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《合成材料老化与应用》2016,(6)
正2016年6月23日,独山子石化公司研究院的科研人员正在对新开发试产的聚丙烯锂电池隔膜专用料T98F进行产品性能测试,经过为期半个多月的产品性能评测,熔指、等规度、灰分等主要指标满足锂电池隔膜产品质量要求。6月上旬,独山子石化公司在其14万t/年聚丙烯装置上,采用我国自有的第二代环管仿SPHERIPOL-Ⅱ工艺生产技术,运用新型超高活性催化剂,首次成功试产了聚丙烯锂电池隔膜专用料T98F近 相似文献
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大庆石化分公司聚丙烯装置采用单环管液相本体均聚工艺,通过对影响产品质量因素的调查,研究探讨T38F产品后加工膜卷发红问题,结合公司聚丙烯装置的具体实际情况,研制开发出新配方助剂,降低了T38F产品的黄度指数,解决了产品后加工膜卷发红的问题,改善了产品质量。[编者按] 相似文献
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BOPP专用料的生产开发 总被引:2,自引:1,他引:2
介绍了聚丙烯双向拉薄膜(BOPP)专用料T46F-M的生产工艺和BOPP的发展现状,分析了BOPP专用料性能上存在的问题,并提出了相应的解决办法。 相似文献
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Chenyue Zhao Yanan Su Shaoqiu Zheng Hangyu He Xiaoxia Zheng Zhiqiang Li 《应用聚合物科学杂志》2024,141(13):e55170
A high-toughness epoxy has been prepared using carboxyl-terminated butadiene acrylonitrile (CTBN) as a toughening agent to modify the AG-80 epoxy resin. High-performance carbon fiber/epoxy (CF/EP) composites are fabricated using the CTBN-toughened epoxy resin as the matrix and two types of CF, namely, T800SC and T800HB, as reinforcement. The mechanical properties of the matrix, surface properties of the CFs, tensile properties, and fracture morphologies of the composites are systematically investigated to elucidate the key factors influencing interfacial bonding in high-performance CF/EP composites. The results reveal that the most significant improvement in toughness is achieved when the CTBN content is 6.90 wt.% in the epoxy resin. Owing to the high content of polar functional groups and excellent surface wettability of T800SC, the T800SC/EP composite exhibits superior mechanical properties compared with the T800HB/EP composite. 相似文献
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《合成纤维》2016,(2):13-18
利用环氧树脂(EP)与聚对苯二甲酸丁二醇酯(PBT)的相容性,考察了EP对共混物PBT/ABS-gGMA性能的影响。采用动态力学分析仪(DMA)、旋转流变仪、Haake流变仪和扫描电镜(SEM)研究共混物的性能。DMA、DSC和旋转流变仪的测试结果表明PBT与EP是相容的;流变性能测试结果表明EP对PBT/ABS-g-GMA共混体系起到增容作用;SEM观察结果发现少量的EP加入对共混物的相形态没有明显影响,分散相在PBT基体中均匀、稳定分散,而过量的EP使共混物中出现一些较大的相区,分散相发生团聚;力学性能测试结果表明适量的EP就能明显提高共混物的冲击性能,而过量的EP又会使共混物的冲击强度下降。 相似文献
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Sensing and surface morphological properties of a poly[(9,9‐dioctylfluorenyl‐2,7‐diyl)‐co‐bithiophene] liquid‐crystalline polymer for optoelectronic applications
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Bayram Gündüz 《应用聚合物科学杂志》2015,132(11)
The sensing properties of a poly[(9,9‐dioctylfluorenyl‐2,7‐diyl)‐co‐bithiophene] (F8T2) polymer were investigated at different concentrations and volume percentages. The effects of the concentrations and volume percentages on the sensing parameters were investigated. The sensitivities of F8T2 were found to be 3.190, 1.434, and 0.362 dB/vol % at 290, 580, and 940 nm, respectively. The response of the F8T2 increased with increasing concentration. F8T2 exhibited good sensitivity and response behaviors. Then, the optical parameters based on the refractive indices of the F8T2 at different molarities were calculated. The dispersion energy, moment of the dielectric constant optical spectrum (M?1, M?3), oscillator strength, and contrast of the F8T2 increased with increasing molarity, whereas the average excitation energy or single‐oscillator energy decreased with increasing molarity. The surface morphological properties of the F8T2 polymer film were investigated, and the roughness parameters were obtained. The F8T2 polymer could be used in the fabrication of various sensors because of the good solubility, sensitivity, and response behaviors. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41659. 相似文献
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使用十六烷基三甲基溴化铵(CTAB)、烷基酚聚氧乙烯醚(NP)和辛基酚类聚氧乙烯醚(S-13)3种不同表面活性剂乳化铁硅铬磁粉,通过共凝聚方法制备四氟乙烯与六氟丙烯共聚物(F46)包覆乳化后磁粉(F46/铁硅铬磁粉)的复合材料。通过扫描电子显微镜(SEM)表征共凝聚粒子的形貌,通过热重分析仪(TG)测试共凝聚粒子的热稳定性,通过矢量网络分析仪(VNA)测定样品的磁介性能。结果表明:在共凝聚过程中,阳离子型表面活性剂CTAB不仅对铁硅铬磁粉进行乳化,利于磁粉分散,而且在整个共凝聚体系起到破乳作用。采用CTAB乳化磁粉的共凝聚反应,出现凝胶的时间为第12 min,整个共凝聚过程耗时33 min,相比于其他共凝聚反应,缩短了反应时间;且加入质量分数10%乳化剂的磁粉剩余质量分数为0.59%,磁粉残余量最低。F46/铁硅铬磁粉复合材料的磁导率在18.00 GHz下还能保持在1.10左右,介电常数在1.00~18.00 GHz范围内稳定在2.30以下,F46/铁硅铬磁粉复合材料的磁介性能有所改善。 相似文献
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To improve the thermostability properties of epoxy (EP) resin, two kinds of novel hyperbranched polysiloxanes containing fluorine were prepared via the sol–gel process and the convenient transesterification process, respectively (F-HBPSi-1 and F-HBPSi-2). These two prepared F-HBPSi were then used as modifier phased to blend with EP to obtain two new series polymer alloys F-HBPSi-1/EP and F-HBPSi-2/EP. The dielectric properties and thermal conductivities of the cured F-HBPSi/EP resins were measured, while their thermal properties were also investigated by thermogravimetry (TG). The results showed that both the thermal conductivities and the thermostability properties of these two F-HBPSi/EP were increased effectively, without further damaging their dielectric properties. Meanwhile, the F-HBPSi-2/EP exhibits better thermal conductivities and thermostability properties than that of F-HBPSi-1/EP. The improved overall performance of F-HBPSi-2/EP can be attributed to the low viscosity and excellent compatibility of F-HBPSi-2, as well as the good synergism between fluorine and silicon. 相似文献
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organoclay‐modified polyurethane/epoxy interpenetrating network nanocomposites (oM‐PU/EP nanocomposites) were prepared by adding organophilic montmorillonite (oMMT) to interpenetrating polymer networks (IPNs) of polyurethane and epoxy resin (PU/EP) which had been prepared by a sequential polymerization technique. Wide‐angle X‐ray diffraction (WAXD) and transmission electronic microscopy (TEM) analysis showed that the interpenetrating process of PU and EP improved the exfoliation and dispersion degree of oMMT. The effects of the NCO/OH ratio (isocyanate index), the weight ratio of PU/EP and oMMT content on the phase structure and the mechanical properties of the oM‐PU/EP nanocomposites were studied by tensile testing and scanning electronic microscopy (SEM). Water absorption tests showed that the PU/EP interpenetrating networks and oMMT had synergistic effects on improvement in the water resistance of the oM‐PU/EP nanocomposites. Differential scanning calorimetry (DSC) analysis showed that PU was compatible with EP and that the glass transition temperature (Tg) of the oM‐PU/EP nanocomposites increased with the oMMT content up to 3 wt%, and then decreased with further increasing oMMT content. The thermal stability of these nanocomposites with various oMMT contents was studied by thermogravimetric analysis (TGA), and the mechanism of thermal stability improvement was discussed according to the experimental results. Copyright © 2005 Society of Chemical Industry 相似文献
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采用非等温DSC(差示扫描量热)法对EP(环氧树脂)/改性DDM(4,4′-二氨基二苯基甲烷)体系的固化反应过程进行了跟踪。采用Kissinger、Ozawa、Crane和T-β(温度-升温速率)外推法等得到该固化体系的动力学参数和固化工艺条件,并对其力学性能和热变形温度进行了测定。结果表明:EP/改性DDM体系的表观活化能为49.43 kJ/mol,反应级数为0.869,固化条件为"85℃/2 h→125℃/2 h",热变形温度为130℃;与EP/DDM体系相比,该固化体系的表观活化能降低了7.0%,热变形温度下降了16.1%,拉伸强度和压缩强度提高了20%以上,而弯曲强度和弯曲模量基本上保持不变。 相似文献
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采用聚氨酯(PU)和环氧树脂(EP)及云母填料合成了PU/EP二元IPN水声吸声材料,对该材料的动态模量和声速进行了测量,研究了EP含量和云母填料及含量对材料动态模量及声速的影响,并对材料的吸声性能进行了分析。结果表明,材料弹性模量越大,材料中声波传播速度就越大;随着填料含量的增加,声速的下降幅度增大。并用直观的物理量表征了抽象的声学量,为指导水声材料的设计提供了基础。 相似文献
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Effect of processing conditions on physical properties of 3‐aminophenoxyphthalonitrile/epoxy laminates
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To develop high performances of polymer composite laminates, differential scanning calorimetry and dynamic rheological analysis studies were conducted to show curing behaviors of 3‐aminophenoxyphthalonitrile/epoxy resin (3‐APN/EP) matrix and define cure parameters of manufacturing processes. Glass fiber reinforced 3‐APN/EP (GF/3‐APN/EP) composite laminates were successfully prepared through different processing conditions with three parameters such as pressures, temperatures, and time. Based on flexure tests, dynamic mechanical analysis, thermal gravimetric analysis, and scanning electron microscope, the complementary catalytic effect of the three processing parameters is investigated by studying mechanical behavior, thermomechanical behavior, thermal behavior, and fracture morphology of GF/3‐APN/EP laminates. The 50/50 GF/3‐APN/EP laminates showed a significant improvement in flexural strength, glass transition temperature (Tg), and thermal stability with favorable processing parameters. It was also found that the Tg and thermal stability were significantly improved by the postheated treatment method. The effect of manufacturing process provides a new and simple route for the polymer–matrix composites application, which indicates that the composites can be manufactured at low temperatures. But, they can be used in a high temperature environment. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39746. 相似文献