastisol (PVCP)] with tissuelike optical properties was measured, and empirical relationships between these optical properties and the photoacoustic (PA) signal amplitude and the laser fluence rate were derived for the water (PVCP system with and without optical scatterers). The measured relationships between these sample optical properties and the PA signal amplitude were found to be linear, consistent with FD-PA theory: micro(a)=a(A/Phi)-b and micro(eff)=c(A/Phi)+d, where Phi is the laser fluence, A is the FD-PA amplitude, and a, ...,d are empirical coefficients determined from the experiment using linear frequency-swept modulation and a lock-in heterodyne detection technique. This quantitative technique can easily be used to measure the optical properties of general turbid media using FD-PAs.     

Enhanced optical limiting performance in phthalocyanine-quantum dot nanocomposites by free-carrier absorption mechanism

Enhanced nonlinear optical properties (in dimethyl sulphoxide) is observed for 2(3),9(10),16(17),23(24)-tetrakis-(4-aminophenoxy)phthalocyaninato indium(III) chloride (InPc) when covalently linked to CdSe/ZnS or CdSe quantum dots (QDs). The experimental nonlinear optical parameters were obtained from Z-Scan measurements. Contributions from two-photon absorption (2PA) due to the InPc, and free-carrier absorption (FCA) by QDS have been identified as the main factors responsible for the enhanced optical limiting. The effective nonlinear absorption coefficient for InPc-CdSe/ZnS was found to be 700.0 cm/GW. The FCA cross-sections for InPc-CdSe/ZnS and InPc-CdSe composites were found to be 1.52 × 10⁻¹⁹ and 6.00 × 10⁻²⁰ cm² respectively. A much lower limiting threshold of 92 mJ cm⁻² was observed for InPc-CdSe/ZnS nanocomposite, hence, making it suitable for use as optical limiting material. Density Functional Theory (DFT) calculations on similar phthalocyanine-quantum dots system was modeled in order to explain the enhancement in the observed nonlinear optical properties of the Pc in the presence of the QDs. The experimentally determined nonlinear optical properties are well within the range of the DFT calculated properties.     

Variability of the downwelling diffuse attenuation coefficient with consideration of inelastic scattering

In situ time-series measurements of spectral diffuse downwelling irradiance from the Bermuda Testbed Mooring are presented. Averaged diffuse attenuation coefficients of downwelling irradiance, Kd,and their elastic and inelastic components are investigated at seven wavelengths. At shorter wavelengths (<510 nm), Kd is weakly dependent on the solar zenith angle owing to the prevailing scattering effect and therefore can be considered a quasi-inherent optical property. At longer wavelengths (>510 nm), Kd shows a strong dependence on the solar zenith angle. As depth increases, inelastic scattering plays a greater role for the underwater light field at red wavelengths.     

Standoff determination of the particle size and concentration of small optical depth clouds based on double scattering measurements: concept and experimental validation with bioaerosols

A multiple-field-of-view (MFOV) lidar is used to characterize size and optical depth of low concentration of bioaerosol clouds. The concept relies on the measurement of the forward scattered light by using the background aerosols at various distances at the back of a subvisible cloud. It also relies on the subtraction of the background aerosol forward scattering contribution and on the partial attenuation of the first-order backscattering. The validity of the concept developed to retrieve the effective diameter and the optical depth of low concentration bioaerosol clouds with good precision is demonstrated using simulation results and experimental MFOV lidar measurements. Calculations are also done to show that the method presented can be extended to small optical depth cloud retrieval.     

Retrieval of cloud optical parameters from space-based backscatter lidar data

We present an approach to estimating the multiple-scattering (MS) contribution to lidar return signals from clouds recorded from space that enables us to describe in more detail the return formation at the depth where first orders of scattering dominate. Estimates made have enabled us to propose a method for correcting solutions of single-scattering lidar equations for the MS contribution. We also describe an algorithm for reconstructing the profiles of the cloud scattering coefficient and the optical thickness tau under conditions of a priori uncertainties. The approach proposed is illustrated with results for optical parameters of cirrus and stratiform clouds determined from return signals calculated by the Monte Carlo method as well as from return signals acquired with the American spaceborne lidar during the Lidar In-Space Technology Experiment (LITE).     

Retrieving seawater-backscattering profiles from coupling Raman and elastic lidar data

We propose a technique for retrieving seawater-backscattering profiles that is based on the joint use of elastic and Raman lidar returns. We suggest using two lidar channels: the Raman channel and the elastic channel with a light frequency equal to a half-sum of initial and Raman-shifted frequencies of the Raman channel. These specific wavelengths provide the same attenuation laws for elastic and Raman signals if absorption and scattering spectra can be approximated by a power law. In particular, seawater supplies such a possibility in the region of 400-500 nm if extremely bioproductive waters are not considered and the chlorophyll absorption peak at 440 nm does not come out of the background of dissolved organic matter absorption. With these specific initial wavelengths, the elastic and Raman lidar returns differ only in the backscattering coefficients. Because the Raman-backscattering coefficient is constant along the profile, the (elastic-to-Raman) ratio of these lidar returns directly produces the profile of the elastic-backscattering coefficient. This technique stays valid even under multiple-scattering conditions, which is of great importance for seawater sounding.     

Use of a field lens for improving the overlap function of a lidar system employing an optical fiber in the receiver assembly

This paper presents a method to compute the overlap function of a lidar system in which a step-index optical fiber (or a bundle of such fibers) is used to carry the light collected by the telescope to the photoreceiver and a field lens is placed between the telescope and the optical fiber to increase the receiver field of view (FOV). The use of field lenses is a classical way to increase the FOV of radiometric systems (such as the receiving part of a lidar) when there is no numerical aperture (NA) limitation after the lens. However, when such a limitation exists, as in the case studied here, it will place a limit on the maximum attainable FOV. In the case of lidars, which have range-resolution capabilities, the limited FOV has an effect on the fraction of power coming from scattering volumes at different ranges that actually reaches the photodetector. This fraction is a function (the so-called overlap function) of the range of the scattering volume and its behavior has an impact on the accuracy of the retrievals. The application of the method developed in this paper shows that, in spite of the fiber NA limit, in practical situations the goal is attained of making the overlap function steeper and reaching higher values by using a field lens.     

Monte Carlo model of the penetration depth for polarization gating spectroscopy: influence of illumination-collection geometry and sample optical properties

Polarization-gating has been widely used to probe superficial tissue structures, but the penetration depth properties of this method have not been completely elucidated. This study employs a polarization-sensitive Monte Carlo method to characterize the penetration depth statistics of polarization-gating. The analysis demonstrates that the penetration depth depends on both the illumination-collection geometry [illumination-collection area (R) and collection angle (θ(c))] and on the optical properties of the sample, which include the scattering coefficient (μ(s)), absorption coefficient (μ(a)), anisotropy factor (g), and the type of the phase function. We develop a mathematical expression relating the average penetration depth to the illumination-collection beam properties and optical properties of the medium. Finally, we quantify the sensitivity of the average penetration depth to changes in optical properties for different geometries of illumination and collection. The penetration depth model derived in this study can be applied to optimizing application-specific fiber-optic probes to target a sampling depth of interest with minimal sensitivity to the optical properties of the sample.