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苯乙烯是重要的石油化工原料。本文介绍了国内外苯乙烯生产的发展概况,合成乙苯,苯乙烯所用的催化剂种类,并就苯乙烯生产及催化剂的发展趋势提出了自己的观点。 相似文献
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Synthesis and characterization of homopolymers and copolymers of various acrylates and acrylonitrile
Various homopolymers and copolymers of methyl acrylate, ethyl acrylate, butyl acrylate, and acrylonitrile in different feed ratios were synthesized. These were characterized by IR, 13C-NMR, DSC, DTA, and TGA. Spectroscopic characterization helped in differentiating copolymers of different mol ratios. Thermal analysis revealed different degradation patterns for homopolymers and copolymers. The temperature and energy changes associated with various phase transitions were dependent on the chemical composition of homo- and copolymers, as expected. © 1993 John Wiley & Sons, Inc. 相似文献
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The variation of the Au 4f binding energy of Au clusters with the cluster size has been established by measuring the binding energies of clusters whose size distributions were independently determined by HREM and STM. The binding energy increases significantly when the cluster size is less than 2 nm. Au-Cu bimetallic clusters of the composition Cu3Au have been deposited for the first time on carbon substrates. The shifts in the core level binding energies of the bimetallic clusters show the effect of alloying in the case of large clusters, but show effects of both alloying and cluster size in the case of the small clusters. The interaction of CO with Cu3Au clusters is stronger than with a bulk Cu metal. The interaction of CO with small Cu clusters also seems to be stronger than with bulk Cu or with large Cu clusters. 相似文献
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《国际聚合物材料杂志》2012,61(1-4):113-122
Abstract Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15–16 hr) leads to the formation monoethers of the corresponding glycols with 68–90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed. 相似文献
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G. R. Hamed 《The Journal of Adhesion》1983,16(1):31-39
A substantially greater detachment energy is required to strip a polyethylene tereph-thalate (Mylar) film from a styrene-butadiene-styrene (SBS) triblock copolymer compared to that for peeling from a random styrene-butadiene (SBR) copolymer. This is true even though the intrinsic interaction between the Mylar and each elastomer is expected to be similar because of their virtually identical chemical composition. It is proposed that this difference in peel strength (between the SBS and SBR) is a consequence of the much higher dissipative capacity of the former elastomer. Another manifestation of this is the higher cohesive tear strength of the SBS compared to the SBR. Extents of energy dissipation within each elastomer during detachment of the Mylar adherend are consistent with the hypothesis that the average maximum stress experience before detachment is some similar fraction of each elastomer's tensile strength. 相似文献
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Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method1 was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity. 相似文献
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责任是人应主动承担的角色义务和对其因过失所造成后果应承担的责罚.有两层涵义:一是义务;二是后果.责任心是个体自觉做好分内事务和履行道德义务的心理倾向,是个性心理品质成分中自我特征维度上的重要内容.责任心具有两个方面的涵义:一是角色分内职责;二是角色道德义务.责任心是一种通过责任认知、责任个性和责任适应的动态形式表现出来的静态品质,责任心是责任心过程结构与责任心关系结构相互制约、相互影响的统一体. 相似文献
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对用甘油锌作光稳定剂的光稳定作用进行了测试,并与光稳定剂NBC,BZ进行了比较。研究了甘油锌,NBC和BZ与双酚A的复配效果。研究结果表明,甘油锌是一种性能优良的光稳定剂。 相似文献
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Antioxidative activity and phenolic composition of pilot-plant and commercial extracts of sage and rosemary 总被引:5,自引:0,他引:5
Marie-Elisabeth Cuvelier Hubert Richard Claudette Berset 《Journal of the American Oil Chemists' Society》1996,73(5):645-652
Eight sage (Salvia officinalis) and twenty-four rosemary (Rosmarinus officinalis) extracts, originating from pilot-plant or commercial sources, had different antioxidative activities as measured by accelerated
autoxidation of methyl linoleate. Twenty-seven compounds were characterized in the Labiatae family extracts by high-performance
liquid chromatography (HPLC) coupled with mass spectrometry, equipped with an atmospheric pressure chemical ionization interface,
and by HPLC coupled with a photodiode array spectrophotometer. Twenty-two compounds were identified, including phenolic acids,
carnosol derivatives, and flavonoids. The extracts showed great variation in their HPLC profiles, and no correlation was apparent
between their antioxidative efficiency and their composition, in twenty specific phenols. Data indicated that the most effective
compounds were carnosol, rosmarinic acid, and carnosic acid, followed by caffeic acid, rosmanol, rosmadial, genkwanin, and
cirsimaritin. 相似文献
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随着我国经济的高速发展,对油气资源的需求量不断增加,油气生产事业发展非常迅速。在实际油气生产的过程中,油气储运是其中重要的一项,各种油气储运设备承担着大量的油气储运任务,一旦对其日常管理工作没有做到位,就很容易导致各种问题的发生,严重影响到生产的有序进行。 相似文献
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We reported earlier on the occurrence of cholinephosphotransferase in the mitochondria of guinea pig lung. In order to determine
whether organ and/or species specificities exist in regard to the cholinephosphotransferase activity in mitochondria, we have
compared the subcellular distribution of the enzyme in the liver and lungs of rats and guinea pigs. Even though the activity
of the enzyme was higher in microsomes than it was in mitochondria, the mitochondrial activity was authentic in both tissues
of both species. The authenticity of mitochondrial activity was established by marker enzyme studies and ultrastructural examination
of mitochondrial preparations.
Presented in part at the Seventy-third Annual Meeting of the Federation of American Societies for Experimental Biology, New
Orleans, LA, March 1989. 相似文献