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1.
Recycling of sludge with the Aqua Reci process.   总被引:3,自引:0,他引:3  
Supercritical Water Oxidation (SCWO) is an innovative and effective destruction method for organics in sewage sludge. The SCWO process leaves a slurry of inorganic ash in a pure water phase free from organic contaminants, which opens possibilities for a simple process to recover components like phosphates and/or coagulants from the sewage sludge, a process marketed as the Aqua Reci. In a continuous pilot plant for the SCWO process digested sludge has been treated. The ash has been extracted in lab- and pilot scale with both caustic and acids in order to recover phosphates and coagulants. The particle size of the inorganic contaminants in the water after the SCWO process is between 1-10 microm, which means that it is very reactive. The phosphate, and partly the aluminium, can be extracted with caustic as iron and heavy metals are completely insoluble in caustic. This is a method to separate the phosphates from the rest of the contaminants. However, high calcium content will bind the phosphate as calcium phosphate insoluble in caustic. In most cases the calcium content is too high and the best solution is to dissolve phosphates and all metals with sulphuric acid. From this solution first iron phosphate can be separated and thereafter in a second step aluminium and finally heavy metals in a third step. Iron can be separated from the phosphate, either by leaching the phosphate with caustic off to sodium phosphate leaving a precipitate consisting of iron hydroxide, or the iron phosphate can be dissolved in hydrochloric acid followed by a liquid extraction process where ferric chloride can be separated leaving a phosphoric acid. By the acid dissolving process it is possible to recover phosphate, iron, aluminium, and heavy metals from the inorganic since the Aqua Reci process only leaves a silica residue representing about 10% of the DS content in the original sludge.  相似文献   

2.
In this paper, phosphorus balances are calculated for the wastewater purification and sludge treatment stages for wastewater treatment plants (WWTPs) applying Enhanced Biological Phosphorus Removal (EBPR). The possible P-recovery potential is then estimated and evaluated regarding different locations along the process of wastewater purification and sludge treatment, taking the different phosphorus bonding forms into account. Caused by the more favourable bonding forms in the excess sludge as well as possibly also in the sludge ash a recovery of the phosphorus seems especially favoured for WWTPs with EBPR. The processes available for a P recycling are named, and special regard is given to the Phostrip-process, which is a possible recycling process already tested in practice. Further R&D demand consists in basic research regarding disintegration, fermentation or acidic total digestion of excess sludge followed by phosphorus precipitation including separation of the precipitates, MAP-precipitation and separation from digested sludge and on the ability to extract phosphorus and heavy metals from sewage sludge ash. These investigations are a precondition to enable purposeful process developments. At the present state the cost of recycled phosphorus earned from wastewater, sludge and ash, respectively, are a multiple higher than the costs for raw phosphate taking into account the suitable processes. Thus, up to now no phosphorus recycling with a defrayal of costs is possible. The future importance of phosphorus recycling will depend on the market price for raw phosphate, the recycling costs and, furthermore, on the general political framework.  相似文献   

3.
Global reserves of mineral phosphorus are finite and the recycling of phosphorus from wastewater, a significant sink for phosphorus, can contribute to a more sustainable use. In Germany, Switzerland, and the Netherlands, an increasing percentage of municipal sewage sludge is incinerated and the contained phosphorus is lost. This paper reviews current technologies and shows that a complete phosphorus recovery from wastewater is technically feasible. Depending on the composition of the sewage sludge ash (SSA), there are various options for phosphorus recovery that are presented. Iron-poor SSAs can be used directly as substitute for phosphate rock in the electrothermal phosphorus process. SSAs with low heavy metal contents can be used as fertilizer without prior metal elimination. Ashes not suitable for direct recycling can be processed by thermal processes. Operators of wastewater treatment plants can additionally influence the ash composition via the selection of precipitants and the control of (indirect) dischargers. This way, they can choose the most suitable phosphorus recovery option. For sewage sludge that is co-incinerated in power plants, municipal waste incinerators or cement kilns phosphorus recovery is not possible. The phosphorus is lost forever.  相似文献   

4.
Removal and recovery of phosphorus from sewage in form of MAP (magnesium ammonium phosphate) have attracted attention from the viewpoint of eutrophication prevention and phosphorus resource recovery as well as scaling prevention inside digestion tanks. In this work, phosphorus recovery demonstration tests were conducted in a 50 m3/d facility having a complete mixing type reactor and a liquid cyclone. Digested sludge, having 690 mg/L T-P and 268 mg/L PO4-P, was used as test material. The T-P and PO4-P of treated sludge were 464 mg/L and 20 mg/L achieving a T-P recovery efficiency of 33% and a PO4-P crystallization ratio of 93%. The reacted phosphorus did not become fine crystals and the recovered MAP particles were found to be valuable as a fertilizer. A case study in applying this phosphorus recovery process for treatment of sludge from an anaerobic-aerobic process of a 21,000 m3/d sewage system, showed that 30% of phosphorus concentration can be reduced in the final effluent, recovering 315 kg/d as MAP.  相似文献   

5.
The recovery of phosphorus from sewage and sludge treatment systems is particularly important because it is a limited resource and a large proportion of the phosphorus currently used in Japan must be imported. We have been experimentally evaluating recovery methods with sulphide. In this study, we focussed on the extraction of phosphate from the sludge, and sought to achieve a greater extraction efficiency and to validate the extraction mechanism. We conducted three experiments, i.e. a sludge-type experiment, a coagulant ratio of pre-coagulated sludge experiment, and a concentration of pre-coagulated sludge experiment. Phosphate was extracted not with normal sewage sludge but with pre-coagulated sludge and FePO4 reagent at S/Fe = 1.0-2.0. A coagulant ratio of 23mg Fe L(-1) was required in the precoagulation process to effectively extract phosphate. A high concentration of pre-coagulated sludge was required for the phosphate extraction. The mass balance was calculated, and 44.0% of phosphorus was extracted to supernatant, and 98.5% of iron and 98.3% of sulphur (44.1% of sulphur was sulphide). Thus, phosphate can be selectively separated from iron by the phosphate extraction method with NaHS, and phosphorus and iron can be recovered and reused at sewage treatment plants using ferric chloride as a coagulant.  相似文献   

6.
Phosphorus (P) is a vital but limited resource. Though Austria has no P deposits, municipal wastewater offers a potential but largely overlooked source of phosphorus. Over the last several years, numerous technologies have been developed for recovering P from various streams at a wastewater treatment plant. This work uses an approach developed by the authors to assess these technologies on the basis of technical, ecological and economic criteria, providing a basis that legislators and political decision-makers can orient a future, optimized P management system on. The study shows that e.g. technologies for recovering P from process water are already available, and that under the right circumstances they can be used to affordably deliver a high-purity, plant-available end product; however, the potential for P recovery is relatively low. In order to arrive at maximal utilization of the phosphorus from wastewater, the future focus should be on recovery from sewage sludge ash. In this regard, mixing with low-phosphorus ash should be avoided. At this time, however, the necessary structures like e.g. monoincineration plants still need to be expanded. Which technology/ technologies will ultimately be used for the treatment of sewage sludge ash depends e.g. on considerations of affordability, heavy metal elimination, and the plant-availability of the P recovered. The advantages of a strategy based on “monocombustion” of sewage sludge are on the one hand the option of using further P-rich material flows (e.g. meat and bone meal) and on the other, the freedom to store the ash for future recovery (creating an Austrian “phosphate mine”).  相似文献   

7.
Due to the depletion of mineral phosphorus resources there is an increasing demand for efficient phosphorus recovery technologies. In this study the potential of nanofiltration to recover phosphorus from pre-treated sewage sludge is investigated. The efficiency of three commercial nanofiltration membranes (Desal 5DK, NP030; MPF34) was tested using model solutions. Desal 5DK showed the best selectivity for phosphorus. A pH of lower than 1.5 was found to be most suitable. Desal 5DK was used on four different sewage sludge ash eluates and on one sewage sludge. In these experiments it was shown that a separation of phosphorus from undesired components such as heavy metals was possible with significant variations in the efficiency for the different ash and sludge types. Additionally the achievable product recovery was investigated with model solutions. A product recovery of 57.1% was attained for pH 1 and 41.4% for pH 1.5.  相似文献   

8.
Heavy metals removal without phosphorus loss from anaerobically digested sewage sludge was investigated by conducting batch experiments using hydrogen peroxide and/or iron sulphate under acidified conditions at pH 3. The addition of hydrogen peroxide to the sludge improved the elution efficiencies of As, Cd, Cu and Zn with phosphorus loss from the sludge. The optimum initial concentrations of hydrogen peroxide were. Respectively. 0.1% for As, Cd, Mn and Zn and 0.5% for Cu and Ni. The combined process of 0.1% hydrogen peroxide and 1 g Fe/L ferric sulphate enhanced the initial elution rate of Cu and Cr compared to the addition of either ferric sulphate or hydrogen peroxide, indicating that oxidants stronger than hydrogen peroxide were produced in the sludge. Furthermore, the combined process immobilised phosphorus in the sludge due to co-precipitation with ferric hydroxide or precipitation as ferric phosphate. It was concluded that there is a possibility that the combined process could remove heavy metals effectively without phosphorus loss from anaerobically digested sewage sludge.  相似文献   

9.
Currently, the phosphorus (P) used in Austria is essentially of a linear structure. Cyclical ring structures—with the exception of those in manure (slurry, dung) used for local agricultural purposes—are as yet rudimentary. Simultaneously, Austria is entirely dependent on imports of the raw material rock phosphate, partly from geopolitically unstable regions. In contrast, sewage and animal meat and bone meal as significant sources of P are largely ignored. In view of the importance of P, numerous technologies for targeted P recycling from sewage have been developed—some already operational from a purely technical perspective and others already implemented on an industrial scale (particularly, recycling from the liquid phase). In order to make the best possible use of sewage-borne P, recycling from pure sewage sludge or animal meat and bone meal ash combined with sewage sludge ash would be desirable in future. Necessary structures, such as incinerators for sewage sludge alone or in combination with animal meat and bone meal, however, have yet to be developed. In addition to newly developed methods, recyclates (materials that are recyclable) from recycling processes (e.g., struvite), pure sewage sludge ash or animal meat and bone meal ash can be used as secondary raw materials in existing industrial processes, for instance, in the fertilizer or phosphoric acid industries. Neighboring countries Germany and Switzerland already recycle P from sewage sludge and sewage sludge ash to legally binding targets. Implementation in Austria too would initially require (political) commitment and, consequently, changes in the legal framework (e.g., fertilizer legislation) as well as binding standards. Implementation instruments for P recycling could be, for instance: defined recycling quotas for the fertilizer industry (e.g., “Pxx”, according to the E10 bioethanol quota); or levying “phosphorus cents” additional to the sewage treatment and waste management fees, to be used to develop the necessary structures (e.g., incinerators for sewage sludge and animal meal).  相似文献   

10.
The amount of excess sludge produced in municipal wastewater treatment plants in Japan is increasing every year as the urban population increases. Phosphorus in excess sludge could be a potential phosphorus resource since at present, phosphate rock is being exhausted all over the world. Every year, Japan imports large quantities of phosphorus from abroad but much is discharged as excess sludge. Therefore, the solubilization process, one method of recovering phosphorus from sludge, could be a promising solution. In this study, a subcritical water process, a new technology that solubilizes sludge under subcritical conditions, was applied before the phosphorus in sludge was recovered with the magnesium ammonium phosphate (MAP) process. As a result, the solubilization rate of excess sludge achieved approximately 80% and about 94-97% of the phosphorus could be recovered.  相似文献   

11.
Energy and nutrient recovery from sewage sludge via pyrolysis.   总被引:2,自引:0,他引:2  
Energy recovery and nutrient reuse from sewage sludge has traditionally been achieved via anaerobic digestion/power generation with land application of the biosolids. By contrast, thermal processes such as pyrolysis have typically been used only for energy recovery. One such technology has demonstrated at commercial scale that all of the energy in sludge can be beneficially recovered and reused. No attempt was however made to recover and reuse sludge nutrients. There are many potential benefits of using pyrolysis for both energy and nutrient recovery. Firstly, unlike digestion, the principal energy product is oil, which can readily be stored and used when required, ensuring that energy recovery is maximised. Secondly is that the sludge nutrients are recovered in the pyrolysis char. Laboratory soil incubation studies using char from the Subiaco demonstration plant were conducted over an eight-week period to confirm nutrient availability. Results from this study showed that the phosphorus in the char is plant available although the nitrogen was insoluble. Based on these results it appears that there is potential to use pyrolysis as an effective means to recover and reuse both the energy and the very valuable phosphorus present in sewage sludges.  相似文献   

12.
This paper shows the potential application of a new sewage treatment process with technologies of excess sludge reduction and phosphorus recovery. The process incorporated ozonation for excess sludge reduction and crystallisation process for phosphorus recovery to a conventional anaerobic/oxic (A/O) phosphorus removal process. A lab-scale continuous operation experiment was conducted with the ratio of sludge flow rate to ozonation tank of 1.1% of sewage inflow under 30 to 40 mgO3/gSS of ozone consumption and with sludge wasting ratio of 0.34% (one-fifth of a conventional A/O process). Throughout the operational experiment, a 60% reduction of excess sludge production was achieved in the new process. A biomass concentration of 2300 mg/L was maintained, and the accumulation of inactive biomass was not observed. The new process was estimated to give a phosphorus recovery degree of more than 70% as an advantage of excess sludge reduction. The slight increase in effluent COD was observed, but the process performance was maintained at a satisfactory level. These facts demonstrate an effectiveness of the new process for excess sludge reduction as well as for phosphorus recovery.  相似文献   

13.
污水处理领域磷回收技术及其应用   总被引:3,自引:0,他引:3       下载免费PDF全文
介绍了国内外从污水中磷回收研究与应用现状,多以含磷丰富的污泥脱水上清液、厌氧污泥消化液以及富磷废水为磷源,鸟粪石、磷酸钙等沉淀是目前广泛采用的回收形式。简述污水处理领域的磷回收技术有沉淀法,结晶法,电渗析法、离子交换等。沉淀法中鸟粪石、磷酸钙等的研究相对较为成熟,应用较多。最后展望了我国污水处理领域磷回收前景,2005年我国污水中的磷量相当于2000年全国磷矿开采量的42.7%,具有广泛的回收前景和环境经济效益。  相似文献   

14.
Source-separated black water (BW) (toilet water) containing 38% of the organic material and 68% of the phosphorus in the total household waste (water) stream including kitchen waste, is a potential source for energy and phosphorus recovery. The energy recovered, in the form of electricity and heat, is more than sufficient for anaerobic treatment, nitrogen removal and phosphorus recovery. The phosphorus balance of an upflow anaerobic sludge blanket reactor treating concentrated BW showed a phosphorus conservation of 61% in the anaerobic effluent. Precipitation of phosphate as struvite from this stream resulted in a recovery of 0.22 kgP/p/y, representing 10% of the artificial phosphorus fertiliser production in the world. The remaining part of the phosphorus ended up in the anaerobic sludge, mainly due to precipitation (39%). Low dilution and a high pH favour the accumulation of phosphorus in the anaerobic sludge and this sludge could be used as a phosphorus-enriched organic fertiliser, provided that it is safe regarding heavy metals, pathogens and micro-pollutants.  相似文献   

15.
KURZFASSUNG Aus einer Analyse der Phosphorstr?me in Siedlungswasserwirtschaft und Landwirtschaft k?nnen für den künftigen Gew?sser- und Ressourcenschutz bezüglich Phosphor die folgenden Schlüsse gezogen werden: Für den Gew?sserschutz im Rahmen von Flussgebieten inklusive der betroffenen Meeresküstengew?sser sowie von Seen ist eine konsequente Phosphorentfernung bei allen Kl?ranlagen (> 1000 EW) sinnvoll, wirtschaftlich vertretbar und technisch einfach. Die Einführung phosphatfreier Waschmittel im gesamten Donaueinzugsgebiet ist ?kologisch sinnvoll und verringert die Kosten der Abwasserreinigung. über die Anforderung an die Phosphorentfernung werden etwa 85 bis 90 % der Phosphorfrachten im Abwasser in den Kl?rschlamm verlagert. Diese Phosphorfracht hat in ?sterreich das Potenzial knapp 30 % der derzeitigen Phosphorzufuhr in die Landwirtschaft über Handelsdünger- und Futtermittelimporte zu substituieren. Der ?konomische Wert des Phosphors im Kl?rschlamm von Kl?ranlagen mit Phosphorentfernung ist h?her als die Kosten für die Phosphorentfernung. Für die nationale Landwirtschaft ist der ?konomische Wert des Phosphors im Kl?rschlamm jedoch nicht relevant, solange der Preis von Düngerphosphaten sich nicht wesentlich erh?ht. Für eine/n einzelne/n LandwirtIn hingegen, der/die seinen/ihren Phosphorbedarf weitgehend über Verwertung von entw?ssertem Kl?rschlamm deckt, stellt diese Ma?nahme einen deutlichen ?konomischen Vorteil dar. Die Problematik der potenziellen Schadstoffe wird auch in Zukunft zu beachten sein. Die Gef?hrdung für landwirtschaftliche B?den und Produkte erscheint jedoch nach dem heutigen Stand des Wissens gering zu sein, wenn über Vorsorgema?nahmen die Belastungen der Kl?rschl?mme gering gehalten werden, wie dies in ?sterreich in den letzten Jahren geschehen ist. Als Alternative zu einer direkten landwirtschaftlichen Verwertung müssen in Zukunft aber auch die M?glichkeiten einer Aufbereitung von Kl?rschlamm und Kl?rschlammasche zu Phosphordüngern im Auge behalten werden, wenn das Phosphorpotenzial des Kl?rschlammes vor allem aus Ballungszentren genutzt werden soll.
The importance of phosphorus in residential water management as demonstrated in the Danube Basin
SUMMARY Analysis of the phosphorus flows in residential water management and agriculture in the Danube Basin allows the following conclusions in terms of future protection of water and resources. Consistent removal of phosphorus from all water-treatment plants (larger than 1000 population equivalents) is sensible, for the sake of protecting water in river basins including the coastal waters involved as well as lakes, and is economically justified and technically simple. The introduction of phosphate-free detergents in the entire catchment area of the River Danube is of ecological advantage and reduces the cost of waste water treatment. The requirement of phosphorus removal means that about 85 to 90 % of the phosphorus loads in sewage are transferred to the sewage sludge. The phosphorus load that could potentially be recovered in Austria could substitute almost 30% of the amount of phosphorus imported for agricultural use in the form of commercial fertiliser and feedstuff. The economic value of the phosphorus contained in the sewage sludge of water treatment plants equipped with phosphorus-removal facilities exceeds the cost of phosphorus removal. However, this sludge is of no great economic importance to domestic agriculture as long the price of fertiliser phosphate does not rise substantially. But such a measure offers a clear economic advantage to individual farmers meeting the greater part of their phosphorus demand through dewatered sewage sludge. Nevertheless, the potential contaminants will continue to be a problem calling for a solution. According to the present state of knowledge, the hazard for agricultural soils and products appears to be low provided precautions are taken to keep the contaminant level in sewage sludge down, as has been practised in Austria over the past years. But the possibilities of processing sewage sludge and sludge ash for phosphorus fertiliser production will need to be kept in mind as an alternative to direct agricultural use, if use is to be made of the phosphorus potential in sewage sludge, especially at population centres.
  相似文献   

16.
In order to produce drinking water, coagulants--such as aluminium salts--are widely used for precipitation and separation of impurities from raw water. The residual from the process is sludge, which presents a disposal problem. The REAL process is a method for recycling the aluminium from the sludge. In a first step, the aluminium hydroxide is dissolved in sulphuric acid. In a second step, an ultra filtration will separate all suspended matter and large molecules, leaving a concentrate of 15-20% dry solids. The permeate will contain the trivalent aluminium ions together with 30-50% of the organic contaminants. In a third step, by concentrating the permeate in a nano filter, the concentration of aluminium will be high enough to, in a fourth step, be precipitated with potassium sulphate to form a pure crystal: potassium aluminium sulphate. The potassium aluminium sulphate is comparable to standard aluminium sulphate. The process will give a residual in form of a concentrate from the ultra filtration, representing a few per cent of the incoming volume. This paper presents the results from a long time pilot-scale continuous test run at V?ster?s water works in Sweden, as well as calculations of costs for full-scale operations.  相似文献   

17.
Reuse of sewage sludges as phosphorus fertiliser requires the estimation of the plant availabilities of phosphorus (P) from different sludges. This study investigates the effect of lime stabilisation on the phosphorus availability from biological phosphorus removal sludges. In the first part of the study, pot experiments were carried out to assess the fertilising effect of a dewatered biological phosphorus removal sludge. Availability of P was determined in terms of plant-uptake. In the second part of the study, incubation tests were carried out to observe the change in the available P with time when the waste activated sludge (WAS) from an enhanced biological phosphorus removal (EBPR) process is mixed with the same soil. In this part, the plant available P was measured in terms of Olsen extractable P. A P-deficient, alkaline soil was used in the experiments and Lollium Perenne was selected as the testing plant. The results of the pot experiments revealed that lime-stabilisation of the sludge considerably decreased or retarded the availability of P in the sludge. In the incubation tests, the availability of phosphorus in the lime stabilised and nonstabilised sludge amended soil samples was close to each other. In general, P-availability was increased due to the sludge application except for the lime-stabilised dewatered sludge.  相似文献   

18.
Decentralized advanced wastewater treatment using adsorption and desorption process for recovery and recycling oriented phosphorus removal was developed. Adsorbent particles made of zirconium were set in a column, and it was installed as subsequent stage of BOD and nitrogen removal type Johkasou, a household domestic wastewater treatment facility. The water quality of the effluent of adsorption column in a number of experimental sites was monitored. The effluent phosphorus concentration was kept below 1 mg l(-1) during 90 days at all the sites. Furthermore, over 80% of the sites achieved 1 mg l(-1) of T-P during 200 days. This adsorbent was durable, and deterioration of the particles was not observed over a long duration. The adsorbent collected from each site was immersed in alkali solution to desorb phosphorus. Then the adsorbent was reactivated by soaking in acid solution. The reactivated adsorbent was reused and showed almost the same phosphorus adsorption capacity as a new one. Meanwhile, the desorbed phosphorus was recovered with high purity as trisodium phosphate by crystallization. It is proposed as a new decentralized system for recycling phosphorus that paves the way to high-purity recovery of finite phosphorus.  相似文献   

19.
Potential of activated sludge ozonation.   总被引:2,自引:0,他引:2  
The disposal of sewage sludge and the agricultural use of stabilised sludge are decreasing due to more stringent regulations in Europe. An increasing fraction of sewage sludge must therefore be dewatered, dried, incinerated and the ashes disposed of in landfills. These processes are cost-intensive and also lead to the loss of the valuable phosphate resources incorporated in the sludge ash. The implementation of processes that could reduce excess sludge production and recycle phosphate is therefore recommended. Partial ozonation of the return sludge of an activated sludge system significantly reduces excess sludge production, improves the settling properties of the sludge and reduces bulking and scumming. The solubilised COD will also improve denitrification if the treated sludge is recycled to the anoxic zone. However, ozonation partly kills nitrifiers and could therefore lead to a decrease of the effective solid retention time of the nitrifier, thus reducing the safety of the nitrification. This paper discusses the effect of ozonation on sludge reduction, the operating stability of nitrification, the improvement of denitrification and also presents an energy and cost evaluation.  相似文献   

20.
This study focused on the treatment performance of membrane-coupled organic acid fermentor (MOF) with intermittent reciprocal air/ozone backwashing for the keeping of high permeation flux as well as for the effective recovery of dissolved organics from municipal sewage sludge. Intermittent reciprocal air/ozone backwashing was effective for membrane fouling reduction. When MOF was operated under the conditions of pH 5.5, hydraulic retention time (HRT) of 2 days and 20 days of solids retention time (SRT), most favourable fermentation efficiency was attained. Great inhibition for acid producing by intermittent reciprocal air/ozone backwashing was not observed during long-term operation. MOF with intermittent reciprocal air/ozone backwashing is believed to be an effective system for the recovery of organic matter from municipal sewage sludge and membrane fouling reduction.  相似文献   

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