Solar energy powered Rankine cycle using supercritical CO2

A solar energy powered Rankine cycle using supercritical CO₂ for combined production of electricity and thermal energy is proposed. The proposed system consists of evacuated solar collectors, power generating turbine, high-temperature heat recovery system, low-temperature heat recovery system, and feed pump. The system utilizes evacuated solar collectors to convert CO₂ into high-temperature supercritical state, used to drive a turbine and thereby produce mechanical energy and hence electricity. The system also recovers heat (high-temperature heat and low-temperature heat), which could be used for refrigeration, air conditioning, hot water supply, etc. in domestic or commercial buildings. An experimental prototype has been designed and constructed. The prototype system has been tested under typical summer conditions in Kyoto, Japan; It was found that CO₂ is efficiently converted into high-temperature supercritical state, of while electricity and hot water can be generated. The experimental results show that the solar energy powered Rankine cycle using CO₂ works stably in a trans-critical region. The estimated power generation efficiency is 0.25 and heat recovery efficiency is 0.65. This study shows the potential of the application of the solar-powered Rankine cycle using supercritical CO₂.     

Experimental study on the performance of solar Rankine system using supercritical CO2

An experimental study is carried out to investigate the performance of a solar Rankine system using supercritical CO₂ as a working fluid. The testing machine of the solar Rankine system consists of an evacuated solar collector, a pressure relief valve, heat exchangers and CO₂ feed pump, etc. The solar energy powered system can provide electricity output as well as heat supply/refrigeration, etc. The system performance is evaluated based on daily, monthly and yearly experiment data. The results obtained show that heat collection efficiency for the CO₂-based solar collector is measured at 65.0–70.0%. The power generation efficiency is found at 8.78–9.45%, which is higher than the value 8.20% of a solar cell. The result presents a potential future for the solar powered CO₂ Rankine system to be used as distributed energy supply system for buildings or others.     

Thermoeconomic optimization and exergy analysis of CO2/NH3 cascade refrigeration systems

In this paper, thermoeconomic optimization and exergy analysis are applied to a CO₂/NH₃ cascade refrigeration cycle. Cooling capacity, ambient temperature and cold space temperature are constraints of the optimization procedure. Four parameters including condensing temperature of ammonia, evaporating temperature of carbon dioxide, condensing temperature of carbon dioxide and temperature difference in the cascade condenser are chosen as decision variables. The objective function is the total annual cost of the system which includes costs of input exergy to the system and annualized capital cost of the system. Input exergy to the system is the electricity consumption of compressors and fans, and the capital cost includes purchase costs of components. Results show that, optimum values of decision variables may be found by trade-off between the input exergy cost and capital cost. Results of the exergy analysis for each of the system components in the optimum state are also given.     

Development of a new forced convection heat transfer correlation for CO2 in both heating and cooling modes at supercritical pressures

Experimental and numerical investigations on forced convection heat transfer of carbon dioxide at supercritical pressures in a prototypic printed circuit heat exchanger under both cooling and heating conditions have been performed in this present study. The experiment test section has nine semi-circular channels with a hydraulic diameter of 1.16 mm and a length of 0.5 m. Primary operational parameters include inlet pressure of 7.5–10 MPa, mass fluxes of 326 kg/m² s and 762 kg/m² s, inlet temperatures from 10 °C to 90 °C and the average heat flux was 30 kW/m². Beyond reproducing the regular experimental cases, numerical modeling also implemented higher heat fluxes of 60 kW/m² and 90 kW/m² in order to investigate the effect of heat flux. Good agreement was found between the experiments and FLUENT simulations using an SST k–w model with the near-wall region being completely resolved. The distinctive behavior of convection heat transfer at supercritical pressures between heating and cooling modes was systematically analyzed. A more physically reasonable property-averaging technique, Probability Density Function (PDF)-based time-averaged property, was developed to account for the effect of nonlinear dependency of properties on instantaneous local temperature. Furthermore, experimental and computational data were compared to empirical predictions by the Dittus–Boelter and Jackson correlations. The results showed that Dittus–Boelter correlation has better precision for the average value of the predicted heat transfer coefficient but cannot take account of the effect of heat flux. In contrast, the Jackson correlation, with property ratio correction terms to account for the distribution of the properties in the radial direction, could predict the distinction of heat transfer characteristics under heating and cooling conditions. However, it overestimates the average value of heat transfer coefficient in the whole range of the experiment conditions. Finally, a new correlation evaluated by PDF-based time-averaged properties for forced convection heat transfer of CO₂ in both heating and cooling mode at supercritical pressures was developed. Comparison of experimental and computational data with the prediction results by the new developed correlation reveals that it works quite well; i.e., more than 90% data in either heating or cooling mode with various heat fluxes are predicted within an accuracy of ±25%.     

跨临界CO2循环的研究进展及应用

近年来,跨临界CO_2循环制冷系统的研究发展非常迅速,已经成为国内外学者竞相研究的热点.综述了跨临界CO_2循环的国内外研究现状以及跨临界CO_2循环的商业应用研究和发展前景.经分析发现,跨临界CO_2循环系统的研究方向主要集中在提高循环性能、充注量对系统性能的影响和跨临界CO_2毛细管节流这三个方面.总结了跨临界CO_2循环应用于热泵热水器、汽车空调和超市冷冻冷藏领域的研究状况.总之,CO_2是一种非常具有发展潜力的制冷剂,在超临界CO_2制冷方面还需要进行更多的研究,逐步解决生产技术、运行效率、安全等方面的问题.     

Performance analysis and optimization of a new two-stage ejector-expansion transcritical CO2 refrigeration cycle

In this paper, a new two-stage configuration of ejector-expansion transcritical CO₂ (TRCC) refrigeration cycle is presented, which uses an internal heat exchanger and intercooler to enhance the performance of the new cycle. The theoretical analysis on the performance characteristics was carried out for the new cycle based on the first and second laws of thermodynamics. Based on the simulation results, it is found that, compared with the conventional two-stage transcritical CO₂ cycle, the COP and second law efficiency of the new two-stage cycle are about 12.5–21% higher than that of conventional two-stage cycle. It is also concluded that, the performance of the new two-stage transcritical CO₂ refrigeration can be significantly improved based on the presented new two-stage cycle. Hence the new two-stage refrigeration cycle is a promising refrigeration cycle from the thermodynamically and technical point of views. A regression analysis in terms of evaporator and gas cooler exit temperatures has been used, in order to develop mathematical expressions for maximum COP, optimum discharge and inter-stage pressures and entrainment ratio.     

Second law analysis of supercritical CO2 recompression Brayton cycle

In the present study, exergetic analyses and optimization of S-CO₂ recompression cycle have been performed to study the effect of operating parameters on the optimum pressure ratio, energetic and exergetic efficiencies and component irreversibilities. Effect of isentropic efficiency, recuperator effectiveness and component pressure drop on the second law efficiency is presented as well. Results show that the effect of minimum operating temperature on the optimum pressure ratio and cycle efficiencies is more predominant than the maximum operating temperature, whereas the effect of maximum cycle pressure is significant only for lower values and the optimum pressure ratio leads to near critical minimum cycle pressure. Result shows that the irreversibilities of heat exchangers are significantly more compared to that of turbo-machineries and the effect of operating parameters on irreversibility is also more significant for recuperators compared to turbo-machines. Effect of isentropic efficiency of turbine is more predominant (about 2.5 times) than that of compressors and effect of high temperature recuperator (HTR) effectiveness is more predominant (about double) than that of low temperature recuperator (LTR) on the second law efficiency. Effect of pressure drop in reactor is more significant compared to others components on the second law efficiency reduction.     

Performance of an oxy-fuel combustion CO2 power cycle including blade cooling

The guiding idea behind oxy-fuel combustion power cycles is guaranteeing a high level of performance as can be obtained by today's advanced power plants, together with CO₂ separation in conditions ready for transport and final disposal. In order to achieve all these goals, oxy-combustion – allowing CO₂ separation by simple cooling of the combustion products – is combined with large heat recovery and staged expansions/compressions, making use of new components, technology and materials upgraded from modern gas turbine engines. In order to provide realistic results, the power plant performance should include the effects of blade cooling. In the present work an advanced cooled expansion model has been included in the model of the MATIANT cycle in order to assess the effects of blade cooling on the cycle efficiency. The results show that the penalty in efficiency due to blade cooling using steam from the heat recovery boiler is about 1.4 percentage points, mainly due to the reheat of the steam, which, on the other hand, leads to an improvement in specific work of about 6%.     

Optimization of ejector-expansion transcritical CO2 heat pump cycle

Optimization studies along with optimum parameter correlations, using constant area mixing model are presented in this article for ejector-expansion transcritical CO₂ heat pump cycle with both conventional and modified layouts. Both the energetic and exergetic comparisons between valve, turbine and ejector-expansions-based transcritical CO₂ heat pump cycles are also studied for simultaneous cooling and heating applications. Performances for conventional layouts are presented by maximum COP, optimum discharge pressure and corresponding entrainment ratio and pressure lift ratio of ejector, whereas for modified layout by maximum COP, optimum discharge pressure and corresponding pressure lift ratio. The optimization for modified layout can be realized for certain entrainment ratio, evaporator and gas cooler exit temperature combinations. Considering the trade-off between the system energetic and exergetic performances, and cost associated with expansion devices, the ejector may be the promising alternative expansion device for transcritical CO₂ heat pump cycle.     

Thermodynamic analysis and optimization of novel ejector-expansion TRCC (transcritical CO2) cascade refrigeration cycles (Novel transcritical CO2 cycle)

In this paper, two new CO₂ cascade refrigeration cycles are proposed and analyzed. In both these cycles the top cycle is an ejector-expansion transcritical cycle and the bottom cycle is a sub-critical CO₂ cycle. In one of these proposed cycles the waste heat from the gas cooler is utilized to drive a supercritical CO₂ power cycle making the plant a combination of three cycles. Using the first and second laws of thermodynamics, theoretical analyses on the performance characteristics of the cycles are carried out. Also a parametric study is conducted to optimize the performance of each cycle under various operating conditions. The proposed cycles exhibit a reasonable value of COP (coefficient of performance) with a much less value of compressor discharge temperature, compared to the conventional cycles.     

Hydrogen storage in carbon fibers activated with supercritical CO2: Models and the importance of porosity

In this work we studied the adsorption of H₂ at 77 K and 0.0–0.12 MPa onto carbon fibers activated with supercritical CO₂ (ACFs) and with different burn-offs (10–53%). The highest amount of H₂ stored was 2.45 wt% in an ACF with a burn-off of 51% at 0.12 MPa. The measured isotherms were analyzed using an equilibrium model derived by analogy with a multiple-site Langmuir-type adsorption model. The different equilibria correspond to adsorption in pores of different sizes. The experimental results fitted a model with two different adsorption sites satisfactorily, allowing such sites to be related to the microporous structure of the ACFs. Thus, a high-energy adsorbent–adsorbate interaction site, associated with very small micropores, accessible only to very small molecules such as H₂, and another lower-energy site associated with larger pores can be proposed. The model also predicts the adsorption behavior under equilibrium conditions at higher pressures, allowing the maximum adsorption capacity of the ACFs to be determined. The results show that the ACFs adsorb most of the H₂ molecules at low equilibrium pressures, and that they become almost saturated at pressures around 1.0 MPa. The maximum H₂ storage capacity in these ACFs lies between 1.50 and 3.15 wt%.     

Experimental and numerical investigation of convection heat transfer of CO2 at supercritical pressures in a vertical mini-tube

Convection heat transfer of CO₂ at supercritical pressures in a 0.27 mm diameter vertical mini-tube was investigated experimentally and numerically for inlet Reynolds numbers exceeding 4.0 × 10³. The tests investigated the effects of heat flux, flow direction, buoyancy and flow acceleration on the convection heat transfer. The experimental results indicate that the flow direction, buoyancy and flow acceleration have little influence on the local wall temperature, with no deterioration of the convection heat transfer observed in either flow direction for the studied conditions. The heat transfer coefficient initially increases with increasing heat flux and then decreases with further increases in the heat flux for both upward and downward flows. These phenomena are due to the variation of the thermophysical properties, especially c_p. The numerical results correspond well with the experimental data using several turbulence models, especially the Realizable k–ε turbulence model.     

Role of CO2 in the CH4 oxidation and H2 formation during fuel-rich combustion in O2/CO2 environments

The effect of CO₂ reactivity on CH₄ oxidation and H₂ formation in fuel-rich O₂/CO₂ combustion where the concentrations of reactants were high was studied by a CH₄ flat flame experiment, detailed chemical analysis, and a pulverized coal combustion experiment. In the CH₄ flat flame experiment, the residual CH₄ and formed H₂ in fuel-rich O₂/CO₂ combustion were significantly lower than those formed in air combustion, whereas the amount of CO formed in fuel-rich O₂/CO₂ combustion was noticeably higher than that in air. In addition to this experiment, calculations were performed using CHEMKIN-PRO. They generally agreed with the experimental results and showed that CO₂ reactivity, mainly expressed by the reaction CO₂ + H → CO + OH (R1), caused the differences between air and O₂/CO₂ combustion under fuel-rich condition. R1 was able to advance without oxygen. And, OH radicals were more active than H radicals in the hydrocarbon oxidation in the specific temperature range. It was shown that the role of CO₂ was to advance CH₄ oxidation during fuel-rich O₂/CO₂ combustion. Under fuel-rich combustion, H₂ was mainly produced when the hydrocarbon reacted with H radicals. However, the hydrocarbon also reacted with the OH radicals, leading to H₂O production. In fact, these hydrocarbon reactions were competitive. With increasing H/OH ratio, H₂ formed more easily; however, CO₂ reactivity reduced the H/OH ratio by converting H to OH. Moreover, the OH radicals reacted with H₂, whereas the H radicals did not reduce H₂. It was shown that OH radicals formed by CO₂ reactivity were not suitable for H₂ formation. As for pulverized coal combustion, the tendencies of CH₄, CO, and H₂ formation in pulverized coal combustion were almost the same as those in the CH₄ flat flame.     

Long-term CO2 emissions reduction target and scenarios of power sector in Taiwan

This study analyses a series of carbon dioxide (CO₂) emissions abatement scenarios of the power sector in Taiwan according to the Sustainable Energy Policy Guidelines, which was released by Executive Yuan in June 2008. The MARKAL-MACRO energy model was adopted to evaluate economic impacts and optimal energy deployment for CO₂ emissions reduction scenarios. This study includes analyses of life extension of nuclear power plant, the construction of new nuclear power units, commercialized timing of fossil fuel power plants with CO₂ capture and storage (CCS) technology and two alternative flexible trajectories of CO₂ emissions constraints. The CO₂ emissions reduction target in reference reduction scenario is back to 70% of 2000 levels in 2050. The two alternative flexible scenarios, Rt4 and Rt5, are back to 70% of 2005 and 80% of 2005 levels in 2050. The results show that nuclear power plants and CCS technology will further lower the marginal cost of CO₂ emissions reduction. Gross domestic product (GDP) loss rate in reference reduction scenario is 16.9% in 2050, but 8.9% and 6.4% in Rt4 and Rt5, respectively. This study shows the economic impacts in achieving Taiwan's CO₂ emissions mitigation targets and reveals feasible CO₂ emissions reduction strategies for the power sector.     

Estimating marginal CO2 emissions rates for national electricity systems

The carbon dioxide (CO₂) emissions reduction afforded by a demand-side intervention in the electricity system is typically assessed by means of an assumed grid emissions rate, which measures the CO₂ intensity of electricity not used as a result of the intervention. This emissions rate is called the “marginal emissions factor” (MEF). Accurate estimation of MEFs is crucial for performance assessment because their application leads to decisions regarding the relative merits of CO₂ reduction strategies. This article contributes to formulating the principles by which MEFs are estimated, highlighting the strengths and weaknesses in existing approaches, and presenting an alternative based on the observed behaviour of power stations. The case of Great Britain is considered, demonstrating an MEF of 0.69 kgCO₂/kW h for 2002–2009, with error bars at +/−10%. This value could reduce to 0.6 kgCO₂/kW h over the next decade under planned changes to the underlying generation mix, and could further reduce to approximately 0.51 kgCO₂/kW h before 2025 if all power stations commissioned pre-1970 are replaced by their modern counterparts. Given that these rates are higher than commonly applied system-average or assumed “long term marginal” emissions rates, it is concluded that maintenance of an improved understanding of MEFs is valuable to better inform policy decisions.     

Power and cogeneration technology environomic performance typification in the context of CO2 abatement part II: Combined heat and power cogeneration

This is the second of a series of two articles, dealing with a new approach of environomic (thermodynamic, economic and environmental) performance ‘Typification’ and optimization of power generation technologies. This part treats specifically of combined heat and power (CHP) cogeneration technologies in the context of CO₂ abatement and provides a methodology for a flexible and fast project based CHP system design evaluation. One of the aspect of the approach is the post-optimization integration of the operating and capital costs, in order to effectively deal with the uncertainty of the project specific design and operation conditions (fuel, electricity and heat selling prices, project financial conditions such as investment amortization periods, annual operating hours, etc). In addition the approach also allows to efficiently evaluate the influence of the external cost such as the CO₂ tax level under a tax scheme or the CO₂ permit price in the emission trading market.     

Conventional and advanced CO2 based district energy systems

District energy systems can potentially decrease the CO₂ emissions linked to energy services, thanks to the implementation of large polygeneration energy conversion technologies connected to buildings over a network. To transfer the energy from these large technologies to the users, conventional district energy systems use water with often two independent supply and return piping systems for heat and cold. However, sharing energy or interacting with decentralised heat pump units often results in relatively large heat transfer exergy losses due to the large temperature differences that are economically required from the water network. Besides, the implementation of two independent supply and return piping systems for heat and cold, results in large space requirements in underground technical galleries. Using refrigerants as a district heating or cooling fluid at an intermediate temperature could alleviate some of these drawbacks. A new system has been developed, that requires only two pipes, filled with refrigerant, to meet heating, hot water and cooling requirements. Because of the environmental concerns about conventional refrigerants, CO₂, a natural refrigerant, used under its critical point, is considered an interesting candidate. A comparative analysis shows that both in terms of exergy efficiency and costs the proposed CO₂ network is favourable.     

Reducing energy-related CO2 emissions using accelerated weathering of limestone

The use and impacts of accelerated weathering of limestone (AWL; reaction: CO₂+H₂O+CaCO₃→Ca²⁺+2(HCO₃⁻) is explored as a CO₂ capture and sequestration method. It is shown that significant limestone resources are relatively close to a majority of CO₂-emitting power plants along the coastal US, a favored siting location for AWL. Waste fines, representing more than 20% of current US crushed limestone production (>10⁹ tonnes/yr), could provide an inexpensive or free source of AWL carbonate. With limestone transportation then as the dominant cost variable, CO₂ mitigation costs of $3-$4/tonne appear to be possible in certain locations. Perhaps 10–20% of US point–source CO₂ emissions could be mitigated in this fashion. It is experimentally shown that CO₂ sequestration rates of 10⁻⁶ to 10⁻⁵ moles/sec per m² of limestone surface area are achievable, with reaction densities on the order of 10⁻² tonnes CO₂ m⁻³day⁻¹, highly dependent on limestone particle size, solution turbulence and flow, and CO₂ concentration. Modeling shows that AWL would allow carbon storage in the ocean with significantly reduced impacts to seawater pH relative to direct CO₂ disposal into the atmosphere or sea. The addition of AWL-derived alkalinity to the ocean may itself be beneficial for marine biota.     

Theoretical thermodynamic analysis of Rankine power cycle with thermal driven pump

A new approach to improve the performance of supercritical carbon dioxide Rankine cycle which uses low temperature heat source is presented. The mechanical pump in conventional supercritical carbon dioxide Rankine cycle is replaced by thermal driven pump. The concept of thermal driven pump is to increase the pressure of a fluid in a closed container by supplying heat. A low grade heat source is used to increase the pressure of the fluid instead of a mechanical pump, this increase the net power output and avoid the need for mechanical pump which requires regular maintenance and operational cost. The thermal driven pump considered is a shell and tube heat exchanger where the working fluid is contained in the tube, a tube diameter of 5 mm is chosen to reduce the heating time. The net power output of the Rankine cycle with thermal driven pump is compared to that of Rankine cycle with mechanical pump and it is observed that the net power output is higher when low grade thermal energy is used to pressurize the working fluid. The thermal driven pump consumes additional heat at low temperature (60 °C) to pressurize the working fluid.     

Supercritical water oxidation of coal in power plants with low CO2 emissions

In this paper, the application of Super Critical Water Oxidation (SCWO) to direct combustion at low temperature of coal fine particles with pure oxygen for power generation is presented, including also a novel method for capturing and storing carbon dioxide as liquid. A detailed simulation model of a 100 MW_th coal-fired SWCO plant with low CO₂ emissions characterised by a steam cooled membraned SC reactor has been developed using Aspen Plus software. According to the well-known Semenov's thermal-ignition theory, the coal particle ignition temperature in SCW conditions has been also evaluated and the results have been integrated within the Aspen Plus model. This has been tested under different operating conditions. The simulation results are presented and the effects of the main plant operating conditions, such as ignition temperature, coal particle size and combustion pressure on the plant performances are discussed. The gross and net thermodynamic efficiencies of the power plant have been estimated to be around 44% and 28%, respectively. The pure oxygen production process results the main energy penalty.