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1.
The (CO2 + 2-ethoxyethyl acetate) and (CO2 + 2-(2-ethoxyethoxy)ethyl acetate) systems at 313.2, 333.2, 353.2, 373.2 and 393.2 K as well as pressures up to 20.59 MPa have been investigated using variable-volume high pressure view cell by static-type. The solubility curve of 2-ethoxyethyl acetate and 2-(2-ethoxyethoxy)ethyl acetate in the (CO2 + 2-ethoxyethyl acetate) and (CO2 + 2-(2-ethoxyethoxy)ethyl acetate) systems increases as the temperature increases at a constant pressure. The (CO2 + 2-ethoxyethyl acetate) and (CO2 + 2-(2-ethoxyethoxy)ethyl acetate) systems exhibit type-I phase behavior. The experimental results for the (CO2 + 2-ethoxyethyl acetate) and (CO2 + 2-(2-ethoxyethoxy)ethyl acetate) systems correlate with the Peng–Robinson equation of state using a van der Waals one-fluid mixing rule including two adjustable parameters. The critical properties of 2-ethoxyethyl acetate and 2-(2-ethoxyethoxy)ethyl acetate are predicted with the Joback–Lyderson group contribution and Lee–Kesler method.  相似文献   

2.
Experimental cloud-point data up to 433.2 K and 193.0 MPa are reported for binary and ternary mixtures of poly(benzyl methacrylate) [poly(BzMA)] + carbon dioxide + benzyl methacrylate (BzMA) and poly(benzyl acrylate) [Poly(BzA)] + carbon dioxide + benzyl acrylate (BzA) systems. High-pressure cloud-point data are also reported for Poly(BzMA) + carbon dioxide and Poly(BzA) + carbon dioxide in supercritical dimethyl ether (DME). Cloud-point behavior for the Poly(BzMA) + carbon dioxide + BzMA system was measured in changes of the pressure–temperature (pT) slope, and with BzMA weight fraction of 50.6, 61.0, 67.2 and 95.0 wt.%. The Poly(BzA) + carbon dioxide + 30.4, 40.7 and 49.4 wt.% BzA systems change the (pT) curve from upper critical solution temperature region (UCST) to lower critical solution temperature (LCST) region as the BzA concentration increases. With 52.3 wt.% BzA to the Poly(BzA) + carbon dioxide solution, the cloud-point curves are taken on the appearance of a typical lower critical solution temperature boundary. Also, the impact by cosolvent (BzMA and BzA) concentrations for the Poly(BzMA) + DME and Poly(BzA) + DME systems is measured at temperature to 453.2 K and pressure range of 24.6–61.3 MPa.  相似文献   

3.
In this work, cloud-point and bubble-point phase behavior data are reported for the poly(dimethylsiloxane) [PDMSA] in supercritical carbon dioxide, propane, propylene, butane, 1-butene and dimethyl ether (DME). The static-type method, using a variable-volume view cell, was employed to obtain the experimental data at the temperature range for (315.2–454.9) K and pressure up to 55.52 MPa. PDMS (Mw = 38,900) + C4 cloud-point curves are ~10 MPa lower than the PDMS + C3 curves at constant temperature of 423 K. Cloud-point curves for the PDMS + solvents system show the lower critical solution temperature (LCST) region.  相似文献   

4.
We have conducted experiments to obtain cloud-point data of binary and ternary mixtures for poly(isobornyl acrylate) [P(IBnA)] (Mw = 100,000) + isobornyl acrylate(IBnA) in supercritical carbon dioxide (CO2), P(IBnA) (Mw = 100,000) + dimethyl ether (DME) in CO2, P(IBnA) (Mw = 100,000) in propane and butane, and P(IBnA) (Mw = 1,000,000) in propane, propylene, butane and 1-butene at high pressure conditions. Phase behaviors for these systems were measured at a temperature range from 323.4 K to 474.1 K and pressure up to 296.7 MPa. The cloud-point curves of P(IBnA) (Mw = 100,000) + IBnA and DME in CO2 change from upper critical solution temperature (UCST) behavior to lower critical solution temperature (LCST) behavior as IBnA and DME concentration increases, and liquid–liquid–vapor phase behavior appears for the P(IBnA) (Mw = 100,000) + CO2 + 80.3 wt.% IBnA system. Phase behaviors of P(IBnA) and 50 wt.% IBnA in CO2 and P(IBnA) in propane and butane show the pressure difference in accordance with Mw = 1,000,000 and Mw = 100,000 of P(IBnA). Also, the solubility curves for IBnA in supercritical CO2 were measured at a temperature range of (313.2–393.2) K and pressure up to 22.86 MPa. The experimental results were modeled with the Peng–Robinson equation of state (PR-EOS) using a mixing rule including two adjustable parameters. The critical property of IBnA is estimated with the Joback–Lyderson method.  相似文献   

5.
High pressure phase equilibria for the (carbon dioxide + n-vinyl pyrrolidone) and (carbon dioxide + N,N-dimethylacrylamide) systems are measured in a static apparatus at five temperatures of 313.2, 333.2, 353.2, 373.2 and 393.2 K and pressures up to 24.66 MPa. These two systems exhibit maximums in pressure at temperatures between the critical temperatures of carbon dioxide and n-vinyl pyrrolidone or N,N-dimethylacrylamide. The solubility of n-vinyl pyrrolidone and N,N-dimethylacrylamide for the carbon dioxide + n-vinyl pyrrolidone and carbon dioxide + N,N-dimethylacrylamide systems increases as the temperature increases at a fixed pressure. The carbon dioxide + n-vinyl pyrrolidone and carbon dioxide + N,N-dimethylacrylamide systems exhibit type-I phase behavior. The experimental results for the carbon dioxide + n-vinyl pyrrolidone and carbon dioxide + N,N-dimethylacrylamide systems are correlated with the Peng–Robinson equation of state using a mixing rule including binary interaction parameters (kij and ηij).  相似文献   

6.
Acquiring a comprehensive understanding of the phase behaviour of mixtures of crude-oil with carbon dioxide and water is a key input for reservoir engineering in processes of enhanced oil recovery and geological storage of carbon dioxide. To gain an insight, given the very complex nature of crude-oil mixtures, the study of simpler systems is of interest. In this work the system (propane + carbon dioxide + water) has been chosen as a model (light oil fraction + carbon dioxide + water) mixture. Phase equilibrium measurements have been carried out using a quasi-static-analytical high-pressure apparatus that was validated on the system (n-decane + carbon dioxide) in comparison with literature data, and used to study the system (n-decane + carbon dioxide + water) [E. Forte, A. Galindo, J. P.M. Trusler, The Journal of Physical Chemistry B 115 (49) (2011) 14591–14609]. In the present work, new experimental data have been measured for the system (propane + carbon dioxide + water) under conditions of three-phase equilibria. Compositions of the three coexisting phases have been obtained along four isotherms at temperatures from 311 to 353 K and at pressures up to the upper critical end points where the propane-rich and the carbon dioxide-rich phases become critical. The experimental data obtained for the ternary mixture have been compared to the predictions obtained with the statistical associating fluid theory for potentials of variable range (SAFT-VR). The phase behaviour of each pair of binary subsystems has been calculated using this theory and, where applicable, a modification of the Hudson and McCoubrey combining rules has been used to treat the systems predictively. Furthermore, a detailed analysis of the phase behaviour of the ternary mixture has been carried out based on comparison with available data for the constituent binary subsystems, as well as with the previous findings for the ternary (n-decane + carbon dioxide + water). Such comparison is useful to examine the effect that adding a third component has in the mutual solubility of each pair. Remarks relevant to reservoir processing are also highlighted.  相似文献   

7.
Cloud-point data are reported for poly(isopropyl acrylate) [P(IPA)] in CO2, propane, propylene, butane, 1-butene, and dimethyl ether (DME) and for poly(isopropyl methacrylate) [P(IPMA)] in CO2. P(IPA) + alkene cloud-point curves are ∼100 °C lower than the P(IPA) + alkane curves, which are close to the P(IPA) + CO2 curve located at temperatures greater than 130 °C and pressures of 2500 bar. P(IPA) dissolves in pure DME at conditions as mild as 50 °C and 200 bar. Since IPA and IPMA monomers are used as cosolvents with CO2, binary IPA + CO2 and IPMA + CO2 data are reported to complement the ternary cloud-point data. Both monomer + CO2 mixtures exhibit type-I behavior and both are adequately modeled with the Peng–Robinson equation of state. IPMA is a more effective cosolvent than IPA. The polymer + CO2 + monomer phase behavior suggests that it is viable to polymerize IPA or IPMA in CO2 at moderate operating conditions.  相似文献   

8.
Isothermal vapor⿿liquid equilibrium data for the binary system carbon dioxide + methyl iodide were measured at temperatures from 283.15 to 323.15 K at 10 K intervals. Data in the two-phase region were measured by using a circulation-type equilibrium apparatus and gas chromatography. This binary mixture system showed positive deviation from the Raoult's law and no azotrope observance. The experimental data were correlated with the Peng⿿Robinson equation of state (PR-EoS) using the Wong⿿Sandler (W⿿S) mixing rule, which was combined with the nonrandom two-liquid (NRTL) excess Gibbs free energy model and Peng⿿Robinson equation of state (PR-EoS) using the Universal mixing rule (UMR) as well as with the UNIQUAC model. The calculated results with this combination of equations show positive agreement with experimental data taken within this study.  相似文献   

9.
A visual and variable volume view cell analyzer was installed and the phase behaviors of the carbon dioxide + water system were measured in the temperature and pressure ranges from 313.2 K to 343.2 K and from 4.33 MPa to 18.34 MPa, respectively. The measured data were correlated with the MF-NLF-HB equation of state to consider the effects of the hydrogen bonding of the saturated liquid and vapor mixture. The calculated data agree well with the measured data within an absolute average error deviation of 5%. The fraction of hydrogen bonding could be calculated by the MF-NLF-HB EOS for the carbon dioxide + water system with the obtained VLE data. The calculated hydrogen bonding fraction of the saturated liquid phase of the mixture decreased with increasing pressure in the isothermal calculations. The hydrogen bond strength was affected by the concentration of carbon dioxide and solubility of carbon dioxide was affected by pressure. The calculated hydrogen bonding fraction of the saturated vapor phase of the mixture had a minimum value near 10 MPa for the three isothermal calculations.  相似文献   

10.
The hydrogenation of 1,3-butadiene on Pd(1 1 1) at 300 K was studied at atmospheric pressure by infrared reflection absorption spectroscopy (IRAS) and gas chromatography (GC). Kinetic measurements showed 1-butene, trans-2-butene and cis-2-butene as primary products. Once 1,3-butadiene had been completely consumed, 1-butene was re-adsorbed on the surface producing trans-/cis-2-butene through isomerization and n-butane through hydrogenation. These results were corroborated by in situ IRAS spectroscopy. Post-reaction analysis by X-ray photoelectron spectroscopy (XPS) in the C1s region revealed a band at 284.2 eV, corresponding to adsorbed butadiene and/or carbonaceous deposits. Quantification of this peak revealed a total carbon coverage of 0.3 ML. Nevertheless, deactivation due to carbon deposition was a minor effect under our reaction conditions, as indicated by the kinetics of the subsequent butene hydrogenation reaction. Temperature-dependent XPS experiments after butadiene adsorption at 100 K indicated a high stability of the diene molecule with hardly any desorption and/or decomposition up to 500 K. Above this temperature, butadiene decomposed to carbon species that eventually dissolved in the Pd bulk above 700 K.  相似文献   

11.
Pressure-composition isotherms for the (carbon dioxide + propionitrile) and (carbon dioxide + butyronitrile) systems are measured in static-type high pressure apparatus at several temperatures of 313.2, 333.2, 353.2, 373.2 and 393.2 K and at pressures range from 3.5 to 16.7 MPa. The carbon dioxide + nitriles systems have continuous critical mixture (local) curves that exhibit maximums in pressure–temperature space between the critical point of carbon dioxide and monomers (propionitrile or butyronitrile). At a fixed pressure, the solubility of propionitrile or butyronitrile for the two binary systems increases as the temperature increases. The (carbon dioxide + propionitrile) and (carbon dioxide + butyronitrile) systems exhibit type-I phase behavior. The experimental results for the (carbon dioxide + propionitrile) and (carbon dioxide + butyronitrile) systems are correlated with Peng–Robinson equation of state using mixing rule including two adjustable parameters.  相似文献   

12.
Biodegradable polymers have received increased attention due to their potential applications in the medicine and food industries; in particular, poly(l-lactic acid) (PLA) is of primary importance because of its biocompatibility and resorbable features. Recently, the synthesis of this biopolymer through the enzyme-catalyzed ring-opening polymerization of l-lactic acid in a compressed fluid has been considered promising. The aim of this work was to report the phase equilibrium data (cloud points) of the l-lactic acid + (propane + ethanol) and the l-lactic acid + (carbon dioxide + ethanol) systems. The phase equilibrium experiments were conducted in a variable-volume view cell employing the static synthetic method. These experiments were conducted in the temperature range of 323.15–353.15 K and at pressures up to 25 MPa; the mass ratio of ethanol to either CO2 or propane was maintained at 1:9. The l-lactic acid + (propane + ethanol) system exhibited vapor–liquid, liquid–liquid and vapor–liquid–liquid transitions, whereas the l-lactic acid + (carbon dioxide + ethanol) system only exhibited liquid–liquid type transitions.  相似文献   

13.
We report experimental measurements of the phase behavior of (CO2 + H2O + NaCl) and (CO2 + H2O + KCl) at temperatures from 323.15 K to 423.15 K, pressure up to 18.0 MPa, and molalities of 2.5 and 4.0 mol kg−1. The present study was made using an analytical apparatus and is the first in which coexisting vapor- and liquid-phase composition data are provided. The new measurements are compared with the available literature data for the solubility of CO2 in brines, many of which were measured with the synthetic method. Some literature data show large deviations from our results.The asymmetric (γφ) approach is used to model the phase behavior of the two systems, with the Peng–Robinson equation of state to describe the vapor phase, and the electrolyte NRTL solution model to describe the liquid phase. The model describes the mixtures in a way that preserves from our previous work on (CO2 + H2O) the values of the Henry's law constant and the partial molar volume of CO2 at infinite dilution Hou et al. [22]. The activity coefficients of CO2 in the aqueous phase are provided. Additionally, the correlation of Duan et al. [14] for the solubility of CO2 in brines is tested against our liquid-phase data.  相似文献   

14.
The main goal of this study was to assess the yield and the antimicrobial activity of extracts from Cyperus articulatus L. var. articulatus obtained by pressurized carbon dioxide based on their system phase diagram behavior. The extractions were carried out at 313, 323, 333 K temperatures and, 13 and 25 MPa pressures. The extracts were quantified and chemically characterized by using gas chromatography coupled to mass spectrometry technique. The extracts obtained at the following experimental conditions: 333 K and 13 MPa, showed antifungal activity against Cladosporium sphaerospermum ATCC 4464. At 323 K – 25 MPa, and 333 K – 25 MPa, the extracts showed antibacterial activity against Staphylococcus aureus ATCC 25923. To describe the kinetics of extraction with a packed bed, a mathematical model was employed highlighting the transference mechanisms for masses in the pseudo-binary system as follows (1) carbon dioxide and (2) priprioca extract, the monophasic and multiphasic regions.  相似文献   

15.
In order to improve the efficiency of processes using supercritical (sc) carbon dioxide (CO2) to micronize the carotenoid “lycopene”, it is important to know the solubility of lycopene in mixtures of the organic solvent ethyl acetate (EA) and the antisolvent CO2 at elevated pressures. The solubility of lycopene has been determined for different temperatures (313–333 K), pressures (12–16 MPa) and CO2 molar fractions (0.58–1). The obtained data show that CO2 acts as an antisolvent in the system lycopene/EA/CO2 in the range of CO2/EA ratios studied. The solubility of lycopene is rather small with lycopene molar fractions ranging from 0.1 × 10−6 to 46 × 10−6. The solubility of lycopene increases with temperature, pressure and EA concentration.  相似文献   

16.
The high-pressure vapour–liquid phase equilibria (PTxy) of the binary mixture propylene glycol/CO2 have been experimentally investigated at temperatures of (398.2, 423.2 and 453.2) K over the pressure range from (2.5 to 55.0) MPa using a static-analytic method. Furthermore, the high-pressure vapour–liquid phase equilibria (PTxy) of the ternary mixture propylene glycol/CO2/ethanol at constant temperatures of (398.2, 423.2 and 453.2) K and at constant pressure of 15.0 MPa have been determined using a static-analytic method. Initial concentrations of components in propylene glycol (PG)/ethanol (EtOH) mixture vary from 10 up to 90 wt.%. In general, for binary system it was observed that the solubility of CO2 in the heavy propylene glycol reach phase increases with increasing pressure at constant temperature. On the contrary, the composition of gaseous phase is not influenced by the pressure or the temperature. On average the solubility of PG in light phase of CO2 amounts to 30 wt.%. The system behaviour at temperature of 398.2 K was investigated up to 70.0 MPa and a single-phase region was not observed. Above the pressure 60.0 MPa a single-phase region of the system was observed for the temperature of 423.2 K. For the temperature of 453.2 K the single-phase was observed above the pressure of 48.0 MPa. For ternary system it was observed that the composition of heavy phase is slightly influenced by the temperature when the mass fraction of EtOH in initial mixture is higher than 50 wt.%. If the mass fraction of PG in initial mixture is higher than 50 wt.%, the composition of heavy phase is not influenced by the temperature anymore. The composition of the PG, EtOH and CO2 in light phase remains more or less unchanged and it is not influenced by the conditions.  相似文献   

17.
The phase behavior of the carbon dioxide + 1-methylimidazole binary system has been investigated in a high-pressure variable-volume view cell using an analytical method. Phase equilibrium data for the system carbon dioxide + 1-methylimidazole was measured at 293.15, 309.75 and 323.15 K. The pressure under investigation was between 2.83 and 14.16 MPa. There coexisted three phases (LLV) of the binary system, which were found in a temperature range of 297.85–313.95 K. The densities of the binary mixture at phase transition points were also measured. The experimental data were correlated well by the Peng–Robinson equation of state with two binary parameters. According to the experimental results, the phase behavior of the binary system might be classified to Type-IV or Type-V according to the classification of six principal types of binary phase diagrams.  相似文献   

18.
A visual and volume-variable high-pressure phase equilibrium analyzer was used for measuring the vapor–liquid phase boundaries of the ternary systems containing carbon dioxide and mixed solvents of dimethyl sulfoxide (DMSO) + ethanol or chloroform + methanol at temperatures from 298.15 K to 348.15 K over wide composition ranges including near critical points. Four pseudo-binary systems of carbon dioxide plus mixed solvents with constant molar ratios of DMSO/ethanol = 3/7, 5/5, 7/3, and chloroform/methanol = 1/2, were studied in this work. The critical conditions at each investigated temperature were estimated from the experimental isothermal phase boundaries by interpolation. The Peng–Robinson equation of state with the two-parameter van der Waals mixing rules was applied to calculate the phase boundaries. The experimental values were compared with the predicted results from the Peng–Robinson equation using the binary interaction parameters determined from the vapor–liquid equilibrium data of the constituent binaries. The agreement is reasonably well for carbon dioxide + chloroform + methanol, but obvious overestimations are found near the critical regions of carbon dioxide + DMSO + ethanol, especially at higher temperatures.  相似文献   

19.
Kejian Bian 《Polymer》2006,47(16):5744-5753
2-(Dimethylamino)ethyl acrylate (DMAEA) was grafted from the surface of alkoxyamine-functionalized crosslinked poly(styrene-co-chloromethylstyrene) microspheres by nitroxide-mediated radical polymerization (NMRP). Latex particles (∼60 nm diameter) bearing chloromethyl groups were synthesized by emulsion polymerization. N-tert-butyl-N-(1-diethyl phosphono-2,2-dimethylpropyl)nitroxide (SG1) was then immobilized on the particle surface. Microspheres grafted with the homopolymer pDMAEA, as well as block copolymers poly(styrene-b-DMAEA) and poly(butyl acrylate-b-DMAEA) were prepared by surface-initiated NMRP in N,N-dimethylformamide at 112 °C, with the addition of free SG1 to ensure that control is maintained. Particle size increases with number average molecular weight (Mn) of untethered polymers. The polymerizations exhibit linear first order kinetic plots and slight curvature of evolution of Mn with conversion. The functional microspheres were analyzed by infrared spectroscopy, transmission electron microscopy and thermal analysis, as well as their dispersibility in water; the results support the formation of surface-grafted pDMAEA on the microspheres.  相似文献   

20.
This paper reports on the foaming of poly(ɛ-caprolactone-co-lactide) in carbon dioxide and carbon dioxide + acetone mixtures. Experiments were carried out in specially designed molds with porous metal surfaces and fluid circulation features to generate foams with uniform dimensions at 60, 70 and 80 °C at pressures in the range 7–28 MPa. Depending upon the conditions, foams with pores in the range from 5 to 200 μm were generated. Adding acetone to carbon dioxide improved the uniformity of the pores compared to foams formed by carbon dioxide alone. In addition, a unique high-pressure solution extrusion system was designed and used to form porous tubular constructs by piston-extrusion of a solution from a high-pressure dissolution chamber through an annular die into a second chamber maintained at controlled pressure/temperature and fluid conditions. Long uniform porous tubular constructs with 6 mm ID and 1 mm wall thickness were generated with glassy polymers like poly(methyl methacrylate) by extruding solutions composed of 50 wt% polymer + 50 wt% acetone, or 25 wt% polymer + 10% acetone + 65% carbon dioxide at 70 °C and 28 MPa. Pores were in the 50 μm range. The feasibility of forming similar tubular constructs were demonstrated with poly(ɛ-caprolactone-co-lactide) as well. Tubular foams of the copolymer with interconnected pores with pore sizes in the 50 μm range were generated by extrusion of the copolymer solution composed of 25 wt% polymer + 10 wt% acetone + 65 wt% carbon dioxide at 70 °C and 28 MPa. Reducing the acetone content in the solution led to a reduction of pore sizes. Comparisons with the foaming behavior of the homopolymer poly(ɛ-caprolactone) that were carried out in the molds with porous metal plates show that the foaming behavior of the copolymer is more akin to the foaming behavior of the caprolactone homopolymer component.  相似文献   

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