Production of Biodiesel from Vegetable Oils: A Survey

Abstract

The purpose of this work is to investigate biodiesel production processes from vegetable oils. Biodiesel fuel can be made from new or used vegetable oils and animal fats, which are non-toxic, biodegradable, renewable resources. The vegetable oil fuels were not acceptable because they were more expensive than petroleum fuels. Biodiesel has become more attractive recently because of its environmental benefits. With recent increases in petroleum prices and uncertainties concerning petroleum availability, there is renewed interest in vegetable oil fuels for diesel engines. Dilution of oils with solvents and microemulsions of vegetable oils lowers the viscosity, and some engine performance problems still exist. The purpose of the transesterification process is to lower the viscosity of the oil. Pyrolysis produces more biogasoline than biodiesel fuel.     

Importance of biodiesel as transportation fuel

The scarcity of known petroleum reserves will make renewable energy resources more attractive. The most feasible way to meet this growing demand is by utilizing alternative fuels. Biodiesel is defined as the monoalkyl esters of vegetable oils or animal fats. Biodiesel is the best candidate for diesel fuels in diesel engines. The biggest advantage that biodiesel has over gasoline and petroleum diesel is its environmental friendliness. Biodiesel burns similar to petroleum diesel as it concerns regulated pollutants. On the other hand, biodiesel probably has better efficiency than gasoline. One such fuel for compression-ignition engines that exhibit great potential is biodiesel. Diesel fuel can also be replaced by biodiesel made from vegetable oils. Biodiesel is now mainly being produced from soybean, rapeseed and palm oils. The higher heating values (HHVs) of biodiesels are relatively high. The HHVs of biodiesels (39–41 MJ/kg) are slightly lower than that of gasoline (46 MJ/kg), petrodiesel (43 MJ/kg) or petroleum (42 MJ/kg), but higher than coal (32–37 MJ/kg). Biodiesel has over double the price of petrodiesel. The major economic factor to consider for input costs of biodiesel production is the feedstock, which is about 80% of the total operating cost. The high price of biodiesel is in large part due to the high price of the feedstock. Economic benefits of a biodiesel industry would include value added to the feedstock, an increased number of rural manufacturing jobs, an increased income taxes and investments in plant and equipment. The production and utilization of biodiesel is facilitated firstly through the agricultural policy of subsidizing the cultivation of non-food crops. Secondly, biodiesel is exempt from the oil tax. The European Union accounted for nearly 89% of all biodiesel production worldwide in 2005. By 2010, the United States is expected to become the world's largest single biodiesel market, accounting for roughly 18% of world biodiesel consumption, followed by Germany.     

Prospects of biodiesel from Jatropha in India: A review

The increasing industrialization and modernization of the world has to a steep rise for the demand of petroleum products. Economic development in developing countries has led to huge increase in the energy demand. In India, the energy demand is increasing at a rate of 6.5% per annum. The crude oil demand of the country is met by import of about 80%. Thus the energy security has become a key issue for the nation as a whole. Petroleum-based fuels are limited. The finite reserves are highly concentrated in certain regions of the world. Therefore, those countries not having these reserves are facing foreign exchange crises, mainly due to the import of crude oil. Hence it is necessary to look forward for alternative fuels, which can be produced from feedstocks available within the country.Biodiesel, an ecofriendly and renewable fuel substitute for diesel has been getting the attention of researchers/scientists of all over the world. The R & D has indicated that up to B20, there is no need of modification and little work is available related to suitability and sustainability of biodiesel production from Jatropha as non-edible oil sources. In addition, the use of vegetable oil as fuel is less polluting than petroleum fuels. The basic problem with biodiesel is that it is more prone to oxidation resulting in the increase in viscosity of biodiesel with respect to time which in turn leads to piston sticking, gum formation and fuel atomization problems.The report is an attempt to present the prevailing fossil fuel scenario with respect to petroleum diesel, fuel properties of biodiesel resources for biodiesel production, processes for its production, purification, etc. Lastly, an introduction of stability of biodiesel will also be presented.     

Production of biodiesel fuels from linseed oil using methanol and ethanol in non-catalytic SCF conditions

Methyl and ethyl esters as biodiesel fuels were prepared from linseed oil with transesterification reaction in non-catalytic supercritical fluids conditions. Biodiesel fuel is a renewable substitute fuel for petroleum diesel fuel made from vegetable or animal fats. Biodiesel fuel has better properties than that of petroleum diesel fuel such as renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. The purpose of the transesterification process is to lower the viscosity of the oil. The viscosity values of linseed oil methyl and ethyl esters highly decreases after transesterification process. The viscosity values of vegetable oils vary between 27.2 and 53.6 mm² s^?1, whereas those of vegetable oil methyl esters between 3.59 and 4.63 mm² s^?1. Compared with no. 2 diesel fuel, all of the vegetable oil methyl esters were slightly viscous. The flash point values of vegetable oil methyl esters are highly lower than those of vegetable oils. The transesterification of linseed oil in supercritical fluids such as methanol and ethanol has proved to be the most promising process. Methanol is the commonly used alcohol in this process, due in part to its low cost. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The most important variables affecting the methyl ester yield during the transesterification reaction are molar ratio of alcohol to vegetable oil and reaction temperature. Biodiesel has become more attractive recently because of its environmental benefits. Biodiesel is an environmentally friendly fuel that can be used in any diesel engine without modification.     

Quality analysis studies on biodiesel production of neochloris oleoabundans algae

The petroleum fuels play a major role in industry, agriculture, and transport besides meeting out many other basic human needs. However, fossil fuels are limited in quantity and are depleting day by day as the consumption is increasing very rapidly. Biodiesel is one such fuel in which there is a lot of hope. In the recent past, biodiesel received considerable attention as a renewable fuel. In India, it has not been possible to produce biodiesel from edible oils since the same is very scarce. Hence, the scope of opting to non-edible oils from plants as raw material for biodiesel production recently gained momentum. This paper presents the production of biodiesel from nonedible, Neochloris oleoabundans oil and its characterization. The studies were carried out on transesterification of oil with methanol, sodium hydroxide, and Sodium methoxide as catalyst for the production of biodiesel. The process parameters such as catalyst concentration, reaction time, and reaction temperature were optimized for the production of Neochloris oleoabundans oil biodiesel. The biodiesel yield of 95.15% was noticed at optimal process parameters.     

Performance and emission evaluation of a diesel engine fueled with methyl esters of rubber seed oil

Recent concerns over the environment, increasing fuel prices and scarcity of its supply have promoted the interest in development of the alternative sources for petroleum fuels. At present, biodiesel is commercially produced from the refined edible vegetable oils such as sunflower oil, palm oil and soybean oil, etc. by alkaline-catalyzed esterification process. This process is not suitable for production of biodiesel from many unrefined non-edible vegetable oils because of their high acid value. Hence, a two-step esterification method is developed to produce biodiesel from high FFA vegetable oils. The biodiesel production method consists of acid-catalyzed pretreatment followed by an alkaline-catalyzed transesterification. The important properties of methyl esters of rubber seed oil are compared with other esters and diesel. Pure rubber seed oil, diesel and biodiesel are used as fuels in the compression ignition engine and the performance and emission characteristics of the engine are analyzed. The lower blends of biodiesel increase the brake thermal efficiency and reduce the fuel consumption. The exhaust gas emissions are reduced with increase in biodiesel concentration. The experimental results proved that the use of biodiesel (produced from unrefined rubber seed oil) in compression ignition engines is a viable alternative to diesel.     

Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods

This paper reviews the production and characterization of biodiesel (BD or B) as well as the experimental work carried out by many researchers in this field. BD fuel is a renewable substitute fuel for petroleum diesel or petrodiesel (PD) fuel made from vegetable or animal fats. BD fuel can be used in any mixture with PD fuel as it has very similar characteristics but it has lower exhaust emissions. BD fuel has better properties than that of PD fuel such as renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. There are more than 350 oil bearing crops identified, among which only sunflower, safflower, soybean, cottonseed, rapeseed and peanut oils are considered as potential alternative fuels for diesel engines. The major problem associated with the use of pure vegetable oils as fuels, for Diesel engines are caused by high fuel viscosity in compression ignition. Dilution, micro-emulsification, pyrolysis and transesterification are the four techniques applied to solve the problems encountered with the high fuel viscosity. Dilution of oils with solvents and microemulsions of vegetable oils lowers the viscosity, some engine performance problems still exist. The viscosity values of vegetable oils vary between 27.2 and 53.6 mm²/s whereas those of vegetable oil methyl esters between 3.59 and 4.63 mm²/s. The viscosity values of vegetable oil methyl esters highly decreases after transesterification process. Compared to no. 2 diesel fuel, all of the vegetable oil methyl esters were slightly viscous. The flash point values of vegetable oil methyl esters are highly lower than those of vegetable oils. An increase in density from 860 to 885 kg/m³ for vegetable oil methyl esters or biodiesels increases the viscosity from 3.59 to 4.63 mm²/s and the increases are highly regular. The purpose of the transesterification process is to lower the viscosity of the oil. The transesterfication of triglycerides by methanol, ethanol, propanol and butanol, has proved to be the most promising process. Methanol is the commonly used alcohol in this process, due in part to its low cost. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The most important variables affecting the methyl ester yield during the transesterification reaction are molar ratio of alcohol to vegetable oil and reaction temperature. Biodiesel has become more attractive recently because of its environmental benefits. Biodiesel is an environmentally friendly fuel that can be used in any diesel engine without modification.     

Progress in biodiesel processing

Biodiesel is a notable alternative to the widely used petroleum-derived diesel fuel since it can be generated by domestic natural sources such as soybeans, rapeseeds, coconuts, and even recycled cooking oil, and thus reduces dependence on diminishing petroleum fuel from foreign sources. The injection and atomization characteristics of the vegetable oils are significantly different than those of petroleum-derived diesel fuels, mainly as the result of their high viscosities. Modern diesel engines have fuel-injection system that is sensitive to viscosity change. One way to avoid these problems is to reduce fuel viscosity of vegetable oil in order to improve its performance. The conversion of vegetable oils into biodiesel is an effective way to overcome all the problems associated with the vegetable oils. Dilution, micro-emulsification, pyrolysis, and transesterification are the four techniques applied to solve the problems encountered with the high fuel viscosity. Transesterification is the most common method and leads to monoalkyl esters of vegetable oils and fats, now called biodiesel when used for fuel purposes. The methyl ester produced by transesterification of vegetable oil has a high cetane number, low viscosity and improved heating value compared to those of pure vegetable oil which results in shorter ignition delay and longer combustion duration and hence low particulate emissions.     

Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review

The world is confronted with the twin crises of fossil fuel depletion and environmental degradation. The indiscriminate extraction and consumption of fossil fuels have led to a reduction in petroleum reserves. Petroleum based fuels are obtained from limited reserves. These finite reserves are highly concentrated in certain region of the world. Therefore, those countries not having these resources are facing a foreign exchange crisis, mainly due to the import of crude petroleum oil. Hence it is necessary to look for alternative fuels, which can be produced from materials available within the country. Although vegetative oils can be fuel for diesel engines, but their high viscosities, low volatilities and poor cold flow properties have led to the investigation of its various derivatives. Among the different possible sources, fatty acid methyl esters, known as Biodiesel fuel derived from triglycerides (vegetable oil and animal fates) by transesterification with methanol, present the promising alternative substitute to diesel fuels and have received the most attention now a day. The main advantages of using Biodiesel are its renewability, better quality exhaust gas emission, its biodegradability and the organic carbon present in it is photosynthetic in origin. It does not contribute to a rise in the level of carbon dioxide in the atmosphere and consequently to the green house effect. This paper reviews the source of production and characterization of vegetable oils and their methyl ester as the substitute of the petroleum fuel and future possibilities of Biodiesel production.     

New Options for Conversion of Vegetable Oils to Alternative Fuels

Biodiesel from transesterification of vegetable oils is an excellent alternative fuel. There is, however, a need to develop a direct process for conversion of vegetable oils into gasoline-competitive biodiesel and other petroleum products. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The purpose of the transesterification process is to lower the viscosity of vegetable oil. Compared to No. 2 diesel fuel, all of the vegetable oils are much more viscous, whereas methyl esters of vegetable oils are slightly more viscous. The methyl esters are more volatile than those of the vegetable oils. Conversion of vegetable oils to useful fuels involves the pyrolysis and catalytic cracking of the oils into lower molecular products. Pyrolysis produces more biogasoline than biodiesel fuel. Soap pyrolysis products of vegetable oils can be used as alternative diesel engine fuel. The soaps obtained from the vegetable oils can be pyrolyzed into hydrocarbon-rich products. Zinc chloride catalyst contributed greatly to high amounts of hydrocarbons in the liquid product. The yield of ZnCl ₂ catalytic conversion of the soybean oil reached the maximum 79.9% at 660 K.     

High quality biodiesel and its diesel engine application: A review

The continuous increasing demand for energy and the diminishing tendency of petroleum resources has led to the search for alternative renewable and sustainable fuel. Biodiesel is best substitute for petro-diesel and also most advantageous over petro-diesel for its environmental friendliness. The quality of biodiesel fuel was found to be significant for its successful use on compression ignition engines and subsequent replacement of non-renewable fossil fuels. Conventional biodiesel separation and purification technologies were noticed to yield lower quality biodiesel fuel with resultant excessive energy and water consumptions. Membrane technology showed more potential for effective and efficient separation and purification of biodiesel. This technology need be explored for the attainment of better quality biodiesel fuels. This paper reviews the technologies used for the biodiesel separation and purification, biodiesel quality, and its effects on diesel engines. Biodiesel biodegradability, lubricity, stability, economic importance, and gaseous emissions have been discussed.     

Ethyl levulinate: A potential bio-based diluent for biodiesel which improves cold flow properties

Biodiesel, defined as mono-alkyl esters of long-chain fatty acids derived from vegetable oils or animal fats, is an attractive renewable fuel alternative to conventional petroleum diesel fuel. Biodiesel produced from oils such as cottonseed oil and poultry fats suffer from extremely poor cold flow properties because of their high saturated fatty acid content. In the current study, Ethyl Levulinate (ethyl 4-oxopentanoate) was investigated as a novel, bio-based cold flow improver for use in biodiesel fuels. The cloud (CP), pour (PP), and cold filter plugging points (CFPP) of biodiesel fuels prepared from cottonseed oil and poultry fat were improved upon addition of ethyl levulinate at 2.5, 5.0, 10.0, and 20.0% (vol). Reductions of 4-5 °C in CP, 3-4 °C in PP and 3 °C in CFPP were observed at 20 vol % ethyl levulinate. The influence of ethyl levulinate on acid value, induction period, kinematic viscosity and flash point was determined. The kinematic viscosities and flash points decreased with increasing content of ethyl levulinate. All samples (≤15 vol % ethyl levulinate) satisfied the ASTM D6751 limit with respect to flash point, but none of the 20 vol % blends were acceptable when compared to the higher EN 14214 specification. Acid value and oxidative stability were essentially unchanged upon addition of ethyl levulinate. In summary, ethyl levulinate appears acceptable as a diluent for biodiesel fuels with high saturated fatty acid content.     

Combustion of fat and vegetable oil derived fuels in diesel engines

In this article, the status of fat and oil derived diesel fuels with respect to fuel properties, engine performance, and emissions is reviewed. The fuels considered are primarily the methyl esters of fatty acids derived from a variety of vegetable oils and animal fats, and referred to as biodiesel. The major obstacle to widespread use of biodiesel is the high cost relative to petroleum. Economics of biodiesel production are discussed, and it is concluded that the price of the feedstock fat or oil is the major factor determining biodiesel price.Biodiesel is completely miscible with petroleum diesel fuel, and is generally tested as a blend. The use of biodiesel in neat or blended form has no effect on the energy based engine fuel economy. The lubricity of these fuels is superior to conventional diesel, and this property is imparted to blends at levels above 20 vol%. Emissions of PM can be reduced dramatically through use of biodiesel in engines that are not high lube oil emitters. Emissions of NO_x increase significantly for both neat and blended fuels in both two- and four-stroke engines. The increase may be lower in newer, lower NO_x emitting four-strokes, but additional data are needed to confirm this conclusion. A discussion of available data on unregulated air toxins is presented, and it is concluded that definitive studies have yet to be performed in this area. A detailed discussion of important biodiesel properties and recommendations for future research is presented. Among the most important recommendations is the need for all future studies to employ biodiesel of well-known composition and purity, and to report detailed analyses. The purity levels necessary for achieving adequate engine endurance, compatibility with coatings and elastomers, cold flow properties, stability, and emissions performance must be better defined.     

生物柴油特性分析与应用

生产生物柴油的主要原料是可再生的生物资源,生物柴油含氧而基本不合硫和芳香烃,具有良好的燃料品质和环境友好性,从能源战略角度分析,生物柴油是最为重要的代用燃料之一.柴油机不需改动即可使用生物柴油,柴油机使用生物柴油不仅利于改善燃料结构,而且可以降低有害排放.本文对比了生物柴油与矿物柴油的燃料特性,分析了柴油机燃用生物柴油的好处,介绍了生物柴油在国内外的发展情况,指出发展生物柴油的目的并不是要取代矿物柴油,而在于改善矿物柴油的性能,以满足不断严格的排放标准,并对推动我国生物柴油的发展提出了建议.     

Palm oil: Addressing issues and towards sustainable development

The quest for renewable energy has intensified since the escalating price of crude petroleum in the recent years. Renewable energy such as biodiesel has the potential to replace petroleum-derived transportation fuel in the future. Biodiesel is defined as the mono-alkyl esters of long-chain fatty acids derived from vegetable oils such palm oil, rapeseed and soybean. Currently, more than 80% of the world biodiesel productions are from rapeseed oil. However, the cost of palm oil which is at least US$ 200 per tonne cheaper than rapeseed oil indicates that palm oil could be a more suitable and attractive candidate as the source of biodiesel compared to other vegetable oils. Although palm oil is known to be a multi-purpose vegetable oil with products ranging from food to biodiesel, there are a lot of issues surrounding palm oil production. Nevertheless, some of these issues reported in the literature were found to be misleading and are thus confusing the public perception on palm oil. Thus, the aim of this paper is to highlight and clarify the negative issues reported in the literature surrounding palm oil production. Apart from that, various policies or/and strategies that will lead to a more sustainable production and development of palm oil industries will also be proposed. Hence, palm oil will be able to become the leading vegetable oil in terms of food and non-food production, especially as the main source of renewable energy, biodiesel.     

非直喷式增压柴油机燃用生物柴油的性能与排放特性

研究了非直喷式增压柴油机燃用柴油一生物柴油混合燃料的性能和排放特性。未对原机作任何调整和改动,研究了不同生物柴油掺混比例的混合燃料对功率、油耗、烟度和NOx排放的影响。结果表明：非直喷式柴油机燃用生物柴油后柴油机功率略有下降,油耗有所上升,烟度大幅下降,NOx排放增加明显。油耗、烟度和NOx的变化均与生物柴油掺混比例呈线性关系,合适的生物柴油掺混比例即可以保持柴油机的性能,又可有效地降低碳烟排放,且不引起NOx排放的显著变化。对于该增压柴油机,掺混生物柴油对外特性下的排放影响最大,影响最小的为标定转速下的负荷特性。不论是全负荷还是部分负荷,燃用生物柴油时低速下的烟度降低和NOx上升幅度均比高速时大,而同转速下高负荷时烟度降低和NOx上升更为明显。     

Progress and recent trends in biofuels

In this paper, the modern biomass-based transportation fuels such as fuels from Fischer–Tropsch synthesis, bioethanol, fatty acid (m)ethylester, biomethanol, and biohydrogen are briefly reviewed. Here, the term biofuel is referred to as liquid or gaseous fuels for the transport sector that are predominantly produced from biomass. There are several reasons for bio-fuels to be considered as relevant technologies by both developing and industrialized countries. They include energy security reasons, environmental concerns, foreign exchange savings, and socioeconomic issues related to the rural sector. The term modern biomass is generally used to describe the traditional biomass use through the efficient and clean combustion technologies and sustained supply of biomass resources, environmentally sound and competitive fuels, heat and electricity using modern conversion technologies. Modern biomass can be used for the generation of electricity and heat. Bioethanol and biodiesel as well as diesel produced from biomass by Fischer–Tropsch synthesis are the most modern biomass-based transportation fuels. Bio-ethanol is a petrol additive/substitute. It is possible that wood, straw and even household wastes may be economically converted to bio-ethanol. Bio-ethanol is derived from alcoholic fermentation of sucrose or simple sugars, which are produced from biomass by hydrolysis process. Currently crops generating starch, sugar or oil are the basis for transport fuel production. There has been renewed interest in the use of vegetable oils for making biodiesel due to its less polluting and renewable nature as against the conventional petroleum diesel fuel. Biodiesel is a renewable replacement to petroleum-based diesel. Biomass energy conversion facilities are important for obtaining bio-oil. Pyrolysis is the most important process among the thermal conversion processes of biomass. Brief summaries of the basic concepts involved in the thermochemical conversions of biomass fuels are presented. The percentage share of biomass was 62.1% of the total renewable energy sources in 1995. The reduction of greenhouse gases pollution is the main advantage of utilizing biomass energy.     

Theoretical modeling and experimental studies on biodiesel-fueled engine

In recent years, much research has been carried out to find suitable alternative fuel to petroleum products. The use of renewable fuels like ethanol, biogas and biodiesel in diesel engines is significant in this context. The properties of biodiesel depend on the type of the vegetable oil used for the trans-esterification process. Experimental analysis of the engine with various biodiesel and its blends requires much effort and time. Hence, a theoretical model is developed to analyze the performance characteristics of the compression ignition engine fueled by biodiesel and its blends. In the present investigation, biodiesel is produced using unrefined rubber seed oil. A two-step trans-esterification process (i.e. acid–alkaline trans-esterification) is developed for the production of methyl-esters of rubber seed oil. The properties of this biodiesel are closely matched with those of diesel fuel. The performance tests are carried out on a C.I. engine using biodiesel and its blends with diesel (B20 and B100) as fuel. The effects of relative air-fuel ratio and compression ratio on the engine performance for different fuels are also analyzed using this model. The comparison of theoretical and experimental results are presented.     

Necessity of biodiesel utilization as a source of renewable energy in Malaysia

In recent decades, the energy crisis and environmental issues have become a crucial problem. The rapid industrialization has lead humankind to deplete the fossil fuels and consequently the pollutant emissions have increased in the world. Many investigations have been done to find an alternative fuel to fulfill increasing energy demand. Recently, biodiesel has been introduced as an economical renewable and sustainable fuel which is cited as an environment-friendly resource. Around 350 oil-bearing crops were analyzed and some of them were capable to be considered as potential alternative fuels for diesel engines. These include virgin vegetable oils and waste vegetable oils. Rapeseed, jatropha, soybean, and palm oil are mentioned as the most common sources of biodiesel. Many countries have invested in biodiesel as an acceptable source of energy not only in research area but also in production and export. It has been proven that the biodiesel combustion characteristics are similar as petroleum. Higher ignition pressure and temperature, shorter ignition delay and higher peak release were reported in experimental combustion of biodiesel blends. Also, the efficiency of biodiesel base catalysts is more than enzymes and acid catalysts. This article is a literature review on necessity of biodiesel production as alternative fuel recourse in Malaysia and tries to illustrate the combustion characteristics and pollutant formation in biodiesel application.     

Optimization of ethanolic transesterification ultrasound‐assisted from oil mixtures utilizing Box‐Behnken design

Biodiesel is an alternative renewable fuel in the world energy matrix, originating from animal fats and vegetable oils from grains, such as the castor bean cultivated by family farmers in the Brazilian semiarid region. However, the production of biodiesel has some disadvantages. For example, it is difficult to use the same types of oil/fat all year round. In addition, the use of methanol in the biodiesel synthesis and agitation process results in a high consumption of energy. Given this background, this article proposes an alternative biodiesel synthesis using castor oil and peanut oil mixtures, ultrasound‐assisted in an ethylic route. The experimental conditions were optimized utilizing a Box‐Behnken design. The response variable was a biodiesel yield. In this work, it was possible to reduce the ratio of alcohol to oil and thus reduce the energy consumption and increase the mass yield. This permitted the generation of biofuel with lower production costs. Finally, the response surface methodology leads to operational conditions more suitable for the production of biodiesel. In this work, the best conditions were obtained using 0.50% catalyst concentration, 50/50 castor:peanut oil rate, and 5:1 alcohol:oil ratio. These were moderate and suitable conditions for the synthesis of biodiesel in comparison with the works found in the literature, reaching a high yield of 97.93%.