Study of integrated metal hydrides heat pump and cascade utilization of liquefied natural gas cold energy recovery system

The traditional cold energy utilization of the liquefied natural gas system needs a higher temperature heat source to improve exergy efficiency, which barricades the application of the common low quality thermal energy. The adoption of a metal hydride heat pump system powered by low quality energy could provide the necessary high temperature heat and reduce the overall energy consumption. Thus, an LNG cold energy recovery system integrating metal hydride heat pump was proposed, and the exergy analysis method was applied to study the case. The performance of the proposed integration system was evaluated. Moreover, some key factors were also theoretically investigated about their influences on the system performance. According to the results of the analysis, some optimization directions of the integrated system were also pointed out.     

Evaluation of exergy and energy efficiencies of photothermal solar radiation conversion

In this paper, a new thermodynamic model for photothermal solar radiation conversion into mechanical through a heat engines is proposed. The developed equations allow for the energy and exergy contents of solar radiation to be found, as well as the energy and exergy efficiencies corresponding to concentration type solar-thermal heat engines operating under a range of conditions. The calculation method remains accurate to other published models when their assumed conditions are imposed to the newly developed model. The heat flux absorbed by the receiver (which is assumed to be a grey body and is placed in the focal point of the solar concentrator) depends on the hemispherical absorptivity and emissivity, concentration ratio and receiver temperature. The model is used to conduct a parametric study regarding the energy and exergy efficiencies of the system for assessing its performance. The use of a selective grey body receiver (having a reduced emissivity and a high absorptivity) for enhancing the conversion efficiency is also studied. If the absorptivity approaches one and the emissivity is low enough the photothermal conversion efficiency becomes superior to the known black body receiver limit of 0.853. It is found that in the limit of receiver emissivity tending to zero and absorptivity lending to one, the present model gives the exergy content of solar radiation because the work generated reaches its maximum. In this situation the energy efficiency approaches the exergy efficiency at 1-ITTIN0/TINS where T_S and T₀ are the sun and ambient temperatures, respectively. The influence of the ambient temperature on the exergy and energy efficiencies becomes apparent, with effects of up to 15%, particularly for high absorptivity and low emissivity. The heat transfer conductances at sink and source of the heat engine have a considerable impact on the efficiency of solar energy conversion. The present model is developed in line with actual power system operations for better practical acceptance. In addition, some irreversibility parameters (absorptivity, emissivity, heat transfer conductivity, etc.) are studied and discussed to evaluate the possible photothermal solar radiation conversion systems and assess their energy and exergy efficiencies.     

Exergy and energy analysis of hydrogen production by the degradation of sodium borohydride in the presence of novel Ru based catalyst

Chemically possible hydrogen storage material of the most important and widely used metal hydride compound is sodium borohydride. A current research issue is the development of systems that allow regulated hydrogen generation employing appropriate catalysts for the creation of hydrogen gas from the hydrolysis of sodium borohydride (NaBH₄). In this study, controlled hydrogen production from alkali solution of NaBH₄ was aimed. On hydrogen generation rate (HGR), the effects of NaBH₄ and alkaline solution concentrations, catalyst quantity, and temperature were examined. Considering the energy and exergy analysis, which have gained importance in the international arena in recent years, in this study, the exergy energy analysis of the environment in which the sodium borohydride solution is located was performed. The best one of the Ru-based catalysts synthesized in different atomic ratios was determined as 90:10 RuCr. The surface characterization of the obtained catalyst was carried out using scanning electron microscope (SEM-EDX) and X-ray diffractometer (XRD). In the kinetic calculations, the activation energy was calculated as 35,024 kj/mol and the reaction ordered n was found to be 0,65. By applying exergy and energy analysis to the hydrogen production step, the energy and exergy efficiency of the system were found to be 24% and 7%, respectively.     

Performance evaluation of solar air heater having expanded metal mesh as artificial roughness on absorber plate

A parametric study of artificial roughness geometry of expanded metal mesh type in the absorber plate of solar air heater duct has been carried out and compared with smooth duct. The performance evaluation in terms of energy augmentation ratio (EAR), effective energy augmentation ratio (EEAR) and exergy augmentation ratio (EXAR) has been carried out for various values of Reynolds number (Re) and roughness parameters of expanded metal mesh roughness geometry in the absorber plate of solar air heater duct. It is found that the augmentation ratios decrease at faster rate with Re in the order of EAR, EEAR and EXAR. It is also found that augmentation ratios increase with increase in duct depth and intensity of solar radiation. The artificially roughened solar air heater duct performs better as per EAR or heat energy gain criteria for any values of Re and roughness parameters of expanded metal mesh. The EAR is high for the parameters of expanded metal mesh type roughness geometry which create more turbulence, however the pump work required for flow of air will also increase. The EXAR is a more suitable criterion to incorporate the quality of heat collected and pump work required. The EXAR is more for higher duct depth and low Re range. Based on EXAR the suitable design parameters of expanded metal mesh roughness geometry are determined.     

Energetic and exergetic performance evaluation of natural circulation solar water heating systems

This study deals with the energy and exergy analyses of natural circulation solar water heating (SWH) systems. The system comprises of a single glazed flat plate solar collector (FPSC) with absorber plate of 2 m², and a separate insulated well-mixed vertical water storage tank (WST) of 125 liters. The variable heat transfer coefficients, water inlet and outlet temperatures of the FPSC; and temperature of heated water stored in the WST are predicted theoretically for each interval. The daily energy and exergy efficiency of the FPSC, WST and SWH system are estimated to be about 39 and 4.36%, 67 and 38.55%, 27 and 1.01%, respectively. It is found that the water inlet temperature, optical efficiency and the solar radiation strongly influence the performance of the FPSC both energetically and exergetically. It is observed that change in the mass flow rate of water improves the exergy efficiency of the FPSC significantly. FPSC has been identified as a critical component of the system where exergy destruction of 308 W/m² takes place daily as compared to 24 W/m² in the WST against available solar exergy of about 663 W/m².     

Component exergy analysis of solar powered transcritical CO<Subscript>2</Subscript> rankine cycle system

In this paper,exergy analysis method is developed to assess a Rankine cycle system,by using supercritical CO2 as working fluid and powered by solar energy.The proposed system consists of evacuated solar collectors,throttling valve,high-temperature heat exchanger,low-temperature heat exchanger,and feed pump.The system is designed for utilize evacuated solar collectors to convert solar energy into mechanical energy and hence electricity.In order to investigate and estimate exergy performance of this system,the energy,entropy,exergy balances are developed for the components.The exergy destructions and exergy efficiency values of the system components are also determined.The results indicate that solar collector and high temperature heat exchanger which have low exergy efficiencies contribute the largest share to system irreversibility and should be the optimization design focus to improve system exergy effectiveness.Further,exergy analysis is a useful tool in this regard as it permits the performance of each process to be assessed and losses to be quantified.Exergy analysis results can be used in design,optimization,and improvement efforts.     

A comprehensive comparative energy and exergy analysis in solar based hydrogen production systems

In the presented paper, energy and exergy analysis is performed for thermochemical hydrogen (H₂) production facility based on solar power. Thermal power used in thermochemical cycles and electricity production is obtained from concentrated solar power systems. In order to investigate the effect of thermochemical cycles on hydrogen production, three different cycles which are low temperature Mg–Cl, H₂SO₄ and UT-3 cycles are compared. Reheat-regenerative Rankine and recompression S–CO₂ Brayton power cycles are considered to supply electricity needed in the Mg–Cl and H₂SO₄ thermochemical cycles. Furthermore, the effects of instant solar radiation and concentration ratio on the system performance are investigated. The integration of S–CO₂ Brayton power cycle instead of reheat-regenerative Rankine enhances the system performance. The maximum exergy efficiency which is obtained in the system with Mg–Cl thermochemical and recompression S–CO₂ Brayton power cycles is 27%. Although the energy and exergy efficiencies decrease with the increase of the solar radiation, they increase with the increase of the concentration ratio. The highest exergy destruction occurred in the solar energy unit.     

Energy and Exergy Analysis on Drying of Banana Using Indirect Type Natural Convection Solar Dryer

Abstract

Energy and exergy analysis, in the thermodynamics, is an important tool used to predict the performance of drying system. In this work, energy and exergy analyses are made during the drying process of banana using an indirect type passive solar dryer. Solar flat plate air collector is used to heat the air. Banana gets sufficiently dried at temperatures between 28 and 82?°C. Solar radiation is measured and it is ranged from 335 to 1210?W/m². Using the first law of thermodynamics, energy analysis was carried out to estimate the amounts of energy gained from solar air heater. Also, applying the second law of thermodynamics, exergy analysis was carried out to determine exergy losses during the drying process. The exergy losses varied from 3.36 to 25.21?kJ/kg. In particular, the exergy efficiency values vary from 7.4 to 45.32%.     

Thermal management of metal hydride hydrogen storage using phase change materials for standalone solar hydrogen systems: An energy/exergy investigation

This paper reports on an energy/exergy analysis of a standalone solar-hydrogen system with a metal hydride (MH) system thermally managed using a phase change material (PCM). This is a self-contained thermal management arrangement that stores the heat released from the MH unit, when it is being charged and transfers it back to the MH while discharging hydrogen. The first and second laws of thermodynamics were used to develop a mathematical model in MATLAB to simulate this system and quality its performance from the energy and exergy viewpoints. The model was then applied on a passive standalone house, with ～3.8 MWh/year electricity demand, located in southeast Australia. The exergy efficiencies of the solar PV, electrolyser, fuel cell and the whole solar hydrogen system were found to be 6.5%, 88%, 50.6%, and 3.74%, respectively. The paper also provides the detailed entropy generation and exergy analysis on the MH hydrogen storage unit together with its PCM-based thermal management arrangement. The results show that the annual entropy generation, exergy destruction and exergy efficiency of the MH hydrogen storage unit were 173 Wh/K, 51.5 kWh, and 98.8%, respectively.     

Effect of irreversibilities on performance of an absorption heat transformer used to increase solar pond’s temperature

Absorption thermal systems are attractive for using waste heat energy from industrial processes and renewable energy such as geothermal energy, solar energy, etc. The Absorption Heat Transformer (AHT) is a promising system for recovering low-level waste heat. The thermal processes in the absorption system release a large amount of heat to the environment. This heat is evolved considerably at temperature, the ambient temperature results in a major irreversible loss in the absorption system components. Exergy analysis emphasises that both losses and irreversibility have an impact on system performance. Therefore, evaluating of the AHT in exergy basis is a much more suitable approach. In this study, a mathematical model of AHTs operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds. A heat source at temperatures not higher than 100 °C was used to simulate the heat input to an AHT from a solar pond. In this paper, exergy analysis of the AHT were performed and effects of exergy losses of the system components on performance of the AHT used to increase solar pond’s temperature were investigated. The maximum upgrading of solar pond’s temperature by the AHT, is obtained at 51.5 °C and gross temperature lift at 93.5 °C with coefficients of performance of about 0.4. The maximum temperature of the useful heat produced by the AHT was ˜150 °C. As a result, determining of exergy losses for the system components show that the absorber and the generator need to be improved thermally. If the exergy losses are reduced, use of the AHT to increase the temperature of the heat used from solar ponds will be more feasable.     

Exergetic performance evaluation and parametric studies of solar air heater

The present study aims to establish the optimal performance parameters for the maximum exergy delivery during the collection of solar energy in a flat-plate solar air heater. The procedure to determine optimum aspect ratio (length to width ratio of the absorber plate) and optimum duct depth (the distance between the absorber and the bottom plates) for maximum exergy delivery has been developed. It is known that heat energy gain and blower work increase monotonically with mass flow rate, while the temperature of air decreases; therefore, it is desirable to incorporate the quality of heat energy collected and the blower work. First it is proved analytically that the optimum exergy output, neglecting blower work, and the corresponding mass flow rate depend on the inlet temperature of air. The energy and exergy output rates of the solar air heater were evaluated for various values of collector aspect ratio (AR) of the collector, mass flow rate per unit area of the collector plate (G) and solar air heater duct depth (H). Results have been presented to discuss the effects of G, AR and H on the energy and exergy output rates of the solar air heater. The energy output rate increases with G and AR, and decreases with H and the inlet temperature of air. The exergy-based evaluation criterion shows that performance is not a monotonically increasing function of G and AR, and a decreasing function of H and inlet temperature of air. Based on the exergy output rate, it is found that there must be an optimum inlet temperature of air and a corresponding optimum G for any value of AR and H. For values of G lesser than optimal corresponding to inlet temperature of air equals to ambient, higher exergy output rate is achieved for the low value of duct depth and high AR in the range of parameters investigated. If G is high, for an application requiring less temperature increase, then either low AR or high H would give higher exergy output rate.     

Exergy Analysis of Solar Still with Sand Heat Energy Storage

This paper studies the experimental and exergy analysis of solar still with the sand heat energy storage system. The cumulative yield from solar still with and without energy storage material is found to be 3.3 and 1.89 kg/m², respectively for 8-h operation. Results show that the exergy efficiency of the system is higher with the least water depth of 0.02 m (m_w = 20 kg). Competitive analysis of second law efficiency shows that the exergy efficiency improves the system by 30% than conventional single slope solar still without any heat storage. The maximum exergy efficiency with energy storage material is found as 13.2% and it is less than the conventional solar still without any material inside the basin.     

Preliminary investigation of a transcritical CO2 heat pump driven by a solar‐powered CO2 Rankine cycle

In this paper, a transcritical carbon dioxide heat pump system driven by solar‐owered CO₂ Rankine cycle is proposed for simultaneous heating and cooling applications. Based on the first and second laws of thermodynamics, a theoretical analysis on the performance characteristic is carried out for this solar‐powered heat pump cycle using CO₂ as working fluid. Further, the effects of the governing parameters on the performance such as coefficient of performance (COP) and the system exergy destruction rate are investigated numerically. With the simulation results, it is found that, the cooling COP for the transcritical CO₂ heat pump syatem is somewhat above 0.3 and the heating COP is above 0.9. It is also concluded that, the performance of the combined transcritical CO₂ heat pump system can be significantly improved based on the optimized governing parameters, such as solar radiation, solar collector efficient area, the heat transfer area and the inlet water temperature of heat exchange components, and the CO₂ flow rate of two sub‐cycles. Where, the cooling capacity, heating capacity, and exergy destruction rate are found to increase with solar radiation, but the COPs of combined system are decreased with it. Furthermore, in terms of improvement in COPs and reduction in system exergy destruction at the same time, it is more effective to employ a large heat transfer area of heat exchange components in the combined heat pump system. Copyright © 2012 John Wiley & Sons, Ltd.     

小型太阳能热泵地板供暖系统的优化研究

建立了太阳能热泵地板供暖系统的能量分析、可用能分析数学模型,模拟了上海供暖期的气候条件,给出了系统各部件的可用能损失情况。着重从太阳能集热器并联的组数出发对系统进行了优化研究,并给出了系统供暖性能系数和可用能效率,为该系统的设计及应用提供参考。     

Numerical evaluation of the mixed convective heat transfer in a double-pane window integrated with see-through a-Si PV cells with low-e coatings

This study presents a two-dimensional numerical analysis for thermal control strategies on potential energy savings in a double-pane window integrated with see-through a-Si photovoltaic (PV) cells with low-emittance (low-e) coatings. Both heat transmission through the air gap by combined convection and radiation, and air flow patterns within the cavity of the window were considered. The convection-conducting mechanisms in the cavity of the double-pane window have been closely investigated in this paper. Based on numerical predictions, the effect of Rayleigh number on airflow patterns was investigated for low Rayleigh numbers in the range of 10³ ? Ra ? 10⁵. The effect of the low-e coatings on the glazing U-value was also explored in this paper. It was found that a large quantity of heat transfer by radiation could be reduced. This novel glazing system could help engineers’ design in more advanced window systems with building-integrated photovoltaic (BIPV) applications in modern buildings.     

Exergetic analysis and optimization of a solar-powered reformed methanol fuel cell micro-powerplant

The present study proposes a combination of solar-powered components (two heaters, an evaporator, and a steam reformer) with a proton exchange membrane fuel cell to form a powerplant that converts methanol to electricity. The solar radiation heats up the mass flows of methanol-water mixture and air and sustains the endothermic methanol steam reformer at a sufficient reaction temperature (typically between 220 and 300 °C). In order to compare the different types of energy (thermal, chemical, and electrical), an exergetic analysis is applied to the entire system, considering only the useful part of energy that can be converted to work. The effect of the solar radiation intensity and of different operational and geometrical parameters like the total inlet flow rate of methanol-water mixture, the size of the fuel cell, and the cell voltage on the performance of the entire system is investigated. The total exergetic efficiency comparing the electrical power output with the exergy input in form of chemical and solar exergy reaches values of up to 35%, while the exergetic efficiency only accounting for the conversion of chemical fuel to electricity (and neglecting the ‘cost-free’ solar input) is increased up to 59%. At the same time, an electrical power density per irradiated area of more than 920 W m⁻² is obtained for a solar heat flux of 1000 W m⁻².     

Simulation of high temperature thermal energy storage system based on coupled metal hydrides for solar driven steam power plants

Concentrating solar power plants can achieve low cost and efficient renewable electricity production if equipped with adequate thermal energy storage systems. Metal hydride based thermal energy storage systems are appealing candidates due to their demonstrated potential for very high volumetric energy densities, high exergetic efficiencies, and low costs. The feasibility and performance of a thermal energy storage system based on NaMgH₂F hydride paired with TiCr_1.6Mn_0.2 is examined, discussing its integration with a solar-driven ultra-supercritical steam power plant. The simulated storage system is based on a laboratory-scale experimental apparatus. It is analyzed using a detailed transport model accounting for the thermochemical hydrogen absorption and desorption reactions, including kinetics expressions adequate for the current metal hydride system. The results show that the proposed metal hydride pair can suitably be integrated with a high temperature steam power plant. The thermal energy storage system achieves output energy densities of 226 kWh/m³, 9 times the DOE SunShot target, with moderate temperature and pressure swings. In addition, simulations indicate that there is significant scope for performance improvement via heat-transfer enhancement strategies.     

Exergetic comparison of wind energy storage with ice making cycle versus mini-hydrogen economy cycle in off-grid district cooling

For the feasible and continuous utilization of intermittent wind and solar energy sources for electricity generation in district energy systems in hot-climates, where cooling loads are dominant, ice storage may be an option. In this study, the rationality of the ice storage system for wind energy was investigated using the Rational Exergy Management Model, REMM for two options and compared with a base scenario, which comprises a wind turbine system, grid connection, conventional chillers, and the district cooling system. The main objective is to minimize exergy destructions and thus to improve the exergy performance. The first ice storage option is composed of wind turbines, deep chillers for ice making, ice storage tanks, and the district cooling system. The second option is similar to the first option but it also includes a ground-source heat pump upstream the deep chiller. These options were also compared against a mini-hydrogen economy (District size) alternative, which encompasses a hydrogen-water cycle with excess renewable energy-powered PEM electrolysis unit, hydrogen tank, fuel cell, absorption chiller, gas compression chiller, and the district cooling system. These two options and the hydrogen-water cycle alternative were compared in terms of their REMM efficiency, First and Second-law efficiencies, and the primary energy ratio. A new Sustainability Performance Index, namely SPI was also defined. SPI is the product of the REMM efficiency, First-Law Efficiency, and the load coincidence factor, CF of wind energy. In order to establish a realistic application background for the comparisons, first a nearly-net-zero exergy farmland (nZEXF) utilizing biogas, cogeneration, solar photovoltaics, heat, absorption cycle, ground-source heat pump, Organic Rankine Cycle, and wind turbines was introduced as a model. The primary objective of this study is to determine the best option with the least avoidable CO₂ emissions responsibility of the systems considered in terms of the REMM efficiency in thermal or hydrogen storage systems. Results have been compared in terms of SPI with the base scenario and it has been concluded that the second option (SPI = 0.88) is better than the first option (SPI = 0.38). However, hydrogen storage is an even better alternative with an SPI value of 1.06. These figures according to REMM with the coincidence factor being considered, mean that the avoidable CO₂ emissions may be reduced by up to 54% compared to the base case. Hydrogen cycle option may also be used with the same effectiveness in district heating, while ice storage options are limited to district cooling only. This paper provides the relevant theory, shows the fundamental calculations about the option rankings based on a unit cooling load, makes recommendations for future district energy systems, and refers to a conceptual hydrogen economy driven city.     

Performance assessment of a magnesium chloride saturated solar pond

This paper deals with the experimental investigation of a magnesium chloride saturated solar pond and its performance evaluation through energy and exergy efficiencies. The solar pond system is filled with magnesium chloride containing water to form layers with varying densities. A solar pond generally consists of three zones, and the densities of these zones increase from the top convective zone to the bottom storage zone. The incoming solar radiation is absorbed by salty water (with magnesium chloride) which eventually increases the temperature of the storage zone. The high-temperature salty water at the bottom of the solar pond remains much denser than the salty water in the upper layers. Thus, the convective heat losses are prevented by gradient layers. The experimental temperature changes of the solar pond are measured by using thermocouples from August to November. The densities of the layers are also measured and analysed by taking samples from at the same point of the temperature sensors. The energy and exergy content distributions are determined for the heat storage zone and the non-convective zone. The maximum exergy destructions and losses appear to be 79.05 MJ for the heat storage zone and 175.01 MJ for the non-convective zone in August. The energy and exergy efficiencies of the solar pond are defined as a function of solar radiation and temperatures. As a result, the maximum energy and exergy efficiencies are found to be 27.41% and 26.04% for the heat storage zone, 19.71% and 17.45% for the non-convective zone in August, respectively.     

Selection of metal hydrides-based thermal energy storage: Energy storage efficiency and density targets

Thermo-chemical energy storage based on metal hydrides has gained tremendous interest in solar heat storage applications such as concentrated solar power systems (CSP) and parabolic troughs. In such systems, two metal hydride beds are connected and operating in an alternative way as energy storage or hydrogen storage. However, the selection of metal hydrides is essential for a smooth operation of these CSP systems in terms of energy storage efficiency and density. In this study, thermal energy storage systems using metal hydrides are modeled and analyzed in detail using first law of thermodynamics. For these purpose, four conventional metal hydrides are selected namely LaNi₅, Mg, Mg₂Ni and Mg₂FeH₆. The comparison of performance is made in terms of volumetric energy storage and energy storage efficiency. The effects of operating conditions (temperature, hydrogen pressure and heat transfer fluid mass flow rates) and reactor design on the aforementioned performance metrics are studied and discussed in detail. The preliminary results showed that Mg-based hydrides store energy ranging from 1.3 to 2.4 GJ m^?3 while the energy storage can be as low as 30% due to their slow intrinsic kinetics. On the other hand, coupling Mg-based hydrides with LaNi₅ allow us to recover heat at a useful temperature above 330 K with low energy density ca.500 MJ m^?3 provided suitable operating conditions are selected. The results of this study will be helpful to screen out all potentially viable hydrides materials for heat storage applications.