Thermodynamic study of multistage absorption cycles using low‐temperature heat

The use of low‐temperature heat (between 50 and 90°C) is studied to drive absorption systems in two different applications: refrigeration and heat pump cycles. Double‐ and triple‐stage absorption systems are modelled and simulated, allowing a comparison between the absorbent–refrigerant solutions H₂O–NH₃, LiNO₃–NH₃ and NaSCN–NH₃. The results obtained for the double‐stage cycle show that in the refrigeration cycle the LiNO₃–NH₃ solution operates with a COP of 0.32, the H₂O–NH₃ pair with a COP of 0.29 and the NaSCN–NH₃ solution with a COP of 0.27, when it evaporates at ?15°C, condenses and absorbs refrigerant at 40°C and generates vapour at 90°C. The results are presented for double‐ and triple‐stage absorption systems with evaporation temperatures ranging between ?40 and 0°C and condensation temperatures ranging from 15°C to 45°C. The results obtained for the double‐stage heat pump cycle show that the LiNO₃–NH₃ solution reaches a COP of 1.32, the NaSCN–NH₃ pair a COP of 1.30 and the H₂O–NH₃ mixture a COP of 1.24, when it condenses and absorbs refrigerant at 50°C, evaporates at 0°C and generates vapour at 90°C. For the double‐ and triple‐stage cycles, the results are presented for evaporation temperatures ranging between 0 and 15°C. The minimum temperature required in the generators to operate the refrigeration and heat pump cycles are also presented. Copyright © 2002 John Wiley & Sons, Ltd.     

Performance improvement of absorption heat transformer

In this study, a mathematical model of absorption heat transformer (AHT) operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds and used a special ejector located at the absorber inlet. By the use of the ejector, the obtained absorber pressure becomes higher than the evaporator pressure and thus the system works with triple-pressure-level. The ejector has two functions: (i) aids pressure recovery from the evaporator and (ii) upgrades the mixing process and the pre-absorption by the weak solution of the ammonia coming from the evaporator. The other advantage of the system with ejector is increased absorber temperature. Therefore, pressure recovery and pre-absorption in the ejector improves the efficiency of the AHT. Under the same circumstances, when compared to an AHT with and without an ejector, the system's COP and exergetic coefficient of performance (ECOP) were improved by 14% and 30%, respectively and the circulation ratio (f) was reduced by 57% at the maximum efficiency condition. Due to the reduced circulation ratio, the system dimensions can be reduced; consequently, this decreases overall cost. The maximum upgrading of the solar pond's temperature by the AHT was obtained at 57.5 °C and gross temperature lift at 97.5 °C with coefficients of performance of about 0.5. The maximum temperature of the useful heat produced by the AHT was 150 °C. In addition, exergy losses for each component in the system were calculated at different working temperatures and the results of both systems with and without an ejector were compared. Exergy analysis emphasised that both the losses and irreversibilities have an impact on the system performance and exergy analysis can be used to identify the less efficient components of the system. Exergy analyses also showed that the exergy loss of the absorber of AHT with ejector was higher than those of other components.     

Solid/vapour sorption heat transformer: Design and performance

A high temperature high lift solid sorption based heat transformer has been successfully designed and tested. The sorption reactor concept is based on a tube-fin heat exchanger where the heat exchanging fluids can flow through the hollow fins. The plates were brazed together with porous metal foam that was impregnated with either of the sorbents, LiCl and MgCl₂. The adsorbate is ammonia. The batch system was tested as to the power delivered at high temperatures, 150–200 °C. Peak power at 200 °C was about 0.8 kW, the average power about 0.4 kW. The thermal efficiency, COP, was calculated from the experimental results to be 0.11. This is only 40% of the expected theoretical value and can largely be attributed to the thermal mass of the reactor.     

Effect of irreversibilities on performance of an absorption heat transformer used to increase solar pond’s temperature

Absorption thermal systems are attractive for using waste heat energy from industrial processes and renewable energy such as geothermal energy, solar energy, etc. The Absorption Heat Transformer (AHT) is a promising system for recovering low-level waste heat. The thermal processes in the absorption system release a large amount of heat to the environment. This heat is evolved considerably at temperature, the ambient temperature results in a major irreversible loss in the absorption system components. Exergy analysis emphasises that both losses and irreversibility have an impact on system performance. Therefore, evaluating of the AHT in exergy basis is a much more suitable approach. In this study, a mathematical model of AHTs operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds. A heat source at temperatures not higher than 100 °C was used to simulate the heat input to an AHT from a solar pond. In this paper, exergy analysis of the AHT were performed and effects of exergy losses of the system components on performance of the AHT used to increase solar pond’s temperature were investigated. The maximum upgrading of solar pond’s temperature by the AHT, is obtained at 51.5 °C and gross temperature lift at 93.5 °C with coefficients of performance of about 0.4. The maximum temperature of the useful heat produced by the AHT was ˜150 °C. As a result, determining of exergy losses for the system components show that the absorber and the generator need to be improved thermally. If the exergy losses are reduced, use of the AHT to increase the temperature of the heat used from solar ponds will be more feasable.     

Performance analysis and validation on transportation of heat energy over long distance by ammonia–water absorption cycle

This paper presents the thermodynamic and hydrodynamic feasibility of the application of the ammonia–water absorption system for heat or cold transportation over long distance. A model of a long‐distance heat energy transportation system is built and analyzed, and it shows satisfactory and attractive results. When a steam heat source at the temperature of 120°C is available, the user site can get hot water output at about 55°C with the thermal COP of about 0.6 and the electric COP of about 100 in winter, and cold water output at about 8°C with the thermal COP of about 0.5 and the electric COP of 50 in summer. A small‐size prototype is built to verify the performance analysis. Basically the experimental data show good accordance with the analysis results. The ammonia–water absorption system is a potential prospective solution for the heat or cold transportation over long distance. Copyright © 2009 John Wiley & Sons, Ltd.     

Absorption heat transformers and an industrial application

Absorption Heat Transformer (AHT) systems are devices with the unique capability of raising the temperature of low or moderately warm waste heat sources to more useful levels. The study includes an investigation to analyze the AHT systems using water-lithium bromide solutions with water as the refrigerant. First, a basic AHT system was described, the operating sequence was explained and thermodynamic system analysis was presented. Next, an application of the AHT system to an industrial company was analyzed. A computer code was prepared to determine the effect of different parameters on the AHT system performance and the results were presented in graphical form. Additionally, it was shown that how the basic AHT system could be modified to increase the COP and the heat transfer at the absorber, in other words, the hot process water produced. The system performance data were presented in a tabular form for different system modifications from the base system for comparison. It was proven that, by applying different modifications, the COP could be increased by 14.1%, the heat transfer at the absorber by 158.5% and the hot process water produced by 3.59% compared to the basic AHT system.     

Experimental investigation on heat recovery from condensation of thermal power plant exhaust steam by a CO2 vapor compression cycle

In this paper, a method that utilizes CO₂ vapor compression thermodynamic cycle to recover low‐temperature heat from exhausted water steam of fossil fuel thermal power plants is reported. Experimental investigation was carried out to study the characteristics of low‐temperature heat recovery by liquid CO₂ evaporation process from vacuum exhausted steam condensation occurring at the turbine exit. Furthermore, measured heat recovery performances over one whole year are presented and discussed. Experimental results show that the present heat recovery process by CO₂ vapor compression cycle is able to operate stably. The yearly averaged water temperature at the CO₂ condenser outlet was measured at 87.5 °C with a COP value above 5.0. This high energy efficiency ratio is found to be mainly due to two factors: the transcritical CO₂ vapor compression and steam condensation phase change occurring on the CO₂ evaporator. The findings from this paper provide helpful guidelines for low‐temperature heat recovery system design and improving fossil fuel utilization efficiency. Copyright © 2013 John Wiley & Sons, Ltd.     

Study on performance of a heat pump water heater using suction stream liquid injection

Liquid refrigerant injection into a suction line is an effective and practical method to reduce the discharge temperature when a scroll compressor operates at high compression ratios. In the present study, correlations among the compressor suction temperature, discharge temperature, heat pump heating capacity, power consumption, coefficient of performance (COP) and the quantity of suction liquid injection are established. The paper presents experimental analysis and a comparison with calculated results of the heat pump water heater (HPWH) performance with suction liquid injection in different conditions. It is found that the suction liquid injection explicitly lowers the discharge temperature of the compressor and the heating capacity of the unit, but the power consumption increases with COP decreasing. In addition, the highest injection ratio must be controlled fewer than 5%. The suction liquid injection has a better effect on the HPWH at the temperature ranging from ?15 °C to 20 °C. Within this temperature range, the 5% ratio suction liquid injection decreases the discharge temperature of the compressor by 10 °C, while the heating capacity of the HPWH decreases by less than 5%, power consumption increases by less than 1.5%, and COP decreases by less than 7%.     

Catalyst-assisted chemical heat pump with reaction couple of acetone hydrogenation/2–propanol dehydrogenation for upgrading low-level thermal energy: Proposal and evaluation

A chemical heat pump for upgrading low-level thermal energy has been proposed by adopting a reversible organic reaction couple, endothermic liquid-phase dehydrogenation of 2–propanol at low temperature and exothermic gas-phase hydrogenation of acetone at high temperature, where thermodynamical work is done by separating condensed 2–propanol from the gaseous mixture of 2–propanol, acetone and hydrogen in a fractionation column. In the system constitution of the continuous type, the overhead vapour of the fractionation column is fed through the heat exchanger into the exothermic reactor, where acetone and hydrogen in excess are changed at 200°C into the equilibrium mixture, from which condensable 2–propanol is separated in the column by cooling at 30°C. The reverse reaction of 2–propanol decomposition into acetone and hydrogen proceeds in the endothermic reactor, i.e. the reboiler of the column, absorbing heat at 80°C. On the contrary, acetone and hydrogen in the overhead vapour of the fractionation column are stored at 30°C as liquid and metal hydride, respectively, in the system constitution of the storage type; when necessary, metal hydride is decomposed by heating at 80°C, with hydrogen at high pressure evolved and fed through the heat exchanger into the exothermic reactor, giving the equilibrium mixture at high pressure and temperature. Product condensates are transferred through a valve into the fractionation column in order to separate 2–propanol and acetone, the former of which is dehydrogenated in the endothermic liquid-phase reactor, regenerating acetone and hydrogen at 80°C and atmospheric pressure. Energy efficiencies were evaluated for the system constitutions of both the continuous and storage types; the 80°C heat supplied was convertible into the 200°C heat continuously at the enthalpy efficiency or coefficient of performance (COP) of 0·36 in the former, whereas the 270°C heat was obtainable with the aid of metal hydride from the same heat source at COP of 0·21 in the latter.     

An experimental investigation of steam ejector refrigeration system powered by extra low temperature heat source

A steam ejector refrigeration system is a low capital cost solution for utilizing industrial waste heat or solar energy. When the heat source temperature is lower than 80 °C, the utilization of the thermal energy from such a low-temperature heat source can be a considerable challenge. In this investigation, an experimental prototype for the steam ejector refrigeration system was designed and manufactured, which can operate using extra low-temperature heat source below 80 °C. The effects of the operation temperature, the nozzle exit position (NXP) and the diameter of the constant area section on the working performance of the steam ejector were investigated at generating temperatures ranging from 40 °C to 70 °C. Three ejectors with a same de Laval nozzle for the primary nozzle and three different constant-area sections were designed and fabricated. The experimental results show that a steam ejector can function for a certain configuration size of the steam ejector with a generating temperature ranging from 40 °C to 70 °C and an evaporating temperature of 10 °C. For a given NXP, the system COP and cooling capacity of the steam ejector decreased until inoperative as the diameter of the constant area section reduced. The results of this investigation provided a good solution for the refrigeration application of the steam ejector refrigeration system powered by an extra low-temperature heat source.     

Performance of a solar air composite heat source heat pump system

For the shortcoming of air source heat pump in heating condition, a composite heat exchanger was designed which integrates fin tube and tube heat exchanger, and it can achieve synchronous and composite heat exchange in one heat exchanger between working fluids, gaseous and liquid heat source. With the above composite heat exchanger as the core component, the Solar Air Composite Heat Source Heat Pump System (SACHP) was developed which has three working modes, including single solar heat source mode, single air heat source mode and solar air dual heat sources mode. A SACHP experiment table was established and conducted a comprehensive experimental study of three working modes of this system in the standard enthalpy difference laboratory. The results show that when the ambient temperature was −15 °C, compared to the single air heat source mode, the dual heat source mode increased 62% in heat capacity and 59% in COP; when the temperature difference of combined heat transfer was 5 °C, compared to the single air heat source mode, the dual heat source mode increased 51% in heat capacity and 49% in COP. Experimental results demonstrate that the application of the solar air composite heat pump technology can accelerate the application process of the solar heat pump in air conditioners for buildings.     

Lithium bromide high-temperature absorption heat pump: Coefficient of performance and exergetic efficiency

A theoretical study on the employment of a lithium bromide absorption heat pump in Spain, used as machine type I and aimed to produce heat at 120°C via waste heat sources at 60°C, is given in the paper. Real performance conditions are stated for each component of the machine, namely the absorber, the heat recoverer, the generator, the condenser, the solution pump, the expansion valve and the evaporator. By means of thermodynamic diagrams (p, t, x) and (h, x), the required data are obtained for calculation of the heat recovered in the evaporator Q_e, and the heat delivered to the absorber Q_a and to the condenser Q_c, as well as the heat supplied to the generator Q_g. In addition, the heat delivered by the hot solution to the cold solution in the heat recovered Q_r, and the work W_p done by the solution pump are calculated. The probable COP is calculated, and values are obtained close to 1.4. The working temperature in the generator is determined; it ranges from 178 to 200°C. The heat produced by the lithium bromide absorption heat pump is 22% cheaper than the heat obtained from a cogeneration system comprising natural gas internal combustion engine and a high temperature heat pump with mechanical compression. Compared with a high temperature heat pump with mechanical compression, the heat produced by the absorption heat pump is 31% cheaper. From (h, x) and (s, x) diagrams, exergy losses for each component can be determined, and, from these results, an exergetic efficiency of 75% is obtained, which provides the quality index of absorption cycle.     

Flue gas waste heat affects algal liquid temperature for microalgal production in column photobioreactors

To explore the effects of waste heat (50–170°C) from steel plant flue gas on the column photobioreactor algal liquid temperature for microalgal production, a flue gas-microalgal liquid heat transfer model was developed that simulated the microalgal growth environment for flue-gas carbon dioxide (CO₂) fixation. The simulation results showed that the influence of high-temperature flue gas weakened with the increasing microalgal liquid temperature due to enhanced evaporation and heat dissipation. Increasing the flue gas temperature and aeration rate resulted in a higher microalgal liquid temperature up to a maximum increase of 4.16°C at an ambient temperature of 25°C, an aeration rate of 2 L/min, and a flue gas temperature of 170°C. In an experiment on the effect of incubation temperature on the growth rate of microalgae, at an optimal temperature of 35°C, the Chlorella sp. PY-ZU1 growth rate exhibited a remarkable increase of 104.7% compared to that at 42.5°C. Therefore, modulating the flue gas conditions can significantly increase the microalgal growth rate for CO₂ fixation, making it a promising approach to increase biomass production for efficient carbon utilization.     

Heat pump assisted distillation. III: Experimental studies using an external heat pump

An experimental study has been carried out on a continuously operated pilot fractional distillation column equipped with an external heat pump. The distillation column was a 15 cm diameter glass unit containing eleven single bubble cap plates. A methanol-water mixture was fed to the column and the heat pump working fluid was R114. The actual coefficient of performance (COP)_A of the heat pump increased with an increase in the mass flow rate of the working fluid. A maximum (COP)_A value of 4–3 was obtained with a gross temperature lift of 41–3°C. The performance of two reciprocating compressors was compared. The experiments have shown that continuous heat pump assisted distillation using an external working fluid can greatly reduce the energy used in a distillation process. No control problems were encountered in the experiments.     

Experimental performance of ternary solutions in an absorption heat transformer

In this work, results from experiments with ternary solutions in an absorption heat transformer are presented. The experiments were performed under controlled conditions using water/lithium chloride/zinc chloride and water/calcium chloride/zinc chloride solutions as working pairs. The results showed that the gross temperature lift is increased with regard to the results obtained using binary solutions because the concentration of the solutions was enhanced. The water/lithium chloride/zinc chloride solution showed a generally better performance than the water/calcium chloride/zinc chloride mixture. The highest gross temperature lift for the former solution was 37·5°C for an absorber temperature of 96°C. This result compared favourably to that previously obtained for water/lithium bromide in the University of Salford. © 1998 John Wiley & Sons, Ltd.     

Performance of a high temperature hydrate solid/gas sorption heat pump used as topping cycle for cascaded sorption chillers

The purpose of this paper is to study and analyse the experimental performances of a solid/gas sorption heat pump using a new working pair such as MnCl₂ hydrate reacting reversibly with water. The aim of this heat pump device is to produce heat at a temperature level suitable for industrial purposes (typically 160 °C), from waste heat at 90 °C or from environment at 35 °C. Moreover, this kind of process can be efficiently used as a high-temperature topping cycle to drive by means of efficient heat pipes a lower temperature double effect absorption cycle in order to increase the cooling performances by achieving a quadri-effect cascaded chiller. This paper presents the experimental results of the water/hydrate reaction topping cycle and demonstrates the feasibility of a cascading cooling device with high cooling performance: a COP of 1.35 should effectively be attainable.     

Thermodynamic and heat-hydrogen transfer analyses of novel multistage hydrogen-alloy sorption heat pump

The requirement of simultaneous heating and cooling effects at different zones of a building demands for the development of an energy-efficient air-conditioning system for heating and cooling outputs. In order to fulfil this requirement, a novel multistage hydrogen-alloy–based sorption heat pump (H-A SHP) for space air-conditioning is proposed in the present work. The proposed system produces multiple cooling and heating outputs at 20°C and 45°C, respectively, with single heat input at 160°C. A set of MmNi₅, La_0.8Ce_0.2Ni₅, MmNi_4.4Al_0.6, and LaNi_4.6Al_0.4 metal hydrides (MHs) is chosen to operate at the above-mentioned temperature range with hydrogen as working fluid. The proposed system can completely eliminate the requirement of conventional compressor because it operates using waste heat, and useful outputs (cooling-heating) result from reaction enthalpies (MH + H₂ interaction). The thermodynamic and heat-hydrogen transfer analyses of H-A SHP are carried out through finite volume approach, in which heat and mass transfer equations are solved to foresee the variations in MH bed temperature, hydrogen concentration, and heat interactions during cycle operation as well as the amount of cooling and heating outputs delivered to the air-conditioning space. The numerical code is validated with experimental pressure-concentration isotherms (PCIs) measured through Sievert's apparatus. The maximum heat exchange during the cooling and heating processes, at a particular instant of time, is observed as 257.5 and 286.1 W with cooling temperature of 10°C and heating temperature of 53°C, respectively. The thermodynamic performance is estimated as 178.5 kJ of cooling effect, 265.5 kJ of upgraded heat with overall coefficient of performance (COP) of 6.8, and overall specific alloy output of 396.5 W/0.34 kg of alloy.     

Heat Transfer and Thermodynamic Performance of LiBr/H2O Absorption Heat Transformer with Vapor Absorption Inside Vertical Spiral Tubes

In this paper, an absorption heat transformer (AHT) with falling film of aqueous LiBr solution inside vertical spiral tubes is installed and tested. The variations of coefficient of performance (COP), thermal efficiency (E_th ), and the heat transfer coefficient of the absorber at different falling film flow rates, hot water flow rates, and operating temperatures are investigated experimentally. The results demonstrated that the coefficient of performance and thermal efficiency of the system decrease with the increase in the flow rate of LiBr solution, and the influence of flow rate of hot water on COP and E_th is insignificant. The available COP in the experiments is higher than 0.4. The heat and mass transfer coefficients of the absorber increase with the increase of the flow rate of LiBr solution, up to 400W/m²/K and 0.013 kg/m²/s (temperature of waste heat is 90°C). The heat transfer coefficient of the absorber increases with the increase of the temperature of waste heat, and decreases with the increase of the cooling water temperature. Meanwhile, the computer code ABSIM (Absorption Simulation) is used to simulate the AHT systems, and the simulated results are compared with the experimental data.     

Dynamic characteristics of a novel adsorption refrigerator with compound mass‐heat recovery

A three‐effect heat pipe (heat pipe heating, heat pipe cooling and heat pipe heat recovery) adsorption refrigeration system using compound adsorbent (calcium chloride and activated carbon) was designed. The dynamic characteristics of mass and heat pipe heat recovery were studied. The results show that mass recovery and heat pipe heat recovery can improve (specific cooling power) SCP and (coefficient of performance) COP greatly. The averaged SCP of the cycle with mass recovery and the cycle without mass recovery is 502.9 W/kg and 436.7 W/kg at about 30 °C of cooling water temperature and ?15 °C of evaporating temperature. The corresponding COP is 0.27 and 0.24 respectively. Copyright © 2011 John Wiley & Sons, Ltd.     

The potential for heat pumps in drying and dehumidification systems II: An experimental assessment of the heat pump characteristics of a heat pump dehumidification system using R114

An experimental heat pump dehumidifier is described. Actual coefficients of performance (COP)_A are plotted against the gross temperature lift (T_CO - T_EV) for various bypass ratios and air velocities. Interpolated values of (COP)_A for a specified temperature lift were obtained by fitting each set for various dry bulb temperatures of air leaving the humidifier using a linear equation. These values of (COP)_A are plotted against the linear velocity of the air stream approaching the evaporator at different dry bulb temperatures. The curves show a maximum of (COP)_A at approach velocities in the region of 1·6 ms^?1.