Comparison between high strength concrete and normal strength concrete subjected to high temperature

Two normal strength concretes and three high strength concretes, with 28-day compressive strengths of 28, 47, 76, 79 and 94 MPa respectively, were used to compare the effect of high temperatures on high strength concrete and normal strength concrete. After being heated to a series of maximum temperatures at 400, 600, 800, 1000 and 1200°C, and maintained for 1 hour, their compressive strengths and tensile splitting strengths were determined. The pore size distribution of hardened cement paste in high strength concrete and normal strength concrete was also investigated. Results show that high strength concrete lost its mechanical strength in a manner similar to or slightly better than that of NSC. The range between 400 and 800°C was critical to the strength loss of concrete with a large percentage of loss of strength. Microstructural study carried out revealed that high temperatures have a coarsening effect on the microstructure of both of high strength concrete and normal strength concrete.     

High strength blended cement concrete incorporating volcanic ash: Performance at high temperatures

The strength and durability of high strength blended cement concretes incorporating up to 20% of volcanic ash (VA) subjected to high temperatures up to 800 °C are described. The strength was assessed by unstressed residual compressive strength, while durability was investigated by rapid chloride permeability (RCP), mercury intrusion porosimetry (MIP), differential scanning calorimetry (DSC), crack pattern observations and microhardness testing. High strength volcanic ash concrete (HSVAC) exhibited better performance showing higher residual strength, chloride resistance and resistance against deterioration at high temperatures compared to the control high strength OPC concrete. However, deterioration of both strength and durability of HSVACs increased with the increase of temperature up to 800 °C due to weakened interfacial transition zone (ITZ) between hardened cement paste (hcp) and aggregate and concurrent coarsening of the hcp pore structure. The serviceability assessment of HSVACs after a fire should therefore, be based on both strength and durability considerations.     

Influence of steam curing on the properties of concretes incorporating metakaolin and silica fume

In this paper, influence of steam curing on the compressive strength, ultrasonic pulse velocity, water sorptivity, chloride ion permeability, and electrical resistivity of metakaolin and silica fume blended concretes were investigated. A total of seven mixtures containing various combinations of Portland cement (PC), silica fume (SF), and metakaolin (MK) were produced with 400 kg/m³ of total cementitious materials content and with a constant water/binder ratio of 0.44. For each mixture, concrete samples were either standard-cured in water at 23°C or steam-cured at 70°C maximum temperature over 17 h curing period. Test results revealed that steam curing enhanced the 1-day compressive strength and ultrasonic pulse velocity while leading to reduced long term strength in line with earlier findings. At the end of the water sorptivity, chloride ion permeability, and electrical resistivity tests, it was found that the steam-cured concretes had higher water sorptivity and chloride ion permeability, and lower electrical resistivity values compared to the standard cured specimens. Use of SF and MK as cementitious materials remarkably decreased the water sorptivity and chloride ion permeability of concretes, irrespective of the curing condition.     

Effects of slag and cooling method on the progressive deterioration of concrete after exposure to elevated temperatures as in a fire event

In the present work OPC and OPC/slag concretes were exposed to elevated temperatures, 400 and 800°C. The critical temperature of 400°C has been reported for OPC paste. Above 400°C, the paste hydrate Ca(OH)₂ dehydrates into CaO causing the OPC paste to shrink and crack. After cooling and in the presence of air moisture, CaO rehydrates into Ca(OH)₂, resulting in disintegration due to re-expansion of OPC paste. Therefore, the present work assessed whether this also applies to OPC concretes. Two cooling methods were used: furnace and water cooling. Following the heat treatment/cooling method, compressive tests and Infrared (IR) spectroscopic studies were conducted. Results showed that after 400°C, water cooling caused all concrete, regardless of the type of blended cement binder, a further 20% loss in the residual strength. After 800°C, water cooling caused OPC concrete a further 14% loss while slag blends presented around 5% loss. IR indicated that the further loss observed in the OPC concrete is due to the accelerated CaO rehydration into Ca(OH)₂. Afterward, the non-wetted furnace cooled specimens were exposed to air moisture for one week, resulting in further strength loss of 13%. IR results suggested that slow rehydration of CaO occur with exposure to air moisture. In conclusion, water cooling caused more damage in OPC concrete, while the concrete that has not been wetted undergoes progressive deterioration. This indicates a need to monitor the non-wetted concrete after a fire event has occurred for potential further deterioration.     

The effect of temperature on the hydration of composite cements containing limestone powder and fly ash

The effect of the curing temperature (5, 20 and 40°C) on the degree of hydration, amount of bound water and calcium hydroxide, porosity and the development of mechanical properties was investigated on pastes and mortars prepared with fly ash (FA)?Climestone (L) Portland composite cements. Increasing the curing temperature for ordinary Portland cement (OPC) leads to a more inhomogeneous distribution of hydration products, resulting in an increased coarse porosity and therefore a lower compressive strength after 7?days and longer. In contrast, the FA containing mortars showed higher compressive strength with increasing curing temperature up to 90?days. The reaction of the FA is increased at 40°C and strongly retarded at 5°C. At 20 and 40°C, FA reduces the porosity at later ages. The replacement of 5% of the OPC or FA by L powder did not impair the strength at 5 and 20°C, but lowered strength slightly at 40°C for the FA blended cements. The porosity appears to be the dominating factor regarding the compressive strength, independent of whether part of the OPC is replaced by FA and L powder or not.     

Residue strength,water absorption and pore size distributions of recycled aggregate concrete after exposure to elevated temperatures

In this paper, the effects of high temperature exposure of recycled aggregate concretes in terms of residual strengths, capillary water absorption capacity and pore size distribution are discussed. Two mineral admixtures, fly ash (FA) and ground granulated blast furnace (GGBS) were used in the experiment to partially replace ordinary Portland cement for concrete production. The water to cementitious materials ratio was maintained at 0.50 for all the concrete mixes. The replacement levels of natural aggregates by recycled aggregates were at 0%, 50% and 100%. The concretes were exposed separately to 300 °C, 500 °C and 800 °C, and the compressive and splitting tensile strength, capillary water coefficient, porosity and pore size distribution were determined before and after the exposure to the high temperatures. The results show that the concretes made with recycled aggregates suffered less deteriorations in mechanical and durability properties than the concrete made with natural aggregates after the high temperature exposures.     

Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature

Most previous works on fly ash based geopolymer concrete focused on concretes subjected to heat curing. Development of geopolymer concrete that can set and harden at normal temperature will widen its application beyond precast concrete. This paper has focused on a study of fly ash based geopolymer concrete suitable for ambient curing condition. A small proportion of ordinary Portland cement (OPC) was added with low calcium fly ash to accelerate the curing of geopolymer concrete instead of using elevated heat. Samples were cured in room environment (about 23 °C and RH 65 ± 10%) until tested. Inclusion of OPC as little as 5% of total binder reduced the setting time to acceptable ranges and caused slight decrease of workability. The early-age compressive strength improved significantly with higher strength at the age of 28 days. Geopolymer microstructure showed considerable portion of calcium-rich aluminosilicate gel resulting from the addition of OPC.     

Effects of different curing regimes on the compressive strength properties of self compacting concrete incorporating fly ash and silica fume

This paper presents the effect of air curing, water curing and steam curing on the compressive strength of Self Compacting Concrete (SCC). For experimental study, SCC is produced with using silica fume (SF) instead of cement by weight, by the ratios of 5%, 10% and 15%, and fly ash (FA) with the ratios of 25%, 40% and 55%. It is observed that mineral admixtures have positive effects on the self settlement properties. The highest compressive strength was observed in the concrete specimens with using 15% SF and for 28 days water curing. Air curing caused compressive strength losses in all groups. Relative strengths of concretes with mineral admixtures were determined higher than concretes without admixtures at steam curing conditions.     

The effect of mineral admixtures on the properties of high-performance concrete

The paper presents a laboratory study on the influence of two mineral admixtures, silica fume (SF) and fly ash (FA), on the properties of superplasticised high-performance concrete. Assessment of the concrete mixes was based on short- and long-term testing techniques used for the purpose of designing and controlling the quality of high-performance concrete. These include compressive strength, porosity, oxygen permeability, oxygen diffusion and chloride migration. Measurements were carried out after curing at 20% and 65% relative humidity up to the age of 1 yr. The results, in general, showed that mineral admixtures improved the properties of high-performance concretes, but at different rates depending on the binder type. While SF contributed to both short- and long-term properties of concrete, FA required a relatively longer time to get its beneficial effect. In the long term, both mineral admixtures slightly increased compressive strength by about 10%, but contributed more to the improvement of transport properties of concretes.     

Effect of fire exposure on cracking,spalling and residual strength of fly ash geopolymer concrete

Fly ash based geopolymer is an emerging alternative binder to cement for making concrete. The cracking, spalling and residual strength behaviours of geopolymer concrete were studied in order to understand its fire endurance, which is essential for its use as a building material. Fly ash based geopolymer and ordinary portland cement (OPC) concrete cylinder specimens were exposed to fires at different temperatures up to 1000 °C, with a heating rate of that given in the International Standards Organization (ISO) 834 standard. Compressive strength of the concretes varied in the range of 39–58 MPa. After the fire exposures, the geopolymer concrete specimens were found to suffer less damage in terms of cracking than the OPC concrete specimens. The OPC concrete cylinders suffered severe spalling for 800 and 1000 °C exposures, while there was no spalling in the geopolymer concrete specimens. The geopolymer concrete specimens generally retained higher strength than the OPC concrete specimens. The Scanning Electron Microscope (SEM) images of geopolymer concrete showed continued densification of the microstructure with the increase of fire temperature. The strength loss in the geopolymer concrete specimens was mainly because of the difference between the thermal expansions of geopolymer matrix and the aggregates.     

Influence of calcining temperature on the pozzolanic characteristics of elephant grass ash

The influence of calcining temperature on the pozzolanic properties of elephant grass ash (EGA) for application as a supplementary cementitious material is reported. Five different calcining temperatures were used (ranging from 500 to 900 °C for 3 h at 100 °C increments) after a first calcining step at 350 °C for 3 h, a 10 °C/min heating rate, and a 0.04 constant volumetric ratio between the sample and the internal furnace chamber. After calcining and high energy grinding, all ashes were characterized based on particle size distribution, oxide composition, loss on ignition, B.E.T. specific surface area, X-ray diffraction, and scanning electron microscopy. The pozzolanic behavior was investigated based on pozzolanic activity index test and compressive strength of concretes up to 180 days of curing. An expressive decrease in loss on ignition values and, consequently, increase in silica content of EGA produced at higher temperatures were observed. Overall, the results demonstrated that 600 °C was the most suitable temperature for producing EGA. Additionally, the replacement of 20% (in volume) of cement by 600 °C-calcining EGA did not change significantly the 28-day compressive strength of concrete, and increased the strength after 180 days of curing in relation to a reference concrete.     

Effects of mineral admixtures on fresh and hardened properties of self-compacting concretes: binary,ternary and quaternary systems

The paper presented herein investigates the effects of using supplementary cementitious materials in binary, ternary, and quaternary blends on the fresh and hardened properties of self-compacting concretes (SCCs). A total of 22 concrete mixtures were designed having a constant water/binder ratio of 0.32 and total binder content of 550 kg/m³. The control mixture contained only portland cement (PC) as the binder while the remaining mixtures incorporated binary, ternary, and quaternary cementitious blends of PC, fly ash (FA), ground granulated blast furnace slag (GGBFS), and silica fume (SF). After mixing, the fresh properties of the concretes were tested for slump flow time, L-box height ratio, V-funnel flow time, setting time, and viscosity. Moreover, compressive strength, ultrasonic pulse velocity, and electrical resistivity of the hardened concretes were measured. Test results have revealed that incorporating the mineral admixtures improved the fresh properties and rheology of the concrete mixtures. The compressive strength and electrical resistivity of the concretes with SF and GGBFS were much higher than those of the control concrete.     

Strength,drying shrinkage,and water permeability of concrete incorporating ground palm oil fuel ash

In this study, palm oil fuel ash (POFA) was used as a pozzolanic material in concrete. The POFA was ground to obtain two different finenesses: coarse (CP) and fine (FP). A portion of ordinary type I Portland cement (OPC) was replaced by CP and FP at 10%, 20%, and 30% by weight of binder to cast concrete. Compressive strength, modulus of elasticity, drying shrinkage, and water permeability of concretes containing ground POFA were measured. The results showed that the compressive strength of the concrete increased with the fineness of the POFA. With 10% and 30% replacement of OPC by CP and FP, respectively, the compressive strength of the resulting concrete was as high as that of OPC concrete at 90 days. Moreover, the use of 10–30% of FP as a cement replacement in concrete reduced its drying shrinkage and water permeability. Finally, there was also a strong correlation between the compressive strength and the water permeability of ground POFA concrete.     

Comparative study on strength,sorptivity, and chloride ingress characteristics of air-cured and water-cured concretes modified with metakaolin

This paper reports an investigation in which the performance of plain and metakaolin (MK)-modified concretes were studied under two different curing regimes. The purpose of this study is to evaluate the effectiveness of MK in enhancing the strength and permeation properties of concrete. MK was used to replace 0–20% of Portland cement by weight in concrete with two water-binder (w/b) ratios of 0.35 and 0.55. The change in compressive strength, sorptivity, and chloride ingress with age at all cement replacement levels under both air and water curing are compared with those of the control concrete. The results indicated that the inclusion of MK greatly reduced sorptivity and chloride permeability of concrete in varying magnitudes, depending mainly on replacement level of MK, w/b ratio, curing condition, and chloride exposure period. It was found that under the inadequate or poor curing, MK-modified concretes suffered a more severe loss of compressive strength and permeability-related durability than the plain concretes.     

Mechanical properties of ultra-lightweight cement composite at low temperatures of 0 to −60 °C

This paper presents an experimental study on mechanical properties of an innovative ultra-lightweight cement composite (ULCC) at low temperatures down to −60 °C in comparison with those at ambient temperature. Those properties include stress-strain curve, ultimate strength, elastic modulus, Poisson ratio, and flexural tensile behavior. Effect of curing condition is also evaluated. In addition, the performance of the ULCC is compared with that of a normal weight concrete (NWC) and a lightweight concrete (LWC) with similar 28-day compressive strength. The cylindrical compressive strength of the NWC and LWC was increased generally with the reduction in temperature. However, the same phenomenon was not observed for the ULCC. The elastic modulus of the ULCC did not change much, whereas the elastic modulus of the NWC increased significantly with the reduction of temperature from 30 °C to −60 °C. Strain of the ULCC at the peak load was generally much higher than that of the NWC and LWC, and was generally not affected by the temperature. The flexural strength of the three concretes was increased with the reduction in temperature. Duration of the moist curing did not affect the performance of the ULCC under compression significantly, but influenced its flexural strength significantly.     

Transport and mechanical properties of self consolidating concrete with high volume fly ash

This paper presents the transport and mechanical properties of self consolidating concrete that contain high percentages of low-lime and high-lime fly ash (FA). Self consolidating concretes (SCC) containing five different contents of high-lime FA and low-lime FA as a replacement of cement (30, 40, 50, 60 and 70 by weight of total cementitious material) are examined. For comparison, a control SCC mixture without any FA was also produced. The fresh properties of the SCCs were observed through, slump flow time and diameter, V-funnel flow time, L-box height ratio, and segregation ratio. The hardened properties included the compressive strength, split tensile strength, drying shrinkage and transport properties (absorption, sorptivity and rapid chloride permeability tests) up to 365 days. Test results confirm that it is possible to produce SCC with a 70% of cement replacement by both types of FA. The use of high volumes of FA in SCC not only improved the workability and transport properties but also made it possible to produce concretes between 33 and 40 MPa compressive strength at 28 days, which exceeds the nominal compressive strength for normal concrete (30 MPa).     

Durability aspect of concretes composed of cold bonded and sintered fly ash lightweight aggregates

This study reports the finding of an experimental study carried out on the durability related properties of the lightweight concretes (LWCs) including either cold bonded (CB) or sintered (S) fly ash aggregates. CB aggregate was produced with cold bonding pelletization of class F fly ash (FA) and Portland cement (PC) while S aggregate was produced by sintering the fresh aggregate pellets manufactured from FA and bentonite (BN). Two concrete series with water-to-binder (w/b) ratios of 0.35 and 0.55 were designed. Moreover, silica fume (SF) with 10% replacement level was also utilized for the purpose of comparing the performances of LWCs with and without ultrafine SF. The durability properties of concretes composed of CB and S aggregates were evaluated in terms of water sorptivity, rapid chloride ion permeability, gas permeability, and accelerated corrosion testing after 28 days of water curing period. The compressive strength test was also applied to observe the strength level at the same age. The results revealed that S aggregate containing LWCs had relatively better performance than LWCs with CB aggregates. Moreover, the incorporation of SF provided further enhancement in permeability and corrosion resistance of the concretes.     

Mechanical properties of concrete containing phase-change material

This study aimed to investigate the mechanical properties of concrete containing solid–liquid phase-change material (PCM) and focused on two key factors. First, a systematic study on the mechanical performance of PCM-modified concretes was conducted, including compressive, elastic modulus, and shrinkage tests. Second, because PCM provides high latent heat during the solid–liquid phase change, the effects of the solid phase and liquid phase on the mechanical properties of concrete were also explored. Results of this study showed that the solid–liquid phase of PCM affected the mechanical properties of concrete. For example, the compressive strength of 10% PCM concrete in solid phase (23 °C) and liquid phase (40 °C) at 28 days was 29.30 and 19.57 MPa, respectively. In addition, with increasing PCM content, the mechanical properties were degraded. For example, 10, 20, and 30% of PCM content lowered the compressive strength by 35.4, 58.4, and 74.3%, respectively. Therefore, concrete with PCM may not be suitable for structural elements. However, PCM is an important solution for optimizing energy consumption in modern buildings. It can absorb or emit large amounts of heat to store or release thermal energy. These properties can be used to control building temperatures resulting in energy saving and carbon reduction.     

Bar-concrete bond in mixes containing calcium carbide residue,fly ash and recycled concrete aggregate

A mixture of calcium carbide residue and fly ash (CRFA) is an innovative new binder for concrete instead of using ordinary Portland cement (OPC). Therefore, this study aims at investigating the bond interaction between common steel reinforcing bars and the aforementioned concrete. To this end, both CRFA and OPC concretes using crushed limestone and recycled concrete aggregate (RCA) as a coarse aggregate were prepared to investigate the bond strength of smooth and deformed bars by pull-out tests. The bond stress−slip relationships were also identified to determine the effects of CRFA binder and RCA on the bond strength behavior. The results indicate that the values the of bond-slip behavior and bond strengths of steel bar in CRFA concretes are similar to those embedded in OPC concrete. Moreover, the bond strength was significantly affected by RCA and the types of steel bar. Although the concretes had the same compressive strengths, the deformed bar embedded in CRFA concrete with RCA had a lower bond strength than the one with crushed limestone. However, the reduction in bond strength of the CRFA concrete with RCA was still less than that of OPC concrete with RCA. For the CRFA concretes, the bond strengths of the deformed bars were approximately 1.7–3.6 times higher than that of smooth bars.     

Characterizing the bond strength of geopolymers at ambient and elevated temperatures

This paper presents characterization of bond strength of geopolymers at ambient and elevated temperatures. The bond strength of 18 different formulations of metakaolin (MK)/fly ash (FA) based geopolymers is evaluated through double shear tests in 20–300 °C temperature range. The test parameters include fly ash content, SiO₂/K₂O ratio, solid-to-liquid ratio and Si/Al ratio. In addition the effect of additives, namely short carbon fibers, basalt fibers and styrene–acrylate emulsion in MK/FA precursor, on bond strength is studied. Data from the tests show that geopolymers exhibit slightly lower bond strength than that of epoxy resin at room temperature, however geopolymers retain much higher bond strength in 100–300 °C range. Addition of small quantity of short carbon fibers in MK/FA precursor does not significantly influence bond strength of geopolymers at ambient temperature, but greatly improve bond strength retention in 100–300 °C through crack control mechanism.