Burning rate and flame heat flux for PMMA in a cone calorimeter

Ignition and burning rate data are developed for thick (25 mm) black Polycast PMMA in a cone calorimeter heating assembly. The objective is to establish a testing protocol that will lead to the prediction of ignition and burning rate from cone data. This is done for a thermoplastic like PMMA. The incident flame heat flux, for irradiation levels of 0–75 kW/m², is found to be approximately 37 kW/m² for black PMMA. Its constancy is shown due to the geometry of the cone flame. Also, this flame is shown to be nearly transparent for cone irradiance (>90%). The heat of gasification of the black PMMA used is found to be approximately 2.8 kJ/g; higher than values reported for other PMMA samples. This is believed to be due to differences in molecular structure or pigmentation of the PMMA tested. A burning rate model is demonstrated to yield good accuracy in comparison to measured transient values. An exact solution is found for constant heat flux conditions.     

Radiant smoldering ignition of plywood

This paper investigates the role of self-heating in the smoldering ignition of 18 mm (three-quarter inch) thick maple plywood exposed to radiant heat fluxes between 6 and 15 kW/m² in the cone calorimeter for up to 8 h. The minimum heat flux for smoldering ignition was experimentally determined to be 7.5 kW/m². This compares favorably to predictions made using classical self-heating theory. The role of self-heating was explored via temperature measurements distributed within the specimens. Elevated subsurface temperature profiles indicated self-heating was an important ignition factor resulting in ignition at depth with smolder propagation to the surface and into the material. The ignition depth was shown to be a function of the heat flux with the depth moving towards the surface as the heat flux increased.     

Ignition,Heat Release Rate and Suppression of Elastomeric Materials

The focus of this paper is to determine flammability characteristics of rubber materials that are common to vehicle tires, conveyor belts, and electrical power cable insulation and to compare the thermal magnitude of cargo quantities of these materials to other fuels that are publicly transported. Although a literature review was performed, very little data was found on this topic. Standard flammability test procedures were used to measure the critical flux for ignition, critical ignition temperature, and heat release rates (HRR) of rubber compounds common to tire tread materials and conveyor belt covers. Both the intermediate scale calorimeter: ISO 14696, ASTM E-1623 (ICAL) and the cone calorimeter: ISO E-5660, ASTM 1354 (Cone) provided the bulk of the data. Critical ignition flux and vertical flame spread data for rubber based electrical insulations were determined using a radiant panel from a modified ASTM flame spread apparatus: ASTM E-162. thermogravimetric analysis was also used to evaluate thermal decomposition progression of selected test materials. Further, suppression tests were conducted on tire piles to evaluate agents to extinguish and control tire fires. Also, the HRR of the tire piles were measured and compared to work performed by others. Results confirm that the area heat release rate of rubber materials is directly proportional to exposure flux intensity. The critical exposure flux for ignition of a variety of rubber-based materials is approximately 20 kW/m² to 30 kW/m² and the critical temperature for piloted and non-piloted ignition were independent of exposure intensity at ~400°C and ~600°C respectively. In large quantities, rubber tire loads have total HRR comparable to the heat released from similar areas of liquid hydrocarbon spills.     

Burning Characteristics of Automotive Tires

The ignition and burning characteristics of individual un-mounted automotive tires are presented including heat release rate and heat flux. The propensity for ignition at various locations on the tire is discussed. The burning characteristics of the tire are discussed for both accelerated and non-accelerated fires along with the effects of tire orientation on burning behavior. Ignition by non-accelerated means was only successful at the tire bead. Ignition location was found to have an effect on time to fire growth and overall burning duration with times ranging from 16.5 min to 47.5 min. Duration of significant burning was 25 min to 30 min for the sidewall orientation and 10 min to 15 min for the on-tread orientation. Tires in the on-tread orientation provide a substantially greater heat release rate (350 kW to 450 kW) and corresponding radiant ignition hazard (20 kW/m² to 35 kW/m²) than the sidewall orientation (200 kW and 10 kW/m² to 13 kW/m²).     

Evaluating Models for Predicting Full-Scale Fire Behaviour of Polyurethane Foam Using Cone Calorimeter Data

Two models that can be used to predict full-scale heat release rates of polyurethane foam slabs were evaluated in this study. Predictions were compared with results of furniture calorimeter tests of 10 cm thick polyurethane foam specimens which were ignited in the centre or on the edge. Furniture calorimeter results indicated that peak heat release rates and fire growth rates were higher during centre ignition tests than edge ignition tests. For both situations, the growth phase of the heat release rate curves measured in the full-scale tests was successfully predicted using t ² design fires; the choice of a specific t ² fire depended on the surface area of the specimen and ignition location. A model originally developed during the European Combustion Behaviour of Upholstered Furniture (CBUF) project was also evaluated using heat release rate data from cone calorimeter tests and flame area burning rates measured using infrared video records of the furniture calorimeter tests. This model was able to successfully predict the initial growth phase of the fires and predictions of peak heat release rates were within 17% of measured values. The model had less success in predicting heat release rates later in the growth phase and during the decay phase of the fires, and did not appear to capture all of the physics of the full-scale tests, in particular foam melting and subsequent liquid pool burning. As the model did show promise, future work is planned to address these shortcomings and to develop improved flame spread models for polyurethane foam.     

典型汽车内饰材料的燃烧特性研究

采用锥形量热仪实验对涤纶面料丙纶玻璃纤维板、涤纶面料丙纶麻纤维板和 PVC 革丙纶麻纤维板 3 种典型汽车内饰材料在 25、35、50 kW/m2 热辐射强度下的点燃时间、质量损失率、热释放速率等燃烧特性参数进行研究,并选取点燃预测模型计算材料的临界热辐射强度,使用轰燃倾向指数和热释放总量评价其潜在火灾危险性。结果表明,在实验热辐射强度下,涤纶面料丙纶麻纤维板质量损失百分率最大,结构完整性最差;涤纶面料丙纶玻璃纤维板平均点燃时间最短,临界热辐射强度最小,最容易被引燃;PVC 革丙纶麻纤维板热释放速率峰值最大,火灾性能指数最小,发生轰燃的可能性最大。     

辐射热作用下金属钠燃烧现象试验研究

在辐射热通量为25~60kW/m²条件下对利用锥形量热仪对金属钠的燃烧现象进行了研究,测量了燃烧尾气中的氧气含量与剩余物料的质量。结果表明:随着环境热通量增加,金属钠燃烧现象存在较大差异性,残留物数量逐渐减少至完全参与燃烧。当辐射热通量小于30kW/m²时,金属钠未出现明火燃烧;在外界辐射热通量为50~60kW/m²时,金属钠发生较不稳定、不充分的明火燃烧;当辐射热通量大于60kW/m²时,金属钠发生较为稳定且全面的明火燃烧。     

Influences of Talc on Fire Performance of Low Density Polyethylene

In this paper the effects of talc on the ignition time, the burning rate and the downward flame spread rate of low density polyethylene were studied through the cone calorimeter test, the modified UL 94 vertical burning test and a designed downward flame spread experiment. Cone calorimeter tests show that the mass loss rate (MLR) and the heat release rate (HRR) decrease with increasing the talc content, which is ascribed to the residue formed by talc. When the loading of talc is low, talc powders aggregate to form separate talc tablets during burning, leading to the slight decrease of MLR and HRR. When the mass fraction of talc is higher than 20%, possibly the percolation threshold for barrier effect of talc, an integral crust covering the whole specimen surface is generated to act as a good heat and mass barrier, resulting in the significant drop of MLR and HRR. However, no evidence of char in the residue is found. The ignition time in both the cone calorimeter test and the modified UL 94 test initially decreases and then increases with increasing the talc content. It is supposed that the wick effect of talc aggregations reduces the ignition time while the dilution effect and the barrier effect delay the ignition time. The downward flame spread rate initially increases and then decreases with increasing the talc content, which is suspected to be related with the reduction of ignition time and melt flow rate during burning caused by talc.     

On the flame height definition for upward flame spread

Flame height is defined by the experimentalists as the average position of the luminous flame and, consequently is not directly linked with a quantitative value of a physical parameter. To determine flame heights from both numerical and theoretical results, a more quantifiable criterion is needed to define flame heights and must be in agreement with the experiments to allow comparisons. For wall flames, steady wall flame experiments revealed that flame height may be defined by a threshold value on the wall heat flux. From steady wall flame measurements, three definitions of flame height from wall heat flux are retained: the first is based on the continuous flame while the two others are based on threshold values of 4 kW/m² and 10 kW/m². These definitions are applied to determine flame heights from a two-dimensional time-dependent CFD model used to describe flame spread on a vertical slab of PMMA. Results show that the predicted flame heights are consistent with the available data of the literature. Defining flame height by threshold values on the wall heat flux of 4 and 10 kW/m² allows the correlation of the wall heat flux in terms of (x−x_p)/(x_fl−x_p), which is the dimensionless characteristic length scale for upward flame spread. It is also found that the continuous flame is not a characteristic length for the heat transfer to the unburnt fuel and is not really appropriate to define flame height in upward flame spread.     

Piloted ignition times,critical heat fluxes and mass loss rates at reduced oxygen atmospheres

Ignition, pyrolysis and burning of materials in reduced oxygen atmospheres occur when recirculating combustion gases are mixed with the air flowing into an enclosure. Still the incoming air can be sufficient for the complete combustion of the pyrolysis gases. Thus, for the prediction of fires in enclosures it is essential to understand the ignition and burning of materials in a reduced oxygen atmosphere even when plenty of oxidizer is available for complete combustion. Previous work employing gaseous fuels has shown that under these conditions, but before extinction, burning of gaseous fuels issuing from a nozzle is complete but radiation from the flames decreases owing to the reduction of their temperature. Complementary to that work, piloted ignition of solids is investigated here at reduced oxygen concentrations by measuring the ignition times and mass loss rates of the solid at ignition.These results were obtained in a cone calorimeter modified to supply air at reduced oxygen concentrations. Two types of plywood, normal and fire retardant 4 mm thick were examined at three imposed heat fluxes 25, 35 and 50 kW/m² and at oxygen concentrations of 21%, 18% and 15% by volume. Because heating at these heat fluxes and material thickness corresponds to intermediate thermal conditions (i.e. neither thin nor thick), novel analytical solutions are developed to analyze the data and extract the thermal and ignition properties of the material. The same novel solutions can be applied to modeling concurrent or countercurrent flame spread. Moreover, a theory for piloted ignition explains why the ignition times and mass pyrolysis rates are weakly dependent on reduced oxygen concentrations.     

Characterization of thermal properties and analysis of combustion behavior of PMMA in a cone calorimeter

This paper deals with the thermal degradation of a black poly(methyl)methacrylate (PMMA) in a cone calorimeter (CC) in air with a piloted ignition. The influence of several heat fluxes (11 kW m⁻² and 12 kW m⁻², and ten values from 15 to 60 kW m⁻² in steps of 5 kW m⁻²) on PMMA sample degradation and the decomposition chemistry has been studied. Thus, thermal properties have been deduced and calculated from ignition time and mass loss rate (MLR) curves. During our experiments, among compounds quantified simultaneously by a Fourier transformed infrared (FTIR) or gas analyzer, five main species (CO₂, CO, H₂O, NO and O₂) have been encountered, regardless of the external heat flux considered. The main product concentrations allow calculation of the corresponding emission yields. Thus, mass balances of C and H atoms contained in these exhaust gases were able to be compared with those included in the initial PMMA sample. Using the standard oxygen consumption method, heat release rate (HRR), total heat release (THR) and effective heat of combustion (EHC) have been calculated for each irradiance level. Therefore, these different results (thermal properties, emission yields, HRR, THR and EHC) are in quite good accordance (same order of magnitude) with those found in previous studies.     

基于CONE的超高温耐火电缆火灾危险性分析

利用锥形量热仪对超高温耐火电缆在不同辐射功率下的点燃时间（TTI）、热释放速率（HRR）、质量损失速率（MLR）和燃烧残余物进行了研究。研究表明,随着辐射功率增加,耐火电缆的TTI逐渐缩短,HRR和MLR逐渐增大,火灾危险性逐渐增加。超高温耐火电缆在35 kW/m2和50 kW/m2辐射功率下火灾性能指数相比于25 kW/m2分别增加了44.4%和176.5%,火灾增长指数分别增加了30.4%和83.0%。结合理论分析可以得出,耐火电缆的临界辐射功率为3.61 kW/m2、零辐射平均热释放速率为36.5 kW/m2,表现出较低的火灾危险性。     

Smoke and heat release and ignitability as measures of fire hazard from burning of carpet tiles

A series of 22 commercial carpet tiles, covering the range of backings found in the marketplace, and with the same face material (nylon) was chosen for fire testing. All the carpets were tested in the cone calorimeter rate of heat release apparatus. They were also all tested in the NBS smoke density chamber, in the flaming mode. A selection of samples was further tested using the flooring radiant panel. A preliminary investigation was made to choose the optimum radiant incident flux to be used, which was determined to be 25 kW/m².

It was found that the carpets showed a wide range of fire performance, including ranges of peak rate of heat release and of time to ignition of c. 3 and of smoke factor of c. 8. It was not found possible to correlate the results of the NBS smoke chamber or radiant panel tests with any of the results obtained from the cone calorimeter. A classification scheme was proposed to determine fire performance of carpets, based on the ratio of time to ignition (in seconds) and peak rate of heat release (in kW/m²). According to this scheme, four categories of fire performance would be expected:

4.

     

Effects of nanoclay and fire retardants on fire retardancy of a polymer blend of EVA and LDPE

The effects of nanoclay (organoclay) and fire retardants (aluminium tri-hydroxide and magnesium hydroxide) on the fire retardancy of a polymer blend of ethylene-vinyl acetate (EVA) and low-density polyethylene (LDPE) were assessed using thermogravimetric analysis (TGA) and the cone calorimeter. TGA measurements were conducted in nitrogen and air atmospheres at different heating rates (1–20 °C/min), whilst in the cone calorimeter square samples were tested under various external heat fluxes (15–60 kW/m²). The TGA results indicate that the nanoclay (NC) alone has little effect on the degradation of the polymer blend, whereas aluminium tri-hydroxide (ATH) and magnesium hydroxide (MH), used as fire retardants (FRs), generally decrease the onset degradation temperature and also reduce the peak mass loss rate. However, it was found in the cone calorimeter that, though having negligible effect on ignition, the nanoclay reduces the heat release rate (HRR), and increases smoke and CO yields. In comparison, FRs (ATH or MH) were found to delay ignition owing to loss of water at lower temperatures, reduce the HRR, and have similar smoke and CO yields compared to the polymer blend. The reduced HRRs for both the nanoclay and FRs can be attributed to the formation of a surface layer (a nano layer for nanoclay and a ceramic-like layer of Al₂O₃/MgO for FRs), which acts as mass and heat barriers to the unpyrolysed material underneath. The global effect of the surface layer for the polymer blend nanocomposite was examined using a previously developed numerical model, and a methodology for predicting the mass loss rate was subsequently developed and validated.     

Evaluating the influence of varied fire-retardant surface coatings on post-heat flexural properties of glass/epoxy composites

This paper investigates the influence of char-forming, flame-inhibiting and intumescent surface coatings on the post-heat flexural behavior of glass fibre-reinforced epoxy composites exposed to one-sided radiant heating. The fire performance of glass/epoxy laminates surface-coated with varied formulations was evaluated using a cone calorimeter under various external heat fluxes (25, 50 and 65 kW/m²). Self-sustained ignition was significantly delayed for fire-protected laminates relative to the control. The peak heat release rates and the time to reach this event were significantly reduced in thermally-protected laminates. In addition to the chemical nature of flame retardant chemicals present in the coatings, the time to reach the peak heat release rate and the magnitude of the total heat release were influenced by the quantity and morphology of the char formed by each type of surface coating. The post-heat flexural performance of heat-damaged laminates was determined via three-point bending. There was a significant improvement in the post-heat flexural moduli retention in thermally-protected glass/epoxy laminates. This may be due to the flame retardation efficacy of the coatings and the ability of the charred structures to reduce the heat transfer into the substrate thereby protecting the underlying composite and its mechanical integrity.     

Compressive Response of Composites Under Combined Fire and Compression Loading

The thermal buckling of an axially restrained composite column that is exposed to a heat flux due to fire is studied by both analytical and experimental means. The column is exposed to fire from one-side and the resulting heat damage, the charred layer formation and non-uniform transient temperature distribution are calculated by the thermal model developed by Gibson et al. (Revue de l’Institute Francais du Petrole 50:69–74, 1995). For the thermal buckling analysis, the mechanical properties of the fire-damaged (charred) region are considered negligible; the degradation of the elastic properties with temperature (especially near the glass transition temperature of the matrix) in the undamaged layer, is accounted for by using experimental data for the elastic moduli. Due to the non-uniform stiffness and the effect of the ensuing thermal moment, the structure behaves like an imperfect column, and responds by bending rather than buckling in the classical Euler (bifurcation) sense. Another important effect of the non-uniform temperature is that the neutral axis moves away from the centroid of the cross section, resulting in another moment due to eccentric loading, which would tend to bend the structure away from the fire. In order to verify the mechanical response, the compressive buckling behavior of the same material subjected to simultaneous high intensity surface heating and axial compressive loading were investigated experimentally. Fire exposure was simulated by subjecting the surface of rectangular specimens to radiant heating in a cone calorimeter. Heat flux levels of 25 kW/m², 50 kW/m² and 75 kW/m² were studied. All specimens exhibited buckling and subsequent catastrophic failure, even at compressive stresses as low as 3.5 MPa under a surface heat flux of 25 kW/m². Details of the experimental procedure, including modifications made to a cone calorimeter to allow simultaneous mechanical loading are presented.     

Combustibility Parameters for Enclosure Lining Materials Obtained During Surface Flame Spread Using a Reduced Scale Ignition and Flame Spread Technique

A reduced scale ignition and flame spread technique, RIFT, was implemented in the cone calorimeter system to obtain thermocombustibility properties of enclosure lining materials during flame spread over the sample surface. Previously, a thermal model of ignition and opposed flow flame spread was used to analyze flame spread data obtained using RIFT. Here, a framework is discussed for deducing critical material combustibility parameters from the measured heat release and mass loss rates as the spreading flame proceeds to the point of flame extinction. The nature of the data and analytical framework allows users to deduce spreading flame flux from the heat release rate (HRR) and mass loss rate (MLR) data relatively economically and directly. The anomalies highlighted by comparing flame spread data in the RIFT system compared to data from the BS 476 Part 7 apparatus indicates that the RIFT system is well-suited for developing and refining models describing ignition, flame spread, and mass burning.     

EcoSmart Fire as Structure Ignition Model in Wildland Urban Interface: Predictions and Validations

EcoSmartFire is a Windows program that models heat damage and piloted ignition of structures from radiant exposure to discrete landscaped tree fires. It calculates the radiant heat transfer from cylindrical shaped fires to the walls and roof of the structure while accounting for radiation shadowing, attenuation, and ground reflections. Tests of litter burn, a 0.6 m diameter fire up to 250 kW heat release under a Heat Release Rate (HRR) hood, with Schmidt-Boelter heat flux sensors in the mockup wall receiving up to 5 kW/m² radiant flux, in conjunction with Fire Dynamic Simulator (FDS) modeling verified a 30% radiant fraction, but indicated the need for a new empirical model of flame extinction coefficient and radiation temperature as function of fire diameter and heat release rate for use in ecoSmartFire. The radiant fluxes predicted with both ecoSmartFire and FDS agreed with SB heat flux sensors to within a few percent errors during litter fire growth. Further experimental work done with propane flame heating (also with 30% radiant fraction) on vertical redwood boards instrumented with embedded thermocouples validated the predicted temperature response to within 20% error for both models. The final empirical correlation for flame extinction coefficient and temperature is valid for fire diameters between 0.2 and 7.9 m, with heat release rates up to 1000 kW. From the corrected radiant flux the program calculates surface temperatures for a given burn time (typically 30 s) and weather conditions (typically dry, windy, and warm for website application) for field applications of many trees and many structural surfaces. An example was provided for a simple house exposed to 4 burning trees selected on a Google enhanced mapping that showed ignition of a building redwood siding. These temperatures were compared to damage or ignition temperatures with output of the percentage of each cladding surface that is damaged or ignited, which a homeowner or a landscaper can use to optimize vegetation landscaping in conjunction with house exterior cladding selections. The need for such physics-based fire modeling of tree spacing was indicated in NFPA 1144 for home ignitability in wildland urban interface, whereas no other model is known to provide such capability.     

野外组合式软体油罐罐体材料燃烧特性研究

为了研究野外组合式软体油罐在不同辐射强度下的燃烧特性,通过锥形量热仪对软体油罐样本进行燃烧实验,选用25,35,50 kW/m2三种典型的热辐射强度进行研究,得到点燃时间、热释放速率、比消光面积、烟气生成速率、火焰形态等参数的变化规律.结果发现:热辐射强度为50 kW/m2时,点燃时间分别为25,35 kW/m2时的3...     

氢氧化镁和十溴二苯醚对海水阻燃性能的影响

研究了海水中添加Mg(OH)2和十溴二苯醚后棉布和地毯的热解及燃烧行为,对比了添加量对棉布和地毯的点燃时间、热解速度、火焰持续时间等参数的影响,并利用锥形量热仪测定了添加阻燃剂前后材料的点燃时间、热释放速率、质量损失速率和CO释放速率.结果表明,添加Mg(OH)2和十溴加锑后,浸海水棉布和地毯的热分解速度明显降低,点燃时间延长,最大热释放速率和质量损失速率都显著降低.Mg(OH)2或十溴加锑的最佳添加量分别为10%和5%.