Simulation of thermally‐enhanced combustion in a porous medium burner

Premixed combustion in a porous medium burner is investigated numerically. A two‐dimensional steady, laminar flow model is used. A single‐step reaction of methane is used for the chemical kinetic model. The model also includes thermal radiation transport of the porous media that is placed inside the burner. The radiative transport equation is solved by using the discrete ordinate method. The results show that, for each equivalence ratio, the flame can be stabilized at various axial locations with different flame speeds. The flame temperature increases with the equivalence ratio and flame speed. Furthermore, the energy release rates are much higher than that of a free flame for the same equivalence ratio as a result of higher flame speed. © 2005 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(1): 75–88, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20088     

Design and development of a SPMB (self-aspirating, porous medium burner) with a submerged flame

This work reports design and development of a SPMB (self-aspirating porous medium burner) for replacing the self-aspirating, CB (conventional gaseous fuel, free flame burners), which are widely used in heating process of SMEs (small and medium scale enterprises) in Thailand but they have relatively low thermal efficiency of about 30 percent. Design of the SPMB relies on the same important characteristics of the CB, i.e. using the same mixing tube and the same fuel nozzle. The SPMB is formed by a packed bed of alumina spheres. The pressure drop across the packed bed, diameter of particles and a combustion chamber diameter are estimated by Ergun’s equation in combination with Pe (Peclet number). The SPMB yields a submerged flame with an intense thermal radiation emitted downstream. An output radiation efficiency as high as 23 percent can be achieved at relatively high turn-down ratio of 2.65 and firing rate ranging from 23 to 61 kW. The SPMB shows a more complete combustion with relatively low CO emission of less than 200 ppm and acceptably high NO_x emission of less than 98 ppm as compared with the CB throughout the range of firing rate studied, suggesting the possibility of the SPMB in replacing the CB.     

Syngas production from polyethylene and biogas in porous media combustion

The production of syngas from biogas (surrogate of CH₄/CO₂: 55/45 v/v) and polyethylene in a porous media combustion reactor is experimentally studied. The employed setup is novel and has not been studied before. A semi-continuous feed of solid fuel and a constant filtration velocity of the gaseous reactants of 17 cm/s were considered. Temperature, velocity of propagation, and composition of the syngas produced in the combustion waves were registered in a tubular reactor packed with a ceramic foam porous medium and two solid fuel inlets. In the first part of the study, a baseline determined by the filtration combustion of a biogas/air mixture through the ceramic foam at the equivalence ratio ($\mathrm{?}$) range $0.7\le \mathrm{?}\le 1.6$, having transient (upstream and downstream) and stationary combustion wave propagation regimes, is established. In the second part of this work, portions of the ceramic foam in two different separated zones are extracted, leaving space for the semi-continuous supply of polyethylene. In this second part the biogas-air combustion was performed only for $\mathrm{?}=0.8$ and $\mathrm{?}=1.6$. Although the combustion temperature decreased by the presence of polyethylene, it was found that the syngas (both H₂ and CO) yield was larger than for the baseline. The highest degrees of conversion to hydrogen and carbon monoxide was reached under the presence of polyethylene, having 45% and 67% for $\mathrm{?}=0.8$, and 45% and 60% for $\mathrm{?}=1.6$, respectively. These results are very promising and they demonstrate the capabilities of the presented methodology and experimental setup, which should encourage future attempts of applications of the technology.     

Laminar flow with combustion in inert porous media

This work presents one-dimensional numerical results for combustion of an air/methane mixture in inert porous media using laminar and radiation models. Comparisons with experimental data are reported. The burner is composed by a preheating section followed by a combustion region. Macroscopic equations for mass, momentum and energy are obtained based on the volume average concept. Distinct energy equations are considered for the porous burner and the flowing gas. The numerical technique employed for discretizing the governing equations was the control volume method with a boundary-fitted non-orthogonal coordinate system. The SIMPLE algorithm was used to relax the entire equation set. Inlet velocity, excess air, porosity and solid-to-fluid thermal conductivity ratio were varied in order to investigate their effect on temperature profiles. Results indicate that higher inlet velocities result in higher gas temperatures, following a similar trend observed in the experimental data used for comparisons. Burning of mixtures close to the stoichiometric conditions also increased temperatures, as expected. Increasing the thermal conductivity of the preheating section reduced peak temperature in the combustion region. The use of porous material with very high thermal conductivity on the combustion region did not affect significantly temperature levels in the combustion section.     

Hydrogen production in ultrarich combustion of hydrocarbon fuels in porous media

Rich and ultrarich combustion of methane, ethane, and propane inside inert porous media is studied experimentally and numerically to examine the suitability of the concept for hydrogen production. Temperature, velocities, and chemical products of the combustion waves were recorded experimentally at a range of equivalence ratios from stoichiometry (φ = 1.0) to φ = 2.5, for a filtration velocity of 12 cm/s. Two-temperature numerical model based on comprehensive heat transfer and chemical mechanisms is found to be in a good qualitative agreement with experimental data. Partial oxidation products of methane, ethane, and propane (H₂, CO, and C₂ hydrocarbons) are dominant for ultrarich superadiabatic combustion. The maximum hydrogen yield is close to 50% for all fuels, and carbon monoxide yield is close to 80%.     

Numerical study of transient heat transfer in semitransparent porous medium

Transient solutions were obtained for heat transfer through a semitransparent porous medium placed in a flow passage and submitted to incident radiation. The one-dimensional physical model takes into account, conduction, convection and radiation simultaneously. The porous medium is assumed to be homogenous continuum, which absorbs, emits and scatters thermal radiation. A fully implicit time-marching algorithm was used to solve the nonlinear coupled energy equations for gas and porous medium numerically. The present study utilizes the differential–discrete–ordinate (DDO) method to account for the radiation contribution. The effects of the Reynolds number, optical depth, anisotropic scattering, conduction–radiation parameter and scattering albedo on temperatures and fluxes profiles are investigated.     

Multimode heat transfer in cyclic flow reversal combustion in a porous medium

Experimental and numerical studies of combustion and multimode heat transfer in a porous medium, with and without a cyclic flow reversal of a mixture through a porous medium, were performed. Parametric studies were done in order to understand combustion characteristics such as maximum flame temperature and radiative heat flux using a one‐ dimensional conduction, convection, radiation and premixed flame model. The porous medium was assumed to emit and absorb radiant energy, while scattering is ignored. Non‐local thermodynamic equilibrium between the solid an d gas is taken into account by introducing separate energy equations for the gas and the solid phase. As a prelimina ry study, the combustion regime was described by a one‐step global mechanism with an internal heat source uniformly dist ributed along the reaction zone. The effects of the flame position, cyclic flow reversal, period of the cyclic flow rever sal, the optical thickness and the flow velocity on the burner performance were clarified by a rigorous radiation analysis. Th e model was validated by comparing the theoretical results with the experiments. It was shown that, for maximizing the fl ame temperature and the net radiative heat flux feedback, the flame should be stabilized near the centre of the po rous medium with a cyclic flow reversal, the period of which should be as small as possible. A high optical thickness prod uced a high flame temperature and a high net radiative feedback. Also, a high flow velocity at low period of the cyclic f low reversal of mixture yielded a high value of both the flame temperature and the net radiative feedback. Thermal structure predictions in terms of the gas‐phase and the solid‐phase temperature distributions along the axis of the combustor show good agreement with the experimental ones. Copyright © 1999 John Wiley & Sons, Ltd.     

Porous media combustion for micro thermophotovoltaic system applications

The micro combustor is the key component of the micro TPV power generator. To obtain high power density and performance efficiency, it is important for a micro combustor to achieve a high and uniform temperature distribution along the wall. In this paper, we compare the performance of a micro cylindrical combustor with and without employing porous media. Results indicate that packing the combustor with porous media can significantly enhance the heat transfer between the high temperature combustion products and the emitter wall. The use of porous media increases the contact area thereby increasing the temperature along the wall of the micro combustor resulting in an increase in its radiation energy. The effects of some parameters on radiation energy of the micro combustor are also highlighted.     

Numerical simulation of turbulent combustion in porous materials

This paper presents one-dimensional simulations of combustion of an air/methane mixture in porous materials using a model that explicitly considers the intra-pore levels of turbulent kinetic energy. Transport equations are written in their time-and-volume-averaged form and a volume-based statistical turbulence model is applied to simulate turbulence generation due to the porous matrix. Four different thermo-mechanical models are compared, namely Laminar, Laminar with Radiation Transport, Turbulent, Turbulent with Radiation Transport. Combustion is modeled via a unique simple closure. Preliminary testing results indicate that a substantially different temperature distribution is obtained depending on the model used. In addition, for high excess air peak gas temperature is reduced and the flame front moves towards the exit of the burner. Also, increasing the inlet flow rate for stoichiometric mixture pushes the flame out of the porous material.     

The dynamics of in-situ combustion fronts in porous media

The sustained propagation of combustion fronts in porous media is a necessary condition for the success of in situ combustion for oil recovery. Compared to other recovery methods, in situ combustion involves the complexity of exothermic reactions and temperature-dependent chemical kinetics. In the presence of heat losses, the possibility of ignition and extinction also exists. In this paper, we address some of these issues by studying the properties of forward combustion fronts propagating at a constant velocity in the presence of heat losses. We extend the analytical method used in smoldering combustion [7], to derive expressions for temperature and concentration profiles and the velocity of the combustion front, under both adiabatic and non-adiabatic conditions. Heat losses are assumed to be relatively weak and they are expressed using two modes: 1) a convective type, using an overall heat transfer coefficient; and, 2) a conductive type, for heat transfer by transverse conduction to infinitely large surrounding formations. In their presence we derive multiple steady-state solutions with stable low and high temperature branches, and an unstable intermediate branch. Conditions for self-sustaining front propagation are investigated as a function of injection and reservoir properties. The extinction threshold is expressed in terms of the system properties. An explicit expression is also obtained for the effective heat transfer coefficient in terms of the reservoir thickness and the front propagation speed. This coefficient is not only dependent on the thermal properties of the porous medium but also on the front dynamics.     

Experimental study on Egyptian biomass combustion in circulating fluidized bed

The present study investigates the combustion of four kinds of biomass in a circulating fluidized bed. The combustion chamber is a steel cylinder with 145 mm inner diameter and 2 m height. Tests were conducted on wheat straw, sawdust-wood, cottonseed burs, and corncobs. Excess air was varied for each fuel. Temperature, heat flux and gas emissions were measured along the combustion chamber and at the chimney inlet. Results showed that sawdust-wood produces the highest values of CO emissions (about 3000 mg/Nm³). On the other hand, cottonseed burs produce the lowest values of CO emissions (about 250 mg/Nm³). The SO₂ emissions were very low in all tests (less than 20 mg/Nm³). The lowest emission value occurred at an excess air ratio (EA) of 1.24 except for cottonseed burs where it was 1.4.     

A universal model of opposed flow combustion of solid fuel over an inert porous medium

In this study, a universal model is developed to examine the behavior of combustion wave observed in porous solid matters (e.g., smoldering, self-propagating high-temperature synthesis (SHS), diesel particulate filter (DPF) regeneration process). Analytical expressions of the combustion characters of solid combustible (e.g., diesel particulate matters trapped in a DPF) deposited over an inert porous medium are obtained employing large activation energy asymptotic taking into account the sensible transport processes; namely, heat transfer between the porous medium and gas phases, radiation heat transfer from the porous medium, heat loss from the porous medium to the environment, mass transfer of oxygen from the gas stream to the surface of solid fuel and the effective diffusion in modeling the species diffusion. Then it has been validated that the present model is applicable and adaptable for predicting the characteristics of smoldering combustion and thus SHS process. As a result, the features of combustion wave of the present phenomena would be useful to other processes. From practical point of view and for deep understanding of the behavior of combustion wave of these processes, we investigate the effects of various physical parameters over a wide range of conditions. We observe that the moving speed of the reaction front increases with the increase of porosity of the porous medium, mass transfer coefficient and initial fuel mass fraction; while it decreases owing to the increase of heat transfer rate from the porous medium to the gas, heat loss to the environment and radiative heat transfer. Furthermore, the results reveal that extinction tends to occur due to lower porosity of the porous medium, higher radiative heat transfer from the porous medium, higher heat transfer rate from the porous medium to the gas and higher heat losses from the porous medium to the environment. Even the observed near-extinction behavior in reaction front speed versus heat loss diagram is found to be similar what we got in gaseous premixed flame propagating through the porous medium. An extinction limit diagram has been presented as a function of radiation-conduction parameter and the gas flow velocity. In addition to, the impact of radiation and the combined effect of the inclusion of Knudsen diffusion and tortuosity are demonstrated in terms of the spatial temperature and species profiles to examine how these two parameters modify the reaction front structure. Furthermore, the governing equations have been solved numerically and it is observed that asymptotic analysis gives a good agreement with the numerical solution.     

Catalytic combustion of hydrogen for residential heat supply application

Hydrogen can be converted to thermal energy by combustion or to electricity energy by fuel cells. Considering the stringent requirements for safety from fire hazards and elimination of pollutants, the flameless catalytic combustion of hydrogen is favorable over conventional flame combustion for residential heat supply application. This paper reported an industrial‐scale heat acquisition system based on hydrogen catalytic combustion. The 1 wt% Pt‐loaded glass fiber felts prepared by an impregnation process were used as the combustion catalyst, and a catalytic combustion burner with a capacity of 1 kW was designed. It was found that 100% hydrogen conversion rate could be obtained during the stable combustion stage, and the stable combustion could be achieved by adjusting hydrogen flow rate. The change in H₂/air ratio would influence the initial combustion stage but has little impact on the stable combustion stage. A heat efficiency of 80% for hot water supply was obtained based on the present catalytic hydrogen combustion burner. Copyright © 2016 John Wiley & Sons, Ltd.     

Impact of carbon tax on internal combustion engine size selection in a medium scale CHP system

Combined heat and power (CHP) systems due to their high efficiency compared to the conventional power generation systems have received considerable attention as they have less harmful impact on the environment. Recently, the serious concern with reducing the greenhouse gas emissions has focussed the attention on the possibility of a carbon tax in some countries. Here, we address the impact of such tax on the sizing and economics of a CHP system.     

Syngas production by non-catalytic reforming of biogas with steam addition under filtration combustion mode

Biogas conversion to syngas (mainly H₂ and CO) is considered an upgrade method that yields a fuel with a higher energy density. Studies on syngas production were conducted on an inert porous media reactor under a filtration combustion mode of biogas with steam addition, as a non-catalytic method for biogas valorization. The reactor was operated under a constant filtration velocity of 34.4 cm/s, equivalence ratio of 2.0, and biogas concentration of 60 vol% Natural Gas/40 vol% CO₂, while the steam to carbon ratio (S/C) was varied between 0.0 and 2.0. Total volumetric flow remained constant at 7 L/min. Combustion wave temperature and propagation rate, product gas composition, reactants conversion as well as H₂ and CO selectivity were measured as a function of S/C ratio. Chromatographic parameters, method validation and measurement uncertainty were developed and optimized. It was observed that S/C ratio of 2.0 gave optimal results under studied conditions for biogas conversion, leading to maximum concentrations of 10.34 vol% H₂, 9.98 vol% CO and highest thermal efficiency of 64.2% associated with a modified EROI of 46.3%, which considered energy consumption for steam supply. Conclusions indicated that the increment of the steam co-fed with the reactants favored the non-catalytic conversion of biogas and thus resulted in an effective fuel upgrading.     

Trends in modeling of porous media combustion

Porous media combustion (PMC) has interesting advantages compared with free flame combustion due to higher burning rates, increased power dynamic range, extension of the lean flammability limits, and low emissions of pollutants. Extensive experimental and numerical works were carried out and are still underway, to explore the feasibility of this interesting technology for practical applications. For this purpose, numerical modeling plays a crucial role in the design and development of promising PMC systems. This article provides an exhaustive review of the fundamental aspects and emerging trends in numerical modeling of gas combustion in porous media. The modeling works published to date are reviewed, classified according to their objectives and presented with general conclusions. Numerical modeling of liquid fuel combustion in porous media is excluded.     

Effect of heat loss on the syngas production by fuel-rich combustion in a divergent two-layer burner

The effect of heat loss on the syngas production from partial combustion of fuel-rich in a divergent two-layer burner is numerically studied using two-dimensional model with detailed kinetics GRI-Mech 1.2. Both the radiation and wall heat losses to the surrounding are considered in the computations. It is shown that two types heat losses have different effects on the syngas production. The radiation heat loss has significant effect on the syngas temperature and the syngas temperature is dropped as radiation heat loss is increased, but it has neglected effect on the reforming efficiency and methane conversion efficiency. The wall heat loss has a comprehensive effect on the syngas production. The wall heat loss not only reduces the conversion efficiency, but also significantly decreases the syngas temperature. The effect of wall heat loss becomes weak as the equivalence is increased. The reforming efficiency drops from 0.440 to 0.424 for equivalence ratio of 2 and mixture velocity of 0.17 m/s for the predictions between adiabatic wall and non-adiabatic conditions.     

Syngas production in hybrid filtration combustion

Rich and ultrarich combustion of butane inside porous media composed of aleatory wood pellets and alumina spheres is studied experimentally to evaluate the suitability of the concept for syngas production. Temperature, velocity, and chemical products of the combustion waves were recorded experimentally at a range of equivalence ratios from stoichiometry (φ = 1.0) to φ = 2.6. It is observed that hydrogen and carbon monoxide are dominant partial oxidation products for ultrarich hybrid combustion waves of butane and wood pellets. Syngas yield in hybrid filtration combustion is found to be essentially higher than for butane filtration combustion in an inert porous medium.     

Effects of viscous dissipation on forced convective heat transfer in a channel embedded in a power-law fluid saturated porous medium

The convective heat transfer analysis in a channel embedded in a power-law fluid saturated porous medium subject to uniform heat flux is presented and compared with a Newtonian fluid concerning the effects of viscous dissipation. Governing momentum and energy equations for non-Newtonian fluids which accounts for the viscous dissipation effects are solved numerically. The temperature profiles of the non-Newtonian fluids are found to relate closely to the velocity profiles. When viscous dissipation is taken account of, Nusselt numbers for non-Newtonian fluid are found to deviate more from Newtonian fluid with increasing Brinkman number for a certain range of the Darcy number.