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1.
AbstractA thin buffer layer of cadmium oxide (CdO) was used to enhance the optical and electrical properties of indium tin oxide (ITO) films prepared by an electron-beam evaporation technique. The effects of the thickness and heat treatment of the CdO layer on the structural, optical and electrical properties of ITO films were carried out. It was found that the CdO layer with a thickness of 25 nm results in an optimum transmittance of 70% in the visible region and an optimum resistivity of 5.1×10?3 Ω cm at room temperature. The effect of heat treatment on the CdO buffer layer with a thickness of 25 nm was considered to improve the optoelectronic properties of the formed ITO films. With increasing annealing temperature, the crystallinity of ITO films seemed to improve, enhancing some physical properties, such as film transmittance and conductivity. ITO films deposited onto a CdO buffer layer heated at 450 °C showed a maximum transmittance of 91% in the visible and near-infrared regions of the spectrum associated with the highest optical energy gap of 3.61 eV and electrical resistivity of 4.45×10?4 Ω cm at room temperature. Other optical parameters, such as refractive index, extinction coefficient, dielectric constant, dispersion energy, single effective oscillator energy, packing density and free carrier concentration, were also studied. 相似文献
2.
N. J. Suthan Kissinger M. Jayachandran K. Perumal C. Sanjeevi Raja 《Bulletin of Materials Science》2007,30(6):547-551
Thin films of cadmium selenide (CdSe) as a semiconductor is well suited for opto-electronic applications such as photo detection
or solar energy conversion, due to its optical and electrical properties, as well as its good chemical and mechanical stability.
In order to explore the possibility of using this in optoelectronics, a preliminary and thorough study of optical and structural
properties of the host material is an important step. Based on the above view, the structural and optical properties of CdSe
films have been studied thoroughly in the present work. The host material, CdSe film, has been prepared by the physical vapour
deposition method of electron beam evaporation (PVD: EBE) technique under a pressure of 5 × 10−5 mbar. The structural properties have been studied by XRD technique. The hexagonal structure with a preferred orientation
along the (0 0 2) direction of films has been confirmed by the X-ray diffraction analysis. The films have been analysed for
optical band gap and absorbed a direct intrinsic band gap of 1·92 eV. 相似文献
3.
Thin films of pure cadmium have been deposited using electron beam evaporation technique. Effect of radio frequency (RF) plasma oxidation on structural, optical and electrical properties of cadmium thin films has been investigated. It was found that the RF plasma treatment affects on the physical properties of the oxidized cadmium films. Transmittance values of 87% in the visible region and 90% in the near infrared region have been obtained for cadmium oxide (CdO) film oxidized at a plasma-processing power of 600 W. The optical energy gap, Eg, was found to increase as the RF plasma-processing power increases. The resistivity values of 3 × 10− 3 and 5 × 10− 3 (Ω cm) have been obtained for CdO films oxidized at RF plasma-processing powers of 550 and 600 W respectively. 相似文献
4.
Structural and optical properties of indium tin oxide (ITO) thin films with different compositions prepared by electron beam evaporation 总被引:3,自引:0,他引:3
Tin-doped Indium oxide thin films in different compositions (Sn = 0,5,10,15,20 at.wt%) were prepared on glass substrates at the substrate temperature of 250 °C in an oxygen atmosphere by electron beam evaporation. The structural and morphological studies were carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The grain size of the ITO films decreased when increasing the dopant concentration of Sn in the In2O3 lattice. Optical properties of the films were studied in the UV-Visible-NIR region (300-1000 nm). The optical energy band gap (Eg), as determined by the dependence of the absorption coefficient on the photon energy at short wavelengths was found to increase from 3.61 to 3.89 eV revealing the ascending loading profile of dopant concentration. Optical Parameters, such as absorption depth, refractive index (n), extinction coefficient (k), packing density, porosity, dispersion energy and single effective oscillator energy were also studied to show the composition dependence of tin-doped indium oxide films. 相似文献
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为明确溅射偏压对ITO薄膜性质的影响,用射频磁控溅射法于室温在玻璃衬底制备出ITO透明导电薄膜,研究了不同偏压下ITO薄膜的生长模式、光学和电学性能.结果表明:随着偏压的增加,薄膜沉积模式经历了沉积、沉积和扩散、表面脱附3种方式;AFM和SEM显示,偏压为100 V时,膜层表面光洁、均匀,粗糙度最小,均方根粗糙度为1.61 nm;XRD分析表明偏压会影响与薄膜的择优取向,偏压为100 V时,薄膜晶粒取向为(222)面;薄膜偏压为120 V时,薄膜的光电性能最佳,电阻率最低为2.59×10-4Ω.cm,可见光区的平均透过率在85%以上;偏压的大小使薄膜的吸收边发生了"蓝移"或"红移". 相似文献
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The properties of substrates used to deposit thin films are an important parameter in thin film production. Instead of using a commercial substrate, in this work, borate and phosphate glasses have been obtained by classic melt-quenching technique to be used as substrates for CdO films. Also, a microscope glass substrate has been used to compare the coating properties by other glass substrates. All films have been produced by Ultrasonic Spray Pyrolysis technique. The substrate temperature has been selected as 275 ± 5 °C. Thicknesses and some optical parameters such as refractive index and extinction coefficient have been determined by spectroscopic ellipsometry. Absorbance and transmittance spectra have been taken by UV/VIS spectrophotometer. Four-probe method has been used to determine the electrical resistivity values of the films. XRD investigations have shown that type of the substrate dramatically affects the characteristics of CdO films. CdO film deposited on phosphate glass substrate has the best structural quality. Atomic Force Microscope has been used to investigate the surface properties and roughness values of the films. 相似文献
9.
A large number of thin films of cadmium oxide have been prepared on glass substrates by spray pyrolysis method. The prepared
films have uniform thickness varying from 200–600 nm and good adherence to the glass substrate. A systematic study has been
made on the influence of thickness on resistivity, sheet resistance, carrier concentration and mobility of the films. The
resistivity, sheet resistance, carrier concentration and mobility values varied from 1·56–5·72×10−3 Ω-cm, 128–189 Ω/□, 1·6–3·9×1021 cm−3 and 0·3–3 cm2/Vs, respectively for varying film thicknesses. A systematic increase in mobility with grain size clearly indicates the reduction
of overall scattering of charge carriers at the grain boundaries. The large concentration of charge carriers and low mobility
values have been attributed to the presence of Cd as an impurity in CdO microcrystallites. Using the optical transmission
data, the band gap was estimated and found to vary from 2·20–2·42 eV. These films have transmittance around 77% and average
reflectance is below 2·6% in the spectral range 350–850 nm. The films aren-type and polycrystalline in nature. SEM micrographs of the CdO films were taken and the films exhibit clear grains and grain
boundary formation at a substrate temperature as low as 523 K. 相似文献
10.
Zhao ErjingZhang Weijia Lin JunYang Dongjie Havugimana Jean JacquesZhang Jing 《Vacuum》2011,86(3):290-294
ITO thin films were prepared by changing the experimental parameters including gas flow ratio, sputtering pressure and sputtering time in DC magnetron sputtering equipment. The stable experimental parameters of Ar flow at 70 sccm, O2 flow at 2.5 sccm ∼ 3.0 sccm, sputtering pressure around 0.5 Pa, and sputtering time of 80 s were obtained. Under these parameters, we had achieved the ITO thin films with low resistivity (<4 × 10−4 Ω ? cm) and high average transmissivity (95.48%, 350 nm ∼ 1100 nm). These ITO thin films were applied in nanocrystalline silicon solar cells as top transparent conductive layer. The solar cell test result showed that the open circuit voltage (Voc) was up to 534.9 mV and the short circuit current density (Jsc) was 21.56 mA/cm2. 相似文献
11.
磁控溅射制备ITO薄膜光电性能的研究 总被引:1,自引:0,他引:1
采用直流磁控溅射方法在玻璃基底上制备了ITO薄膜.分别用分光光度计和四探针仪测试了所制备ITO薄膜在可见光区域内的透过率和电阻率,研究了溅射气压、氧氩流量比和溅射功率三个工艺参数对ITO薄膜光电性能的影响.研究结果表明,制备ITO薄膜的最佳工艺参数为:溅射气压0.6 Pa,氧氩流量比1:40,溅射功率108 W.采用此工艺参数制备的ITO薄膜在可见光区平均透过率为81.18%,薄膜电阻率为8.9197×10-3Ω·cm. 相似文献
12.
Thin films of molybdenum trioxide (MoO3) were prepared by activated reactive evaporation technique on Pyrex glass substrates. The influence of oxygen partial pressure, substrate temperature and glow power on the structure, surface morphology and optical properties of MoO3 thin films was studied. The MoO3 films deposited in an oxygen partial pressure of 1×10−3 Torr, glow power of 10 W and substrate temperature of 573 K exhibited predominantly a (0 k 0) orientation corresponding to the orthorhombic layered structure of -MoO3. The evaluated optical band gap was 3.24 eV. The sensing property of these MoO3 films for gases like NH3 and CO was also studied to see the applicability for environmental monitoring. We have observed that the MoO3 thin films of -phase are capable of detecting NH3 and CO gases at concentrations lower than 10 ppm in dry air. 相似文献
13.
Guanghui LiuHua Yu Weili ZhangYunxia Jin Hongbo He Zhengxiu Fan 《Thin solid films》2011,519(11):3487-3491
LaF3 thin films were deposited by electron beam (EB) and resistive heating (RH) evaporation, respectively. Properties such as microstructure, chemical composition, surface morphology and optical constants of the LaF3 thin films were characterized by measurements of X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy and spectrophotometer, then comparison was made between this two deposition methods. It's found that the microstructure properties of the LaF3 films deposited by these two methods were different, and slight content of oxyfluoride films was formed during deposition according to the result of chemical composition analysis. The microstructure of LaF3 bulk materials after interaction with electron beam and resistive heating was also characterized to analyze how the two deposition processes affect the formation of LaF3 thin films and their microstructure properties. When it was for the laser resistance of the films, although the EB evaporated LaF3 thin films occupied lower absorption and optical loss than those of the RH films, they showed slightly smaller laser induced damage thresholds at 355 nm, which was thought to be related to their much more rougher surface and higher tensile stress. 相似文献
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Ar气氛下直流磁控溅射ITO薄膜的结构和性能 总被引:1,自引:0,他引:1
采用直流磁控溅射法在低温、100%Ar的无氧气氛中制备了光电性能优良的铟锡氧化物(ITO,In2O3:SnO2=90:10,质量百分比)薄膜,详细探讨了溅射时改变氩气压强对ITO薄膜结构以及光电性能的影响.结果表明:溅射时氩气压强越小,ITO薄膜的体心立方晶型越完整,导电性越好,但对可见光透过性的影响不大.当氩气压强为0.3Pa时,溅射薄膜性能最佳,其光透过率可达92.9%,电导率为8.9×10-4Ω·cm. 相似文献
16.
Xuemei Teng 《Materials Letters》2007,61(1):201-204
The photoluminescence (PL) properties of ZnO thin films on ITO glass substrate deposited by rf magnetron sputtering with different oxygen partial pressures were studied. It was found that the exciton related emission of ZnO thin films depends on oxygen partial pressure, and that the visible emission related to intrinsic defects has no obvious change with various oxygen partial pressures. Abnormal UV-PL characteristics were observed, and its intensity was obviously enhanced. The emission position has a strong red-shift with increasing excitation intensity, and the emission intensity increases notably with increasing excitation cycle. 相似文献
17.
The growth, structure and room temperature electrical conductivity of electron beam evaporated V2O5 thin films were studied in detail as a function of deposition temperature. The films deposited at Ts≈553 K and subsequently annealed in oxygen atmosphere at 693 K exhibited orthorhombic layered structure. 相似文献
18.
ITO films were deposited onto glass substrates by ion beam assisted deposition method. The oxygen ions were produced using a Kaufman ion source. The oxygen flow was varied from 20 until 60 sccm and the effect of the oxygen flow on properties of ITO films has been studied. The structural properties of the film were characterized by X-ray diffraction and atomic force microscopy. The optical properties were characterized by optical transmission measurements and the optical constants (refractive index n and extinction coefficient k) and film thickness have been obtained by fitting the transmittance using a semi-quantum model. The electrical properties were characterized by Hall effect measurements. It has been found that the ITO film with low electrical resistivity and high transmittance can be obtained with 40 sccm oxygen flow (the working pressure is about 2.3 × 10− 2 Pa at this oxygen flow). 相似文献
19.
M.M. El-NahassE.M. El-Menyawy 《Materials Science and Engineering: B》2012,177(2):145-150
Indium tin oxide (ITO) thin films, produced by electron beam evaporation technique onto quartz substrates maintained at room temperature, are grown as nanofibers. The dependence of structural and optical properties of ITO thin films on the film thickness (99-662 nm) has been reported. The crystal structure and morphology of the films are investigated by X-ray diffraction and scanning electron microscope techniques, respectively. The particle size is found to increase with increasing film thickness without changing the preferred orientation along (2 2 2) direction. The optical properties of the films are investigated in terms of the measurements of the transmittance and reflectance determined at the normal incidence of the light in the wavelength range (250-2500 nm). The absorption coefficient and refractive index are calculated and the related optical parameters are evaluated. The optical band gap is found to decrease with the increase of the film thickness, whereas the refractive index is found to increase. The optical dielectric constant and the ratio of the free carrier concentration to its effective mass are estimated for the films. 相似文献
20.
Negin Manavizadeh Farhad Akbari Boroumand Farshid Raissi Alireza Khodayari 《Thin solid films》2009,517(7):2324-3088
Polycrystalline ITO films were deposited by RF sputtering on three different substrates of glass, p-type (100) and multicrystalline textured silicon wafers. Properties of ITO films were analyzed by XRD, SEM, four point probe system and UV/VIS/IR spectrometer. The ITO film on mono and multi-Si crystallizes in a three-dimensional manner, and a granular crystalline structure is formed with a (222) XRD peak, while the ITO film on glass shows strong XRD (400) peak and grows in two dimensions and a domain structure is formed. Resistivity measurements reveal that resistivity of ITO on glass is minimum due to higher concentration of carriers. 相似文献